CN102002288A - Water-based environment friendly metallic paint and preparation method thereof - Google Patents
Water-based environment friendly metallic paint and preparation method thereof Download PDFInfo
- Publication number
- CN102002288A CN102002288A CN2010105086458A CN201010508645A CN102002288A CN 102002288 A CN102002288 A CN 102002288A CN 2010105086458 A CN2010105086458 A CN 2010105086458A CN 201010508645 A CN201010508645 A CN 201010508645A CN 102002288 A CN102002288 A CN 102002288A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- metallic paint
- agent
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention provides a water-based environment friendly metallic paint and a preparation method thereof. The preparation method comprises the following steps: mixing 40-70 parts of fluorocarbon emulsion, 10-20 parts of film-forming assistant, 0.2-0.4 part of defoamer, 0.1-0.3 part of pH regulator, 1-3 parts of propylene glycol, 0.1-0.3 part of humectant and 0.1-0.3 part of preservative before stirring, and adding 0.3-0.8 part of nano silver oxide before uniformly stirring at a high speed; then sequentially adding 0.2-0.7 part of polyurethane thickening agent, 0.4-0.9 part of flatting agent and 6-9 parts of water-based aluminum silver paste soaked in 9-15 parts of water, and uniformly stirring; and finally, adding 0.3-1 part of alkali-swelling acrylic acid thickening agent until the viscosity is regulated to 100+/-2KU, thus obtaining the water-based environment friendly metallic paint. When being used as an exterior wall paint, the water-based environment friendly metallic paint can produce the particular shining metal effect and can achieve the surface effect the same with that of an aluminum plastic composite panel. Besides, the water-based environment friendly metallic paint has the advantages of good weather resistance and antifouling performance and short surface-drying time, is convenient in construction, contains no APEO and low VOC and has unique bacterium resistance and excellent fungus resistance.
Description
Technical field
The present invention relates to aqueous, environmental protective metallic paint and preparation method thereof.
Background technology
At present, aqueous metallic paint is applied in the external wall of building.A kind of fluorine-containing aqueous metallic paint and preparation method thereof is disclosed as Chinese patent 200810183406.2, raw material by following parts by weight is formed: emulsion 35-60 part that fluorine-containing and acrylic monomer form through letex polymerization, deionized water 20-35 part, aqueous dispersant 0.2-0.6 part, water-based solubility promoter 4-8 part, water-based metal powder 5-9 part, propylene glycol 0.5-3 part, defoamer 0.02-0.08 part, sanitas 0.02-0.1 part, mould inhibitor 0.02-0.1 part, PH conditioning agent 0.1-0.5 part, water-based thickener 0.5-1.5 part.The preparation method of this fluorine-containing aqueous metallic paint is: each raw material is added in the container successively, in 20～50 ℃ of stirrings of temperature, regulate viscosity and pH value, filter and package.The fluorine-containing aqueous metallic paint that makes can directly spray, and adds the water construction, and environmental pollution is little, resistant and good weatherability, and tint retention is lasting, and apparent metal-like is strong.But because it has used more water-based solubility promoter, cause VOC higher, fungus resistance can be poor.
Summary of the invention
The objective of the invention is to overcome the above-mentioned defective that prior art exists, a kind of aqueous, environmental protective metallic paint is provided, reach the surface effect general with aluminium-plastic panel, have better weather energy and antifouling property, surface drying time is short, and easy construction does not contain APEO, have lower VOC, and fungus resistance can be excellent.
Aqueous, environmental protective metallic paint provided by the invention comprises the raw material of following parts by weight: 40～70 parts of fluorine carbon emulsions, 10～20 parts of film coalescence aid, 0.2～0.4 part of defoamer, 0.1～0.3 part of PH conditioning agent, 1～3 part of propylene glycol, 0.1～0.3 part of wetting agent, 0.1～0.3 part of sanitas, 0.3～0.8 part of nano phase ag_2 o, 0.2～0.7 part of polyurethane thickener, 0.4～0.9 part of flow agent, 6～9 parts of water aluminum-silver slurries, 9～15 parts in water, 0.3～1 part of alkali swelling acrylic thickener.
Preferably, described film coalescence aid is 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate; Described defoamer is a silicone antifoam agent; Described PH conditioning agent is 2-methyl-2-hydroxyl-1-propyl alcohol; Described wetting agent is an alkyl polyoxyethylene ether; Described sanitas is 1, the 2-benzisothiazole-3-ketone: described water aluminum-silver slurry is 20 microns a aluminium-silver slurry.
According to the present invention, described fluorine carbon emulsion, nano phase ag_2 o, polyurethane thickener, flow agent, alkali swelling acrylic thickener, water aluminum-silver slurry, defoamer all can adopt the commercially available prod, fluorine carbon emulsion 4311B as Changxing, Taiwan chemical company, the nano phase ag_2 o JMAC LP 10 of Clariant chemical industry, the alkyl polyoxyethylene ether LCN407 of Ke Laien, the sanitas NIPACIDE BIT 20 of Ke Laien, the polyurethane thickener RM-8W of ROHM AND HAAS, the flow agent 2020 of ROHM AND HAAS, the alkali swelling acrylic thickener TT-935 of ROHM AND HAAS, the aluminium-silver slurry BK600 of your water aluminum-silver slurry company limited of Bake, the silicone antifoam agent SN-154 of NOPOC.
Another object of the present invention is to provide the preparation method of this aqueous, environmental protective metallic paint, comprise the steps:
(1) with fluorine carbon emulsion, film coalescence aid, defoamer, the PH conditioning agent, propylene glycol, wetting agent, sanitas mix, and stir, and it is even to add the nano phase ag_2 o high-speed stirring again;
(2) add polyurethane thickener successively, flow agent, and be immersed in water aluminum-silver slurry in the water, and stirring, wherein said soak time is 1～1.5 hour;
(3) add alkali swelling acrylic thickener, adjust viscosity to 100 ± 2KU, can obtain described aqueous, environmental protective metallic paint.
Wherein, each raw materials in part by weight is as follows: 40～70 parts of fluorine carbon emulsions, 10～20 parts of film coalescence aid, 0.2～0.4 part of defoamer, 0.1～0.3 part of PH conditioning agent, 1～3 part of propylene glycol, 0.1～0.3 part of wetting agent, 0.1～0.3 part of sanitas, 0.3～0.8 part of nano phase ag_2 o, 0.2～0.7 part of polyurethane thickener, 0.4～0.9 part of flow agent, 6～9 parts of water aluminum-silver slurries, 9～15 parts in water, 0.3～1 part of alkali swelling acrylic thickener.
Aqueous, environmental protective metallic paint of the present invention can reach the surface effect general with aluminium-plastic panel, has better weather energy and antifouling property, and surface drying time is short, easy construction.And do not contain alkylphenol polyoxyethylene compounds APEO, VOC is lower, and germ resistance, fungus resistance can be excellent.
Embodiment
Below in conjunction with specific embodiment, the present invention will be further described.Should be understood that following examples only are used to the present invention to be described but not to be used to limits the scope of the invention.
Embodiment 1
The preparation method of aqueous, environmental protective metallic paint in the present embodiment may further comprise the steps:
(1) with 55 parts of fluorine carbon emulsions, 17 parts of film coalescence aid, 0.3 part of defoamer, 0.15 part of PH conditioning agent, 1.5 parts of propylene glycol, 0.2 part of wetting agent, 0.1 portion of sanitas mixes, and stirs, and adds 0.4 part again, and the nano phase ag_2 o high-speed stirring is even;
(2) add 0.5 part of polyurethane thickener successively, 0.6 part of flow agent, and be immersed in 7 parts of water aluminum-silver slurries in 10 parts of water, stir, wherein, water aluminum-silver slurry is immersed in the water in advance, soak time is 1～1.5 hour, and during use, water aluminum-silver slurry together adds together with water;
(3) add 0.75 part of alkali swelling acrylic thickener, adjust viscosity to 100 ± 2KU, get final product.
Preferably, described film coalescence aid is 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate; Described defoamer is a silicone antifoam agent; Described PH conditioning agent is 2-methyl-2-hydroxyl-1-propyl alcohol; Described wetting agent is an alkyl polyoxyethylene ether; Described sanitas is 1, the 2-benzisothiazole-3-ketone; Described water aluminum-silver slurry is 20 microns a aluminium-silver slurry.
The method of limits of harmful substances national standard and GB/T 1741-2007 paint film fungus resistance assay method national Specification detects the aqueous, environmental protective metallic paint of present embodiment preparation in GB/T 9755-2001 exterior wall coating material of synthetic resin emulsion national standard shown in the employing table 1, the GB24408-2009 exterior coating for building, and every performance is as shown in table 1.
The performance of the aqueous, environmental protective metallic paint of table 1 embodiment 1 preparation
| Index | The result | Detection method |
| Time of drying | ≤ 40 minutes | GB/T?9755-2001 |
| Application property | The brushing twice are accessible | GB/T?9755-2001 |
| The artificial weathering ageing resistance | By 1000 hours | GB/T?9755-2001 |
| Water tolerance | By 96 hours | GB/T?97552001 |
| Alkali resistance | By 48 hours | GB/T?9755-2001 |
| Abrasion resistance | 〉=5000 times | GB/T?9755-2001 |
| Volatile organic compounds (VOC) | 120 | GB24408-2009 |
| Fungus resistance | 1 | GB/T?1741-2007 |
Embodiment 2
Among the embodiment 2, the equal embodiment of raw material and preparation method 1 is identical, and difference only is each raw materials in part by weight, and is as follows:
65 parts of fluorine carbon emulsions, 12 parts of film coalescence aid, 0.2 part of defoamer, PH conditioning agent 0.2,3 parts of propylene glycol, 0.3 part of wetting agent, 0.2 part of sanitas, 0.8 part of nano phase ag_2 o, 0.6 part of polyurethane thickener, 0.5 part of flow agent, 8 parts of water aluminum-silver slurries, 8.4 parts in water, 0.8 part of alkali swelling acrylic thickener.
Adopt the national standard method shown in the table 2 to detect the aqueous, environmental protective metallic paint of present embodiment preparation, every performance is as shown in table 2.
The performance of the aqueous, environmental protective metallic paint of table 2 embodiment 2 preparations
| Index | The result | Detection method |
| Time of drying | ≤ 40 minutes | GB/T?97552001 |
| Application property | The brushing twice are accessible | GB/T?97552001 |
| The artificial weathering ageing resistance | By 1000 hours | GB/T?9755-2001 |
| Water tolerance | By 96 hours | GB/T?9755-2001 |
| Alkali resistance | By 48 hours | GB/T?9755-2001 |
| Abrasion resistance | 〉=5000 times | GB/T?97552001 |
| Volatile organic compounds (VOC) | ≤130 | GB244082009 |
| Fungus resistance | 0 | GB/T?17412007 |
In the above embodiment of the present invention, described fluorine carbon emulsion, nano phase ag_2 o, polyurethane thickener, flow agent, alkali swelling acrylic thickener, water aluminum-silver slurry, defoamer all can adopt the commercially available prod, fluorine carbon emulsion 4311B as Changxing, Taiwan chemical company, the nano phase ag_2 o JMAC LP 10 of Clariant chemical industry, the alkyl polyoxyethylene ether LCN407 of Ke Laien, the sanitas NIPACIDE BIT 20 of Ke Laien, the polyurethane thickener RM-8W of ROHM AND HAAS, the flow agent 2020 of ROHM AND HAAS, the alkali swelling acrylic thickener TT-935 of ROHM AND HAAS, the aluminium-silver slurry BK600 of your water aluminum-silver slurry company limited of Bake, the silicone antifoam agent SN-154 of NOPOC.
Aqueous, environmental protective metallic paint of the present invention is as exterior coating, can produce special flash of light metal effect, reach the surface effect general with aluminium-plastic panel, as shown in Table 1 and Table 2, surface drying time is short, easy construction, have better weather energy and antifouling property, and do not contain APEO, VOC is lower, and germ resistance, fungus resistance can be excellent.
Claims (4)
1. aqueous, environmental protective metallic paint comprises the raw material of following parts by weight:
40～70 parts of fluorine carbon emulsions, 10～20 parts of film coalescence aid, 0.2～0.4 part of defoamer, 0.1～0.3 part of PH conditioning agent, 1～3 part of propylene glycol, 0.1～0.3 part of wetting agent, 0.1～0.3 part of sanitas, 0.3～0.8 part of nano phase ag_2 o, 0.2～0.7 part of polyurethane thickener, 0.4～0.9 part of flow agent, 6～9 parts of water aluminum-silver slurries, 9～15 parts in water, 0.3～1 part of alkali swelling acrylic thickener.
2. aqueous, environmental protective metallic paint according to claim 1 is characterized in that, described film coalescence aid is 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate; Described defoamer is a silicone antifoam agent; Described PH conditioning agent is an alcohol in 2-methyl-2-hydroxyl-1-; Described wetting agent is an alkyl polyoxyethylene ether; Described sanitas is 1, the 2-benzisothiazole-3-ketone; Described water aluminum-silver slurry is 20 microns a aluminium-silver slurry.
3. the preparation method of an aqueous, environmental protective metallic paint as claimed in claim 1 or 2 is characterized in that, may further comprise the steps:
(a) with 40～70 parts of fluorine carbon emulsions, 10～20 parts of film coalescence aid, 0.2～0.4 part of defoamer, 0.1～0.3 part of PH conditioning agent, 1～3 part of propylene glycol, 0.1～0.3 part of wetting agent, 0.1～0.3 portion of sanitas mixes, and stirs, it is even to add 0.3～0.8 part of nano phase ag_2 o high-speed stirring again;
(b) add 0.2～0.7 part of polyurethane thickener, 0.4～0.9 part of flow agent and be immersed in 6～9 parts of water aluminum-silver slurries in 9～15 parts of water successively, stir;
(c) add 0.3～1 part of alkali swelling acrylic thickener, adjust viscosity to 100 ± 2KU, can obtain described aqueous, environmental protective metallic paint.
4. preparation method as claimed in claim 3 is characterized in that, the soak time of described water aluminum-silver slurry in described water is 1～1.5 hour.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105086458A CN102002288A (en) | 2010-10-15 | 2010-10-15 | Water-based environment friendly metallic paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105086458A CN102002288A (en) | 2010-10-15 | 2010-10-15 | Water-based environment friendly metallic paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102002288A true CN102002288A (en) | 2011-04-06 |
Family
ID=43809995
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010105086458A Pending CN102002288A (en) | 2010-10-15 | 2010-10-15 | Water-based environment friendly metallic paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102002288A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102888179A (en) * | 2012-09-15 | 2013-01-23 | 安徽省怀远县尚冠模具科技有限公司 | Oil-resisting and alkali-resisting metal anti-rust paint and preparation method thereof |
| CN103059662A (en) * | 2012-12-20 | 2013-04-24 | 三棵树涂料股份有限公司 | Waterborne fluorocarbon metal paint capable of being used for roller coating construction and preparation method thereof |
| CN104178012A (en) * | 2014-09-09 | 2014-12-03 | 江苏美亿晨新材料科技有限公司 | High-property environment-friendly water-based activation nano metallic paint and preparation method |
| CN104263117A (en) * | 2014-07-16 | 2015-01-07 | 宿州众力融创新型建材有限公司 | Water-based metal paint with high adhesive force, and preparation method thereof |
| CN105238169A (en) * | 2015-10-16 | 2016-01-13 | 三棵树涂料股份有限公司 | Water-based fluorocarbon metal paint with high weather resistance and low VOC and preparing method of water-based fluorocarbon metal paint |
| CN105255274A (en) * | 2015-11-30 | 2016-01-20 | 北京雅点聚美广告策划有限公司 | Water-based environment-friendly metallic paint and preparing method thereof |
| CN106543880A (en) * | 2016-12-12 | 2017-03-29 | 郑州艾莫弗信息技术有限公司 | A kind of environmental protection coating material that can lift spectacle-frame comfort level and preparation method thereof |
| CN109504191A (en) * | 2018-11-09 | 2019-03-22 | 沪宝新材料科技（上海）股份有限公司 | A kind of antistatic fluorine carbon metal paint and preparation method thereof |
| CN110028888A (en) * | 2019-04-19 | 2019-07-19 | 上海福岛新材料科技有限公司 | A kind of environment-friendly water-based metallic paint |
| CN112795246A (en) * | 2021-01-15 | 2021-05-14 | 湖州和悦新材料科技股份有限公司 | Water-based fluorocarbon outdoor paint and preparation method thereof |
| CN114574058A (en) * | 2022-02-12 | 2022-06-03 | 固克节能科技股份有限公司 | Single-component water-based flashing building coating and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117484A (en) * | 2007-08-28 | 2008-02-06 | 深圳市广田环保涂料有限公司 | Metal-pseudo fluorine-carbon paint for building exterior wall and method for making same |
| CN101186467A (en) * | 2007-12-05 | 2008-05-28 | 南宝树脂（中国）有限公司 | Thermal insulation energy-saving composite material and preparing method thereof |
| CN101191024A (en) * | 2006-11-29 | 2008-06-04 | 刘秉顺 | Biological antibiosis anti-cracking putty powder and preparation method thereof |
| CN101397435A (en) * | 2008-07-10 | 2009-04-01 | 上海三银制漆有限公司 | Environment friendly water-soluble metal fluorocarbon coatings |
-
2010
- 2010-10-15 CN CN2010105086458A patent/CN102002288A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101191024A (en) * | 2006-11-29 | 2008-06-04 | 刘秉顺 | Biological antibiosis anti-cracking putty powder and preparation method thereof |
| CN101117484A (en) * | 2007-08-28 | 2008-02-06 | 深圳市广田环保涂料有限公司 | Metal-pseudo fluorine-carbon paint for building exterior wall and method for making same |
| CN101186467A (en) * | 2007-12-05 | 2008-05-28 | 南宝树脂（中国）有限公司 | Thermal insulation energy-saving composite material and preparing method thereof |
| CN101397435A (en) * | 2008-07-10 | 2009-04-01 | 上海三银制漆有限公司 | Environment friendly water-soluble metal fluorocarbon coatings |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102888179A (en) * | 2012-09-15 | 2013-01-23 | 安徽省怀远县尚冠模具科技有限公司 | Oil-resisting and alkali-resisting metal anti-rust paint and preparation method thereof |
| CN102888179B (en) * | 2012-09-15 | 2016-01-20 | 安徽省怀远县尚冠模具科技有限公司 | Alkaline-resisting metallic anti-rust paint of a kind of oil resistant and preparation method thereof |
| CN103059662A (en) * | 2012-12-20 | 2013-04-24 | 三棵树涂料股份有限公司 | Waterborne fluorocarbon metal paint capable of being used for roller coating construction and preparation method thereof |
| CN104263117A (en) * | 2014-07-16 | 2015-01-07 | 宿州众力融创新型建材有限公司 | Water-based metal paint with high adhesive force, and preparation method thereof |
| CN104178012A (en) * | 2014-09-09 | 2014-12-03 | 江苏美亿晨新材料科技有限公司 | High-property environment-friendly water-based activation nano metallic paint and preparation method |
| CN105238169A (en) * | 2015-10-16 | 2016-01-13 | 三棵树涂料股份有限公司 | Water-based fluorocarbon metal paint with high weather resistance and low VOC and preparing method of water-based fluorocarbon metal paint |
| CN105255274A (en) * | 2015-11-30 | 2016-01-20 | 北京雅点聚美广告策划有限公司 | Water-based environment-friendly metallic paint and preparing method thereof |
| CN106543880A (en) * | 2016-12-12 | 2017-03-29 | 郑州艾莫弗信息技术有限公司 | A kind of environmental protection coating material that can lift spectacle-frame comfort level and preparation method thereof |
| CN109504191A (en) * | 2018-11-09 | 2019-03-22 | 沪宝新材料科技（上海）股份有限公司 | A kind of antistatic fluorine carbon metal paint and preparation method thereof |
| CN110028888A (en) * | 2019-04-19 | 2019-07-19 | 上海福岛新材料科技有限公司 | A kind of environment-friendly water-based metallic paint |
| CN112795246A (en) * | 2021-01-15 | 2021-05-14 | 湖州和悦新材料科技股份有限公司 | Water-based fluorocarbon outdoor paint and preparation method thereof |
| CN114574058A (en) * | 2022-02-12 | 2022-06-03 | 固克节能科技股份有限公司 | Single-component water-based flashing building coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102002288A (en) | Water-based environment friendly metallic paint and preparation method thereof | |
| CN104559617B (en) | A kind of application type aqueous dual-component fluorocarbon coating and its preparation and application | |
| CN103319965B (en) | A kind of automobile water-based property metal flash paint and preparation method thereof | |
| CN102675998B (en) | Water-based fluorocarbon top coat for wind-powered blades and method for preparing water-based fluorocarbon top coat | |
| CN104877484B (en) | Petrochemical industry oil tank aqueous energy-saving heat-insulating thermal insulation coatings and preparation method thereof | |
| CN110229601B (en) | Fluorocarbon coating and preparation method and coating method thereof | |
| CN107760140B (en) | High-alcohol-resistance water-based glass baking varnish and preparation method thereof | |
| CN103319971A (en) | Metalized aqueous fluorocarbon coating for exterior wall and preparation method thereof | |
| CN109370411A (en) | A kind of acrylic resin modified aqueous industrial coating of fluorine-silicon polyurethane | |
| CN110655855B (en) | Industrial heavy-duty corrosion-resistant long-acting weather-resistant water-based acrylic polyurethane anticorrosive paint and preparation method thereof | |
| CN108329824A (en) | A kind of aqueous light UV solidification aluminium paint, preparation method and its application method | |
| CN103965716A (en) | Water-based quick-drying acrylic acid protective coating and preparation method thereof | |
| CN104327655A (en) | Water-based air topcoat and preparation method thereof | |
| CN110229602A (en) | Fluorocarbon coating and preparation method thereof and coating process | |
| CN107652729A (en) | A kind of municipal environment-friendly type aqueous protective paint of iron guardrail and preparation method thereof | |
| CN108795176B (en) | Mirror-effect double-component top-coat paint with thick coating and no miliaria | |
| CN112266663A (en) | Quick-drying primer for renovating exterior wall tiles and preparation method thereof | |
| CN112646481A (en) | Water-based UV silver paint and preparation method thereof | |
| CN113372768B (en) | Bottom-surface-in-one water paint for container and preparation method thereof | |
| CN106543836A (en) | A kind of water-based anticorrosive paint | |
| CN112094369A (en) | Reactive acrylic resin and preparation method and application thereof | |
| CN113025132A (en) | Water-based organic silicon modified fluorocarbon wind power blade coating and preparation method thereof | |
| CN112266678A (en) | Waterproof coating for external wall and preparation method thereof | |
| CN104497734A (en) | Extra-weather-resistant environment-friendly metallic paint | |
| CN109689808A (en) | Water base sealant with exceptional durability |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20110406 |