CN101560351B - Corrosion proof impregnating varnish used for water-based metal components and manufacturing method thereof - Google Patents
Corrosion proof impregnating varnish used for water-based metal components and manufacturing method thereof Download PDFInfo
- Publication number
- CN101560351B CN101560351B CN2009100092337A CN200910009233A CN101560351B CN 101560351 B CN101560351 B CN 101560351B CN 2009100092337 A CN2009100092337 A CN 2009100092337A CN 200910009233 A CN200910009233 A CN 200910009233A CN 101560351 B CN101560351 B CN 101560351B
- Authority
- CN
- China
- Prior art keywords
- polyaniline
- water
- described amount
- deionized water
- aniline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 94
- 238000005260 corrosion Methods 0.000 title claims abstract description 25
- 230000007797 corrosion Effects 0.000 title claims abstract description 24
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 24
- 239000002184 metal Substances 0.000 title claims abstract description 24
- 239000002966 varnish Substances 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 229920000767 polyaniline Polymers 0.000 claims abstract description 78
- 239000008367 deionised water Substances 0.000 claims abstract description 71
- 239000000243 solution Substances 0.000 claims abstract description 25
- 239000000839 emulsion Substances 0.000 claims abstract description 24
- 239000003822 epoxy resin Substances 0.000 claims abstract description 24
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 24
- 239000000080 wetting agent Substances 0.000 claims abstract description 24
- 239000002245 particle Substances 0.000 claims abstract description 23
- 239000006229 carbon black Substances 0.000 claims abstract description 21
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims abstract description 20
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 12
- 239000011259 mixed solution Substances 0.000 claims abstract description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 117
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 78
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 78
- 229910021641 deionized water Inorganic materials 0.000 claims description 65
- 238000003756 stirring Methods 0.000 claims description 44
- -1 polyoxyethylene Polymers 0.000 claims description 41
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 39
- 239000007864 aqueous solution Substances 0.000 claims description 36
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 33
- 239000006185 dispersion Substances 0.000 claims description 30
- 239000002994 raw material Substances 0.000 claims description 28
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 25
- 239000013530 defoamer Substances 0.000 claims description 24
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 23
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 23
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 23
- 229910052708 sodium Inorganic materials 0.000 claims description 23
- 239000011734 sodium Substances 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 22
- 239000004925 Acrylic resin Substances 0.000 claims description 21
- 229920000178 Acrylic resin Polymers 0.000 claims description 21
- 239000002253 acid Substances 0.000 claims description 21
- 229920001577 copolymer Polymers 0.000 claims description 17
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 16
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 16
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 14
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 13
- 229920001296 polysiloxane Polymers 0.000 claims description 11
- MIOPJNTWMNEORI-GMSGAONNSA-N (S)-camphorsulfonic acid Chemical compound C1C[C@@]2(CS(O)(=O)=O)C(=O)C[C@@H]1C2(C)C MIOPJNTWMNEORI-GMSGAONNSA-N 0.000 claims description 10
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000005303 weighing Methods 0.000 claims description 9
- 238000000227 grinding Methods 0.000 claims description 8
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 7
- 150000003863 ammonium salts Chemical class 0.000 claims description 7
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000000706 filtrate Substances 0.000 claims description 3
- 238000009830 intercalation Methods 0.000 claims description 3
- 230000002687 intercalation Effects 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 238000000967 suction filtration Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 230000008961 swelling Effects 0.000 claims description 2
- 239000003973 paint Substances 0.000 abstract description 14
- 238000003618 dip coating Methods 0.000 abstract description 7
- 239000011248 coating agent Substances 0.000 abstract description 5
- 238000000576 coating method Methods 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 5
- 229920005989 resin Polymers 0.000 abstract description 5
- 239000011347 resin Substances 0.000 abstract description 5
- 150000003839 salts Chemical class 0.000 abstract description 5
- 239000000049 pigment Substances 0.000 abstract description 3
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 2
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 238000010422 painting Methods 0.000 abstract 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 abstract 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000003595 mist Substances 0.000 abstract 1
- 239000012258 stirred mixture Substances 0.000 abstract 1
- 229960004063 propylene glycol Drugs 0.000 description 35
- 235000013772 propylene glycol Nutrition 0.000 description 35
- 239000008187 granular material Substances 0.000 description 11
- 239000004922 lacquer Substances 0.000 description 9
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 5
- 230000008676 import Effects 0.000 description 5
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 4
- 239000008267 milk Substances 0.000 description 4
- 210000004080 milk Anatomy 0.000 description 4
- 235000013336 milk Nutrition 0.000 description 4
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 230000002421 anti-septic effect Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000012296 anti-solvent Substances 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 150000005826 halohydrocarbons Chemical class 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229940074869 marquis Drugs 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Abstract
The invention discloses a corrosion proof impregnating varnish used for water-based metal components and a manufacturing method thereof. The corrosion proof impregnating varnish is made of de-ionized water, propanediol, dispersant, antifoaming agent, wetting agent, carbon black, iron oxide black, water borne acroid resin, water borne epoxy resin, dipropylene glycol butyl ether, propylene glycol ether and polyaniline water solution, polyaniline carrier particles or polyaniline emulsion. The manufacturing method comprises: the propanediol and the de-ionized water are mixed and stirred, and then added with the dispersant, the antifoaming agent, the wetting agent and the polyaniline water solution or the water solution of emulsion or carrier particles to be evenly mixed together; the carbon black and the iron oxide black are added in to the mixed solution to form uniform pigment paste which is then put into a blending tank after being ground to be evenly stirred; the obtained mixture is added with the water borne acroid resin, the water borne epoxy resin, the dipropylene glycol butyl ether and the propylene glycol ether to be stirred; finally, the stirred mixture is added with the de-ionized water to be diluted and ground. The invention has the advantages of high coating efficiency, stable coating quality, uniform paint film of dip coating, flat and smooth paint film, good hardness, strong adhesive attraction, good corrosion proof performance, excellent painting performance at edges and corners, no leaking painting, good salt mist resistance, environmental protection, low cost,etc.
Description
One, technical field
The present invention relates to a kind of polyaniline-modified aqueous metal member special anti-corrosion impregnating varnish and preparation method thereof.
Two, background technology
Countries such as the hardware main exit America and Europe of domestic production, its application mode is based on dip-coating, showering, lacquer liquid stability requirement height, after the dip-coating, it is thinner to film, be generally 5-15um, antiseptic property is had relatively high expectations, in particular for the hardwares such as sofa extensible member on the indoor sofa, it also has strict requirement with lacquer on the feature of environmental protection, do not contain harmful materials such as phthalate, gylcol ether, halohydrocarbon, benzene,toluene,xylene, ethylbenzene, do not contain poisonous heavy metal lead, cadmium, chromium, mercury.
The application of hardware is monopolized by Shanghai Li Li factory of U.S. The Valspar Corporation with lacquer always, the hardware of its production is made by single water-borne acrylic resin with lacquer, it meets above-mentioned environmental requirement, but because the preservative property of acrylic resin, solvent resistance is relatively poor, in use there are problems, salt fog resistance is relatively poor, paint film thickness is that the salt spray resistance of the paint film of 5-10um has only 8 hours, dip-coating workpiece corner angle are not hung lacquer, be unsuitable for carrying out shower coat, and price is higher, existing market is difficult to accept, our company's disclosure of an invention number be the aqueous metal member of CN 101255303A with lacquer, the problems referred to above have been had tangible improvement, but aspect antiseptic property, have still lacked perfection.
Three, summary of the invention
The present invention solves the above-mentioned problems in the prior art exactly, provides a kind of aqueous, environmental protective, stability is high, rate of drying is fast, hardness is high, strong adhesion, good corrosion resistance, dip-coating workpiece corner angle are hung good corrosion proof impregnating varnish used for water-based metal components of lacquer performance and preparation method thereof.
For addressing the above problem; technical scheme of the present invention is: a kind of corrosion proof impregnating varnish used for water-based metal components; it is made by following proportioning raw materials, counts by weight percentage: the deionized water of 8-15%; the propylene glycol of 1-5%; the dispersion agent of 0.5-1.5%; the defoamer of 0.1-0.5%; the wetting agent of 0.5-1.5%; the carbon black of 2-8%; the iron oxide black of 10-22%; the water-borne acrylic resin of 25-33%; the aqueous epoxy resins of 20-28%; the dipropylene glycol butyl ether of 1-3%; the polyaniline aqueous solution of the propylene glycol of 2-5% and 1-12% or polyaniline carrier particles or polyaniline emulsion.
Dispersion agent in the above-mentioned described corrosion proof impregnating varnish used for water-based metal components is one or more in ammonium salt, maleic anhydride copolymer and the Viscotrol C sulphate of acrylate copolymer; Defoamer is one or both in polyoxyethylene glycol and the polysiloxane, and when defoamer was two kinds of polyoxyethylene glycol and polysiloxane, its proportioning was 1: 0.5-2; Wetting agent is polyether-modified polydimethylsiloxane or polydimethylsiloxane.
The polyaniline aqueous solution in the above-mentioned described corrosion proof impregnating varnish used for water-based metal components is made by following proportioning raw materials, count by weight percentage: the deionized water of 85-95%, the sodium-based montmorillonite of 2-10%, the aniline of 0.5-1.5%, the organic sulfonic acid of 0.8-3.0% and the Ammonium Persulfate 98.5 of 1-3%; Described organic sulfonic acid is a kind of in tosic acid, Witco 1298 Soft Acid, camphorsulfonic acid and the polystyrolsulfon acid.
Polyaniline carrier particles in the above-mentioned described corrosion proof impregnating varnish used for water-based metal components is made by following proportioning raw materials, count by weight percentage: the deionized water of 60-80%, the sodium-based montmorillonite of 10-32%, the aniline of 1.5-2.5%, the organic sulfonic acid of 4-6.5% and the Ammonium Persulfate 98.5 of 2-8%; Described organic sulfonic acid is a kind of in tosic acid, Witco 1298 Soft Acid, camphorsulfonic acid and the polystyrolsulfon acid.
Polyaniline emulsion in the above-mentioned described corrosion proof impregnating varnish used for water-based metal components is made by following proportioning raw materials, counts by weight percentage: the deionized water of 84-92%, the aniline of 0.5-2.5%, the organic sulfonic acid of 5.5-8.5% and the Ammonium Persulfate 98.5 of 1-6%; Described organic sulfonic acid is a kind of in tosic acid, Witco 1298 Soft Acid, camphorsulfonic acid and the polystyrolsulfon acid.
A kind of making method of corrosion proof impregnating varnish used for water-based metal components, it may further comprise the steps:
1, as using the polyaniline carrier granule, in the deionized water of elder generation with the 1/5-1/4 of the polyaniline carrier granule adding 8-15% of 1-12%, forms the aqueous solution of polyaniline carrier granule;
2, with 2/3 the deionized water of the propylene glycol of 1-5%, 8-15%,,, add in the pot of getting the raw materials ready, with the speed stirring at low speed of 400-600rpm with the deionized water of 1/2-8/15 as using the polyaniline carrier granule;
3, the aqueous solution that adds the polyaniline aqueous solution of the wetting agent of defoamer, 0.5-1.5% of dispersion agent, the 0.1-0.5% of 0.5-1.5% and 1-12% or polyaniline emulsion or the above-mentioned polyaniline carrier granule that mixes successively evenly after, add the carbon black of 2-8% and the iron oxide black of 10-22%, with the speed high speed dispersion of 1200rpm more than 20 minutes, form even mill base, do not have obvious dry mash piece;
4, the mill base that stirs is ground, till fineness≤20um; The qualified mill base of grinding is squeezed into accent to be converted in the jar, start stirring, low speed mixing is even, slowly add the water-borne acrylic resin of 25-33%, the aqueous epoxy resins of 20-28%, the dipropylene glycol butyl ether of 1-3% and the propylene glycol of 2-5% successively, stir more than at least 15 minutes, add 1/3, as using the polyaniline carrier granule, the deionized water that adds 1/4-4/15 is transferred rare to being coated with for 4 viscosity 30-50 seconds.
The making method of the polyaniline aqueous solution in the making method of above-mentioned described corrosion proof impregnating varnish used for water-based metal components, it may further comprise the steps: (1) places ultrasonic generator or beaker with the sodium-based montmorillonite of 2-10%, 9/10 the deionized water that adds 85-95%, ultrasonic dispersing or dispersed with stirring are more than 1 hour, make sodium-based montmorillonite homodisperse and abundant swelling in deionized water, stirring, heat temperature raising are to 78-82 ℃; (2) with the aniline of 0.5-1.5% and the organic sulfonic acid wiring solution-forming of 0.8-3.0%, and the formation aniline solution that stirs; (3) Ammonium Persulfate 98.5 that takes by weighing 1-3% is dissolved in 1/10 the deionized water of 85-95% and forms ammonium persulfate aqueous solution; (4) in nitrogen N
2Protection under, aniline solution is splashed in the described sodium-based montmorillonite aqueous dispersions, keep 78-82 ℃, stir and to disperse intercalation compound more than 3 hours down, form mixing solutions; Cooling subsequently, to the described Ammonium Persulfate 98.5 aqueous solution of mixed solution and dripping, the mixing solutions color is deepened gradually, after blackish green, continues reaction again more than 24 hours; Promptly get the polyaniline aqueous solution.Described organic sulfonic acid is a kind of in tosic acid, Witco 1298 Soft Acid, camphorsulfonic acid and the polystyrolsulfon acid.
The making method of polyaniline carrier particles in the making method of above-mentioned described corrosion proof impregnating varnish used for water-based metal components, it may further comprise the steps: it may further comprise the steps (1): (1) at room temperature, the deionized water of 60-80% is inserted in the beaker, the sodium-based montmorillonite that takes by weighing 10-32% adds beaker, beaker is put into ultrasonic generator carry out ultrasonic dispersing, make it to be uniformly dispersed, be warming up to 78-82 ℃; (2) with the aniline of 1.5-2.5% and the organic sulfonic acid wiring solution-forming of 4-6.5%, and the formation aniline solution that stirs; (3) aniline solution is joined in the beaker lentamente, continue ultrasonic dispersing more than 5 hours in ultrasonic generator, reduce to the Ammonium Persulfate 98.5 that room temperature slowly adds 2-8%, reaction was continued more than 24 hours in the back that stirs; (4) then with its suction filtration, colourless to filtrate with washed with de-ionized water, 58-62 ℃ of oven dry promptly gets the polyaniline carrier granule after the grinding.Described organic sulfonic acid is a kind of in tosic acid, Witco 1298 Soft Acid, camphorsulfonic acid and the polystyrolsulfon acid.
The making method of polyaniline emulsion in the making method of above-mentioned described corrosion proof impregnating varnish used for water-based metal components, it may further comprise the steps: (1) at room temperature, 9/10 the deionized water of 84-92% is placed there-necked flask, the organic sulfonic acid that adds 5.5-8.5%, brute force stirs, (2) aniline that then slowly drips 0.5-2.5% forms emulsion, the Ammonium Persulfate 98.5 that takes by weighing 1-6% is dissolved in 1/10 the deionized water of 84-92% and forms ammonium persulfate aqueous solution, stir and slowly be added to ammonium persulfate aqueous solution in the emulsion down, dropwise the back and continue reaction 5～8 hours, promptly get the polyaniline emulsion.Described organic sulfonic acid is a kind of in tosic acid, Witco 1298 Soft Acid, camphorsulfonic acid and the polystyrolsulfon acid.
Water-borne acrylic resin is the water-repellent preservation resin that U.S. ROHM AND HAAS is produced, and for aquosity metallic protective paint has been set up new standard of performance, and provides reference formulation for water-based metal priming paint and finish paint.Paint film property, corrosion-resistant as high gloss, hardness, levelling and solvent resistance are good.Comprise that at various metal substrates good sticking power etc. is all arranged on the galvanized sheet.The aqueous metallic paint that uses the watersoluble modified acrylic acid resin to make; reduced the maintenance cost of metal building, reduced the number of times of recoat, the good protection to metal substrate is provided; has excellent gloss retention; corrosion-resistant, anti-solvent, the lasting anti-marquis of color; dryness speed is fast; hardness is good, and is good to the wettability of pigment, coating surface color even unanimity.Aqueous epoxy resins and their derivative have excellent sticking power usually on steel, water tolerance, the erosion resistance of the aqueous metallic paint paint film of its making are stronger, and the while has also increased the sticking power with ground, have improved the hardness of paint film.
Because the present invention has adopted water-borne acrylic resin and aqueous epoxy resins composite, realize the mutual supplement with each other's advantages of two kinds of resins, the gloss retention of water-based protection usefulness resin excellence, corrosion-resistant, anti-solvent, the lasting anti-marquis of color, fast drying, hardness is good, and is good to the wettability of pigment; The aqueous epoxy resins water tolerance, erosion resistance is strong, has excellent sticking power on steel, the hardness height.Two kinds of composite resins are good stability also, does not fire, not quick-fried, nuisanceless, low tempertaure storage never degenerates.Efficient auxiliary agent enhancements such as employing dispersion agent, defoamer and wetting agent are wetting to ground, prevented shrinkage cavity.In addition, also promote surperficial smooth and gloss, made paint film uniform distribution on the metallic surface, and strengthened the extension lacquer performance of workpiece corner angle.
In a word, the present invention has easy construction, quick, adopts the production technique of spraying or dip-coating, the coating efficiency height, and coating quality is stable, the paint film of dip-coating is even, and paint film is smooth, smooth, and hardness is good, strong adhesion, antiseptic property is good, and corner angle extension lacquer property is good, no holiday phenomenon, and salt spray resistance can reach 96 hours.In the scope of application of more extensively drawing together, the application property that can obtain to suit.This product does not contain harmful materials such as phthalate, glycol ester class, halohydrocarbon, benzene,toluene,xylene, ethylbenzene, not leaded Ge, Cadmium, mercury or the like heavy metal.Meet the requirement of international up-to-date environmental regulation, characteristics such as the cost of material is low are suitable for the use of domestic export hardware fully.
Four, embodiment
The invention will be further described below in conjunction with specific examples, and following content all calculates according to weight ratio.
Embodiment 1, present embodiment is made by following proportioning raw materials:8% deionized water, 1% propylene glycol, 0.5% dispersion agent:acrylate copolymer De salt, defoamer:0.05% polyoxyethylene glycol and 0.05% polysiloxane, 0.5% wetting agent:polyether-modified polydimethylsiloxane, 4% carbon black, 11.9% iron oxide black, 33% water-borne acrylic resin, 28% aqueous epoxy resins, 3% dipropylene glycol butyl ether, 5% propylene glycol:propylene glycol butyl ether and, 5.0% polyaniline solutions.The polyaniline aqueous solution is by, 85% deionized water, 10% sodium-based montmorillonite, and 1.5% aniline, 2% organic sulfonic acid:tosic acid and, 1.5% Ammonium Persulfate, 98.5 are made.
Its making method may further comprise the steps:
1, the making of the polyaniline aqueous solution: (1) places ultrasonic wave to send out the sodium-based montmorillonite of above-mentioned described amount and answers device, adds 9/10 deionized water of above-mentioned described amount, and ultrasonic dispersing is more than 1 hour, and stir the back, heat temperature raising is to 78-82 ℃; (2) with the aniline and the organic sulfonic acid wiring solution-forming of described amount, and the formation aniline solution that stirs; (3) Ammonium Persulfate 98.5 that takes by weighing described amount is dissolved in 1/10 the deionized water and forms ammonium persulfate aqueous solution; (4) in nitrogen N
2Protection under, aniline solution is splashed in the described sodium-based montmorillonite aqueous dispersions, keep 78-82 ℃, stir and to disperse intercalation compound more than 3 hours down, form mixing solutions; Cooling subsequently, to the Ammonium Persulfate 98.5 aqueous solution initiated polymerization of the described amount of mixed solution and dripping, the mixing solutions color become blackish green after, continue reaction more than 24 hours, promptly get the polyaniline aqueous solution.
2, with 2/3 deionized water, propylene glycol, the polyaniline aqueous solution, add in the pot of getting the raw materials ready according to formula ratio, stir with the 400-600rpm rotating speed.
3, according to formula ratio, add successively after dispersion agent, defoamer and wetting agent mix, add color stuffing: carbon black and iron oxide black, more than 20 minutes, form even mill base with the speed high speed dispersion of 1200rpm, there is not obvious dry mash piece.
4, the mill base that stirs is ground, fineness≤20um; The qualified mill base of grinding is squeezed into accent to be converted in the jar, start stirring, low speed mixing is even, the water-borne acrylic resin and aqueous epoxy resins and the solubility promoter that slowly add formula ratio successively: dipropylene glycol butyl ether and propylene glycol, stir more than at least 15 minutes, survey initial viscosity, according to initial viscosity, the deionized water that adds 1/4-4/15 is transferred rare to being coated with for 4 viscosity 30-50 seconds.
5, check its viscosity to meet the requirements, soak plate checking dryness, hardness, surface effect, meet the requirements, surfacing, no significant defect is packed.
Embodiment 2, present embodiment are made by following proportioning raw materials: 15% deionized water, 2.5% propylene glycol, 1% dispersion agent: maleic anhydride copolymer, 0.5% defoamer: polyoxyethylene glycol, 1% wetting agent: polydimethylsiloxane, 7% carbon black, 14% iron oxide black, 25% water-borne acrylic resin, 24% aqueous epoxy resins, 1.5% dipropylene glycol, 2.5% propylene glycol: the propylene glycol monomethyl ether and 6% the polyaniline aqueous solution.The polyaniline aqueous solution is by 90% deionized water, 5% sodium-based montmorillonite, and 0.5% aniline, 1.5% organic sulfonic acid: Witco 1298 Soft Acid and 3% Ammonium Persulfate 98.5 are made.Its making method is with example 1.
Embodiment 3, present embodiment is made by following proportioning raw materials: 10.8% deionized water, 5% propylene glycol, 1.5% dispersion agent: Viscotrol C sulphate, 0.2% defoamer: polysiloxane, 1.5% wetting agent: polyether-modified polydimethylsiloxane, 8% import carbon black, 22% iron oxide black, 27% water-borne acrylic resin, 20% aqueous epoxy resins, 1% dipropylene glycol butyl ether, 2% propylene glycol: the propylene-glycol ethyl ether and 1% the polyaniline aqueous solution.The polyaniline aqueous solution is by 95% deionized water, 2% sodium-based montmorillonite, and 1.2% aniline, 0.8% organic sulfonic acid: camphorsulfonic acid and 1% Ammonium Persulfate 98.5 are made.Its making method is with example 1.
Embodiment 4, present embodiment is made by following proportioning raw materials: 12% deionized water, 3% propylene glycol, dispersion agent: the ammonium salt of 0.4% acrylate copolymer, 0.4% maleic anhydride copolymer and 0.45% Viscotrol C sulphate, defoamer: 0.2% polyoxyethylene glycol and 0.1% polysiloxane, 1.25% wetting agent: polydimethylsiloxane, 2% import carbon black, 10% iron oxide black, 30.2% watersoluble modified acrylic acid resin, 22% aqueous epoxy resins, 2% dipropylene glycol butyl ether, 4% propylene glycol: propylene glycol butyl ether and 12% polyaniline solutions.The polyaniline aqueous solution is by 91.2% deionized water, 3% sodium-based montmorillonite, and 0.8% aniline, 3% organic sulfonic acid: polystyrolsulfon acid and 2% Ammonium Persulfate 98.5 are made.Its making method is with example 1.
Embodiment 5, present embodiment is made by following proportioning raw materials: 15% deionized water, 3% propylene glycol, dispersion agent: the ammonium salt of 0.3% acrylate copolymer and 0.3% maleic anhydride copolymer, defoamer: 0.1% polyoxyethylene glycol and 0.2% polysiloxane, 0.5% wetting agent: polyether-modified polydimethylsiloxane, 4% carbon black, 12.8% iron oxide black, 29% water-borne acrylic resin, 27% aqueous epoxy resins, 2.6% dipropylene glycol, 4.2% propylene glycol: propylene glycol monomethyl ether, 1% polyaniline carrier particles.The polyaniline carrier particles is by 60% deionized water, 32% sodium-based montmorillonite, and 2% aniline, 4% organic sulfonic acid: tosic acid and 2% Ammonium Persulfate 98.5 are made.
Its making method may further comprise the steps:
1, the making of polyaniline carrier granule: (1) at room temperature, the deionized water of above-mentioned described amount is inserted in the beaker, and the sodium-based montmorillonite that takes by weighing described amount adds beaker, beaker is put into ultrasonic generator carry out ultrasonic dispersing, make it to be uniformly dispersed, be warming up to 78-82 ℃; (2) aniline of described amount and organic sulfonic acid are made into the aqueous solution formation aniline solution that stirs; (3) aniline solution is joined lentamente in the beaker continue ultrasonic dispersing more than 5 hours after, reduce to the Ammonium Persulfate 98.5 that room temperature slowly adds described amount, reaction was continued more than 24 hours in the back that stirs; (4) then with its suction filtration, colourless to filtrate with washed with de-ionized water, 58-62 ℃ of oven dry promptly gets the polyaniline carrier granule after the grinding.
2, the polyaniline carrier of described amount is added in the deionized water of 1/5-1/4, form the aqueous solution of polyaniline carrier granule;
3, add in the pot of getting the raw materials ready according to the aqueous solution of formula ratio, stir with the 400-600rpm rotating speed with deionized water, propylene glycol and the polyaniline carrier granule of 1/2-8/15;
4, according to formula ratio, add successively after dispersion agent, defoamer and wetting agent mix, add color stuffing: import carbon black and iron black, high speed dispersion (1200rpm) formed even mill base more than 20 minutes, did not have obvious dry mash piece;
5, the mill base that stirs is ground, fineness≤20um; The qualified mill base of grinding is squeezed into accent to be converted in the jar, start stirring, low speed mixing is even, the water-borne acrylic resin and aqueous epoxy resins and the solubility promoter that slowly add formula ratio successively: dipropylene glycol butyl ether and propylene glycol, stir more than at least 15 minutes, survey initial viscosity, according to initial viscosity, the deionized water that adds 1/4-4/15 is transferred rare to being coated with for 4 viscosity 30-50 seconds.
6, check its viscosity to meet the requirements, soak plate checking dryness, hardness, surface effect, meet the requirements, surfacing, no significant defect is packed.
Embodiment 6, present embodiment is made by following proportioning raw materials: 13% deionized water, 4% propylene glycol, dispersion agent: 0.45% maleic anhydride copolymer and 0.3% Viscotrol C sulphate, 0.3% defoamer: polyoxyethylene glycol, 0.75% wetting agent: polyether-modified polydimethylsiloxane, 5% carbon black, 16% iron oxide black, 26% water-borne acrylic resin, 25% aqueous epoxy resins, 2.5% dipropylene glycol, 3% propylene glycol: propylene glycol butyl ether and 3.7% polyaniline carrier particles.The polyaniline carrier particles is by 80% deionized water, 10% sodium-based montmorillonite, and 1.5% aniline, 5% organic sulfonic acid: Witco 1298 Soft Acid and 3.5% Ammonium Persulfate 98.5 are made.Its making method is with embodiment 5.
Embodiment 7, present embodiment is made by following proportioning raw materials: 14.1% deionized water, 3.5% propylene glycol, 0.8% dispersion agent: maleic anhydride copolymer, 0.5% defoamer: polyoxyethylene glycol, 0.6% wetting agent: polyether-modified polydimethylsiloxane, 6% carbon black, 13% iron oxide black, 26% water-borne acrylic resin, 24% aqueous epoxy resins, 2.5% dipropylene glycol, 4% propylene glycol: propylene glycol propyl ether, 5% polyaniline carrier particles.The polyaniline carrier particles is by 63% deionized water, 20% sodium-based montmorillonite, and 2.5% aniline, 6.5% organic sulfonic acid: camphorsulfonic acid and 8% Ammonium Persulfate 98.5 are made.Its making method is with embodiment 5.
Embodiment 8, present embodiment is made by following proportioning raw materials: 10% deionized water, 4% propylene glycol, 0.9% dispersion agent: the ammonium salt of acrylate copolymer, 0.2% defoamer: polysiloxane, 0.9% wetting agent: polyether-modified polydimethylsiloxane, 5% carbon black, 15% iron oxide black, 31% water-borne acrylic resin, 21% aqueous epoxy resins, 1% dipropylene glycol, 3% propylene glycol: propylene glycol butyl ether and 8% polyaniline carrier particles.The polyaniline carrier particles is by 72% deionized water, 15% sodium-based montmorillonite, and 1% aniline, 6% organic sulfonic acid: polystyrolsulfon acid and 6% Ammonium Persulfate 98.5 are made.Its making method is with embodiment 5.
Embodiment 9, present embodiment are made by following proportioning raw materials, 9% deionized water, 2% propylene glycol, 1.5% dispersion agent: the ammonium salt of acrylate copolymer, 0.5% defoamer: polyoxyethylene glycol, 1.5% wetting agent: polyether-modified polydimethylsiloxane, 3% carbon black, 18% iron oxide black, 28% water-borne acrylic resin, 26% aqueous epoxy resins, 1% dipropylene glycol, 3.5% propylene glycol: propylene-glycol ethyl ether, 6% polyaniline milk sap.The polyaniline emulsion is by 84% deionized water, 2.5% aniline, and 8.5% organic sulfonic acid: tosic acid and 5% Ammonium Persulfate 98.5 are made.
Its making method may further comprise the steps:
1, the making of polyaniline emulsion: (1) at room temperature, with 9/10 deionized water of above-mentioned described amount in there-necked flask, the Witco 1298 Soft Acid that adds described amount, brute force stirs, (2) aniline that then slowly drips described amount forms emulsion, and the Ammonium Persulfate 98.5 that takes by weighing described amount is dissolved in 1/10 the deionized water and forms ammonium persulfate solution, stirs slowly to be added to ammonium persulfate solution in the emulsion down, dropwise the back and continue reaction 5～8 hours, promptly get the polyaniline emulsion.
2, with 2/3 deionized water, propylene glycol, polyaniline emulsion, add in the pot of getting the raw materials ready according to formula ratio, stir with the 400-600rpm rotating speed;
2, with 2/3 deionized water, propylene glycol, the polyaniline aqueous solution, add in the pot of getting the raw materials ready according to formula ratio, stir with the 400-600rpm rotating speed.
3, according to formula ratio, add successively after dispersion agent, defoamer and wetting agent mix, add color stuffing: carbon black and iron oxide black, more than 20 minutes, form even mill base with the speed high speed dispersion of 1200rpm, there is not obvious dry mash piece.
4, the mill base that stirs is ground, fineness≤20um; The qualified mill base of grinding is squeezed into accent to be converted in the jar, start stirring, low speed mixing is even, the water-borne acrylic resin and aqueous epoxy resins and the solubility promoter that slowly add formula ratio successively: dipropylene glycol butyl ether and propylene glycol, stir more than at least 15 minutes, survey initial viscosity, according to initial viscosity, the deionized water that adds 1/4-4/15 is transferred rare to being coated with for 4 viscosity 30-50 seconds.
5, check its viscosity to meet the requirements, soak plate checking dryness, hardness, surface effect, meet the requirements, surfacing, no significant defect is packed.
Embodiment 10, present embodiment are made by following proportioning raw materials, 15% deionized water, 2.5% propylene glycol, 1% dispersion agent: maleic anhydride copolymer, 0.5% defoamer: polyoxyethylene glycol, 1% wetting agent: polydimethylsiloxane, 7% carbon black, 14% iron oxide black, 25% water-borne acrylic resin, 24% aqueous epoxy resins, 1.5% dipropylene glycol, 2.5% propylene glycol: propylene glycol monomethyl ether and 6% polyaniline milk sap.The polyaniline emulsion is by 92% deionized water, 0.5% aniline, and 5.5% organic sulfonic acid: Witco 1298 Soft Acid and 2% Ammonium Persulfate 98.5 are made.Its making method is with embodiment 9.
Embodiment 11, present embodiment are made by following proportioning raw materials, 10.8% deionized water, 5% propylene glycol, 1.5% dispersion agent: Viscotrol C sulphate, 0.2% defoamer: polysiloxane, 1.5% wetting agent: polyether-modified polydimethylsiloxane, 8% import carbon black, 22% iron oxide black, 27% water-borne acrylic resin, 20% aqueous epoxy resins, 1% dipropylene glycol butyl ether, 2% propylene glycol: propylene-glycol ethyl ether and 1% polyaniline milk sap.The polyaniline emulsion is by 90% deionized water, 2% aniline, and 7% organic sulfonic acid: camphorsulfonic acid and 1% Ammonium Persulfate 98.5 are made.Its making method is with embodiment 9.
Embodiment 12, present embodiment is made by following proportioning raw materials, 12% deionized water, 3% propylene glycol, dispersion agent: the ammonium salt of 0.4% acrylate copolymer, 0.4% maleic anhydride copolymer and 0.45% Viscotrol C sulphate, defoamer: 0.2% polyoxyethylene glycol and 0.1% polysiloxane, 1.25% wetting agent: polydimethylsiloxane, 2% import carbon black, 10% iron oxide black, 30.2% watersoluble modified acrylic acid resin, 22% aqueous epoxy resins, 2% dipropylene glycol butyl ether, 4% propylene glycol: propylene glycol butyl ether and 12% polyaniline milk sap.The polyaniline emulsion is by 87% deionized water, 1% aniline, and 6% organic sulfonic acid: polystyrolsulfon acid and 6% Ammonium Persulfate 98.5 are made.Its making method is with embodiment 9.
Claims (4)
1. corrosion proof impregnating varnish used for water-based metal components, it is characterized in that: it is made by following proportioning raw materials, counts by weight percentage: the aqueous epoxy resins of the iron oxide black of the wetting agent of the dispersion agent of the deionized water of 8-15%, the propylene glycol of 1-5%, 0.5-1.5%, the defoamer of 0.1-0.5%, 0.5-1.5%, the carbon black of 2-8%, 10-22%, the water-borne acrylic resin of 25-33%, 20-28%, the dipropylene glycol butyl ether of 1-3%, the propylene glycol of 2-5% and the polyaniline aqueous solution or polyaniline carrier particles or the polyaniline emulsion of 1-12%; The described polyaniline aqueous solution is made by following proportioning raw materials, counts by weight percentage: the deionized water of 85-95%, the sodium-based montmorillonite of 2-10%, the aniline of 0.5-1.5%, the organic sulfonic acid of 0.8-3.0% and the Ammonium Persulfate 98.5 of 1-3%; Described polyaniline carrier particles is made by following proportioning raw materials, counts by weight percentage: the deionized water of 60-80%, the sodium-based montmorillonite of 10-32%, the aniline of 1.5-2.5%, the organic sulfonic acid of 4-6.5% and the Ammonium Persulfate 98.5 of 2-8%; Described polyaniline emulsion is made by following proportioning raw materials, counts by weight percentage: the deionized water of 84-92%, the aniline of 0.5-2.5%, the organic sulfonic acid of 5.5-8.5% and the Ammonium Persulfate 98.5 of 1-6%.
2. corrosion proof impregnating varnish used for water-based metal components according to claim 1 is characterized in that: described dispersion agent is one or more in ammonium salt, maleic anhydride copolymer and the Viscotrol C sulphate of acrylate copolymer; Defoamer is one or both in polyoxyethylene glycol and the polysiloxane, and when defoamer was two kinds of polyoxyethylene glycol and polysiloxane, its proportioning was 1: 0.5-2; Wetting agent is polyether-modified polydimethylsiloxane or polydimethylsiloxane.
3. according to claim 1 or 2 described corrosion proof impregnating varnish used for water-based metal components, it is characterized in that: described organic sulfonic acid is a kind of in tosic acid, Witco 1298 Soft Acid, camphorsulfonic acid and the polystyrolsulfon acid.
4. the making method of a corrosion proof impregnating varnish used for water-based metal components is characterized in that: described raw material and proportioning are according to the raw material and the proportioning of each described corrosion proof impregnating varnish used for water-based metal components among the claim 1-3:
It may further comprise the steps:
(1) as using the polyaniline carrier particles, earlier the polyaniline carrier particles of described amount is added in the deionized water of 1/5-1/4 of described amount, form the aqueous solution of polyaniline carrier particles;
(2) with 2/3 deionized water of the propylene glycol of described amount, described amount, as using the polyaniline carrier particles, with the deionized water of the 1/2-8/15 of described amount, adding is got the raw materials ready in the pot, with the speed stirring at low speed of 400-600rpm;
(3) aqueous solution that adds dispersion agent, defoamer, wetting agent and the polyaniline aqueous solution of described amount or polyaniline emulsion or the above-mentioned polyaniline carrier particles that mixes successively evenly after, the carbon black and the iron oxide black that add described amount, with the speed high speed dispersion of 1200rpm more than 20 minutes, form even mill base, do not have obvious dry mash piece;
(4) mill base that stirs is ground, till fineness≤20 μ m; The qualified mill base of grinding is squeezed into accent to be converted in the jar, start stirring, low speed mixing is even, the water-borne acrylic resin, the aqueous epoxy resins of described amount, the dipropylene glycol butyl ether of described amount and the propylene glycol of described amount that slowly add described amount successively, stir more than at least 15 minutes, add 1/3 of described amount, as using the polyaniline carrier particles, the deionized water that adds the 1/4-4/15 of described amount is transferred rare to being coated with for 4 viscosity 30-50 seconds;
The making method of the described polyaniline aqueous solution is, it may further comprise the steps: (1) places ultrasonic generator or beaker with the sodium-based montmorillonite of described amount, 9/10 the deionized water that adds described amount, ultrasonic dispersing or dispersed with stirring are more than 1 hour, make sodium-based montmorillonite homodisperse and abundant swelling in deionized water, stirring, heat temperature raising are to 78-82 ℃; (2) with the aniline of described amount and the organic sulfonic acid wiring solution-forming of described amount, and the formation aniline solution that stirs; (3) Ammonium Persulfate 98.5 that takes by weighing described amount is dissolved in 1/10 the deionized water of described amount and forms ammonium persulfate aqueous solution; (4) in nitrogen N
2Protection under, aniline solution is splashed in the described sodium-based montmorillonite aqueous dispersions, keep 78-82 ℃, stir and to disperse intercalation compound more than 3 hours down, form mixing solutions; Cooling subsequently, to the described Ammonium Persulfate 98.5 aqueous solution of mixed solution and dripping, the mixing solutions color is deepened gradually, after blackish green, continues reaction again more than 24 hours;
The making method of described polyaniline carrier particles, it may further comprise the steps: (1) at room temperature, the deionized water of described amount is inserted in the beaker, the sodium-based montmorillonite that takes by weighing described amount adds beaker, beaker is put into ultrasonic generator carry out ultrasonic dispersing, make it to be uniformly dispersed, be warming up to 78-82 ℃; (2) with the aniline and the organic sulfonic acid wiring solution-forming of described amount, and the formation aniline solution that stirs; (3) aniline solution is joined in the beaker lentamente, continue ultrasonic dispersing more than 5 hours in ultrasonic generator, reduce to the Ammonium Persulfate 98.5 that room temperature slowly adds described amount, reaction was continued more than 24 hours in the back that stirs; (4) then with its suction filtration, colourless to filtrate with washed with de-ionized water, 58-62 ℃ of oven dry promptly gets the polyaniline carrier particles after the grinding;
The making method of described polyaniline emulsion, it may further comprise the steps: (1) at room temperature, 9/10 deionized water of described amount is placed there-necked flask, the organic sulfonic acid that adds described amount, brute force stirs, and aniline that (2) then slowly drip described amount forms emulsion, and the Ammonium Persulfate 98.5 that takes by weighing described amount is dissolved in 1/10 the deionized water of described amount and forms ammonium persulfate aqueous solution, under stirring ammonium persulfate aqueous solution slowly is added in the emulsion, dropwises the back and continue reaction 5～8 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100092337A CN101560351B (en) | 2009-02-25 | 2009-02-25 | Corrosion proof impregnating varnish used for water-based metal components and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100092337A CN101560351B (en) | 2009-02-25 | 2009-02-25 | Corrosion proof impregnating varnish used for water-based metal components and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101560351A CN101560351A (en) | 2009-10-21 |
| CN101560351B true CN101560351B (en) | 2011-09-07 |
Family
ID=41219342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100092337A Active CN101560351B (en) | 2009-02-25 | 2009-02-25 | Corrosion proof impregnating varnish used for water-based metal components and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101560351B (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101768404B (en) * | 2009-12-25 | 2012-04-25 | 艾伦塔斯电气绝缘材料(珠海)有限公司 | Impregnated insulating paint and preparation method thereof |
| CN101775108B (en) * | 2010-03-26 | 2012-10-31 | 哈尔滨工业大学 | Synthesis of modified aqueous epoxy resin and method for preparing antiseptic rusty paint |
| CN102174285B (en) * | 2011-03-04 | 2013-09-11 | 苏州市金近涂料有限公司 | Aqueous anti-corrosion and anti-frost paint for steel structure and preparation method thereof |
| CN102115627B (en) * | 2011-04-12 | 2013-02-06 | 厦门大学 | Expanding type steel structure fireproof and anticorrosion coating and preparation method thereof |
| CN102167944B (en) * | 2011-05-31 | 2013-02-13 | 苏州市金近涂料有限公司 | Water-based dipping lacquer and preparation method thereof |
| CN102702920B (en) * | 2012-06-12 | 2015-07-22 | 中国科学院长春应用化学研究所 | Aqueous polyaniline anti-corrosive paint and preparation method thereof |
| CN103382347B (en) * | 2013-06-27 | 2016-05-04 | 马鞍山采石矶涂料有限公司 | A kind of high temperature resisting dipping paint and preparation method thereof |
| CN105778682B (en) * | 2016-03-28 | 2017-12-12 | 重庆金固特新材料科技有限公司 | A kind of modified metal corrosion resistant coating and preparation method thereof |
| CN106085185A (en) * | 2016-08-22 | 2016-11-09 | 安徽宇瑞环保建设有限公司 | A kind of environmental protection equipment anticorrosion paint special |
| CN106381007A (en) * | 2016-08-29 | 2017-02-08 | 常熟市古里镇淼泉大光金属制品厂 | Rotary rack for supermarket |
| CN109181439A (en) * | 2018-06-13 | 2019-01-11 | 河北晨阳工贸集团有限公司 | A kind of low-VOC aqueous dip painting and preparation method thereof |
| CN110437692B (en) * | 2019-07-18 | 2021-06-04 | 中华制漆（深圳）有限公司 | Dip coating for metal surfaces, and preparation method and application method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1702134A (en) * | 2005-07-13 | 2005-11-30 | 北京格丽斯聚合技术发展有限公司 | Thermostable rustproof metallic paint and preparation method thereof |
| CN1935911A (en) * | 2006-10-24 | 2007-03-28 | 查培法 | Bottom-surface-in-one fluorocarbon enamelled paint and its preparing method |
| CN101045843A (en) * | 2007-04-18 | 2007-10-03 | 邹磊 | Water industrial antirust paint and preparation method thereof |
| CN101255303A (en) * | 2008-02-04 | 2008-09-03 | 刘善江 | Aqueous metal member special-purpose paint and preparation thereof |
-
2009
- 2009-02-25 CN CN2009100092337A patent/CN101560351B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1702134A (en) * | 2005-07-13 | 2005-11-30 | 北京格丽斯聚合技术发展有限公司 | Thermostable rustproof metallic paint and preparation method thereof |
| CN1935911A (en) * | 2006-10-24 | 2007-03-28 | 查培法 | Bottom-surface-in-one fluorocarbon enamelled paint and its preparing method |
| CN101045843A (en) * | 2007-04-18 | 2007-10-03 | 邹磊 | Water industrial antirust paint and preparation method thereof |
| CN101255303A (en) * | 2008-02-04 | 2008-09-03 | 刘善江 | Aqueous metal member special-purpose paint and preparation thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101560351A (en) | 2009-10-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101560351B (en) | Corrosion proof impregnating varnish used for water-based metal components and manufacturing method thereof | |
| CN102504668B (en) | Water-based primer-topcoat synthetic anti-corrosive paint for coating automobile spare parts and preparation method thereof | |
| CN104559617B (en) | A kind of application type aqueous dual-component fluorocarbon coating and its preparation and application | |
| CN108034346A (en) | A kind of coating system for the composition and its formation for being used to produce aqueous coating | |
| CN106497377A (en) | Two-component waterborne polyurethane industrial paint with excellent physical properties and preparation method thereof | |
| CN106883717A (en) | It is a kind of can multiple tracks recoating the acrylic acid aqueous finishing varnish of polyester modification and preparation method | |
| WO2018041129A1 (en) | Epoxy emulsion and preparation method therefor | |
| CN109852181A (en) | The preparation method of epoxy modified acrylic resin antirust emulsion | |
| CN110229602A (en) | Fluorocarbon coating and preparation method thereof and coating process | |
| CN112375469A (en) | Solvent-free epoxy drinking water coating and preparation method thereof | |
| CN109777229A (en) | A kind of acrylic acid protective primer and preparation method thereof | |
| CN106189722A (en) | A kind of water nano heat insulation color steel baking vanish formula and preparation method | |
| CN101486873B (en) | Waterborne metallic anticorrosion paint and preparation thereof | |
| CN110628297A (en) | Solvent type epoxy coating with high solid content and salt fog resistance and preparation method thereof | |
| CN101255303A (en) | Aqueous metal member special-purpose paint and preparation thereof | |
| CN112552777A (en) | Water-based epoxy primer for wet-on-wet process and preparation method thereof | |
| CN106554663A (en) | A kind of corrosion resistant formulation for coating material | |
| CN105885696A (en) | Aqueous coating for electrostatic spraying | |
| CN110028857A (en) | A kind of one-component high adhesion force environmental protection sealing wax and preparation method thereof | |
| CN114686069B (en) | Polyacrylate resin modified waterborne epoxy emulsion and preparation method thereof | |
| CN102286242B (en) | Acrylic polyurethane hot galvanizing substrate paint and preparation method thereof | |
| CN105061693B (en) | Acrylic acid composite epoxy resin and the environmentally friendly acrylic acid composite epoxy coating comprising the resin and preparation method thereof | |
| CN106752959A (en) | A kind of white primer and preparation method thereof | |
| CN115537122A (en) | High-performance water-based wall surface hand-spraying paint and preparation method thereof | |
| CN102827529A (en) | Water-based epoxy antirust paint of iron oxide reds and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: LIU JIANRU Effective date: 20150514 Owner name: LIU SHANJIANG Free format text: FORMER OWNER: HEBEI CHENYANG INDUSTRIALL+TRADE GROUP CO., LTD. Effective date: 20150514 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20150514 Address after: Xushui County, Hebei province 072550 Baoding City, ansu town Yongxing Road No. 12 Patentee after: Liu Shanjiang Patentee after: Liu Jianru Address before: 072550 Hebei city of Baoding province Xushui County Chenyang Street Industrial Park Patentee before: Hebei Chenyang IndustrialL&trade Group Co., Ltd. |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20151026 Address after: Xushui County, Hebei province 072550 Chenyang street Baoding City No. Patentee after: Hebei Chenyang IndustrialL&trade Group Co., Ltd. Address before: Xushui County, Hebei province 072550 Baoding City, ansu town Yongxing Road No. 12 Patentee before: Liu Shanjiang Patentee before: Liu Jianru |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Corrosion proof impregnating varnish used for water-based metal components and manufacturing method thereof Effective date of registration: 20160612 Granted publication date: 20110907 Pledgee: Medium range Leasing Co. Ltd. Pledgor: Hebei Chenyang IndustrialL&trade Group Co., Ltd. Registration number: 2016990000488 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20190116 Granted publication date: 20110907 Pledgee: Medium range Leasing Co. Ltd. Pledgor: Hebei Chenyang IndustrialL&trade Group Co., Ltd. Registration number: 2016990000488 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Corrosion proof impregnating varnish used for water-based metal components and manufacturing method thereof Effective date of registration: 20191224 Granted publication date: 20110907 Pledgee: Shandong Jiaxin Investment Co., Ltd Pledgor: Hebei Chenyang IndustrialL&trade Group Co., Ltd. Registration number: Y2019990000781 |
|
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20200929 Granted publication date: 20110907 |
|
| PD01 | Discharge of preservation of patent | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20210902 Granted publication date: 20110907 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20211203 Granted publication date: 20110907 Pledgee: Shandong Jiaxin Investment Co.,Ltd. Pledgor: HEBEI CHENYANG INDUSTRY&TRADE Group Ltd. Registration number: Y2019990000781 |