CN110484102A - A kind of new polyester oxidation pearl roll coat enamel and its preparation method and application - Google Patents
A kind of new polyester oxidation pearl roll coat enamel and its preparation method and application Download PDFInfo
- Publication number
- CN110484102A CN110484102A CN201910741351.0A CN201910741351A CN110484102A CN 110484102 A CN110484102 A CN 110484102A CN 201910741351 A CN201910741351 A CN 201910741351A CN 110484102 A CN110484102 A CN 110484102A
- Authority
- CN
- China
- Prior art keywords
- pearl
- roll coat
- polyester resin
- polyester
- coat enamel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention belongs to technical field of coatings, a kind of new polyester oxidation pearl roll coat enamel and its preparation method and application is disclosed.It includes following components that the polyester, which aoxidizes pearl roll coat enamel: linear polymeric polyester resin A, solid macromolecule polyester resin B, amino crosslinker, pearl powder, elastic powder, organic environmental-protection solvent, acid catalyst etc..Linear polymeric polyester resin A is the polyol resin of molecular weight 8000 ~ 10000, is structural film-forming resin；The macromolecule polyester resin B is molecular weight 14000 ~ 18000, and the polyester resin of 4 ~ 8mgKOH/g of hydroxyl value is main function film-forming resin；The partial size of the pearl powder is 15 ~ 25 μm.New polyester oxidation pearl roll coat enamel of the invention can realize continuous production and be easy color matching and excellent stability, color is plentiful, hardness is high, paint film decorative performance is good, it is excellent to protect light, unfading, weatherability and chemical corrosion resistance are excellent, guarantee the high adhesion force of coating, good mechanical performance, for the friendly roll-coated coatings instead of electrolytic oxidation layer of environmental protection.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of new polyester oxidation pearl roll coat enamel and its preparation side
Method and application.
Background technique
Substantially there is anodic oxidation, electrophoretic painting, fluorocarbon-sprayed and powder sprays for the surface treatment mode of aluminium alloy building-material
Apply four kinds of processing modes, all each advantage and disadvantage of each mode.
Traditional alumina product is all that can be only achieved ideal effect by some special pre-treatments and electrolysis, oxidation
The thin protectiveness of layer is bad, and corrosion stability and hardness are relatively low, and not easy coloring, and the light resistance after coloring is poor, so aluminium sheet colours
Bad with matching colors, technique is simultaneously unfriendly to environment.
Pearly coating can change thin layer of metal oxide, can generate different pearl effects.Pearlescent pigment and other face
Material is compared, and distinctive soft pearly luster has unrivaled effect.Special surface texture, high refractive index and good
Good transparency makes it in transparent medium, creates effect identical with pearly luster.
For this purpose, how to provide one kind continuous production and can be easy color matching and excellent stability, plentiful, hardness is high, paint film dress
It is good to adorn performance, protects that light, unfading are excellent, weatherability and the excellent roll coat enamel of chemical corrosion resistance guarantee that the height of coating is attached
Put forth effort, good mechanical performance, for the friendly roll-coated coatings instead of electrolytic oxidation layer of environmental protection.
Summary of the invention
In order to solve above-mentioned the shortcomings of the prior art, the primary purpose of the present invention is that providing one kind can continuous production
And be easy color matching and excellent stability, plentiful, hardness is high, paint film decorative performance is good, and it is excellent to protect light, unfading, weatherability and
The excellent new polyester of chemical corrosion resistance aoxidizes pearl roll coat enamel.
Another object of the present invention is to provide the preparation methods of above-mentioned new polyester oxidation pearl roll coat enamel.
Another object of the present invention is to provide the applications of above-mentioned new polyester oxidation pearl roll coat enamel.
The present invention is achieved by the following technical solutions:
A kind of new polyester oxidation pearl roll coat enamel, according to parts by weight, including following components:
The linear polymeric polyester resin A is the polyol resin of molecular weight 8000~10000, is set for structural film forming
Rouge；
The macromolecule polyester resin B be molecular weight 14000~18000, the polyester resin of 4~8mgKOH/g of hydroxyl value,
For main function film-forming resin；The partial size of the pearl powder is 15~25 μm.
Preferably, the glass transition temperature of the linear polymeric polyester resin A is 5~15 DEG C, 40~60mgKOH/ of hydroxyl value
G, 5~15mgKOH/g of acid value；The glass transition temperature of the macromolecule polyester resin B is 40~60 DEG C.
Preferably, the elastic powder is that polyurethane is ground, and the ball-type that average particle diameter is 7um~15um is reunited
Body.Elastic powder of the invention is the ball-type aggregate that 7um~15um is ground by the polyurethane that average grain diameter is nanostructure, shape
At extremely non-uniform distribution of particles, handle effect as the fine and smooth smooth villus of excellent elasticity accumulation overlapping is formed.
Preferably, the amino crosslinker is height Amino resin, the nonvolatile component measured by aluminum foil method
>=98%；23 DEG C of viscosity is 3000~6000mPas；23 DEG C of density is 1000~1500kg/m3.Preferably, described
Amino crosslinker is liquid hexamethoxymethyl melamine.
Preferably, the acid catalyst be enclosed type acid catalyst, pH value: 6.0~7.0, active ingredient: 26%~
35%, seal Xie Wendu: 75~85 DEG C.It is further preferred that enclosed type acid catalyst is that enclosed type sulphonic acids acid catalyst can
Apparent to reduce coating film-forming temperature or shorten the paint solidification time, film has high glaze, fabulous surface property and excellent
Weatherability and outdoor stability.The hardness and gloss that the catalyst can be improved crosslink density, increase paint film, improve the resistance to of paint film
Corrosivity, hydrolytic resistance, solvent resistance and mechanical performance.
The chemical structure and dosage of catalyst have very the adherence of coating, corrosion resistance, flexibility and impact resistance
Big influence.Creative use enclosed type sulphonic acids acid catalyst of the present invention, has been surprisingly found that especially suitable for crosslinking agent of the present invention
Type makes hydroxyl or carbamic acid base functional group in haplotype crosslinking agent " six (methoxy) melamines (HMMM) " and hands over
Connection agent reacts.
Preferably, the organic environmental-protection solvent is mixed dibasic acid ester, ethylene glycol ether acetate, propylene glycol monomethyl ether acetic acid
One or more of ester.
Preferably, other described auxiliary agents are selected from one or more of following: levelling agent, defoaming agent.
Preferably, other described auxiliary agents and its parts by weight are levelling agent 0.5-1；Defoaming agent 0.5-1.
Preferably, the levelling agent be aralkyl modified dimethyl silicone polymer, polyacrylate, acrylate containing silicone or
The mixing of one or more of rilanit special；The defoaming agent is one of benzoin or dimethyl polysiloxane or two
The mixing of kind.
A kind of preparation method of the new polyester oxidation pearl roll coat enamel, includes the following steps:
1, first macromolecule polyester resin B is crushed, in proportion pearl powder and the macromolecule polyester resin B that crushes with tying up
Determine technique and be uniformly mixed to obtain mixture C, wherein the temperature of binding technique is controlled at 40~60 DEG C, and the partial size control of pearl powder
System is at 15~25 μm；
2, it is proportionally added into part organic environmental-protection solvent, revolving speed is controlled at 500~700 revs/min, is added in dispersion mixed
Object C is closed, after all wettings, also to continue stirring 20~40 minutes, obtain mixture D；
3, it will mix, turn in linear polymeric polyester resin A, elastic powder, organic environmental-protection solvent investment dispersion cylinder in proportion
Speed control is at 500~700 revs/min, and dispersion 20~40 minutes to liquid；It is proportionally added into mixture D again, levelling agent, disappears
Infusion, organic environmental-protection solvent and acid catalyst continue to obtain new polyester oxidation pearl roller coating painting after keeping revolving speed to be uniformly dispersed
Material.
Preferably, the partial size of the macromolecule polyester resin B crushed is 10~20 μm.
Preferably, the binding technique is that the macromolecule polyester resin B crushed is mixed with pearl powder high-speed stirred,
Temperature is controlled at 40~60 DEG C, and is passed through nitrogen as protection gas, obtains more stable mixture C.
The present invention also provides above-mentioned new polyester oxidation pearl roll coat enamel building, general industry, household electrical appliances furniture,
The coating layer thickness of application in the industries such as communication apparatus, automobile parts, the new polyester oxidation pearl roll coat enamel is 10um-
30um, preferably 15um-20um.
Compared with prior art, the invention has the following beneficial effects:
New polyester of the invention aoxidizes pearl roll coat enamel and can realize continuous production and be easy color matching and excellent stability,
Color is plentiful, hardness is high, and paint film decorative performance is good, and guarantor's light, unfading are excellent, and weatherability and chemical corrosion resistance are excellent, protects
Demonstrate,prove the high adhesion force of coating, good mechanical performance, for the friendly roll-coated coatings instead of electrolytic oxidation layer of environmental protection.
Coating of the invention is all excellent in gloss, adhesive force, hardness, resistance to MEK wiping (secondary), impact resistance and the curved performance of T etc.
In the product of similar formula, unexpected technical effect is achieved.
Specific embodiment
Embodiment is given below so that the present invention to be specifically described, but not limited to this.Used in embodiment and comparative example
Raw material derive from it is commercially available.
Examples 1 to 3 and comparative example 1~8
The polyester of Examples 1 to 3 and comparative example 1~8 aoxidizes the preparation method of pearl roll coat enamel, includes the following steps:
1, first macromolecule polyester resin B is crushed, in proportion pearl powder and the macromolecule polyester resin B that crushes with tying up
Determine technique and be uniformly mixed to obtain mixture C, wherein the temperature of binding technique is controlled at 40~60 DEG C, and the partial size control of pearl powder
System is at 15~25 μm；
2, it is proportionally added into part organic environmental-protection solvent, revolving speed is controlled at 500~700 revs/min, is added in dispersion mixed
Object C is closed, after all wettings, also to continue stirring 20~40 minutes, obtain mixture D；
3, it will mix, turn in linear polymeric polyester resin A, elastic powder, organic environmental-protection solvent investment dispersion cylinder in proportion
Speed control is at 500~700 revs/min, and dispersion 20~40 minutes to liquid；It is proportionally added into mixture D again, levelling agent, disappears
Infusion, organic environmental-protection solvent and acid catalyst continue to obtain new polyester oxidation pearl roller coating painting after keeping revolving speed to be uniformly dispersed
Material.
The stock chart of table 1 Examples 1 to 3 and comparative example 1~8
The specific proportion (parts by weight) of each component in each embodiment of table 2 and comparative example
Comparative example 10~15
The polyester of comparative example 10~15 aoxidizes the preparation method of pearl roll coat enamel in the same manner as in Example 1, the difference of formula
Place is as shown in table 3:
The formula table of 3 comparative example 10~15 of table
Note: "/" indicates the ingredient in the same manner as in Example 1.
Application examples 1
The coating that above-described embodiment and comparative example are prepared is using roller coating coating process in the alloy sheets of building ceiling
On, after post-treated, the performances such as impact resistance, pencil hardness, adhesive force, the resistance to neutral salt spray of coating are detected, specific detection mark
Quasi- as shown in table 4, test result is as shown in table 5 and table 6.
4 testing standard of table
The performance test data of each embodiment and comparative example sample of table 5
The performance test data of each comparative example sample of table 6
As seen from the results in Table 5, the new polyester oxidation pearl roll coat enamel of Examples 1 to 3 can have good resistance to punching
Hitting property, pencil hardness, adhesive force, resistance to bend(ing), neutral salt spray etc..
However, from comparative example 1 and 2 it is found that obviously increasing in the case where adding less or adding pearl powder to the gloss of sample
Add, influences metal-like and sense of touch elasticity of product etc..From comparative example 3 and 4 it is found that the usage amount of elastic powder is to the curved performance of T
And gloss brings significant impact, such as glossiness is clearly present difference, can not have suitable matte effect；In addition unexpected
It was found that the curved performance of the T of product and sense of touch elasticity significantly reduce when the usage amount of elastic powder reduces.It is surprisingly sent out from comparative example 5 and 6
Existing, the dosage of amino crosslinker significantly affects the curved performance of T and hardness, resistance to MEK wiping.Have been surprisingly found that acid is urged from comparative example 7 and 8
Agent influences hardness and resistance to MEK wiping.It is had been surprisingly found that from comparative example 9, linear polymeric polyester resin A and macromolecule polyester resin
The usage ratio of B significantly affects hardness and gloss, feel.
From table 6, comparative example 10 and 11 is it is found that the partial size of pearl powder directly significantly affects the glossiness of product.Comparative example
12 and 13 physicochemical properties for showing linear polymeric polyester resin A significantly impact the curved performance of glossiness, hardness, T of product
Deng.Comparative example 14 and 15 is it is found that solid macromolecule polyester resin B brings significant shadow to glossiness, the curved performance of T and hardness
It rings.
In conclusion from comparative example 1~15 it is found that the physicochemical property of any raw material or the difference of dosage in formula of the invention
It is different that significant impact all is brought to the performance of final products.The present inventor is just obtained by largely innovating sex exploration
Obtain the product technology scheme of best performance.
New polyester oxidation pearl roll coat enamel of the invention achieves unexpected technical effect.Coating of the invention
It can be used to build on a large scale, the industries such as general industry, household electrical appliances furniture, communication apparatus, automobile parts.
Claims (10)
1. a kind of new polyester aoxidizes pearl roll coat enamel, which is characterized in that according to parts by weight, including following components:
Linear polymeric polyester resin A 45-50
Solid macromolecule polyester resin B 8-10
Amino crosslinker 10-12
Pearl powder 15-25
Elastic powder 1-3
Organic environmental-protection solvent 5-8
Acid catalyst 0.2-0.5
Other auxiliary agents 1-2
The linear polymeric polyester resin A is the polyol resin of molecular weight 8000 ~ 10000, is structural film-forming resin；
The macromolecule polyester resin B is molecular weight 14000 ~ 18000, and the polyester resin of 4 ~ 8mgKOH/g of hydroxyl value is main
Functional film-forming resin；The partial size of the pearl powder is 15 ~ 25 μm.
2. new polyester aoxidizes pearl roll coat enamel according to claim 1, which is characterized in that the linear polymeric polyester
The glass transition temperature of Resin A is 5 ~ 15 DEG C, 40 ~ 60mgKOH/g of hydroxyl value, 5 ~ 15mgKOH/g of acid value；The macromolecule polyester resin
The glass transition temperature of B is 40 ~ 60 DEG C.
3. new polyester aoxidizes pearl roll coat enamel according to claim 2, which is characterized in that the elasticity powder is polyurethane
It grinds, average particle diameter is the ball-type aggregate of 7um ~ 15um.
4. new polyester aoxidizes pearl roll coat enamel according to claim 1, which is characterized in that the amino crosslinker is height
Amino resin is spent, nonvolatile component >=98% measured by aluminum foil method；23 DEG C of viscosity is 3000~6000mPa
s；23 DEG C of density is 1000 ~ 1500kg/m3。
5. new polyester aoxidizes pearl roll coat enamel according to claim 1, which is characterized in that the acid catalyst is closing
Type acid catalyst, pH value: 6.0 ~ 7.0, active ingredient: 26% ~ 35%, seal Xie Wendu: 75 ~ 85 DEG C.
6. new polyester according to claim 1 aoxidizes pearl roll coat enamel, which is characterized in that the organic environmental-protection solvent
For one or more of mixed dibasic acid ester, ethylene glycol ether acetate, propylene glycol methyl ether acetate.
7. the preparation method of described in any item new polyester oxidation pearl roll coat enamels, feature exist according to claim 1 ~ 6
In including the following steps:
1, first macromolecule polyester resin B is crushed, pearl powder is used binding work with the macromolecule polyester resin B crushed in proportion
Skill is uniformly mixed and obtains mixture C, wherein the temperature control of binding technique exists at 40 ~ 60 DEG C, and the size controlling of pearl powder
15~25μm；
2, it is proportionally added into part organic environmental-protection solvent, revolving speed is controlled at 500 ~ 700 revs/min, and mixture is added in dispersion
C will also continue stirring 20 ~ 40 minutes after all wettings, obtain mixture D；
3, it will be mixed in linear polymeric polyester resin A, elastic powder, organic environmental-protection solvent investment dispersion cylinder in proportion, revolving speed control
System is at 500 ~ 700 revs/min, and dispersion 20 ~ 40 minutes to liquid；It is proportionally added into mixture D again, levelling agent, defoaming agent, has
Machine environmentally friendly solvent and acid catalyst continue to obtain new polyester oxidation pearl roll coat enamel after keeping revolving speed to be uniformly dispersed.
8. the preparation method of new polyester oxidation pearl roll coat enamel according to claim 7, which is characterized in that crush
Macromolecule polyester resin B partial size be 10 ~ 20 μm.
9. the preparation method of new polyester oxidation pearl roll coat enamel according to claim 7, which is characterized in that described to tie up
Determining technique is that the macromolecule polyester resin B crushed is mixed with pearl powder high-speed stirred, and temperature is controlled at 40 ~ 60 DEG C, and
Nitrogen is passed through as protection gas, obtains more stable mixture C.
10. described in any item new polyester oxidation pearl roll coat enamels are in building materials, general industry, family according to claim 1 ~ 6
Electricity, furniture, communication apparatus, on automobile parts coating application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910741351.0A CN110484102B (en) | 2019-08-12 | 2019-08-12 | Polyester oxidized pearl roller coating paint and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910741351.0A CN110484102B (en) | 2019-08-12 | 2019-08-12 | Polyester oxidized pearl roller coating paint and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110484102A true CN110484102A (en) | 2019-11-22 |
| CN110484102B CN110484102B (en) | 2021-08-06 |
Family
ID=68550610
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910741351.0A Active CN110484102B (en) | 2019-08-12 | 2019-08-12 | Polyester oxidized pearl roller coating paint and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110484102B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112646460A (en) * | 2020-12-18 | 2021-04-13 | 力同化工(佛山)有限公司 | Roller coating hand-feeling gloss oil |
| CN113999607A (en) * | 2021-11-09 | 2022-02-01 | 广东歌丽斯化学有限公司 | Film-coated adhesive coating and preparation method and application thereof |
| CN117567924A (en) * | 2024-01-15 | 2024-02-20 | 福建安能新材料股份有限公司 | Chemical-resistant surface coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012041464A (en) * | 2010-08-20 | 2012-03-01 | Dic Corp | Resin composition for powder coating, powder coating, and coated article |
| CN104031535A (en) * | 2014-06-26 | 2014-09-10 | 立邦涂料（天津）有限公司 | Novel low-matte polyester finish coating and preparation method thereof |
| CN109735249A (en) * | 2018-12-27 | 2019-05-10 | 合肥乐凯科技产业有限公司 | A kind of dumb light lacquer painting protective film |
-
2019
- 2019-08-12 CN CN201910741351.0A patent/CN110484102B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012041464A (en) * | 2010-08-20 | 2012-03-01 | Dic Corp | Resin composition for powder coating, powder coating, and coated article |
| CN104031535A (en) * | 2014-06-26 | 2014-09-10 | 立邦涂料（天津）有限公司 | Novel low-matte polyester finish coating and preparation method thereof |
| CN109735249A (en) * | 2018-12-27 | 2019-05-10 | 合肥乐凯科技产业有限公司 | A kind of dumb light lacquer painting protective film |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112646460A (en) * | 2020-12-18 | 2021-04-13 | 力同化工(佛山)有限公司 | Roller coating hand-feeling gloss oil |
| CN113999607A (en) * | 2021-11-09 | 2022-02-01 | 广东歌丽斯化学有限公司 | Film-coated adhesive coating and preparation method and application thereof |
| CN117567924A (en) * | 2024-01-15 | 2024-02-20 | 福建安能新材料股份有限公司 | Chemical-resistant surface coating |
| CN117567924B (en) * | 2024-01-15 | 2024-03-22 | 福建安能新材料股份有限公司 | Chemical-resistant surface coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110484102B (en) | 2021-08-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105542630B (en) | A kind of aqueous coil coating polyester back paint and preparation method thereof | |
| CN110484102A (en) | A kind of new polyester oxidation pearl roll coat enamel and its preparation method and application | |
| CN102010648A (en) | Floating coat-free shining base coat used for metal pieces and preparation method thereof | |
| CN109504244B (en) | Water-based coil steel coating and preparation method thereof | |
| CN107418277B (en) | A kind of water nano long-effective corrosion finishing coat and preparation method thereof | |
| CN102746768B (en) | Water-borne colorful glass paint and preparation method and application thereof | |
| CN108192438B (en) | Water-based auxiliary material capable of improving workability of water-based metal and pearlescent paint and preparation method thereof | |
| CN110484103A (en) | A kind of super soft dumb light roll coat enamel of polyester and its preparation method and application | |
| CN101343498B (en) | Paint for high-class woodenware artwork and preparation thereof | |
| CN104136550A (en) | Thin aluminum flakes | |
| CN110028861A (en) | Aqueous industrial aluminium paint, preparation method and its flatulence detection device | |
| CN108977043A (en) | Universal single-component water-based metal flash paint of one kind and preparation method thereof | |
| CN104962189A (en) | Aluminum powder plastic water paint and preparation method thereof | |
| CN104726014A (en) | Ultraviolet curing coating raw material and coating prepared from same | |
| CN103911057B (en) | A kind of aqueous covercoat coating for three painting one bakings and preparation method thereof | |
| CN106752827B (en) | High-adhesion coating on low-surface-energy base material | |
| CN110938338B (en) | Environment-friendly high-solid-content coating and preparation method thereof | |
| CN109535871B (en) | High-wear-resistance high-gloss coating for automotive interior and preparation method thereof | |
| CN104672985B (en) | A kind of ink for decorative material surface printing treatment | |
| CN109880492A (en) | A kind of high tenacity scratch resistance powdery paints | |
| CN109294296A (en) | Aqueous one-component vitreous enamel coating of super resistant and preparation method thereof and construction technology | |
| CN104151989A (en) | Amino drying varnish | |
| CN114806387A (en) | PETG coating and raw material composition, preparation method and use method thereof | |
| CN111410881A (en) | Integrated coating paint for plastic parts and preparation method and coating method thereof | |
| CN106957588A (en) | A kind of raising PET film radioresistance, hardness, the resistance and fingerprint resistance inorganic agent of translucency |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |