CN106010020A - Two-component aqueous acrylate-epoxy resin hybrid coating - Google Patents
Two-component aqueous acrylate-epoxy resin hybrid coating Download PDFInfo
- Publication number
- CN106010020A CN106010020A CN201610644830.7A CN201610644830A CN106010020A CN 106010020 A CN106010020 A CN 106010020A CN 201610644830 A CN201610644830 A CN 201610644830A CN 106010020 A CN106010020 A CN 106010020A
- Authority
- CN
- China
- Prior art keywords
- epoxy resin
- parts
- coating
- acrylate
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Abstract
The invention discloses a two-component aqueous acrylate-epoxy resin hybrid coating. The epoxy resin part comprises 35-55 parts of an acrylate-epoxy resin hybrid emulsion, 5-10 parts of titanium dioxide, 1-5 parts of zinc oxide, 20-35 parts of a filler, 0.1-1 part of an adhesion promoter, 1.1-2.5 parts of an auxiliary agent and 1-11 parts of water. The curing agent part comprises 1-3 parts of aqueous organic amine. Through use of the hybrid system of an acrylate emulsion and epoxy resin, the anticorrosion coating with a fast drying rate, high film formation density, high weatherability and excellent salt mist resistance is prepared. Through formula optimization and curing agent mixing, the coating is a metal anticorrosion waterproof coating with a long service life, good application properties, good low temperature flexibility, good corrosion resistance, high hardness and good contamination resistance. The two-component aqueous acrylate-epoxy resin hybrid coating effectively prolongs a metal device usage time limit, can be used in terrace paint, saves a cost and provides a value for the society.
Description
Technical field
The present invention is under the jurisdiction of field and the floor coatings fields such as industrial antisepsis, metal Roof anticorrosion, engineering machinery anticorrosion,
Particularly relate to relevant anticorrosion, the dual-component coating of waterproof use.
Background technology
Along with the concern of environmental protection is got more and more by people, the requirement to environmental protection is more and more higher, and this is the water of anticorrosive paint
Property provides opportunity.Solvent based coating is producing and is having a large amount of solvent to discharge in work progress, and environment causes bigger wound
Evil, uses environmental protection and oligosaprobic water paint to become a kind of main trend of society.Aqueous tree prepared by single structure
Lipid can not show a candle to solvent type resin, and the aqueous industrial coating prepared such as current water-borne acrylic resin there is also with coatings volatile organic compounds
Bigger gap, limits its promotion and application at aqueous industrial coating.In order to improve single resin defect on using,
Two kinds of coating, by having complementary advantages, combine, and form compounded latex, improve the overall performance of water paint film.
The most current domestic existing anticorrosion output value moon 300,000,000,000, Industrial Metal anticorrosion, metal Roof anticorrosion, engineering machinery protection and
Floor coatings will become important application market.
Epoxy resin is hydroxyl of not facile hydrolysis and ehter bond containing polarized is high, and film forming postadhesion power is strong, and chemicals-resistant is excellent,
And good temperature tolerance and mechanical performance etc..Early stage basic research tentatively shows that this technology is different from traditional being blended
(Blend) and the polymer modification of chemical structure modification, it has in technique, viable economically property, and the performance of hybridisation emulsion is remote
It is much better than two kinds of emulsion blendings, and close to by the corresponding solvent based polymer level of chemical structure modification.Use emulsion
The technique of the polymerization hybridisation emulsion that to obtain filming performance excellent, stable, by two kinds of resin hybridized polymerizations, retains the most intrinsic excellent
Good characteristic, overcomes respective shortcoming, reaches the excellent product emulsion of performance complement.Research epoxy is main to acrylic acid modification at present
Having 2 kinds of methods: one is physical blending, the preparation of this type of method is simple, and product has epoxy and acrylic acid advantage simultaneously, although property
Can increase, but its bin stability is poor, it is easy to layering and gel, working life is short.Two is chemical modification, i.e. uses grafting
Reaction or esterification carry out modified acrylic acid emulsion, to obtaining the emulsion of excellent performance.Epoxy grafting or esterification modification third
Although olefin(e) acid can obtain stable product emulsion, also there is good using value by performance test, but the most do not solve
Medium when reaction is carried out is all the problem of organic solvent, need to improve in terms of environmental protection and low-carbon (LC).
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of double-component aqueous acrylate epoxy resin hybridization coating,
By the design concept of the two hydridization, film forming can be made finer and close, in conjunction with acrylic acid high-weatherability, quick-drying performance, simultaneously
Combine again the high crosslink density of epoxy, excellent adhesive force and antiseptic property, the two is had complementary advantages, an excellence can be reached
The coating of antiseptic property, solves problems present on market.
For solving above-mentioned technical problem, the technical scheme that the present invention uses is: provide a kind of double-component aqueous third
Olefin(e) acid ester epoxy resin hybridization coating, including the first component and second component,
First component:
Second component:
Aqueous organic amine 1～3 parts.
In a preferred embodiment of the present invention, described acrylic acid epoxy hybridisation emulsion includes acrylic emulsion and ring
Epoxy resins.
In a preferred embodiment of the present invention, the vitrification point of described acrylic acid epoxy hybridisation emulsion is between-10
～between-50 spend.
The invention has the beneficial effects as follows: the one double-component aqueous acrylate epoxy resin hybridization coating of the present invention, main
Anti-corrosion of metal to be used for protection and terrace protection etc., after acrylic emulsion and epoxy resin are carried out hydridization, according to joining
Side prepares has rate of drying soon, and film forming is fine and close, high-weatherability, the water paint that salt spray resistance is excellent, is joined by optimization
After side mixes with aqueous amine firming agent so that it is having long pot life, low temperature flexibility is good, resistance to anticorrosion is excellent, high rigidity, anti-
Stain metal anti-corrosive paint of good performance, effectively extend the service life of metal device, can also apply simultaneously and be coated with at terrace
In material, it is possible to effectively save cost, the city fast-developing at current water paint has broad application prospects, simultaneously after the match
May also operate as certain effects of energy saving and emission reduction, save expense for client, bring value for society.
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described enforcement
Example is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area is common
All other embodiments that technical staff is obtained under not making creative work premise, broadly fall into the model of present invention protection
Enclose.
The embodiment of the present invention includes:
A kind of double-component aqueous acrylate epoxy resin hybridization coating, including the first component and second component,
First component:
In above-mentioned, described acrylic acid epoxy hybridisation emulsion includes acrylic emulsion and epoxy resin.
Further, the first component is epoxy resin portion, and second component is amine curing agent system, and described amine is solid
The ratio with epoxy resin portion of agent system is 5～9: 1.
The aqueous double-component coating that a kind of anti-corrosion of metal uses, including acrylic acid epoxy hybridisation emulsion, powder, filler, attached
Adhesion promoter, other auxiliary agents etc., wherein the vitrification point of acrylic acid epoxy hybridisation emulsion is between-10～50 degree, logical
Cross the design concept of this hydridization, film forming can be made finer and close, can be in conjunction with acrylic acid high-weatherability, quick-drying performance, simultaneously
Can also be in conjunction with the high crosslink density of epoxy, excellent adhesive force and antiseptic property, the two is had complementary advantages, one can be reached
The coating of excellent properties, solves problems present on market.The coating of the present invention is mainly used in anti-corrosion of metal protection and ground
Level ground protection etc..
In sum, the one double-component aqueous acrylate epoxy resin hybridization coating of the present invention, mainly solve mesh
The problem that front anti-corrosion of metal exists, and have found the solution of optimization, owing to the material of single resin is difficult to provide more
Fine and close waterproof membrane, so by by acrylic emulsion, preparing after carrying out hydridization with epoxy resin and there is rate of drying soon, film forming
Densification, high-weatherability, the coating that salt spray resistance is excellent, the water-repellent preservation that can be prepared excellent performance by optimization of C/C composites is coated with
Material, this is the innovative point of the invention, can be prepared by the method and have low temperature flexibility, resistance to anticorrosion, high rigidity,
The metal anti-corrosive paint that anti-stain characteristic energy is good, effectively extends the service life of metal device, can also apply at terrace simultaneously
In coating, it is possible to effectively save cost, the city fast-developing at current water paint has broad application prospects after the match, with
Time may also operate as certain effects of energy saving and emission reduction, bring value for society.
The foregoing is only embodiments of the invention, not thereby limit the scope of the claims of the present invention, every utilize this
Equivalent structure or equivalence flow process that bright description is made convert, or are directly or indirectly used in other relevant technology neck
Territory, is the most in like manner included in the scope of patent protection of the present invention.
Claims (3)
1. a double-component aqueous acrylate epoxy resin hybridization coating, it is characterised in that include the first component and second group
Point,
First component:
Second component:
Aqueous organic amine 1～3 parts.
Double-component aqueous acrylate epoxy resin hybridization coating the most according to claim 1, it is characterised in that described
Acrylic acid epoxy hybridisation emulsion includes acrylic emulsion and epoxy resin simultaneously.
Double-component aqueous acrylate epoxy resin hybridization coating the most according to claim 1, it is characterised in that described
Between the vitrification point of acrylic acid epoxy hybridisation emulsion is spent between-10～-50.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610644830.7A CN106010020A (en) | 2016-08-03 | 2016-08-03 | Two-component aqueous acrylate-epoxy resin hybrid coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610644830.7A CN106010020A (en) | 2016-08-03 | 2016-08-03 | Two-component aqueous acrylate-epoxy resin hybrid coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106010020A true CN106010020A (en) | 2016-10-12 |
Family
ID=57134633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610644830.7A Pending CN106010020A (en) | 2016-08-03 | 2016-08-03 | Two-component aqueous acrylate-epoxy resin hybrid coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106010020A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106811006A (en) * | 2017-02-14 | 2017-06-09 | 江苏艾科赛特新材料有限公司 | It is a kind of to can be used for the aqueous epoxy floor coating compositions and preparation method of outdoor |
| CN106832109A (en) * | 2017-02-15 | 2017-06-13 | 苏州凯康化工科技有限公司 | A kind of aqueous double-component plastic paint resin dispersion liquid and preparation method thereof |
| CN107189589A (en) * | 2017-07-11 | 2017-09-22 | 合肥康之恒机械科技有限公司 | A kind of outdoor fitness equipment corrosion resistant coating and preparation method thereof |
| CN107936758A (en) * | 2017-10-30 | 2018-04-20 | 合肥林邦门业有限公司 | A kind of bi-component waterproof aqueous, environmental protective epoxy coating |
| CN108384364A (en) * | 2018-03-29 | 2018-08-10 | 常州永丰涂料有限公司 | Double-component water paint and preparation method thereof |
| CN109554055A (en) * | 2018-08-21 | 2019-04-02 | 成都虹润制漆有限公司 | A kind of aqueous thick coated type water soluble acrylic acid hydridization epoxide terrace paint and preparation method thereof |
| CN110054951A (en) * | 2019-04-11 | 2019-07-26 | 紫荆花涂料（上海）有限公司 | A kind of the floor coatings system and its application method of artificial granite effect |
| CN110272652A (en) * | 2018-03-15 | 2019-09-24 | 立邦涂料（中国）有限公司 | A kind of roof waterpoof material |
| CN110643252A (en) * | 2019-09-27 | 2020-01-03 | 中华制漆（深圳）有限公司 | Water-based epoxy floor coating and preparation method thereof |
| CN111518449A (en) * | 2020-05-11 | 2020-08-11 | 绵阳麦思威尔科技有限公司 | Water-based epoxy hybrid acrylic acid self-crosslinking quick-drying paint used in high humidity environment and preparation method thereof |
| CN111978766A (en) * | 2020-08-31 | 2020-11-24 | 吉力水性新材料科技（珠海）有限公司 | Water-based epoxy emulsion for floor finish |
| CN114672206A (en) * | 2022-03-11 | 2022-06-28 | 山东高速交通科技有限公司 | Aqueous bi-component road marking paint |
| CN114806302A (en) * | 2022-05-28 | 2022-07-29 | 河南蓝翎环科防水材料有限公司 | Antioxidant waterproof protective coating for terrace and production process thereof |
| CN116333569A (en) * | 2023-03-31 | 2023-06-27 | 上海固密特新材料科技有限公司 | Weather-resistant water-based flexible protective coating, preparation method thereof and application thereof in concrete waterproof engineering |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008066319A1 (en) * | 2006-11-28 | 2008-06-05 | Woo-Jae Lee | Inorganic pigments composition having high hardness |
| CN103351775A (en) * | 2013-06-19 | 2013-10-16 | 天长市金陵电子有限责任公司 | Heat dissipation coating used for LED lights and preparation method thereof |
| CN105111860A (en) * | 2015-09-01 | 2015-12-02 | 福建百花化学股份有限公司 | Water-based double-component corrosion-resistant industrial paint and production method thereof |
-
2016
- 2016-08-03 CN CN201610644830.7A patent/CN106010020A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008066319A1 (en) * | 2006-11-28 | 2008-06-05 | Woo-Jae Lee | Inorganic pigments composition having high hardness |
| CN103351775A (en) * | 2013-06-19 | 2013-10-16 | 天长市金陵电子有限责任公司 | Heat dissipation coating used for LED lights and preparation method thereof |
| CN105111860A (en) * | 2015-09-01 | 2015-12-02 | 福建百花化学股份有限公司 | Water-based double-component corrosion-resistant industrial paint and production method thereof |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106811006A (en) * | 2017-02-14 | 2017-06-09 | 江苏艾科赛特新材料有限公司 | It is a kind of to can be used for the aqueous epoxy floor coating compositions and preparation method of outdoor |
| CN106832109A (en) * | 2017-02-15 | 2017-06-13 | 苏州凯康化工科技有限公司 | A kind of aqueous double-component plastic paint resin dispersion liquid and preparation method thereof |
| CN107189589A (en) * | 2017-07-11 | 2017-09-22 | 合肥康之恒机械科技有限公司 | A kind of outdoor fitness equipment corrosion resistant coating and preparation method thereof |
| CN107936758A (en) * | 2017-10-30 | 2018-04-20 | 合肥林邦门业有限公司 | A kind of bi-component waterproof aqueous, environmental protective epoxy coating |
| CN110272652B (en) * | 2018-03-15 | 2021-07-09 | 立邦涂料（中国）有限公司 | Roof waterproof material |
| CN110272652A (en) * | 2018-03-15 | 2019-09-24 | 立邦涂料（中国）有限公司 | A kind of roof waterpoof material |
| CN108384364A (en) * | 2018-03-29 | 2018-08-10 | 常州永丰涂料有限公司 | Double-component water paint and preparation method thereof |
| CN109554055A (en) * | 2018-08-21 | 2019-04-02 | 成都虹润制漆有限公司 | A kind of aqueous thick coated type water soluble acrylic acid hydridization epoxide terrace paint and preparation method thereof |
| CN110054951A (en) * | 2019-04-11 | 2019-07-26 | 紫荆花涂料（上海）有限公司 | A kind of the floor coatings system and its application method of artificial granite effect |
| CN110643252A (en) * | 2019-09-27 | 2020-01-03 | 中华制漆（深圳）有限公司 | Water-based epoxy floor coating and preparation method thereof |
| CN111518449A (en) * | 2020-05-11 | 2020-08-11 | 绵阳麦思威尔科技有限公司 | Water-based epoxy hybrid acrylic acid self-crosslinking quick-drying paint used in high humidity environment and preparation method thereof |
| CN111978766A (en) * | 2020-08-31 | 2020-11-24 | 吉力水性新材料科技（珠海）有限公司 | Water-based epoxy emulsion for floor finish |
| CN114672206A (en) * | 2022-03-11 | 2022-06-28 | 山东高速交通科技有限公司 | Aqueous bi-component road marking paint |
| CN114672206B (en) * | 2022-03-11 | 2023-03-14 | 山东高速交通科技有限公司 | Aqueous bi-component road marking paint |
| CN114806302A (en) * | 2022-05-28 | 2022-07-29 | 河南蓝翎环科防水材料有限公司 | Antioxidant waterproof protective coating for terrace and production process thereof |
| CN116333569A (en) * | 2023-03-31 | 2023-06-27 | 上海固密特新材料科技有限公司 | Weather-resistant water-based flexible protective coating, preparation method thereof and application thereof in concrete waterproof engineering |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106010020A (en) | Two-component aqueous acrylate-epoxy resin hybrid coating | |
| CN104893489B (en) | A kind of one-component salt spray resistance water paint and preparation method thereof | |
| CN104098994B (en) | A kind of anticorrosive paint priming paint and finish compositions | |
| CN108795235A (en) | A kind of graphene modified waterborne epoxy zinc-rich paint and its preparation method and application | |
| CN102675998B (en) | Water-based fluorocarbon top coat for wind-powered blades and method for preparing water-based fluorocarbon top coat | |
| CN101560351B (en) | Corrosion proof impregnating varnish used for water-based metal components and manufacturing method thereof | |
| CN106336754A (en) | Environment-friendly single-component industrial anti-corrosion coating and preparation method thereof | |
| CN102977670B (en) | Cashew phenolic aldehyde amide epoxy hardener for four-season-general type anticorrosive paint and preparation method of cashew phenolic aldehyde amide epoxy hardener | |
| CN105694655A (en) | Environment-friendly, epoxy-resin, acid-resistant and anticorrosive coating material and preparation method thereof | |
| CN105802432B (en) | A kind of antiseptic and rustproof paint of water-base epoxy and preparation method thereof | |
| CN103333595A (en) | Cathode electrophoresis paint with combined bottom surfaces and preparation method and application method thereof | |
| CN103923541A (en) | Preparation method for universal alkali-resistant seal primer | |
| CN102702899A (en) | Water-based modified pure acrylic acid anticorrosive paint | |
| CN104403463A (en) | Aqueous low-surface treatment coating for iron power transmission tower surface protection and preparation method for aqueous low-surface treatment coating | |
| CN102911344A (en) | Preparation method of cationic acrylate epoxy resin | |
| CN105482626A (en) | Powder coating for metal plate | |
| CN204897805U (en) | Anticorrosive waterproof layer series interconnected system of scribbling | |
| CN107629608A (en) | A kind of preparation method and construction technology of elastic roofing waterproof paint | |
| CN105237693A (en) | Organic-inorganic hybrid silica modified acrylic resin and coating thereof | |
| CN104725977A (en) | Heavy anti-corrosion dual-component water-based epoxy zinc-enriched primer and preparation method thereof | |
| CN103666183A (en) | Corrosion-resistant coating | |
| CN113372768A (en) | Bottom-surface-in-one water paint for container and preparation method thereof | |
| CN105419571A (en) | Heavy anti-corrosion coating material | |
| CN101397817B (en) | Coating method of underwater curing anti-corrosive antifouling paint for sea facilities | |
| CN104962179B (en) | It is a kind of suitable for priming paint of antitheft door and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161012 |