CN105907281A - Fireproof flame-retardant energy-saving building paint - Google Patents

Fireproof flame-retardant energy-saving building paint Download PDF

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Publication number
CN105907281A
CN105907281A CN201610493277.1A CN201610493277A CN105907281A CN 105907281 A CN105907281 A CN 105907281A CN 201610493277 A CN201610493277 A CN 201610493277A CN 105907281 A CN105907281 A CN 105907281A
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CN
China
Prior art keywords
energy
saving
saving coatings
modified
building field
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610493277.1A
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Chinese (zh)
Other versions
CN105907281B (en
Inventor
向红先
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Shunde District Polybo Chemicals Co ltd
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Chengdu Yuya Science and Technology Co Ltd
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Priority to CN201610493277.1A priority Critical patent/CN105907281B/en
Publication of CN105907281A publication Critical patent/CN105907281A/en
Application granted granted Critical
Publication of CN105907281B publication Critical patent/CN105907281B/en
Expired - Fee Related legal-status Critical Current
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to application of fireproof flame-retardant energy-saving paint in the field of buildings. The energy-saving paint is composed of acrylate-modified water-based polyurethane, an alkyd resin, a polyester resin, propanol, ammonia water, vitrified microbeads, lauryl alcohol, n-butyl stearate, octyl phenol polyethenoxy ether, a defoaming agent, a wetting and dispersing agent, a leveling agent, yttrium, magnesium hydroxide and deionized water. The energy-saving building paint has the advantages of excellent mechanical properties, excellent adhesive force, heat shielding, thermal insulation, energy saving, environment friendliness, favorable fire resistance and favorable flame retardancy, and can balance the indoor environment temperature.

Description

A kind of energy-saving building coating of fire protection flame retarding
Technical field
The present invention relates to a kind of energy-saving coatings, particularly relate to a kind of fire protection flame retarding energy-saving coatings for construction wall.
Background technology
Under the influence of energy crisis, energy resource consumption is the significant problem that the world today faces.Energy-saving and emission-reduction have become as Every profession and trade be eager solve matter of utmost importance.Along with growth in the living standard, people are to the requirement of indoor environment comfort level the most day by day Increasing, building energy consumption ratio shared by total energy consumption increases day by day.Architectural energy consumption generally comprises building and heating, fall The energy that temperature, electric, illumination etc. are used, wherein most with heating and cooling energy expenditure.So building energy conservation is main still The insulation of building.Therefore, select suitable main materials for wall, exterior wall heat-insulating paint and sash stuff, strengthen thermal insulation separation Heat, is the fundamental way of building energy conservation.
Phase-change material (PCM-Phase Change Material) refers to vary with temperature and change state of matter and can carry Material for latent heat.During phase transition process, phase-change material is by absorption or discharges substantial amounts of latent heat.Therefore, utilize this principle, can be by Phase-change material is applied to building field, mainly has energy-conserving action, up to energy-conservation 60%-99%.
Summary of the invention
It is an object of the invention to provide a kind of energy-saving coatings with fire protection flame retarding function, and for building field.This joint The composition of energy coating and the weight portion of each component are as follows:
Preferably, the composition of this energy-saving coatings and the weight portion of each component are as follows:
Preferably, the composition of this energy-saving coatings and the weight portion of each component are as follows:
Wherein, acrylic ester modified water-soluble polyurethane is to use physical blending process, by stable polyaminoester emulsion and propylene Acid esters emulsion passes through mechanical agitation mix homogeneously, obtains acrylic ester modified water-soluble polyurethane.The preferred organo montmorillonite of lauryl alcohol Modified lauryl alcohol；The stearic acid N-butyl that stearic acid N-butyl is the most organic imvite modified；OPEO is excellent Select organic imvite modified OPEO.Organo montmorillonite refers to use suitable Organic substance, as right in quaternary ammonium salt etc. Montmorillonite carries out organic-treating, is inserted between montmorillonite layer by ion exchange by the organic agents such as quaternary ammonium salt.Froth breaking Agent preferred silicone defoamer.Wetting dispersing agent preferred polyoxyethylene alkyl phenyl ether class, poly-(methyl) sodium acrylate salt, Poly-(methyl) ammonium acrylate salt Ricinate.The preferred polydimethylsiloxane of levelling agent, alkyl-modified organosiloxane, fluorine Modified acroleic acid esters levelling agent.
This has fire protection flame retarding function, as follows for the preparation method of the energy-saving coatings of external wall: changed by acrylate Property aqueous polyurethane and alkyd resin agitator high speed stir, mix homogeneously, obtain compound A；By organic imvite modified Lauryl alcohol, organic imvite modified stearic acid N-butyl and organic imvite modified OPEO and vitreous Microballon mixing, stirring, obtain compound B；Compound A and compound B is stirred in high mixer and mixes, and be sequentially added into moistening and divide Powder, polyester resin, propanol, yttrium, magnesium hydroxide, deionized water, defoamer and levelling agent carry out high-speed stirred, mix homogeneously； Be eventually adding ammonia regulation pH value in 8-8.5, high-speed stirred, obtain energy-saving coatings.
Use the energy-saving building coating of the present invention, there is mechanical performance and the adhesive force of excellence, heat insulation, insulation, balance cylinder Interior ambient temperature, energy-conserving and environment-protective, and fire retardant performance are good.
Detailed description of the invention
In order to make those skilled in the art be more fully understood that the present invention program, below by the technology in the embodiment of the present invention Scheme is clearly and completely described, it is clear that described embodiment be only the present invention part embodiment rather than Whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creative work premise Lower obtained every other embodiment, all should belong to the scope of protection of the invention.
Wherein, table 1 is each composition and the weight portion thereof of energy-saving building coating in each embodiment.Table 2 is to save in each embodiment The performance test of energy building coating.
In each embodiment of table 1, each of energy-saving building coating forms and parts by weight
Embodiment 1 Embodiment 2 Embodiment 3
Acrylic ester modified water-soluble polyurethane 100 120 150
Alkyd resin 80 90 100
Polyester resin 20 30 40
Propanol 30 50 80
Ammonia 10 20 30
Glass bead 40 50 70
Organic imvite modified lauryl alcohol 20 30 40
Organic imvite modified stearic acid N-butyl 20 30 40
Organic imvite modified OPEO 20 30 40
Defoamer 5 8 15
Wetting dispersing agent 5 15 20
Levelling agent 5 8 10
Yttrium 10 20 30
Magnesium hydroxide 30 40 50
Deionized water 100 150 180
The performance test of table 2 energy-saving building coating
Embodiment 1 Embodiment 2 Embodiment 3
Surface drying 25min 28min 35min
Do solid work 4.5h 6h 7h
Adhesive force (drawing compartment away from 2mm)/level 1 1 1
Wearability (750g, 500r)/g 0.034 0.037 0.042
Impact resistance Without exception Without exception Without exception
Fire protecting performance A A A
Phase transition temperature/DEG C 24 21.5 23
Above example only in order to technical scheme to be described, is not intended to limit；Although with reference to previous embodiment The present invention is described in detail, it will be understood by those within the art that: it still can be to aforementioned each enforcement Technical scheme described in example is modified, or wherein portion of techniques feature is carried out equivalent；And these amendment or Replace, do not make the essence of appropriate technical solution depart from the scope of various embodiments of the present invention technical scheme.

Claims (6)

1. the fire protection flame retarding energy-saving coatings application in building field, it is characterised in that the composition of this energy-saving coatings and each The weight portion of component is as follows:
2. energy-saving coatings application in building field as claimed in claim 1, it is characterised in that the composition of this energy-saving coatings And the weight portion of each component is as follows:
3. energy-saving coatings application in building field as claimed in claim 1, it is characterised in that the composition of this energy-saving coatings And the weight portion of each component is as follows:
4. energy-saving coatings application in building field as claimed in claim 1, it is characterised in that described acrylate modified Aqueous polyurethane is to use physical blending process, is mixed all by mechanical agitation with acrylic acid ester emulsion by stable polyaminoester emulsion Even, obtain acrylic ester modified water-soluble polyurethane.
5. energy-saving coatings application in building field as claimed in claim 1, it is characterised in that described lauryl alcohol is organic Imvite modified lauryl alcohol；Stearic acid N-butyl is organic imvite modified stearic acid N-butyl；Octyl phenol polyoxyethylene Ether is organic imvite modified OPEO.
6. energy-saving coatings application in building field as claimed in claim 1, it is characterised in that defoamer is silicone Defoamer, wetting dispersing agent is polyoxyethylene alkyl phenyl ether class, poly-(methyl) sodium acrylate salt, poly-(methyl) ammonium acrylate Salt Ricinate, levelling agent is polydimethylsiloxane, alkyl-modified organosiloxane, fluorin modified crylic acid esters levelling Agent.
CN201610493277.1A 2016-06-28 2016-06-28 A kind of energy-saving building coating of fire protection flame retarding Expired - Fee Related CN105907281B (en)

Priority Applications (1)

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CN201610493277.1A CN105907281B (en) 2016-06-28 2016-06-28 A kind of energy-saving building coating of fire protection flame retarding

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610493277.1A CN105907281B (en) 2016-06-28 2016-06-28 A kind of energy-saving building coating of fire protection flame retarding

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CN105907281B CN105907281B (en) 2018-05-08

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106543883A (en) * 2016-11-25 2017-03-29 江苏环宇纺织科技有限公司 A kind of sprayable aqueous fire-proof coating being applied on glass and preparation method thereof
CN106978052A (en) * 2017-04-19 2017-07-25 福建航程装饰工程有限公司 A kind of preparation method of environmental protection paint

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01141964A (en) * 1987-11-27 1989-06-02 Shin Etsu Chem Co Ltd Coating composition
CN101348626A (en) * 2008-09-17 2009-01-21 中国建筑材料科学研究总院 Temperature adjustment coating and preparation thereof
CN103788849A (en) * 2012-11-01 2014-05-14 深圳市润物科技有限公司 Low-carbon energy-saving coating
CN104194458A (en) * 2014-08-31 2014-12-10 海安南京大学高新技术研究院 Phase change type reflective thermal insulation coating and preparation method thereof
WO2014209222A1 (en) * 2013-06-27 2014-12-31 Lanxess Butyl Pte. Ltd. Antimicrobial coating composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01141964A (en) * 1987-11-27 1989-06-02 Shin Etsu Chem Co Ltd Coating composition
CN101348626A (en) * 2008-09-17 2009-01-21 中国建筑材料科学研究总院 Temperature adjustment coating and preparation thereof
CN103788849A (en) * 2012-11-01 2014-05-14 深圳市润物科技有限公司 Low-carbon energy-saving coating
WO2014209222A1 (en) * 2013-06-27 2014-12-31 Lanxess Butyl Pte. Ltd. Antimicrobial coating composition
CN104194458A (en) * 2014-08-31 2014-12-10 海安南京大学高新技术研究院 Phase change type reflective thermal insulation coating and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106543883A (en) * 2016-11-25 2017-03-29 江苏环宇纺织科技有限公司 A kind of sprayable aqueous fire-proof coating being applied on glass and preparation method thereof
CN106978052A (en) * 2017-04-19 2017-07-25 福建航程装饰工程有限公司 A kind of preparation method of environmental protection paint
CN106978052B (en) * 2017-04-19 2019-09-06 福建航程装饰工程有限公司 A kind of preparation method of environmental protection paint

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CB03 Change of inventor or designer information

Inventor after: Xiang Yi

Inventor before: Xiang Hongxian

CB03 Change of inventor or designer information
TA01 Transfer of patent application right

Effective date of registration: 20180411

Address after: 528300 No. 05, 06, No. A3, Long Wei furniture material city, A68, South Town Road, Lecong Town, Shunde District, Foshan, Guangdong.

Applicant after: Foshan Shunde District polybo Chemicals Co.,Ltd.

Address before: The middle Tianfu Avenue in Chengdu city Sichuan province 610041 No. 1388 1 8 storey building No. 866

Applicant before: CHENGDU YUYA SCIENCE & TECHNOLOGY Co.,Ltd.

TA01 Transfer of patent application right
GR01 Patent grant
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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180508

CF01 Termination of patent right due to non-payment of annual fee