CN105799350B - A kind of heat-transferring method with diamond fantasy coloured effect - Google Patents

A kind of heat-transferring method with diamond fantasy coloured effect Download PDF

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Publication number
CN105799350B
CN105799350B CN201410834933.0A CN201410834933A CN105799350B CN 105799350 B CN105799350 B CN 105799350B CN 201410834933 A CN201410834933 A CN 201410834933A CN 105799350 B CN105799350 B CN 105799350B
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diamond
layer
weight
parts
unreal
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CN201410834933.0A
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CN105799350A (en
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刘奎
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东莞市艺概龙数码服装有限公司
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Abstract

The present invention provides a kind of heat-transferring method with diamond fantasy coloured effect, the heat-transferring method include allocating transparent thermal transfer slurry, printing with the first transparent full figure layer of GTG site, figure layer of the printer air brushing with coloured image, the first bloom figure layer of printing, the second bloom figure layer of printing, the second full figure layer of printing, the 3rd full figure layer of printing, spread TPU thermal fusing powders immediately, dry and base material be made, hot-pressing transfer printing and cooling dyestripping.UV inks and thermoplastic polyurethane aqueous dispersion and water-based acrylic resin emulsion is used only in the heat-transferring method of the present invention, presence without noxious volatile organic solvent, the air brushing of UV inks is on the transfer film of transparent transfer slurry is printed on, wink-dry solidifies, indiffusion, high resolution, diamond fantasy coloured effect pearlite slurry and high-resolution jet ink blend so that transfer product is formed with similar diamond flicker radiance and fantasy coloured effect.

Description

A kind of heat-transferring method with diamond fantasy coloured effect

Technical field

The present invention relates to a kind of heat-transferring method, specifically, is related to a kind of UV inks numerial code spray drawing combination screen painting The heat-transferring method with diamond fantasy coloured effect

Background technology

Hot-pressing transfer printing is also known as xylopyrography, is a kind of the word being printed on heat-transferring printing paper or plastic foil or pattern to be passed through into heating The mode of pressurization is transferred to the method on fabric or leather, is characterized in that transferred image is bright in luster, and level enriches, existing heat Pressure printing transferring method be present, as the coloured image of intaglio plate, relief printing plate, soft version and screen painting has obvious dot matrix, Printing precision is in 300~500dpi;In addition, the thermal dye sublimation transfer printing of numerial code spray drawing can only be confined to terylene or the coating on fabric Processing, it is also possible to diffusion blooming occurs.

Chinese utility model patent CN201120488582 discloses a kind of thermal transfer mark, but the thermal transfer target structure Simply, it is solvent-based inks without clearly digital coating without special-effect, or Weak solvent ink either UV inks.

The content of the invention

In place of solving above-mentioned the deficiencies in the prior art, it is an object of the invention to provide a kind of heat-transferring method, leads to Cross this method so that UV ink numerial code spray drawing combination screen paintings, its printing precision may be up to 5760dpi, and UV ink numbers The precise image of code air brushing merges with diamond illusion-colour pearlite slurry, creates the thermally transferred pattern of diamond fantasy coloured effect.

Therefore, the present invention provides a kind of heat-transferring method with diamond fantasy coloured effect, the heat-transferring method including with Lower step:A) transparent thermal transfer slurry is allocated:The transparent thermal transfer slurry includes the weight of thermoplastic polyurethane aqueous dispersion 40~43 Part, the parts by weight of water-based acrylic resin emulsion 40~43, the parts by weight of NMF 6~9, the parts by weight of emulsifying agent 2~3, thickener 1~ 2 parts by weight and the parts by weight of organic silicon defoamer 0.1~0.2;B) printing is with the first transparent full figure layer of GTG site:Using The half tone of 150~200 mesh prints the transparent thermal transfer on bright face transfer film and starched one time, is done at a temperature of 40~50 DEG C It is dry, it is made with the first transparent full figure layer of GTG site;C) printer air brushing carries the figure layer of coloured image:Described first UV flat-panel printer air brushing coloured images are used on full figure layer, the figure layer with coloured image is made;D) printing carries GTG net First bloom figure layer of point diamond fantasy coloured effect:Printed using the half tone of 120~150 mesh in the figure layer with coloured image After brush diamond illusion-colour pearlite slurry at least one time, dried at a temperature of 40~50 DEG C, be made and imitated with GTG site diamond illusion-colour The first bloom figure layer of fruit, wherein, the diamond illusion-colour pearlite slurry includes the transparent thermal transfer and starches 80~85 parts by weight, 30~ The unreal golden pearl essence of diamond of 100 microns of 1~3 parts by weight, the unreal red pearl essence of diamond of 30~100 microns of 1~3 parts by weight, The unreal blue pearl essence of diamond of 30~100 microns of 1~3 parts by weight, the unreal Japanses beauty-berry light of diamond of 30~100 microns of 1~3 parts by weight Powder, the unreal green pearl essence of diamond of 30~100 microns of 1~3 parts by weight;E) printing second with GTG site silvery white effect is high Light figure layer:Printed in vain in the first bloom figure layer with GTG site diamond fantasy coloured effect using 120~150 mesh half tones After silver transfer slurry at least one time, dried at a temperature of 40~50 DEG C, the second bloom with GTG site silvery white effect is made Figure layer, the silver transfer slurry include the transparent thermal transfer and starch 80~85 parts by weight and 70 μm of the weight of aluminium silver powder 12~18 Part;F) second full figure layer of the printing with GTG site white:Using 120~150 mesh half tones described with GTG site silver After the transfer of printing white is starched at least one time in second bloom figure layer of white effect, dried at a temperature of 40~50 DEG C, obtained band Have the second full figure layer of GTG site white, the white transfer slurry include at least one transparent thermal transfer starch 65~75 parts by weight and 0.36 μm of the parts by weight of titanium dioxide 25~35;G) printing is with the 3rd transparent full figure layer of GTG site:Using 120~150 mesh Half tone is printed on the second full figure layer with GTG site white after the transparent thermal transfer starches at least one time, is not done It is dry, it is made with the 3rd transparent full figure layer of GTG site;H) TPU thermal fusing powders, drying are spread immediately and base material is made:In 30 seconds The TPU thermal fusing powders for scattering 80~180 mesh are covered on the 3rd full figure layer transparent with GTG site, at 60~80 DEG C At a temperature of dry 30~60 minutes after, remove pattern beyond TPU thermal fusing powders, be made base material;I) hot-pressing transfer printing:By the base Material is fitted on the material for treating thermal transfer, wherein, hot pressing temperature is 125~160 DEG C, and hot pressing pressure is 4~7 kilograms/square li Rice, hot pressing time are 15~30 seconds;J) transfer film is torn after cooling down.

Further explanation as the heat-transferring method of the present invention, it is preferable that in step a), the thermoplastic poly ammonia Ester aqueous dispersion is model U-1257 thermoplastic polyurethane aqueous dispersion, and the water-based acrylic resin emulsion is model EM- 184A water-based acrylic resin emulsions, the NMF are ethoxy urea, and the emulsifying agent is BASF model AEO-09's AEO, the thickener is BASF model HIT PLUS acrylic polymer suspended substance, described to have Machine silicon defoaming agent is model C X-470 organosiloxane complexing agent.

As the further explanation of the heat-transferring method of the present invention, the diamond series pearly-lustre of generation diamond colorful effect Powder is using the synthesis platelet of novel transparent as base material, by accurately controlling titanium dioxide and other metal oxide clads Thickness forms the high-end effect pigment of special gloss, wherein, the unreal golden pearl essence of diamond, the unreal red pearly-lustre of diamond that the present invention uses The unreal blue pearl essence of powder, diamond, the unreal purple pearl essence of diamond and the unreal green pearl essence of diamond are purchased in Guangzhou Yue Tai Chemical Co., Ltd.s, The unreal golden pearl essence of diamond, the unreal red pearl essence of diamond, the unreal blue pearl essence of diamond, the unreal purple pearl essence of diamond and the unreal green pearl essence of diamond Model is RS9008, RS9009, RS9011, RS9010 and RS9012 respectively.

Further explanation as the heat-transferring method of the present invention, it is preferable that in step e), the aluminium silver powder is type Number PYS8570 aluminium silver powder.

Further explanation as the heat-transferring method of the present invention, it is preferable that in step f), the titanium dioxide is Du Nation model R706 titanium dioxide.

Further explanation as the heat-transferring method of the present invention, it is preferable that in step h), the TPU thermal fusing powders For model AN-H100 thermoplastic resin rubber powder.

Further explanation as the heat-transferring method of the present invention, it is preferable that cool time in step j) for 2~ 4 hours.

As can be seen here, UV inks, thermoplastic polyurethane aqueous dispersion and water-based third is used only in heat-transferring method of the invention Olefin(e) acid resin emulsion, the presence of no noxious volatile organic solvent (VOC), belongs to environmentally friendly articles for use;And UV inks spray It is painted on and is printed on the transfer film of transparent transfer slurry, wink-dry solidification, indiffusion, printing precision may be up to 5760dpi.In addition, Diamond fantasy coloured effect pearlite slurry and high-resolution jet ink blend so that transfer product is formed with similar diamond flicker radiance And fantasy coloured effect.

Brief description of the drawings

Fig. 1 is the process chart of the heat-transferring method of the present invention.

Embodiment

It is attached in conjunction with appended preferred embodiment in order to further appreciate that structure, feature and the other purposes of the present invention As follows with accompanying drawing detailed description, this accompanying drawing embodiment described is merely to illustrate technical scheme, and non-limiting Invention.

Unless otherwise specified, the sourcing and model of raw material used herein, uses the manufacturer of equipment, model and work Skill requires as described below respectively:

(1) thermoplastic polyurethane aqueous dispersion, purchase in ShangHai SiSheng polymer Materials Co., Ltd, model U- 1257;

(2) water-based acrylic resin emulsion, purchase in Guangzhou star's chemical materials Co., Ltd, model EM-184A;

(3) UV flat-panel printers, purchase in Shenzhen Shenlongjie Technology Co., Ltd., model A3-3E, printing precision 5760dpi;

(4) the unreal golden pearl essence of diamond, purchase in Guangzhou Yue Tai Chemical Co., Ltd.s, model RS9008;

(5) the unreal red pearl essence of diamond, purchase in Guangzhou Yue Tai Chemical Co., Ltd.s, model RS9009;

(6) the unreal blue pearl essence of diamond, purchase in Guangzhou Yue Tai Chemical Co., Ltd.s, model RS9011;

(7) the unreal purple pearl essence of diamond, purchase in Guangzhou Yue Tai Chemical Co., Ltd.s, model RS9010;

(8) the unreal green pearl essence of diamond, purchase in Guangzhou Yue Tai Chemical Co., Ltd.s, model RS9012;

(9) aluminium silver powder, purchase in the mountain aluminum products factory of Boluo County's safety one, model PYS8570;

(10) TPU thermal fusing powders:Purchase in Town in Shanghai labor Industrial Co., Ltd., model AN-H100.

Embodiment 1

By 40 parts by weight model U-1257 thermoplastic polyurethane aqueous dispersion, 42 parts by weight model EM-184A Water-based acrylic resin emulsion, 8 parts by weight ethoxy urea, 2 parts by weight BASF model AEO-09 fatty alcohol polyoxy second The acrylic polymer suspended substance and 0.15 parts by weight model CX- of alkene ether, 1 parts by weight BASF model HIT PLUS 470 organosiloxane complexing agent is well mixed, and transparent thermal transfer slurry is made.

The transparent thermal transfer that the allotment of the 1st step is printed on bright face transfer film using the half tone of 150 mesh is starched one time, at 45 DEG C At a temperature of dry, be made with transparent the first full figure layer in GTG site.Then, beaten on the first full figure layer using UV flat boards Print machine air brushing coloured image, the figure layer with coloured image is made.

Then, the 1st step allotment by 85 parts by weight is printed in the figure layer with coloured image using the half tone of 120 mesh Transparent thermal transfer slurry, 30 microns of the unreal golden pearl essence model RS9008 of diamond of 3 parts by weight, 50 microns of 2 parts by weight It is the unreal red pearl essence model RS9009 of diamond, the unreal blue pearl essence model RS9011 of the diamond of 80 microns of 1 parts by weight, 100 micro- The unreal purple pearl essence model RS9010 of diamond of 1 parts by weight of rice, the unreal green pearl essence model of the diamond of 40 microns of 2 parts by weight After twice of diamond illusion-colour pearlite slurry made of RS9012, dried at a temperature of 40 DEG C, be made and carry GTG site diamond illusion-colour First bloom figure layer of effect.

Then, printed using 130 mesh half tones in the first bloom figure layer with GTG site diamond fantasy coloured effect by 80 The transparent thermal transfer slurry of the 1st step allotment of parts by weight and the model PYS8570 of 12 parts by weight 70 μm of aluminium silver powder are made Silver transfer slurry one time after, at a temperature of 45 DEG C dry, be made with GTG site silvery white effect the second bloom figure layer.

Then, printed using 120 mesh half tones in the second bloom figure layer with GTG site silvery white effect by 65 weight It is white made of the transparent thermal transfer slurry of the 1st step allotment of part and 0.36 μm of Du Pont's model R706 titanium dioxides of 25 parts by weight After twice of color transfer slurry, dried at a temperature of 50 DEG C, the second full figure layer with GTG site white is made.

After again, the saturating of the 1st step allotment is printed on the second full figure layer with GTG site white using 140 mesh half tones It is moist after bright thermal transfer is starched twice, it is made with the 3rd transparent full figure layer of GTG site.100 purposes were scattered after 25 seconds Model AN-H100 thermoplastic resin rubber powder is covered with the 3rd transparent full figure layer of GTG site, then, at 75 DEG C At a temperature of dry 45 minutes after, remove pattern beyond thermoplastic resin rubber powder, be made base material.

Finally, hot pressing, which is fitted in, by base material at a temperature of 160 DEG C, under the pressure of 4 kg/cms treats thermal transfer 20 seconds on material, transfer film is generated, transfer film is torn after cooling down 2 hours, forms thermal transfer product.

UV inks are used only in the thermal transfer product prepared by the heat-transferring method of the present invention, thermoplastic polyurethane moisture dissipates Body and water-based acrylic resin emulsion, the presence of no noxious volatile organic solvent (VOC), and also the air brushing of UV inks is being printed on On the transfer film of bright transfer slurry, wink-dry solidification, indiffusion, printing precision may be up to 5760dpi.In addition, diamond illusion-colour is imitated Fruit pearlite slurry and high-resolution jet ink blend so that transfer product is formed with similar diamond flicker radiance and illusion-colour effect Fruit.

Embodiment 2

By 43 parts by weight model U-1257 thermoplastic polyurethane aqueous dispersion, 40 parts by weight model EM-184A Water-based acrylic resin emulsion, 6 parts by weight ethoxy urea, 2.5 parts by weight BASF model AEO-09 fatty alcohol polyoxy The acrylic polymer suspended substance and 0.1 parts by weight model CX- of vinethene, 2 parts by weight BASF model HIT PLUS 470 organosiloxane complexing agent is well mixed, and transparent thermal transfer slurry is made.

The transparent thermal transfer that the allotment of the 1st step is printed on bright face transfer film using the half tone of 180 mesh is starched one time, at 40 DEG C At a temperature of dry, be made with transparent the first full figure layer in GTG site.Then, beaten on the first full figure layer using UV flat boards Print machine air brushing coloured image, the figure layer with coloured image is made.

Then, the 1st step allotment by 82 parts by weight is printed in the figure layer with coloured image using the half tone of 140 mesh Transparent thermal transfer slurry, 50 microns of the unreal golden pearl essence model RS9008 of diamond of 2 parts by weight, 80 microns of 1 parts by weight It is the unreal red pearl essence model RS9009 of diamond, the unreal blue pearl essence model RS9011 of the diamond of 90 microns of 1 parts by weight, 100 micro- The unreal purple pearl essence model RS9010 of diamond of 1 parts by weight of rice, the unreal green pearl essence model of the diamond of 30 microns of 3 parts by weight After twice of diamond illusion-colour pearlite slurry made of RS9012, dried at a temperature of 50 DEG C, be made and carry GTG site diamond illusion-colour First bloom figure layer of effect.

Then, printed using 120 mesh half tones in the first bloom figure layer with GTG site diamond fantasy coloured effect by 83 The transparent thermal transfer slurry of the 1st step allotment of parts by weight and the model PYS8570 of 15 parts by weight 70 μm of aluminium silver powder are made Silver transfer slurry one time after, at a temperature of 40 DEG C dry, be made with GTG site silvery white effect the second bloom figure layer.

Then, printed using 150 mesh half tones in the second bloom figure layer with GTG site silvery white effect by 70 weight It is white made of the transparent thermal transfer slurry of the 1st step allotment of part and 0.36 μm of Du Pont's model R706 titanium dioxides of 30 parts by weight After color transfer slurry three times, dried at a temperature of 45 DEG C, the second full figure layer with GTG site white is made.

After again, the saturating of the 1st step allotment is printed on the second full figure layer with GTG site white using 120 mesh half tones It is moist after bright thermal transfer is starched twice, it is made with the 3rd transparent full figure layer of GTG site.150 purposes were scattered after 10 seconds Model AN-H100 thermoplastic resin rubber powder is covered with the 3rd transparent full figure layer of GTG site, then, at 60 DEG C At a temperature of dry 30 minutes after, remove pattern beyond thermoplastic resin rubber powder, be made base material.

Finally, hot pressing, which is fitted in, by base material at a temperature of 140 DEG C, under the pressure of 5 kg/cms treats thermal transfer 15 seconds on material, transfer film is generated, transfer film is torn after cooling down 3 hours, forms thermal transfer product.

UV inks are used only in the thermal transfer product prepared by the heat-transferring method of the present invention, thermoplastic polyurethane moisture dissipates Body and water-based acrylic resin emulsion, the presence of no noxious volatile organic solvent (VOC), and also the air brushing of UV inks is being printed on On the transfer film of bright transfer slurry, wink-dry solidification, indiffusion, printing precision may be up to 5760dpi.In addition, diamond illusion-colour is imitated Fruit pearlite slurry and high-resolution jet ink blend so that transfer product is formed with similar diamond flicker radiance and illusion-colour effect Fruit.

Embodiment 3

By 41 parts by weight model U-1257 thermoplastic polyurethane aqueous dispersion, 43 parts by weight model EM-184A Water-based acrylic resin emulsion, 9 parts by weight ethoxy urea, 3 parts by weight BASF model AEO-09 fatty alcohol polyoxy second The acrylic polymer suspended substance and 0.2 parts by weight model CX- of alkene ether, 1.5 parts by weight BASF model HIT PLUS 470 organosiloxane complexing agent is well mixed, and transparent thermal transfer slurry is made.

The transparent thermal transfer that the allotment of the 1st step is printed on bright face transfer film using the half tone of 200 mesh is starched one time, at 50 DEG C At a temperature of dry, be made with transparent the first full figure layer in GTG site.Then, beaten on the first full figure layer using UV flat boards Print machine air brushing coloured image, the figure layer with coloured image is made.

Then, the 1st step allotment by 80 parts by weight is printed in the figure layer with coloured image using the half tone of 150 mesh Transparent thermal transfer slurry, 40 microns of the unreal golden pearl essence model RS9008 of diamond of 3 parts by weight, 60 microns of 2 parts by weight The unreal red pearl essence model RS9009 of diamond, the unreal blue pearl essence model RS9011 of the diamond of 80 microns of 1 parts by weight, 90 microns The unreal purple pearl essence model RS9010 of diamond of 1 parts by weight, the unreal green pearl essence model of the diamond of 70 microns of 2 parts by weight After diamond illusion-colour pearlite slurry made of RS9012 one time, dried at a temperature of 45 DEG C, be made and carry GTG site diamond illusion-colour First bloom figure layer of effect.

Then, printed using 150 mesh half tones in the first bloom figure layer with GTG site diamond fantasy coloured effect by 85 The transparent thermal transfer slurry of the 1st step allotment of parts by weight and the model PYS8570 of 18 parts by weight 70 μm of aluminium silver powder are made Silver transfer slurry twice after, at a temperature of 50 DEG C dry, be made with GTG site silvery white effect the second bloom figure layer.

Then, printed using 140 mesh half tones in the second bloom figure layer with GTG site silvery white effect by 75 weight It is white made of the transparent thermal transfer slurry of the 1st step allotment of part and 0.36 μm of Du Pont's model R706 titanium dioxides of 35 parts by weight After twice of color transfer slurry, dried at a temperature of 40 DEG C, the second full figure layer with GTG site white is made.

After again, the saturating of the 1st step allotment is printed on the second full figure layer with GTG site white using 150 mesh half tones It is moist after bright thermal transfer is starched one time, it is made with the 3rd transparent full figure layer of GTG site.The type of 80 mesh is scattered after 15 second Number covered for AN-H100 thermoplastic resin rubber powder on the 3rd transparent full figure floor of GTG site, then, in 80 DEG C of temperature After lower drying 60 minutes, the thermoplastic resin rubber powder beyond pattern is removed, base material is made.

Finally, hot pressing, which is fitted in, by base material at a temperature of 125 DEG C, under the pressure of 6 kg/cms treats thermal transfer 30 seconds on material, transfer film is generated, transfer film is torn after cooling down 4 hours, forms thermal transfer product.

UV inks are used only in the thermal transfer product prepared by the heat-transferring method of the present invention, thermoplastic polyurethane moisture dissipates Body and water-based acrylic resin emulsion, the presence of no noxious volatile organic solvent (VOC), and also the air brushing of UV inks is being printed on On the transfer film of bright transfer slurry, wink-dry solidification, indiffusion, printing precision may be up to 5760dpi.In addition, diamond illusion-colour is imitated Fruit pearlite slurry and high-resolution jet ink blend so that transfer product is formed with similar diamond flicker radiance and illusion-colour effect Fruit.

Embodiment 4

By 42 parts by weight model U-1257 thermoplastic polyurethane aqueous dispersion, 41 parts by weight model EM-184A Water-based acrylic resin emulsion, 7 parts by weight ethoxy urea, 2.8 parts by weight BASF model AEO-09 fatty alcohol polyoxy The acrylic polymer suspended substance and 0.18 parts by weight model of vinethene, 1.6 parts by weight BASF model HIT PLUS CX-470 organosiloxane complexing agent is well mixed, and transparent thermal transfer slurry is made.

The transparent thermal transfer that the allotment of the 1st step is printed on bright face transfer film using the half tone of 160 mesh is starched one time, at 48 DEG C At a temperature of dry, be made with transparent the first full figure layer in GTG site.Then, beaten on the first full figure layer using UV flat boards Print machine air brushing coloured image, the figure layer with coloured image is made.

Then, the 1st step allotment by 83 parts by weight is printed in the figure layer with coloured image using the half tone of 130 mesh Transparent thermal transfer slurry, 60 microns of the unreal golden pearl essence model RS9008 of diamond of 2 parts by weight, 30 microns of 3 parts by weight It is the unreal red pearl essence model RS9009 of diamond, the unreal blue pearl essence model RS9011 of the diamond of 70 microns of 1 parts by weight, 100 micro- The unreal purple pearl essence model RS9010 of diamond of 1 parts by weight of rice, the unreal green pearl essence model of the diamond of 50 microns of 2 parts by weight After twice of diamond illusion-colour pearlite slurry made of RS9012, dried at a temperature of 48 DEG C, be made and carry GTG site diamond illusion-colour First bloom figure layer of effect.

Then, printed using 140 mesh half tones in the first bloom figure layer with GTG site diamond fantasy coloured effect by 82 The transparent thermal transfer slurry of the 1st step allotment of parts by weight and 70 μm of model PYS8570 of 16 parts by weight aluminium silver powder are made Silver transfer slurry twice after, at a temperature of 48 DEG C dry, be made with GTG site silvery white effect the second bloom figure layer.

Then, printed using 120 mesh half tones in the second bloom figure layer with GTG site silvery white effect by 72 weight It is white made of the transparent thermal transfer slurry of the 1st step allotment of part and 0.36 μm of Du Pont's model R706 titanium dioxides of 28 parts by weight After twice of color transfer slurry, dried at a temperature of 48 DEG C, the second full figure layer with GTG site white is made.

After again, the saturating of the 1st step allotment is printed on the second full figure layer with GTG site white using 130 mesh half tones It is moist after bright thermal transfer is starched one time, it is made with the 3rd transparent full figure layer of GTG site.180 purposes are scattered after 30 seconds Model AN-H100 thermoplastic resin rubber powder is covered with the 3rd transparent full figure layer of GTG site, then, at 70 DEG C At a temperature of dry 50 minutes after, remove pattern beyond thermoplastic resin rubber powder, be made base material.

Finally, hot pressing, which is fitted in, by base material at a temperature of 150 DEG C, under the pressure of 7 kg/cms treats thermal transfer 15 seconds on material, transfer film is generated, transfer film is torn after cooling down 3 hours, forms thermal transfer product.

UV inks are used only in the thermal transfer product prepared by the heat-transferring method of the present invention, thermoplastic polyurethane moisture dissipates Body and water-based acrylic resin emulsion, the presence of no noxious volatile organic solvent (VOC), and also the air brushing of UV inks is being printed on On the transfer film of bright transfer slurry, wink-dry solidification, indiffusion, printing precision may be up to 5760dpi.In addition, diamond illusion-colour is imitated Fruit pearlite slurry and high-resolution jet ink blend so that transfer product is formed with similar diamond flicker radiance and illusion-colour effect Fruit.

Embodiment 5

By 41 parts by weight model U-1257 thermoplastic polyurethane aqueous dispersion, 43 parts by weight model EM-184A Water-based acrylic resin emulsion, 9 parts by weight ethoxy urea, 3 parts by weight BASF model AEO-09 fatty alcohol polyoxy second The acrylic polymer suspended substance and 0.2 parts by weight model CX- of alkene ether, 1.5 parts by weight BASF model HIT PLUS 470 organosiloxane complexing agent is well mixed, and transparent thermal transfer slurry is made.

The transparent thermal transfer that the allotment of the 1st step is printed on bright face transfer film using the half tone of 150 mesh is starched one time, at 45 DEG C At a temperature of dry, be made with transparent the first full figure layer in GTG site.Then, beaten on the first full figure layer using UV flat boards Print machine air brushing coloured image, the figure layer with coloured image is made.

Then, the 1st step allotment by 85 parts by weight is printed in the figure layer with coloured image using the half tone of 120 mesh Transparent thermal transfer slurry, 30 microns of the unreal golden pearl essence model RS9008 of diamond of 3 parts by weight, 60 microns of 1 parts by weight It is the unreal red pearl essence model RS9009 of diamond, the unreal blue pearl essence model RS9011 of the diamond of 100 microns of 1 parts by weight, 70 micro- The unreal purple pearl essence model RS9010 of diamond of 2 parts by weight of rice, the unreal green pearl essence model of the diamond of 50 microns of 3 parts by weight After diamond illusion-colour pearlite slurry made of RS9012 three times, dried at a temperature of 40 DEG C, be made and carry GTG site diamond illusion-colour First bloom figure layer of effect.

Then, printed using 120 mesh half tones in the first bloom figure layer with GTG site diamond fantasy coloured effect by 80 The transparent thermal transfer slurry of the 1st step allotment of parts by weight and 70 μm of model PYS8570 of 12 parts by weight aluminium silver powder are made Silver transfer slurry twice after, at a temperature of 40 DEG C dry, be made with GTG site silvery white effect the second bloom figure layer.

Then, printed using 120 mesh half tones in the second bloom figure layer with GTG site silvery white effect by 65 weight It is white made of the transparent thermal transfer slurry of the 1st step allotment of part and 0.36 μm of Du Pont's model R706 titanium dioxides of 25 parts by weight After twice of color transfer slurry, dried at a temperature of 50 DEG C, the second full figure layer with GTG site white is made.

After again, the saturating of the 1st step allotment is printed on the second full figure layer with GTG site white using 120 mesh half tones It is moist after bright thermal transfer is starched one time, it is made with the 3rd transparent full figure layer of GTG site.180 purposes were scattered after 20 seconds Model AN-H100 thermoplastic resin rubber powder is covered with the 3rd transparent full figure layer of GTG site, then, at 60 DEG C At a temperature of dry 30 minutes after, remove pattern beyond thermoplastic resin rubber powder, be made base material.

Finally, hot pressing, which is fitted in, by base material at a temperature of 160 DEG C, under the pressure of 4 kg/cms treats thermal transfer 30 seconds on material, transfer film is generated, transfer film is torn after cooling down 2 hours, forms thermal transfer product.

UV inks are used only in the thermal transfer product prepared by the heat-transferring method of the present invention, thermoplastic polyurethane moisture dissipates Body and water-based acrylic resin emulsion, the presence of no noxious volatile organic solvent (VOC), and also the air brushing of UV inks is being printed on On the transfer film of bright transfer slurry, wink-dry solidification, indiffusion, resolution ratio may be up to 5760dpi.In addition, diamond fantasy coloured effect Pearlite slurry and high-resolution jet ink blend so that transfer product is formed with similar diamond flicker radiance and fantasy coloured effect.

It is to be understood that foregoing invention content and embodiment are intended to prove technical scheme provided by the present invention Practical application, it should not be construed as limiting the scope of the present invention.Those skilled in the art are in spirit and principles of the present invention It is interior, when can various modifications may be made, equivalent substitution or improvement.Protection scope of the present invention is defined by appended claims.

Claims (7)

1. a kind of heat-transferring method with diamond fantasy coloured effect, it is characterised in that the heat-transferring method comprises the following steps:
A) transparent thermal transfer slurry is allocated:The transparent thermal transfer slurry include the parts by weight of thermoplastic polyurethane aqueous dispersion 40~43, The parts by weight of water-based acrylic resin emulsion 40~43, the parts by weight of NMF 6~9, the parts by weight of emulsifying agent 2~3, the weight of thickener 1~2 Measure part and the parts by weight of organic silicon defoamer 0.1~0.2;
B) printing is with the first transparent full figure layer of GTG site:Printed using the half tone of 150~200 mesh on bright face transfer film The transparent thermal transfer is starched one time, is dried at a temperature of 40~50 DEG C, is made with the first transparent full figure layer of GTG site;
C) printer air brushing carries the figure layer of coloured image:It is colored using the air brushing of UV flat-panel printers on the first full figure layer Image, the figure layer with coloured image is made;
D) first bloom figure layer of the printing with GTG site diamond fantasy coloured effect:Using the half tone of 120~150 mesh in the band After diamond illusion-colour pearlite slurry at least one time is printed in the figure layer of chromatic colour image, dried at a temperature of 40~50 DEG C, be made and bore First bloom figure layer of stone fantasy coloured effect, wherein, the diamond illusion-colour pearlite slurry includes the transparent thermal transfer and starches 80~85 weights Amount part, the unreal golden pearl essence of diamond of 30~100 microns of 1~3 parts by weight, the diamond of 30~100 microns of 1~3 parts by weight are unreal Red pearl essence, the unreal blue pearl essence of diamond of 30~100 microns of 1~3 parts by weight, the brill of 30~100 microns of 1~3 parts by weight The unreal purple pearl essence of stone, the unreal green pearl essence of diamond of 30~100 microns of 1~3 parts by weight;
E) second bloom figure layer of the printing with GTG site silvery white effect:Using 120~150 mesh half tones GTG is carried described After the transfer of printing silver is starched at least one time in first bloom figure layer of site diamond fantasy coloured effect, done at a temperature of 40~50 DEG C It is dry, the second bloom figure layer with GTG site silver effect is made, the silver transfer slurry includes the transparent thermal transfer slurry 80~85 parts by weight and 70 μm of the parts by weight of aluminium silver powder 12~18;
F) second full figure layer of the printing with GTG site white:Using 120~150 mesh half tones described with GTG site silver After the transfer of printing white is starched at least one time in second bloom figure layer of white effect, dried at a temperature of 40~50 DEG C, obtained band Have the second full figure layer of GTG site white, the white transfer slurry include at least one transparent thermal transfer starch 65~75 parts by weight and 0.36 μm of the parts by weight of titanium dioxide 25~35;
G) printing is with the 3rd transparent full figure layer of GTG site:Using 120~150 mesh half tones described white with GTG site Printed on second full figure layer of color after the transparent thermal transfer starches at least one time, it is moist, it is made transparent with GTG site 3rd full figure layer;
H) TPU thermal fusing powders, drying are spread immediately and base material is made:The TPU thermal fusing powders that 80~180 mesh were scattered in 30 seconds cover institute State with transparent the 3rd full figure layer in GTG site, after drying 30~60 minutes at a temperature of 60~80 DEG C, remove pattern TPU thermal fusing powders in addition, so that base material is made;
I) hot-pressing transfer printing:The base material is fitted on the material for treating thermal transfer, wherein, hot pressing temperature is 125~160 DEG C, heat Pressure pressure is 4~7 kg/cms, and hot pressing time is 15~30 seconds;
J) transfer film is torn after cooling down.
2. heat-transferring method as claimed in claim 1, it is characterised in that in step a), the thermoplastic polyurethane moisture dissipates Body is model U-1257 thermoplastic polyurethane aqueous dispersion, and the water-based acrylic resin emulsion is that model EM-184A is water-based Emulsion acrylic resin, the NMF are ethoxy urea, and the emulsifying agent is BASF model AEO-09 poly alkyl alcohol Oxygen vinethene, the thickener are BASF model HIT PLUS acrylic polymer suspended substance, the organosilicon defoaming Agent is model C X-470 organosiloxane complexing agent.
3. heat-transferring method as claimed in claim 1, it is characterised in that in step d), the unreal golden pearl essence of diamond is type Number RS9008 unreal golden pearl essence of diamond, the unreal red pearl essence of diamond is the model RS9009 unreal red pearl essence of diamond, described The unreal blue pearl essence of diamond is the model RS9011 unreal blue pearl essence of diamond, and the unreal purple pearl essence of diamond is model RS9010 brill The unreal purple pearl essence of stone, the unreal green pearl essence of diamond are the model RS9012 unreal green pearl essence of diamond.
4. heat-transferring method as claimed in claim 1, it is characterised in that in step e), the aluminium silver powder is model PYS8570 Aluminium silver powder.
5. heat-transferring method as claimed in claim 1, it is characterised in that in step f), the titanium dioxide is Du Pont's model R706 titanium dioxide.
6. heat-transferring method as claimed in claim 1, it is characterised in that in step h), the TPU thermal fusing powders are model AN- H100 thermoplastic resin rubber powder.
7. heat-transferring method as claimed in claim 1, it is characterised in that the cool time in step j) is 2~4 hours.
CN201410834933.0A 2014-12-29 2014-12-29 A kind of heat-transferring method with diamond fantasy coloured effect CN105799350B (en)

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