CN101343498A - Paint for high-class woodenware artwork and preparation thereof - Google Patents
Paint for high-class woodenware artwork and preparation thereof Download PDFInfo
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- CN101343498A CN101343498A CNA2008100543888A CN200810054388A CN101343498A CN 101343498 A CN101343498 A CN 101343498A CN A2008100543888 A CNA2008100543888 A CN A2008100543888A CN 200810054388 A CN200810054388 A CN 200810054388A CN 101343498 A CN101343498 A CN 101343498A
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Abstract
The invention relates to high-grade wooden artwork coating, which is composed of host crystal and solidifying agent, wherein according to the weight parts: the host crystal and solidifying agent are 100:20 to 100:40. The high-grade wooden artwork coating of the invention is characterized in that the coating is made through utilizing that polyester modified epoxy resin is mixed with materials such as high color pigment, dispersing agent, leveling agent, anti-sagging auxiliary agent, anti-scratching auxiliary agent, filler and the like, and additionally matched with polyamide and aliphatic amine solidifying agent. Under the high temperature and high humidity conditions the coating can be coated on the surfaces of various wooden artworks, when the thickness of one-time coating paint film is within 120 um to 150 um, the high-grade wooden artwork coating can not generate sagging phenomenon, and the paint film is bright and flat and has good physical chemical properties. The coating has the protecting and decorating effects to the wooden artwork, which can be widely used for the coating of the wood sculpture, the long high table, the noble furniture and the wooden artwork products.
Description
Technical field
The invention belongs to the wooden articles technical field of coatings, relate to polyester modified epoxy resin coating, a kind of paint for high-class woodenware artwork and preparation method thereof of saying so more specifically.
Background technology
Along with lasting, the high speed development of national economy, the China and the world integrate with gradually.Particularly in the global development lag phase, the high speed development of China has more attracted the sight in the world.Increase day by day for the demand of wood artwork in countries such as Japan, Singapore, Taiwan, Malaysia, they for the lean woodenware technology of China ask especially if thirsty.Simultaneously the world particularly many countries in Asia make to a certain extent also that for the faith of Buddhism the demand of wooden articles constantly increases.China not only develops Buddhism, in Buddhism top skill is arranged aspect woodenware especially, and this just is enough to make countries in the world that the order of large quantities of wooden articles is invested China.
As everyone knows, wooden articles requires careful technology, and wooden articles will all will reach perfect aspect the choosing of timber, the portrayal of pattern, the grace of outward appearance, time of use or the like.Because wooden articles is very in vogue in states such as Japan, Singapore, Taiwan, Malaysia, these national weathers have the one side of its uniqueness.Particularly be subjected to the influence of oceanic climate and environment, require wooden articles good adaptive faculty to be arranged, good corrosion resistance nature can be arranged for temperature, humidity.Consider that from the functions of use of wooden articles it mostly is the advanced processes product greatly, therefore very strict for its appearance requirement.This has proposed very high requirement also just for coating and coating process.Not only require good plane effect, clarity, also because the reason of transportation requires good wear resistance.It is reported, China to the woodenware artwork of states such as Japan, Singapore, Taiwan, Malaysia only the volumn of purchase in an every year of coating hundred million yuan of 6-7.But because external client's strict demand, the domestic paint for high-class woodenware artwork that does not also satisfy its use properties, these coating import that also places one's entire reliance upon at present, it holds at high price, and this makes that China's woodenware artwork is under one's control.Under such background, China just seems imperative for the exploitation in so huge artwork coating market.
Summary of the invention
The objective of the invention is to, the shortcoming that overcomes prior art provides a kind of paint for high-class woodenware artwork with not enough, and this coating is made up of host and solidifying agent, and wherein the parts by weight of host and solidifying agent are 100: 20～100: 40.Preferred parts by weight are 100: 20-30.Particularly preferred parts by weight are 100: 20.
Particularly preferred parts by weight are 100: 40.
Particularly preferred parts by weight are 100: 25.
Host of the present invention, solidifying agent comprise the raw material of following parts by weight:
Host:
Polyester modified epoxy resin 40-60
High color pigments 3-6
Flow agent 0.5-1
Scratch resistance auxiliary agent 0.2-0.5
Anti-sag auxiliary agent 2-5
Spices 0.05-0.1
Dispersion agent 2-5
Filler 10-20
Solvent 5-10
Solidifying agent:
Polyamide resin 20-30
Aliphatic amide resin 60-70
Curing catalyst 8-15
Spices 0.05-0.1
Solvent in the paint for high-class woodenware artwork of the present invention, comprise: propyl carbinol, Virahol, butyl glycol ether, dimethylbenzene, 150# aromatic hydrocarbons, propylene glycol monomethyl ether, propylene glycol butyl ether, pimelinketone, hexone etc., preferred: Virahol, butyl glycol ether, 150# aromatic hydrocarbons, dimethylbenzene, pimelinketone.Wherein preferred solvent is the raw material of following parts by weight:
Dimethylbenzene 30-40
150# aromatic hydrocarbons 20-30
Virahol 8-15
Butyl glycol ether 5-10
Pimelinketone 20-30
High color pigments of the present invention is the goth black 1# of high pigment, goth black 2#, carbon black C311, high pigment phthalocyanine blue etc., and is preferred: the goth black 1# of high pigment.
Flow agent is: BYK-310 polyester modification siloxanes, EFKA3778 polyacrylate, EFKA3239 polysiloxane, deggusa1484 polyacrylate, preferred EFKA3239 polysiloxane, deggusa1484 polyacrylate.
The scratch resistance auxiliary agent is: KP366 modified polyorganosiloxane, EFKA3288 modified polyorganosiloxane, preferred EFKA3288 modified polyorganosiloxane.
The anti-sag auxiliary agent is the nano level modified urea of NAD-12, BYK-410 modified urea, BYK-430 modified urea, preferred BYK-410 modified urea.
Filler is: G-200 ceramic microsphere, G-400 ceramic microsphere W-210 ceramic microsphere, preferred G-200 ceramic microsphere.
Dispersion agent is: BYK-163 dispersion agent, BYK-161 dispersion agent, ATU wetting agent, preferred BYK-163 dispersion agent.
Solidifying agent is polymeric amide 0415, polymeric amide 885S, polymeric amide 816S, polymeric amide 865-65, aliphatic amide 1328, aliphatic amide 0412, aliphatic amide 5515, and is preferred: polymeric amide 0415, aliphatic amide 1328
Curing catalyst is: K-30 modified amine resin, K-54 modified amine resin, DMP-30 polyimide resin, preferred K-30 polyimide resin.
The preparation method of paint for high-class woodenware artwork of the present invention comprises the steps:
1, host preparation
(1) batching, grinding: with resin, dispersion agent, high color pigments, the filler mixing and stirring of above-mentioned parts by weight, be ground to the fineness 10-20 μ m of requirement, preferred 15 μ m.
(2) paint: add flow agent, sag prevention auxiliary agent, scratch resistance auxiliary agent, spices, solvent, stir and transfer evenly, regulate viscosity to (being coated with-4 glasss, 23 ℃) 105 ± 5 seconds, solids content to 85 ± 2% filters and packages;
2, solidifying agent preparation: with polyamide resin, aliphatic amide resin, curing catalyst, the spices of above-mentioned parts by weight, mixing and stirring filters and packages;
3, paint for high-class woodenware artwork proportioning: the host that will pack respectively during use is mixed with the ratio of weight and number of solidifying agent with 100: 20～100: 40, stirs, and slaking can be carried out spraying application after 20 minutes.
The present invention further discloses the application of paint for high-class woodenware artwork in the application of preparation high-class woodenware artwork.High-class woodenware artwork wherein comprises: woodcarving, pedestal table, noble furniture, senior wooden decorative are drawn or the like.
The present invention is by using polyester modified epoxy resin, utilize its distinctive polyester and epoxy dual nature, make it have well weather-proof, antiseptic property, good construction performance and splendid outward appearance, having solved constructs under high temperature, high humidity can produce the problem of mist shadow.
Woodenware artwork coating of the present invention, the introducing by high color pigments has solved the high chroma problem that wood lacquer is special procured.
Woodenware artwork coating of the present invention has solved the thick contradiction that is coated with paint film sagging and levelling property by the reasonable cooperation to dispersion agent, flow agent, sag prevention auxiliary agent.
Woodenware artwork coating of the present invention has solved the thick paint film that is coated with by the reasonable cooperation to polymeric amide and fatty amine curing agent and has done solid work slow problem.
Woodenware artwork coating of the present invention makes the strong and easily polishing of paint film mar-resistance by the cooperation adjustment to wear resistant filler, anti-zoned trace auxiliary agent and solidifying agent.
Woodenware artwork coating of the present invention; being equipped with materials such as high color pigments, dispersion agent, flow agent, sag prevention auxiliary agent, anti-zoned trace auxiliary agent, filler with above polyester modified epoxy resin cooperates polymeric amide and fatty amine curing agent to make " paint for high-class woodenware artwork " again; can be under high temperature, super-humid conditions; be applied to various wood artworks surface; a coating paint film thickness is when 120-150 μ m; sagging, non-foaming not; the paint film light, smooth, have excellent physicochemical property, wooden articles is played splendid protection, decoration function.
Every index that the paint for high-class woodenware artwork (embodiment 1-3) of the present invention's preparation detects is as follows:
1, performance index
Former lacquer viscosity (being coated with-4 glasss, 23 ℃) 105 ± 5 seconds
Solids content: 85 ± 2%
Solidify: surface drying :≤3 hours
Do solid work :≤24 hours
Flow μ m 〉=120
Appearance of coat: smooth smooth
Gloss of film: (20 ° of angles) 〉=100
Sticking power: (cross-hatching) mm≤1
Hardness: 〉=2H
Snappiness: mm is not more than 1
Deep freeze resistance: (10 ℃, 3 months) paint film does not ftracture, does not come off.
The wiping of anti-MEK: (MEK/500g power): 100 not show-through, depaintings not.
Resistance to salt water: 48 hours, non-foaming, non-corrosive.
2, product performance: " paint for high-class woodenware artwork " of the present invention has following excellent specific property:
(1) application property: can construct under comparatively high temps (35 ℃), humidity (90%) condition, paint film does not produce paint film disadvantages such as mist shadow, bubble.
(2) thick being coated with property; Disposable coating paint film thickness can reach more than the 120 μ m (dry film), does not produce the sagging phenomenon.
(3) high gloss: gloss of film can reach (20 ° of angles) more than 100.
(4) wearability: have good wear resisting property.
(5) resistance to marring: in use do not make coating surface produce cut because of cleaning, slight friction.
Paint for high-class woodenware artwork of the present invention is compared the positively effect that is had with existing coating and is:
1, paint for high-class woodenware artwork of the present invention, its product performance meet or exceed external like product level, fill the domestic gaps, and satisfy domestic wood artwork application service requirements, make the production domesticization of woodenware artwork coating; Solved under high humidity, pyritous condition and constructed, simultaneously outward appearance has been had harsh require and disposable spray finishing thickness height, be easy to generate the difficult problem of sagging, product meets construction requirement; Product does not contain heavy metal, VOC content is low, compliance with environmental protection requirements.
2, end-use: " paint for high-class woodenware artwork " is mainly used in wooden advanced processes product fields as the application of products such as woodcarving, pedestal table, noble furniture, woodenware artwork.
Embodiment
For simple and purpose clearly, hereinafter appropriate omission the description of known technology, in order to avoid those unnecessary details influences are to the description of the technical program.Below in conjunction with preferred embodiment, the present invention will be further described.
What be illustrated especially is: auxiliary agents such as BYK-310, EFKA-3778, EFKA-3239, deggusa-1484, wherein on behalf of Bi Ke company, EFKA, BYK represent EFKA company, deggusa to represent Degussa company.Preparing chemical reagent of the present invention all can buy or easily make by known method from the market.The umber of indication of the present invention can be a gram, and kilogram or ton are mainly selected with the actual needs of producing.
Embodiment 1
Main raw materials in proportion:
Host: solidifying agent=100 part: 20 parts.
Wherein:
Host:
40 parts of polyester modified epoxy resins
3 parts of high color pigments (the goth black 1# of high-carbon black pigment)
0.5 part of flow agent (EFKA3239)
0.2 part of scratch resistance auxiliary agent (EFKA3288)
2 parts of anti-sag auxiliary agents (BYK-430)
0.05 part of spices
2 parts of dispersion agents (BYK-163)
10 parts of fillers (G-200)
5 parts of solvents;
Solvent wherein is: 30 parts of dimethylbenzene, 20 parts in 150# aromatic hydrocarbons, 8 parts of Virahols, 5 parts of butyl glycol ethers, 20 parts of pimelinketone.
Solidifying agent:
20 parts of polyamide resins (polymeric amide 0415)
70 parts of aliphatic amide resins (aliphatic amide 1328)
8 parts of solidifying agent promotor (K-30)
0.05 part of spices.
Embodiment 2
Main raw materials in proportion: host: solidifying agent=100 part: 40 parts
Host:
60 parts of polyester modified epoxy resins
6 parts of high color pigments (the goth black 1# of high-carbon black pigment)
1 part of flow agent (EFKA3239)
0.5 part of scratch resistance auxiliary agent (EFKA3288)
5 parts of anti-sag auxiliary agents (BYK-430)
0.1 part of spices
5 parts of dispersion agents (BYK-163)
20 parts of fillers (G-200)
10 parts of solvents;
Solvent wherein is: 40 parts of dimethylbenzene, 30 parts in 150# aromatic hydrocarbons, 15 parts of Virahols, 10 parts of butyl glycol ethers, 30 parts of pimelinketone.
Solidifying agent:
30 parts of polyamide resins (polymeric amide 0415)
70 parts of aliphatic amide resins (aliphatic amide 1328)
15 parts of solidifying agent promotor (K-30)
0.1 part of spices.
Embodiment 3
Main raw materials in proportion: host: solidifying agent=100 part: 30 parts
Host:
50 parts of polyester modified epoxy resins
5 parts of high color pigments (the goth black 2# of high-carbon black pigment)
0.75 part of flow agent (deggusa1484)
0.3 part of scratch resistance auxiliary agent (KP366)
4 parts of anti-sag auxiliary agents (KP366)
0.08 part of spices
3.5 parts of dispersion agents (ANT204)
15 parts of fillers (G-400)
8 parts of solvents;
Solvent wherein is: 35 parts of dimethylbenzene, 25 parts in 150# aromatic hydrocarbons, 10 parts of Virahols, 8 parts of propylene glycol monomethyl ethers, 25 parts of pimelinketone.
Solidifying agent:
25 parts of polyamide resins (polymeric amide 816S)
65 parts of aliphatic amide resins (aliphatic amide 0412)
10 parts of solidifying agent promotor (K-54)
0.1 part of spices.
The preparation method of embodiment 1-3 paint for high-class woodenware artwork comprises the steps:
1, host preparation
(1) batching, grinding:, be ground to the fineness 15 μ m of requirement with parts by weight resin, dispersion agent, high color pigments, filler, the mixing and stirring that the foregoing description 1-3 is limited.
(2) paint: add flow agent, sag prevention auxiliary agent, scratch resistance auxiliary agent, spices, solvent, stir, regulate viscosity to (being coated with-4 glasss, 23 ℃) 105 ± 5 seconds, solids content to 85 ± 2% filters and packages;
2, solidifying agent preparation: with polyamide resin, aliphatic amide resin, curing catalyst, the spices of above-mentioned parts by weight, mixing and stirring filters and packages;
The host that to pack respectively when 3, using is mixed with the ratio of weight and number of solidifying agent with 100: 20～100: 40, stirs, and slaking can be carried out spraying application after 20 minutes.
Embodiment 4 (the actual use)
The host of packing respectively of embodiment 1-3 preparation is mixed with the ratio of weight and number of solidifying agent with 100: 25, stir, cross 200 order nets, after the slaking 20 minutes, use the aerial spraying method, be sprayed on the good wood pallets of substrate treatment, more than the plane film thickness 200 μ m, more than the facade film thickness 100 μ m, paint film appearance is plentiful, smooth, smooth as a result for it, clarity is high, gloss of film: (20 ° of angles) 〉=100; Sticking power (cross-hatching) mm≤1; Hardness: 〉=2H, snappiness: be not more than 1mm; Deep freeze resistance: (10 ℃, 3 months) paint film does not ftracture, does not come off; The wiping of anti-MEK: (MEK/500g power) 100 times not show-through, depainting not; Resistance to salt water: 48 hours, non-foaming, non-corrosive.The wood pallets that is sprayed has reached the standard of outlet.
Although the present invention has done detailed description in conjunction with its special embodiment, clearly concerning the skilled people in present technique field, still can make various changes and improvements, can not depart from spirit of the present invention and protection domain.
Claims (10)
1, a kind of paint for high-class woodenware artwork is characterized in that this coating is made up of host and solidifying agent, and wherein the parts by weight of host and solidifying agent are 100: 20～100: 40.
2, the described paint for high-class woodenware artwork of claim 1, wherein the parts by weight of host and solidifying agent are 100: 20-30.
3, each described paint for high-class woodenware artwork of claim 1-2, wherein host, solidifying agent comprise the raw material of following parts by weight:
Host:
Polyester modified epoxy resin 40-60
High color pigments 3-6
Flow agent 0.5-1
Scratch resistance auxiliary agent 0.2-0.5
Anti-sag auxiliary agent 2-5
Spices 0.05-0.1
Dispersion agent 2-5
Filler 10-20
Solvent 5-10
Solidifying agent:
Polyamide resin 20-30
Aliphatic amide resin 60-70
Curing catalyst 8-15
Spices 0.05-0.1.
4, the described paint for high-class woodenware artwork of claim 3, wherein high color pigments are the goth black 1# of high pigment, goth black 2#, C311 or high pigment phthalocyanine blue.
5, the described paint for high-class woodenware artwork of claim 3, wherein flow agent is: BYK-310, EFKA3778, EFKA3239 or deggusa1484; The scratch resistance auxiliary agent is KP366, EFKA3288; The anti-sag auxiliary agent is NAD-12, BYK-410 or BYK-430; Filler is ceramic microsphere G-200, G-400, G-600, W-210 or W-410; Dispersion agent is BYK-163, ANT204, BYK-161 or ATU.
6, the described paint for high-class woodenware artwork of claim 3, wherein solvent is the raw material of following parts by weight:
Dimethylbenzene 30-40
150# aromatic hydrocarbons 20-30
Virahol 8-15
Butyl glycol ether 5-10
Pimelinketone 20-30.
7, the described paint for high-class woodenware artwork of claim 3, wherein the polyamide resin of solidifying agent is: polymeric amide 0415, polymeric amide 885S, polymeric amide 816S or polymeric amide 865-65; The aliphatic amide resin is: aliphatic amide 1328, aliphatic amide 0412 or aliphatic amide 5515; Curing catalyst is: K-30, K-54 or DMP-30.
8, a kind of method for preparing each described paint for high-class woodenware artwork of claim 1-7 comprises the steps:
(1) host preparation:
A, batching, grinding: with resin, dispersion agent, high color pigments, filler, the sag prevention auxiliary agent of above-mentioned parts by weight, mixing and stirring is ground to 10-20 μ m;
B, paint: adding flow agent, sag prevention auxiliary agent, scratch resistance auxiliary agent, spices, solvent, stir and transfer evenly, is 105 ± 5 seconds with being coated with-4 glasss in 23 ℃ of mensuration dope viscosities, and solids content is 85 ± 2%, filters and packages;
(2) solidifying agent preparation: with polyamide resin, aliphatic amide resin, curing catalyst, the spices of above-mentioned parts by weight, mixing and stirring filters and packages;
(3) paint for high-class woodenware artwork proportioning: the host that will pack respectively during use is mixed with the ratio of weight and number of solidifying agent with 100: 20～100: 40, stirs, and slaking can be carried out spraying application after 20 minutes.
9, each described paint for high-class woodenware artwork of claim 1-7 is used in the application of preparation high-class woodenware artwork, woodenware artwork product.
10, the described application of claim 9, high-class woodenware artwork wherein comprises: woodcarving, pedestal table, noble furniture or senior wooden decorative are drawn.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2008100543888A CN101343498B (en) | 2008-09-01 | 2008-09-01 | Paint for high-class woodenware artwork and preparation thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100543888A CN101343498B (en) | 2008-09-01 | 2008-09-01 | Paint for high-class woodenware artwork and preparation thereof |
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| Publication Number | Publication Date |
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| CN101343498A true CN101343498A (en) | 2009-01-14 |
| CN101343498B CN101343498B (en) | 2011-05-11 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101781443B (en) * | 2009-01-20 | 2012-03-28 | 财团法人工业技术研究院 | Thermosetting solder masking film composite |
| CN105505223A (en) * | 2015-12-31 | 2016-04-20 | 王璐 | Improved metal pipeline corrosion-resistant coating |
| CN104277661B (en) * | 2014-10-13 | 2017-04-26 | 深圳华美迪油墨有限公司 | Clear lacquer and preparation method thereof |
| CN107286809A (en) * | 2017-07-26 | 2017-10-24 | 安徽省九华山法器有限公司 | A kind of wood carving craft surface modification coatings |
| CN107311515A (en) * | 2017-07-19 | 2017-11-03 | 铜仁市万山区丹凤朱砂工艺品研发检测鉴定中心有限公司 | A kind of cinnabar handicraft and preparation method thereof |
| CN107573805A (en) * | 2017-10-10 | 2018-01-12 | 佛山市三水区白坭镇巨财红木厂 | A kind of antistatic finish paint of mahogany furniture |
| CN109321108A (en) * | 2018-09-25 | 2019-02-12 | 天津科瑞达涂料化工有限公司 | A kind of poly- lucid asparagus craftwork coating and the preparation method and application thereof |
| CN110396343A (en) * | 2018-04-25 | 2019-11-01 | 河北晨阳工贸集团有限公司 | A kind of water-base epoxy anti-corrosion primer and preparation method thereof |
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2008
- 2008-09-01 CN CN2008100543888A patent/CN101343498B/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101781443B (en) * | 2009-01-20 | 2012-03-28 | 财团法人工业技术研究院 | Thermosetting solder masking film composite |
| CN104277661B (en) * | 2014-10-13 | 2017-04-26 | 深圳华美迪油墨有限公司 | Clear lacquer and preparation method thereof |
| CN105505223A (en) * | 2015-12-31 | 2016-04-20 | 王璐 | Improved metal pipeline corrosion-resistant coating |
| CN107311515A (en) * | 2017-07-19 | 2017-11-03 | 铜仁市万山区丹凤朱砂工艺品研发检测鉴定中心有限公司 | A kind of cinnabar handicraft and preparation method thereof |
| CN107286809A (en) * | 2017-07-26 | 2017-10-24 | 安徽省九华山法器有限公司 | A kind of wood carving craft surface modification coatings |
| CN107573805A (en) * | 2017-10-10 | 2018-01-12 | 佛山市三水区白坭镇巨财红木厂 | A kind of antistatic finish paint of mahogany furniture |
| CN110396343A (en) * | 2018-04-25 | 2019-11-01 | 河北晨阳工贸集团有限公司 | A kind of water-base epoxy anti-corrosion primer and preparation method thereof |
| CN109321108A (en) * | 2018-09-25 | 2019-02-12 | 天津科瑞达涂料化工有限公司 | A kind of poly- lucid asparagus craftwork coating and the preparation method and application thereof |
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|---|---|
| CN101343498B (en) | 2011-05-11 |
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Denomination of invention: Paint for high-class woodenware artwork and preparation thereof Effective date of registration: 20111114 Granted publication date: 20110511 Pledgee: Tianjin TEDA Small Enterprise Credit Guarantee Center Pledgor: Tianjin Colouroad Coating & Chemicals Co., Ltd. Registration number: 2011990000431 |
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