CN105799350A - Thermal transfer method with diamond magical color effects - Google Patents
Thermal transfer method with diamond magical color effects Download PDFInfo
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- CN105799350A CN105799350A CN201410834933.0A CN201410834933A CN105799350A CN 105799350 A CN105799350 A CN 105799350A CN 201410834933 A CN201410834933 A CN 201410834933A CN 105799350 A CN105799350 A CN 105799350A
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- 229910003460 diamond Inorganic materials 0.000 title claims abstract description 108
- 239000010432 diamond Substances 0.000 title claims abstract description 108
- 230000000694 effects Effects 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims abstract description 35
- 239000000843 powder Substances 0.000 claims abstract description 34
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims abstract description 29
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 29
- 238000007639 printing Methods 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 26
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 19
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 19
- 239000006185 dispersion Substances 0.000 claims abstract description 19
- 239000000839 emulsion Substances 0.000 claims abstract description 19
- 238000007731 hot pressing Methods 0.000 claims abstract description 16
- 238000001816 cooling Methods 0.000 claims abstract description 8
- 238000010023 transfer printing Methods 0.000 claims abstract description 7
- UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 claims description 61
- 239000002002 slurry Substances 0.000 claims description 58
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 24
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 22
- 239000012141 concentrate Substances 0.000 claims description 16
- 230000001680 brushing effect Effects 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- 229920001971 elastomer Polymers 0.000 claims description 12
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 12
- 229910052737 gold Inorganic materials 0.000 claims description 12
- 239000010931 gold Substances 0.000 claims description 12
- 229920005992 thermoplastic resin Polymers 0.000 claims description 12
- 239000004408 titanium dioxide Substances 0.000 claims description 12
- 229910052709 silver Inorganic materials 0.000 claims description 10
- 239000004332 silver Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 8
- CLAHOZSYMRNIPY-UHFFFAOYSA-N 2-hydroxyethylurea Chemical group NC(=O)NCCO CLAHOZSYMRNIPY-UHFFFAOYSA-N 0.000 claims description 7
- 239000008139 complexing agent Substances 0.000 claims description 7
- 229940031575 hydroxyethyl urea Drugs 0.000 claims description 7
- 125000005375 organosiloxane group Chemical group 0.000 claims description 7
- 229920000058 polyacrylate Polymers 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- 239000013530 defoamer Substances 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- 239000000080 wetting agent Substances 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 claims description 2
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims description 2
- YTAHJIFKAKIKAV-XNMGPUDCSA-N [(1R)-3-morpholin-4-yl-1-phenylpropyl] N-[(3S)-2-oxo-5-phenyl-1,3-dihydro-1,4-benzodiazepin-3-yl]carbamate Chemical compound O=C1[C@H](N=C(C2=C(N1)C=CC=C2)C1=CC=CC=C1)NC(O[C@H](CCN1CCOCC1)C1=CC=CC=C1)=O YTAHJIFKAKIKAV-XNMGPUDCSA-N 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 abstract description 7
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- 239000010985 leather Substances 0.000 description 1
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- 239000011159 matrix material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
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- Decoration By Transfer Pictures (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention provides a thermal transfer method with diamond magical color effects. The thermal transfer method comprises preparing transparent thermal transfer paste, printing a transparent first total graph layer with gray scale net points, spraying a graph layer with colored images through a printer, printing a first high-light graph layer, printing a second high-light graph layer, printing a second total graph layer, printing a third total graph layer, immediately scattering TPU hot-melt powder, carrying out drying, preparing a base material and carrying out hot-pressing transfer, cooling and dyestripping. The thermal transfer method only utilizes UV ink, a thermoplastic polyurethane aqueous dispersion and an aqueous acrylic resin emulsion, is free of a harmful volatile organic solvent, sprays the UV ink to a transfer printing film with transparent transfer printing paste, realizes momentary drying and curing, does not produce diffusion, has a high resolution ratio and utilizes combination of pearly paste with diamond magical color effects and high-resolution ratio spray ink so that the transfer printed product has diamond-like radiance and magical color effects.
Description
Technical field
The present invention relates to a kind of heat-transferring method, specifically, relate to a kind of UV ink numerial code spray drawing heat-transferring method with diamond fantasy coloured effect in conjunction with screen painting
Background technology
Hot-pressing transfer printing is also known as xylopyrography, it is a kind of the word being printed on heat-transferring printing paper or plastic foil or pattern are transferred to the method on fabric or leather by heating the mode of pressurization, it is characterized in that transferred image is bright in luster, levels are rich, there are some problems in existing hot-pressing transfer printing method, coloured image such as intaglio plate, relief printing plate, soft version and screen painting has obvious dot matrix, and printing precision is at 300～500dpi；Additionally, the thermal dye sublimation transfer printing of numerial code spray drawing can only be confined to terylene or coating process on fabric, it is also possible to there will be diffusion blooming.
Chinese utility model patent CN201120488582 discloses a kind of thermal transfer mark, but this thermal transfer target simple in construction, it does not have special-effect, it does not have clearly digital coating is solvent-based inks, or Weak solvent ink or UV ink.
Summary of the invention
In order to solve above-mentioned the deficiencies in the prior art part, it is an object of the invention to provide a kind of heat-transferring method, pass through the method, make UV ink numerial code spray drawing in conjunction with screen painting, its printing precision may be up to 5760dpi, and the precise image of UV ink numerial code spray drawing merges with diamond illusion-colour Pearl Concentrate, creates the thermally transferred pattern of diamond fantasy coloured effect.
For this, the present invention provides a kind of heat-transferring method with diamond fantasy coloured effect, and described heat-transferring method comprises the following steps: a) allocate transparent heat transfer slurry: described transparent heat transfer slurry includes thermoplastic polyurethane aqueous dispersion 40～43 weight portion, water-borne acrylic resin emulsion 40～43 weight portion, wetting agent 6～9 weight portion, emulsifying agent 2～3 weight portion, thickening agent 1～2 weight portion and organic silicon defoamer 0.1～0.2 weight portion；B) the first full figure layer transparent with GTG site is printed: adopt the half tone of 150～200 orders to print described transparent heat transfer slurry on bright transfer film one time, dry at the temperature of 40～50 DEG C, the prepared first full figure layer transparent with GTG site；C) printer air brushing is with the figure layer of coloured image: uses UV flat-panel printer air brushing coloured image on described first full figure layer, prepares the figure layer with coloured image；D) printing is with the first high light figure layer of GTG site diamond fantasy coloured effect: after adopting the half tone of 120～150 orders print at least one time of diamond illusion-colour Pearl Concentrate on the described figure layer with coloured image, dry at the temperature of 40～50 DEG C, prepare the first high light figure layer with GTG site diamond fantasy coloured effect, wherein, described diamond illusion-colour Pearl Concentrate includes described transparent heat transfer slurry 80～85 weight portion, the diamond unreal gold pearl essence of 1～3 weight portion of 30～100 microns, the unreal red pearl essence of diamond of 1～3 weight portion of 30～100 microns, the unreal blue pearl essence of diamond of 1～3 weight portion of 30～100 microns, the unreal purple pearl essence of diamond of 1～3 weight portion of 30～100 microns, the unreal green pearl essence of diamond of 1～3 weight portion of 30～100 microns；E) printing is with the second high light figure layer of GTG site silvery white effect: after adopting 120～150 order half tones print at least one time of silver transfer slurry on described the first high light figure layer with GTG site diamond fantasy coloured effect, dry at the temperature of 40～50 DEG C, preparing the second high light figure layer with GTG site silvery white effect, described silver transfer slurry includes aluminum argentum powder 12～18 weight portion of described transparent heat transfer slurry 80～85 weight portion and 70 μm；F) printing is with the second full figure layer of GTG site white: adopt 120～150 order half tones print on described the second high light figure layer with GTG site silvery white effect white transfer slurry at least one time after, dry at the temperature of 40～50 DEG C, preparing the second full figure layer with GTG site white, described white transfer slurry includes titanium dioxide 25～35 weight portion of at least one transparent heat transfer slurry 65～75 weight portion and 0.36 μm；G) printing is with transparent the 3rd full figure layer in GTG site: adopt 120～150 order half tones print on described the second full figure layer with GTG site white described transparent heat transfer slurry at least one all over after, moist, prepare the threeth full figure layer transparent with GTG site；H) TPU thermal fusing powder, dry and prepared base material are spread immediately: the TPU thermal fusing powder scattering 80～180 orders in 30 seconds covers on the described 3rd full figure layer transparent with GTG site, at the temperature of 60～80 DEG C after dry 30～60 minutes, remove the TPU thermal fusing powder beyond pattern, with prepared base material；I) hot-pressing transfer printing: be fitted on the material treating thermal transfer by described base material, wherein, hot pressing temperature is 125～160 DEG C, and hot pressing pressure is 4～7 kg/cm, and hot pressing time is 15～30 seconds；J) transfer film is torn after cooling.
The further illustrating of described heat-transferring method as the present invention, preferably, in step a), described thermoplastic polyurethane aqueous dispersion is the thermoplastic polyurethane aqueous dispersion of model U-1257, described water-borne acrylic resin emulsion is model EM-184A water-borne acrylic resin emulsion, described wetting agent is hydroxyethyl urea, described emulsifying agent is the fatty alcohol-polyoxyethylene ether of BASF model AEO-09, described thickening agent is the acrylic polymer suspended substance of BASF model HITPLUS, and described organic silicon defoamer is the organosiloxane complexing agent of model C X-470.
The further illustrating of described heat-transferring method as the present invention, the diamond series pearl essence producing diamond colorful effect is using the synthesis platelet of novel transparent as base material, the high-end effect pigment of special gloss is formed by accurately controlling the thickness of titanium dioxide and other metal-oxide clad, wherein, the diamond unreal gold pearl essence that the present invention uses, the unreal red pearl essence of diamond, the unreal blue pearl essence of diamond, the unreal purple pearl essence of diamond and the unreal green pearl essence of diamond are all purchased in Guangzhou Yue Tai Chemical Co., Ltd., diamond unreal gold pearl essence, the unreal red pearl essence of diamond, the unreal blue pearl essence of diamond, the model of the unreal purple pearl essence of diamond and the unreal green pearl essence of diamond is RS9008 respectively, RS9009, RS9011, RS9010 and RS9012.
The further illustrating of described heat-transferring method as the present invention, it is preferable that in step e), described aluminum argentum powder is the aluminum argentum powder of model PYS8570.
The further illustrating of described heat-transferring method as the present invention, it is preferable that in step f), described titanium dioxide is the titanium dioxide of Du Pont model R706.
The further illustrating of described heat-transferring method as the present invention, it is preferable that in step g), described TPU thermal fusing powder is the thermoplastic resin rubber powder of model AN-H100.
The further illustrating of described heat-transferring method as the present invention, it is preferable that the cool time in step j) is 2～4 hours.
As can be seen here, the heat-transferring method of the present invention only uses UV ink, thermoplastic polyurethane aqueous dispersion and water-borne acrylic resin emulsion, without the existence of noxious volatile organic solvent (VOC), belongs to environmentally friendly articles for use；And UV ink air brushing is on the transfer film being printed on transparent transfer slurry, wink-dry solidifies, and indiffusion, printing precision may be up to 5760dpi.Additionally, diamond fantasy coloured effect Pearl Concentrate and high-resolution jet ink blend so that transfer product is formed with similar diamond flicker radiance and fantasy coloured effect.
Accompanying drawing explanation
Fig. 1 is the process chart of the heat-transferring method of the present invention.
Detailed description of the invention
In order to enable auditor to further appreciate that the structure of the present invention, feature and other purposes, being accompanied by accompanying drawing in conjunction with appended preferred embodiment and describe in detail as follows, this accompanying drawing embodiment described is merely to illustrate technical scheme the non-limiting present invention.
If no special instructions, the sourcing of raw material used herein and model, use the manufacturer of equipment, model and technological requirement as described below respectively:
(1) thermoplastic polyurethane aqueous dispersion, purchases in ShangHai SiSheng polymer Materials Co., Ltd, and model is U-1257；
(2) water-borne acrylic resin emulsion, purchases in Guangzhou star's chemical materials company limited, and model is EM-184A；
(3) UV flat-panel printer, purchases in Shenzhen Shenlongjie Technology Co., Ltd., model A3-3E, printing precision 5760dpi；
(4) diamond unreal gold pearl essence, purchases in Guangzhou Yue Tai Chemical Co., Ltd., and model is RS9008；
(5) the unreal red pearl essence of diamond, purchases in Guangzhou Yue Tai Chemical Co., Ltd., and model is RS9009；
(6) the unreal blue pearl essence of diamond, purchases in Guangzhou Yue Tai Chemical Co., Ltd., and model is RS9011；
(7) the unreal purple pearl essence of diamond, purchases in Guangzhou Yue Tai Chemical Co., Ltd., and model is RS9010；
(8) the unreal green pearl essence of diamond, purchases in Guangzhou Yue Tai Chemical Co., Ltd., and model is RS9012；
(9) aluminum argentum powder, purchases in Boluo County's safety one mountain aluminum products factory, and model is PYS8570；
(10) TPU thermal fusing powder: purchasing in Town in Shanghai labor Industrial Co., Ltd., model is AN-H100.
Embodiment 1
By the acrylic polymer suspended substance of 40 weight portion models to be the thermoplastic polyurethane aqueous dispersion of U-1257,42 weight portion models the be water-borne acrylic resin emulsion of EM-184A, 8 weight portion hydroxyethyl urea, 2 weight portion BASF models to be the fatty alcohol-polyoxyethylene ether of AEO-09,1 weight portion BASF model be HITPLUS and organosiloxane complexing agent mix homogeneously that 0.15 weight portion model is CX-470, make transparent heat transfer slurry.
The half tone adopting 150 orders prints the transparent heat transfer of the 1st step allotment on bright transfer film and starches one time, dry at the temperature of 45 DEG C, prepares the first full figure layer transparent with GTG site.Then, the first full figure layer uses UV flat-panel printer air brushing coloured image, prepares the figure layer with coloured image.
Then, the half tone adopting 120 orders prints by the transparent heat transfer slurry of the 1st step allotment of 85 weight portions on the figure layer with coloured image, the diamond unreal gold pearl essence model of 3 weight portions of 30 microns is RS9008, the unreal red pearl essence model of diamond of 2 weight portions of 50 microns is RS9009, the unreal blue pearl essence model of diamond of 1 weight portion of 80 microns is RS9011, the unreal purple pearl essence model of diamond of 1 weight portion of 100 microns is RS9010, the unreal green pearl essence model of diamond of 2 weight portions of 40 microns is after the diamond illusion-colour Pearl Concentrate made of RS9012 twice, dry at the temperature of 40 DEG C, prepare the first high light figure layer with GTG site diamond fantasy coloured effect.
Then, after adopting silver transfer slurry that the aluminum argentum powder that 130 order half tones print the transparent heat transfer slurry by the 1st step allotment of 80 weight portions and model is PYS8570 70 μm of 12 weight portions on the first high light figure layer with GTG site diamond fantasy coloured effect makes a time, dry at the temperature of 45 DEG C, prepare the second high light figure layer with GTG site silvery white effect.
Then, adopting Du Pont's model that 120 order half tones print the transparent heat transfer slurry by the 1st step allotment of 65 weight portions and 0.36 μm of 25 weight portions on the second high light figure layer with GTG site silvery white effect is after twice of the white transfer slurry made of R706 titanium dioxide, dry at the temperature of 50 DEG C, prepare the second full figure layer with GTG site white.
After again, after adopting the transparent heat transfer that printing the 1st step is allocated on the second full figure layer with GTG site white of 140 order half tones to starch twice, moist, prepare the threeth full figure layer transparent with GTG site.After 25 seconds, scatter the thermoplastic resin rubber powder that model is AN-H100 of 100 orders cover with on transparent the 3rd full figure layer in GTG site, then, at the temperature of 75 DEG C after dry 45 minutes, remove the thermoplastic resin rubber powder beyond pattern, prepare base material.
Finally, by base material at the temperature of 160 DEG C, under the pressure of 4 kg/cm, hot pressing is fitted in material upper 20 second treating thermal transfer, generates transfer film, tears transfer film after cooling down 2 hours, forms thermal transfer product.
The thermal transfer product prepared by the heat-transferring method of the present invention only uses UV ink, thermoplastic polyurethane aqueous dispersion and water-borne acrylic resin emulsion, the existence of organic solvent without noxious volatile (VOC), and UV ink air brushing is on the transfer film being printed on transparent transfer slurry, wink-dry solidifies, indiffusion, printing precision may be up to 5760dpi.Additionally, diamond fantasy coloured effect Pearl Concentrate and high-resolution jet ink blend so that transfer product is formed with similar diamond flicker radiance and fantasy coloured effect.
Embodiment 2
By the acrylic polymer suspended substance of 43 weight portion models to be the thermoplastic polyurethane aqueous dispersion of U-1257,40 weight portion models the be water-borne acrylic resin emulsion of EM-184A, 6 weight portion hydroxyethyl urea, 2.5 weight portion BASF models to be the fatty alcohol-polyoxyethylene ether of AEO-09,2 weight portion BASF models be HITPLUS and organosiloxane complexing agent mix homogeneously that 0.1 weight portion model is CX-470, make transparent heat transfer slurry.
The half tone adopting 180 orders prints the transparent heat transfer of the 1st step allotment on bright transfer film and starches one time, dry at the temperature of 40 DEG C, prepares the first full figure layer transparent with GTG site.Then, the first full figure layer uses UV flat-panel printer air brushing coloured image, prepares the figure layer with coloured image.
Then, the half tone adopting 140 orders prints by the transparent heat transfer slurry of the 1st step allotment of 82 weight portions on the figure layer with coloured image, the diamond unreal gold pearl essence model of 2 weight portions of 50 microns is RS9008, the unreal red pearl essence model of diamond of 1 weight portion of 80 microns is RS9009, the unreal blue pearl essence model of diamond of 1 weight portion of 90 microns is RS9011, the unreal purple pearl essence model of diamond of 1 weight portion of 100 microns is RS9010, the unreal green pearl essence model of diamond of 3 weight portions of 30 microns is after the diamond illusion-colour Pearl Concentrate made of RS9012 twice, dry at the temperature of 50 DEG C, prepare the first high light figure layer with GTG site diamond fantasy coloured effect.
Then, after adopting silver transfer slurry that the aluminum argentum powder that 120 order half tones print the transparent heat transfer slurry by the 1st step allotment of 83 weight portions and model is PYS8570 70 μm of 15 weight portions on the first high light figure layer with GTG site diamond fantasy coloured effect makes a time, dry at the temperature of 40 DEG C, prepare the second high light figure layer with GTG site silvery white effect.
Then, adopting Du Pont's model that 150 order half tones print the transparent heat transfer slurry by the 1st step allotment of 70 weight portions and 0.36 μm of 30 weight portions on the second high light figure layer with GTG site silvery white effect is after the white transfer slurry made of R706 titanium dioxide three times, dry at the temperature of 45 DEG C, prepare the second full figure layer with GTG site white.
After again, after adopting the transparent heat transfer that printing the 1st step is allocated on the second full figure layer with GTG site white of 120 order half tones to starch twice, moist, prepare the threeth full figure layer transparent with GTG site.After 10 seconds, scatter the thermoplastic resin rubber powder that model is AN-H100 of 150 orders cover with on transparent the 3rd full figure layer in GTG site, then, at the temperature of 60 DEG C after dry 30 minutes, remove the thermoplastic resin rubber powder beyond pattern, prepare base material.
Finally, by base material at the temperature of 140 DEG C, under the pressure of 5 kg/cm, hot pressing is fitted in material upper 15 second treating thermal transfer, generates transfer film, tears transfer film after cooling down 3 hours, forms thermal transfer product.
The thermal transfer product prepared by the heat-transferring method of the present invention only uses UV ink, thermoplastic polyurethane aqueous dispersion and water-borne acrylic resin emulsion, the existence of organic solvent without noxious volatile (VOC), and UV ink air brushing is on the transfer film being printed on transparent transfer slurry, wink-dry solidifies, indiffusion, printing precision may be up to 5760dpi.Additionally, diamond fantasy coloured effect Pearl Concentrate and high-resolution jet ink blend so that transfer product is formed with similar diamond flicker radiance and fantasy coloured effect.
Embodiment 3
By the acrylic polymer suspended substance of 41 weight portion models to be the thermoplastic polyurethane aqueous dispersion of U-1257,43 weight portion models the be water-borne acrylic resin emulsion of EM-184A, 9 weight portion hydroxyethyl urea, 3 weight portion BASF models to be the fatty alcohol-polyoxyethylene ether of AEO-09,1.5 weight portion BASF models be HITPLUS and organosiloxane complexing agent mix homogeneously that 0.2 weight portion model is CX-470, make transparent heat transfer slurry.
The half tone adopting 200 orders prints the transparent heat transfer of the 1st step allotment on bright transfer film and starches one time, dry at the temperature of 50 DEG C, prepares the first full figure layer transparent with GTG site.Then, the first full figure layer uses UV flat-panel printer air brushing coloured image, prepares the figure layer with coloured image.
Then, the half tone adopting 150 orders prints by the transparent heat transfer slurry of the 1st step allotment of 80 weight portions on the figure layer with coloured image, the diamond unreal gold pearl essence model of 3 weight portions of 40 microns is RS9008, the unreal red pearl essence model of diamond of 2 weight portions of 60 microns is RS9009, the unreal blue pearl essence model of diamond of 1 weight portion of 80 microns is RS9011, the unreal purple pearl essence model of diamond of 1 weight portion of 90 microns is RS9010, the unreal green pearl essence model of diamond of 2 weight portions of 70 microns is after the diamond illusion-colour Pearl Concentrate made of RS9012 one time, dry at the temperature of 45 DEG C, prepare the first high light figure layer with GTG site diamond fantasy coloured effect.
Then, after adopting twice of silver transfer slurry that the aluminum argentum powder that 150 order half tones print the transparent heat transfer slurry by the 1st step allotment of 85 weight portions and model is PYS8570 70 μm of 18 weight portions on the first high light figure layer with GTG site diamond fantasy coloured effect makes, dry at the temperature of 50 DEG C, prepare the second high light figure layer with GTG site silvery white effect.
Then, adopting Du Pont's model that 140 order half tones print the transparent heat transfer slurry by the 1st step allotment of 75 weight portions and 0.36 μm of 35 weight portions on the second high light figure layer with GTG site silvery white effect is after twice of the white transfer slurry made of R706 titanium dioxide, dry at the temperature of 40 DEG C, prepare the second full figure layer with GTG site white.
After again, after adopting the transparent heat transfer that printing the 1st step is allocated on the second full figure layer with GTG site white of 150 order half tones to starch one time, moist, prepare the threeth full figure layer transparent with GTG site.The thermoplastic resin rubber powder that model is AN-H100 scattering 80 orders after 15 second covers on the 3rd full figure layer that GTG site is transparent, then, at the temperature of 80 DEG C after dry 60 minutes, removes the thermoplastic resin rubber powder beyond pattern, prepares base material.
Finally, by base material at the temperature of 125 DEG C, under the pressure of 6 kg/cm, hot pressing is fitted in material upper 30 second treating thermal transfer, generates transfer film, tears transfer film after cooling down 4 hours, forms thermal transfer product.
The thermal transfer product prepared by the heat-transferring method of the present invention only uses UV ink, thermoplastic polyurethane aqueous dispersion and water-borne acrylic resin emulsion, the existence of organic solvent without noxious volatile (VOC), and UV ink air brushing is on the transfer film being printed on transparent transfer slurry, wink-dry solidifies, indiffusion, printing precision may be up to 5760dpi.Additionally, diamond fantasy coloured effect Pearl Concentrate and high-resolution jet ink blend so that transfer product is formed with similar diamond flicker radiance and fantasy coloured effect.
Embodiment 4
By the acrylic polymer suspended substance of 42 weight portion models to be the thermoplastic polyurethane aqueous dispersion of U-1257,41 weight portion models the be water-borne acrylic resin emulsion of EM-184A, 7 weight portion hydroxyethyl urea, 2.8 weight portion BASF models to be the fatty alcohol-polyoxyethylene ether of AEO-09,1.6 weight portion BASF models be HITPLUS and organosiloxane complexing agent mix homogeneously that 0.18 weight portion model is CX-470, make transparent heat transfer slurry.
The half tone adopting 160 orders prints the transparent heat transfer of the 1st step allotment on bright transfer film and starches one time, dry at the temperature of 48 DEG C, prepares the first full figure layer transparent with GTG site.Then, the first full figure layer uses UV flat-panel printer air brushing coloured image, prepares the figure layer with coloured image.
Then, the half tone adopting 130 orders prints by the transparent heat transfer slurry of the 1st step allotment of 83 weight portions on the figure layer with coloured image, the diamond unreal gold pearl essence model of 2 weight portions of 60 microns is RS9008, the unreal red pearl essence model of diamond of 3 weight portions of 30 microns is RS9009, the unreal blue pearl essence model of diamond of 1 weight portion of 70 microns is RS9011, the unreal purple pearl essence model of diamond of 1 weight portion of 100 microns is RS9010, the unreal green pearl essence model of diamond of 2 weight portions of 50 microns is after the diamond illusion-colour Pearl Concentrate made of RS9012 twice, dry at the temperature of 48 DEG C, prepare the first high light figure layer with GTG site diamond fantasy coloured effect.
Then, after adopting twice of silver transfer slurry that the aluminum argentum powder that model is PYS8570 that 140 order half tones print the transparent heat transfer slurry by the 1st step allotment of 82 weight portions and 70 μm of 16 weight portions on the first high light figure layer with GTG site diamond fantasy coloured effect makes, dry at the temperature of 48 DEG C, prepare the second high light figure layer with GTG site silvery white effect.
Then, adopting Du Pont's model that 120 order half tones print the transparent heat transfer slurry by the 1st step allotment of 72 weight portions and 0.36 μm of 28 weight portions on the second high light figure layer with GTG site silvery white effect is after twice of the white transfer slurry made of R706 titanium dioxide, dry at the temperature of 48 DEG C, prepare the second full figure layer with GTG site white.
After again, after adopting the transparent heat transfer that printing the 1st step is allocated on the second full figure layer with GTG site white of 130 order half tones to starch one time, moist, prepare the threeth full figure layer transparent with GTG site.Scatter the thermoplastic resin rubber powder that model is AN-H100 of 180 orders after 30 seconds to cover with on transparent the 3rd full figure layer in GTG site, then, at the temperature of 70 DEG C after dry 50 minutes, remove the thermoplastic resin rubber powder beyond pattern, prepare base material.
Finally, by base material at the temperature of 150 DEG C, under the pressure of 7 kg/cm, hot pressing is fitted in material upper 15 second treating thermal transfer, generates transfer film, tears transfer film after cooling down 3 hours, forms thermal transfer product.
The thermal transfer product prepared by the heat-transferring method of the present invention only uses UV ink, thermoplastic polyurethane aqueous dispersion and water-borne acrylic resin emulsion, the existence of organic solvent without noxious volatile (VOC), and UV ink air brushing is on the transfer film being printed on transparent transfer slurry, wink-dry solidifies, indiffusion, printing precision may be up to 5760dpi.Additionally, diamond fantasy coloured effect Pearl Concentrate and high-resolution jet ink blend so that transfer product is formed with similar diamond flicker radiance and fantasy coloured effect.
Embodiment 5
By the acrylic polymer suspended substance of 41 weight portion models to be the thermoplastic polyurethane aqueous dispersion of U-1257,43 weight portion models the be water-borne acrylic resin emulsion of EM-184A, 9 weight portion hydroxyethyl urea, 3 weight portion BASF models to be the fatty alcohol-polyoxyethylene ether of AEO-09,1.5 weight portion BASF models be HITPLUS and organosiloxane complexing agent mix homogeneously that 0.2 weight portion model is CX-470, make transparent heat transfer slurry.
The half tone adopting 150 orders prints the transparent heat transfer of the 1st step allotment on bright transfer film and starches one time, dry at the temperature of 45 DEG C, prepares the first full figure layer transparent with GTG site.Then, the first full figure layer uses UV flat-panel printer air brushing coloured image, prepares the figure layer with coloured image.
Then, the half tone adopting 120 orders prints by the transparent heat transfer slurry of the 1st step allotment of 85 weight portions on the figure layer with coloured image, the diamond unreal gold pearl essence model of 3 weight portions of 30 microns is RS9008, the unreal red pearl essence model of diamond of 1 weight portion of 60 microns is RS9009, the unreal blue pearl essence model of diamond of 1 weight portion of 100 microns is RS9011, the unreal purple pearl essence model of diamond of 2 weight portions of 70 microns is RS9010, the unreal green pearl essence model of diamond of 3 weight portions of 50 microns is after the diamond illusion-colour Pearl Concentrate made of RS9012 three times, dry at the temperature of 40 DEG C, prepare the first high light figure layer with GTG site diamond fantasy coloured effect.
Then, after adopting twice of silver transfer slurry that the aluminum argentum powder that model is PYS8570 that 120 order half tones print the transparent heat transfer slurry by the 1st step allotment of 80 weight portions and 70 μm of 12 weight portions on the first high light figure layer with GTG site diamond fantasy coloured effect makes, dry at the temperature of 40 DEG C, prepare the second high light figure layer with GTG site silvery white effect.
Then, adopting Du Pont's model that 120 order half tones print the transparent heat transfer slurry by the 1st step allotment of 65 weight portions and 0.36 μm of 25 weight portions on the second high light figure layer with GTG site silvery white effect is after twice of the white transfer slurry made of R706 titanium dioxide, dry at the temperature of 50 DEG C, prepare the second full figure layer with GTG site white.
After again, after adopting the transparent heat transfer that printing the 1st step is allocated on the second full figure layer with GTG site white of 120 order half tones to starch one time, moist, prepare the threeth full figure layer transparent with GTG site.After 20 seconds, scatter the thermoplastic resin rubber powder that model is AN-H100 of 180 orders cover with on transparent the 3rd full figure layer in GTG site, then, at the temperature of 60 DEG C after dry 30 minutes, remove the thermoplastic resin rubber powder beyond pattern, prepare base material.
Finally, by base material at the temperature of 160 DEG C, under the pressure of 4 kg/cm, hot pressing is fitted in material upper 30 second treating thermal transfer, generates transfer film, tears transfer film after cooling down 2 hours, forms thermal transfer product.
The thermal transfer product prepared by the heat-transferring method of the present invention only uses UV ink, thermoplastic polyurethane aqueous dispersion and water-borne acrylic resin emulsion, the existence of organic solvent without noxious volatile (VOC), and UV ink air brushing is on the transfer film being printed on transparent transfer slurry, wink-dry solidifies, indiffusion, resolution may be up to 5760dpi.Additionally, diamond fantasy coloured effect Pearl Concentrate and high-resolution jet ink blend so that transfer product is formed with similar diamond flicker radiance and fantasy coloured effect.
It is to be understood that, foregoing invention content and detailed description of the invention are intended to prove the practical application of technical scheme provided by the present invention to should not be construed as limiting the scope of the present invention.Those skilled in the art are in the spirit and principle of the present invention, when doing various amendment, equivalent replacement or improve.Protection scope of the present invention is as the criterion with appended claims.
Claims (7)
1. a heat-transferring method with diamond fantasy coloured effect, it is characterised in that described heat-transferring method comprises the following steps:
A) allotment transparent heat transfer slurry: described transparent heat transfer slurry includes thermoplastic polyurethane aqueous dispersion 40～43 weight portion, water-borne acrylic resin emulsion 40～43 weight portion, wetting agent 6～9 weight portion, emulsifying agent 2～3 weight portion, thickening agent 1～2 weight portion and defoamer 0.1～0.2 weight portion；
B) the first full figure layer transparent with GTG site is printed: adopt the half tone of 150～200 orders to print described transparent heat transfer slurry on bright transfer film one time, dry at the temperature of 40～50 DEG C, the prepared first full figure layer transparent with GTG site；
C) printer air brushing is with the figure layer of coloured image: uses UV flat-panel printer air brushing coloured image on described first full figure layer, prepares the figure layer with coloured image；
D) printing is with the first high light figure layer of GTG site diamond fantasy coloured effect: after adopting the half tone of 120～150 orders print at least one time of diamond fantasy coloured effect Pearl Concentrate on the described figure layer with coloured image, dry at the temperature of 40～50 DEG C, prepare the first high light figure layer of diamond fantasy coloured effect, wherein, described diamond illusion-colour Pearl Concentrate includes described transparent heat transfer slurry 80～85 weight portion, the diamond unreal gold pearl essence of 1～3 weight portion of 30～100 microns, the unreal red pearl essence of diamond of 1～3 weight portion of 30～100 microns, the unreal blue pearl essence of diamond of 1～3 weight portion of 30～100 microns, the unreal purple pearl essence of diamond of 1～3 weight portion of 30～100 microns, the unreal green pearl essence of diamond of 1～3 weight portion of 30～100 microns；
E) printing is with the second high light figure layer of GTG site silvery white effect: after adopting 120～150 order half tones print at least one time of silver transfer slurry on described the first high light figure layer with GTG site diamond fantasy coloured effect, dry at the temperature of 40～50 DEG C, preparing the second high light figure layer with GTG site silver effect, described silver transfer slurry includes aluminum argentum powder 12～18 weight portion of described transparent heat transfer slurry 80～85 weight portion and 70 μm；
F) printing is with the second full figure layer of GTG site white: adopt 120～150 order half tones print on described the second high light figure layer with GTG site silvery white effect white transfer slurry at least one time after, dry at the temperature of 40～50 DEG C, preparing the second full figure layer with GTG site white, described white transfer slurry includes titanium dioxide 25～35 weight portion of at least one transparent heat transfer slurry 65～75 weight portion and 0.36 μm；
G) printing is with transparent the 3rd full figure layer in GTG site: adopt 120～150 order half tones print on described the second full figure layer with GTG site white described transparent heat transfer slurry at least one all over after, moist, prepare the threeth full figure layer transparent with GTG site；
H) TPU thermal fusing powder, dry and prepared base material are spread immediately: the TPU thermal fusing powder scattering 80～180 orders in 30 seconds covers on the described 3rd full figure layer transparent with GTG site, at the temperature of 60～80 DEG C after dry 30～60 minutes, remove the TPU thermal fusing powder beyond pattern, with prepared base material；
I) hot-pressing transfer printing: be fitted on the material treating thermal transfer by described base material, wherein, hot pressing temperature is 125～160 DEG C, and hot pressing pressure is 4～7 kg/cm, and hot pressing time is 15～30 seconds；
J) transfer film is torn after cooling.
2. heat-transferring method as claimed in claim 1, it is characterized in that, in step a), described thermoplastic polyurethane aqueous dispersion is the thermoplastic polyurethane aqueous dispersion of model U-1257, described water-borne acrylic resin emulsion is model EM-184A water-borne acrylic resin emulsion, described wetting agent is hydroxyethyl urea, described emulsifying agent is the fatty alcohol-polyoxyethylene ether of BASF model AEO-09, described thickening agent is the acrylic polymer suspended substance of BASF model HITPLUS, and described organic silicon defoamer is the organosiloxane complexing agent of model C X-470.
3. heat-transferring method as claimed in claim 1, it is characterized in that, in step d), described diamond unreal gold pearl essence is the diamond unreal gold pearl essence of model RS9008, the unreal red pearl essence of described diamond is the unreal red pearl essence of diamond of model RS9009, the unreal blue pearl essence of described diamond is the unreal blue pearl essence of diamond of model RS9011, and the unreal purple pearl essence of described diamond is the unreal purple pearl essence of diamond of model RS9010, and the unreal green pearl essence of described diamond is the unreal green pearl essence of diamond of model RS9012.
4. heat-transferring method as claimed in claim 1, it is characterised in that in step e), described aluminum argentum powder is the aluminum argentum powder of model PYS8570.
5. heat-transferring method as claimed in claim 1, it is characterised in that in step f), described titanium dioxide is the titanium dioxide of Du Pont model R706.
6. heat-transferring method as claimed in claim 1, it is characterised in that in step g), described TPU thermal fusing powder is the thermoplastic resin rubber powder of model AN-H100.
7. heat-transferring method as claimed in claim 1, it is characterised in that the cool time in step j) is 2～4 hours.
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