CN104725577A - Ink seepage glue for canvas inkjet printing as well as preparation method and application method thereof - Google Patents
Ink seepage glue for canvas inkjet printing as well as preparation method and application method thereof Download PDFInfo
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- CN104725577A CN104725577A CN201510069169.7A CN201510069169A CN104725577A CN 104725577 A CN104725577 A CN 104725577A CN 201510069169 A CN201510069169 A CN 201510069169A CN 104725577 A CN104725577 A CN 104725577A
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Abstract
The invention relates to the technical field of macromolecular materials, in particular relates to an ink seepage glue for canvas inkjet printing as well as a preparation method and an application method thereof. The ink seepage glue is prepared by adopting two or more fluorine-containing methyl acrylate derivative monomers and monomers which contain quaternary ammonium salt molecular structures and are capable of performing free radical polymerization together with the fluorine-containing methyl acrylate derivative monomers. In the invention, a soap-free emulsion polymerization method is adopted to synthesize cationic fluoropolymer emulsion used as an adhesive, and silicon dioxide powder is also adopted to prepare ink seepage paint for large-scale canvas inkjet printing. When the canvas surface is glued with the paint prepared by the invention, the indexes such as whiteness, smoothness, inkjet printing color density and ink dot resolution of the canvas can be improved significantly.
Description
Technical field
The present invention relates to technical field of polymer materials, be specifically related to the anti-strike-through of a kind of painting canvas inkjet printing ink, preparation method and application method.
Background technology
Spray ink Printing printing technology at the print on paper of small breadth, can only be extended to and has printed on the textiles and plastics film (in surface-coated ink absorbing layer) of large format at first now.Printing quality also improves constantly, and substantially can meet the demand of the industries such as decoration and advertisement, and market capacity is that geometry level increases, and has a bright future.
But the quality product of current spray ink Printing also exists some problems, the portrait sharpness as print product is not enough, and drying property is bad, and crocking resistance is not good, under conditions of high humidity, can produce aberration when oil painting stores.These problems all with spray ink Printing before gluing technology be associated.
For general family expenses print and office document prints, printing high quality to improve, obtaining high-resolution exquisite picture, the research and development of domestic and international You Duo company can absorb ink fast, form the colour print of the impermeable coating of ink of firm color for paper products.The common feature of the color ink jet printed coating of these stationeries is as follows:
1. can absorb ink fast.During spray ink Printing, ink droplet, once touch printable fabric surface and interact at once and with it, ensures within the shortest time, make ink setting fix.
2. high-resolution image can be formed.Ensure that ink-jet point is complete, indiffusion, regular shape, correctly can produce the image of expection, color accurate positioning, keeps the shape.
3. printing color can be made to have certain fastness, nondiscoloration within for some time, not come off, namely image and word will have good keeping quality.The keeping quality of image is weighed mainly through water tolerance and photostabilization.The water tolerance of image refers to that image is by the wastage of dyestuff during water to a certain degree moistening, because ink-jet ink is mostly water color ink, this seems particularly important with regard to making the water tolerance of image.Photostabilization refers to the photofading that image produces in preservation process or the discolouration phenomena that oxidizing gas causes, and the method generally by adding UV light absorber and antioxidant in the coating solves problem.
4. color reducibility is good, can true reappearance original color, bright in luster, and optical density (OD) is large.Improve the optical density (OD) of image and the vividness of color, outside the factor of oil removing Miboin body, also will consider to select the coating layer that specific absorbance is large and scattering coefficient is little.
The coated coating of Alhue paper forms primarily of pigment, tackiness agent and auxiliary agent.Pigment more mainly has the material of the vesicular structure of absorbency, as silicon-dioxide, carclazyte, light calcium carbonate, silicate, titanium dioxide and macromolecule resin etc.White Board adhesive type used is a lot, as polyvinyl alcohol, modified polyvinyl alcohol, polyvinyl acetate (PVA), carboxymethyl cellulose, styrene-butadiene latex, treated starch, gelatin, methyl methacrylate acrylate copolymer etc.At present, polyvinyl alcohol uses extensively, better performances.Also need to add some auxiliary agents, to improve painting work and Paper Printing further during preparation coating.Conventional auxiliary agent has pigment dispersing agent, defoamer, linking agent, viscosity modifier, antioxidant, white dyes and cationic fixing agent etc.
Although more for the development research of the coating of color ink jet printer paper, the correlation technique about the special coating of textile materials is rare open.
Fluorine material has extremely low surface energy, is widely used in the fields such as coating, textile finishing, leather, papermaking, optical fiber, packaging, microelectronics, automobile and aerospace.Because the electronegativity of fluorine is large; distribute around its atom higher cloud density; make mutually to repel between adjacent fluorine atom; fluorine atom on result molecular chain is scroll distribution; form the high shielded provide protection to C-C main chain, the structural this singularity of fluorocarbon chain determines physical and chemical performance and the surface property of fluoropolymer excellence.
Letex polymerization refers under the effect of emulsifying agent, and monomer carries out polyreaction and forms a kind of method of emulsion in aqueous phase.This polymerization using water as reaction medium, environmental protection, latex viscosity is low, be convenient to heat transfer, conveying and produce; Temperature of reaction is low, and rate of polymerization is fast, and the number-average molecular weight of polymkeric substance is large.Use emulsifying agent in conventional emulsion polymerization, these tensio-active agent small molecules are difficult to removing in polymer emulsion, and then affect surface property and wash durability etc.Surfactant-free emulsion polymerization can improve above-mentioned deficiency, has now become a popular polymerization technique of chemical field.Emulsifier-free emulsion polymerization fundamentally solves the conventional emulsifier in conventional emulsion and is attached in the mode of physical adsorption the problem such as surface properties and wash durability that polymer beads sub-surface has had a strong impact on polymkeric substance.Introduce polymerisable emulsifier and participate in copolyreaction by the carbon-carbon double bond in molecule, be firmly chemically bonded on polymer molecule, solve the problem that conventional emulsifier remains in the polymer.
Summary of the invention
The object of the invention is to overcome the problems referred to above, providing the anti-strike-through of a kind of painting canvas inkjet printing ink, preparation method and application method.
In order to reach foregoing invention object, the present invention by the following technical solutions:
The anti-strike-through of a kind of painting canvas inkjet printing ink, the anti-strike-through of described ink adopts two or more fluorine-containing methacrylate derivatives monomer and can carry out the free-radical polymerized monomer containing quaternary ammonium salt molecular structure with above-mentioned monomer and is prepared from.
Preferably, the mass ratio of two kinds of fluorine-containing methacrylate derivatives monomers used is 1:2-2:1.
Preferably, described fluorine-containing methacrylate derivatives monomer is trifluoroethyl methacrylate and Hexafluorobutyl mathacrylate, and the described monomer containing quaternary ammonium salt molecular structure is MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride.
The preparation method of the anti-strike-through of a kind of painting canvas inkjet printing ink, described preparation method is letex polymerization, specifically be prepared from by following steps: polyethylene glycol methacrylate-styrene polymer, cationic emulsifier MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride and deionized water are joined in four-hole boiling flask, pre-emulsification 30min is carried out under high-speed stirring, then add the mix monomer of 1/3, mix monomer is made up of trifluoroethyl methacrylate, Hexafluorobutyl mathacrylate, vinylbenzene and butyl acrylate; Be warming up to 80 DEG C under nitrogen protection, drip the azo-bis-isobutyrate hydrochloride aqueous solution, after oyster white appears in question response, start to drip remaining mix monomer and initiation solution simultaneously, be added dropwise to complete in 3h, continue to be warming up to 85 DEG C of reaction 2h, stop heating, be at room temperature cooled to 40 DEG C, regulate emulsion pH to be about pH=6.7, can stable emulsion be obtained, be the anti-strike-through of product painting canvas inkjet printing ink; Each material in letex polymerization is counted specific as follows by weight: 100 parts, water, polyethylene glycol methacrylate-styrene polymer 5-7 part, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride 2.1-4.5 part, Hexafluorobutyl mathacrylate 2.1 parts, trifluoroethyl methacrylate 1.8 parts, vinylbenzene 2.5 parts, butyl acrylate 3.2 parts, azo-bis-isobutyrate hydrochloride 0.2 part.
The application method of the anti-strike-through of a kind of painting canvas inkjet printing ink, specifically comprise the following steps: get the anti-strike-through of ink and use deionized water to be diluted to solid content for 5g/L, then 40 DEG C are heated to, aerosil nano particle is added in the ratio of 0.5g/L, stir under 800rpm stand-by as work body lotion, cloth padding machine is arranged in leaching one mode of rolling, it is 70% that pick-up controls, then cloth specimen is dried 5min under the temperature condition of 100 DEG C, then setting bakes 3min at 170 DEG C of temperature.
Preferably, the median size 10nm of described aerosil nanometer.
Compared with prior art, beneficial effect is in the present invention: the present invention adopts emulsifier-free emulsion polymerization method synthesizing cationic fluorine-containing latex to be used as tackiness agent, coordinates silicon-dioxide powdery to prepare the impermeable coating of large-scale painting canvas spray ink Printing ink.Product coating obviously can improve the indexs such as painting canvas whiteness, smoothness, spray ink Printing colour density and ink dot sharpness to after painting canvas top sizing.
Embodiment
Below by specific embodiment, explanation is further described to technical scheme of the present invention.
If without specified otherwise, the raw material adopted in embodiments of the invention is the conventional raw material in this area, and the method adopted in embodiment, is the ordinary method of this area.
Embodiment 1:
By polyethylene glycol methacrylate-styrene polymer, cationic emulsifier MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, deionized water adds in four-hole boiling flask, high-speed stirring (800rpm) pre-emulsification 30min, add the mix monomer of 1/3 (by trifluoroethyl methacrylate, Hexafluorobutyl mathacrylate, polyethylene glycol methacrylate-styrene polymer, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, vinylbenzene and butyl acrylate composition), 80 DEG C are warming up under nitrogen protection, drip the azo-bis-isobutyrate hydrochloride aqueous solution, after there is oyster white in question response, start to drip remaining mix monomer and initiation solution simultaneously, be added dropwise to complete in 3h, continue to be warming up to 85 DEG C of reaction 2h, stop heating, at room temperature be cooled to 40 DEG C, emulsion pH is regulated to be about pH=6.7, stable emulsion can be obtained.
Each material compositing formula following (unit g) is used in letex polymerization:
Hexafluorobutyl mathacrylate: 2.1
Trifluoroethyl methacrylate: 1.8
MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride: 3.2
Vinylbenzene: 2.5
Butyl acrylate: 3.2
Azo-bis-isobutyrate hydrochloride: 0.2
Water: 100
Get emulsion to use deionized water to be diluted to solid content for 5g/L to be heated to 40 DEG C, aerosil nano particle (median size is about 10nm) is added in 0.5g/L ratio, stir under 800rpm stand-by as work body lotion, cloth small test padding machine arranges in leaching one mode of rolling, it is 70% that pick-up controls, then cloth specimen is dried 5min under the temperature condition of 100 DEG C, then setting bakes 3min at 170 DEG C of temperature.
Product painting canvas uses large-scale ink-jet printer printing, observes printing effect colour density, ink dot sharpness.Evaluation result is, colour density improves 10% than untreated painting canvas, and ink dot sharpness improves 40% than untreated painting canvas.
Embodiment 2:
Polyethylene glycol methacrylate-styrene polymer, cationic emulsifier MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, deionized water adds in four-hole boiling flask, high-speed stirring (800rpm) pre-emulsification 30min, add the mix monomer of about 1/3 (by trifluoroethyl methacrylate, Hexafluorobutyl mathacrylate, polyethylene glycol methacrylate-styrene polymer, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, vinylbenzene and butyl acrylate composition), 80 DEG C are warming up under nitrogen protection, drip the azo-bis-isobutyrate hydrochloride aqueous solution, after there is oyster white in question response, start to drip remaining mix monomer and initiation solution simultaneously, be added dropwise to complete in 3h, continue to be warming up to 85 DEG C of reaction 2h, stop heating, at room temperature be cooled to 40 DEG C, emulsion pH is regulated to be about pH=6.7, stable emulsion can be obtained.
Each material compositing formula following (unit g) is used in letex polymerization:
Hexafluorobutyl mathacrylate: 2.1
Trifluoroethyl methacrylate: 1.8
MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride: 2.1
Vinylbenzene: 2.5
Butyl acrylate: 3.2
Azo-bis-isobutyrate hydrochloride: 0.2
Water: 100
Get emulsion to use deionized water to be diluted to solid content for 5g/L to be heated to 40 DEG C, aerosil nano particle (median size is about 10nm) is added in 0.5g/L ratio, stir under 800rpm stand-by as work body lotion, cloth small test padding machine arranges in leaching one mode of rolling, it is 70% that pick-up controls, then cloth specimen is dried 5min under the temperature condition of 100 DEG C, then setting bakes 3min at 170 DEG C of temperature.
Product painting canvas uses large-scale ink-jet printer printing, observes printing effect colour density, ink dot sharpness.Evaluation result is, colour density improves 5% than untreated painting canvas, and ink dot sharpness improves 36% than untreated painting canvas.
Embodiment 3:
Polyethylene glycol methacrylate-styrene polymer, cationic emulsifier MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, deionized water adds in four-hole boiling flask, high-speed stirring (800rpm) pre-emulsification 30min, add the mix monomer of about 1/3 (by trifluoroethyl methacrylate, Hexafluorobutyl mathacrylate, polyethylene glycol methacrylate-styrene polymer, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, vinylbenzene and butyl acrylate composition), 80 DEG C are warming up under nitrogen protection, drip the azo-bis-isobutyrate hydrochloride aqueous solution, after there is oyster white in question response, start to drip remaining mix monomer and initiation solution simultaneously, be added dropwise to complete in 3h, continue to be warming up to 85 DEG C of reaction 2h, stop heating, at room temperature be cooled to 40 DEG C, emulsion pH is regulated to be about pH=6.7, stable emulsion can be obtained.
Each material compositing formula following (unit g) is used in letex polymerization:
Hexafluorobutyl mathacrylate: 2.1
Trifluoroethyl methacrylate: 1.8
MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride: 4.5
Vinylbenzene: 2.5
Butyl acrylate: 3.2
Azo-bis-isobutyrate hydrochloride: 0.2
Water: 100
Get emulsion to use deionized water to be diluted to solid content for 5g/L to be heated to 40 DEG C, aerosil nano particle (median size is about 10nm) is added in 0.5g/L ratio, stir under 800rpm stand-by as work body lotion, cloth small test padding machine arranges in leaching one mode of rolling, it is 70% that pick-up controls, then cloth specimen is dried 5min under the temperature condition of 100 DEG C, then setting bakes 3min at 170 DEG C of temperature.
Product painting canvas uses large-scale ink-jet printer printing, observes printing effect colour density, ink dot sharpness.Evaluation result is, colour density improves 5% than untreated painting canvas, and ink dot sharpness improves 20% than untreated painting canvas.
Claims (6)
1. the anti-strike-through of painting canvas inkjet printing ink, it is characterized in that, the anti-strike-through of described ink adopts two or more fluorine-containing methacrylate derivatives monomer and can carry out the free-radical polymerized monomer containing quaternary ammonium salt molecular structure with above-mentioned monomer and is prepared from.
2. the anti-strike-through of a kind of painting canvas inkjet printing ink according to claim 1, is characterized in that, the mass ratio of two kinds of fluorine-containing methacrylate derivatives monomers used is 1:2-2:1.
3. the anti-strike-through of a kind of painting canvas inkjet printing ink according to claim 1, it is characterized in that, described fluorine-containing methacrylate derivatives monomer is trifluoroethyl methacrylate and Hexafluorobutyl mathacrylate, and the described monomer containing quaternary ammonium salt molecular structure is MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride.
4. the preparation method of the anti-strike-through of a kind of painting canvas inkjet printing ink according to claim 1, it is characterized in that, described preparation method is letex polymerization, specifically be prepared from by following steps: polyethylene glycol methacrylate-styrene polymer, cationic emulsifier MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride and deionized water are joined in four-hole boiling flask, pre-emulsification 30min is carried out under high-speed stirring, then add the mix monomer of 1/3, mix monomer is made up of trifluoroethyl methacrylate, Hexafluorobutyl mathacrylate, vinylbenzene and butyl acrylate; Be warming up to 80 DEG C under nitrogen protection, drip the azo-bis-isobutyrate hydrochloride aqueous solution, after oyster white appears in question response, start to drip remaining mix monomer and initiation solution simultaneously, be added dropwise to complete in 3h, continue to be warming up to 85 DEG C of reaction 2h, stop heating, be at room temperature cooled to 40 DEG C, regulate emulsion pH to be about pH=6.7, can stable emulsion be obtained, be the anti-strike-through of product painting canvas inkjet printing ink; Each material in letex polymerization is counted specific as follows by weight: 100 parts, water, polyethylene glycol methacrylate-styrene polymer 5-7 part, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride 2.1-4.5 part, Hexafluorobutyl mathacrylate 2.1 parts, trifluoroethyl methacrylate 1.8 parts, vinylbenzene 2.5 parts, butyl acrylate 3.2 parts, azo-bis-isobutyrate hydrochloride 0.2 part.
5. the application method of the anti-strike-through of a kind of painting canvas inkjet printing ink according to claim 1, it is characterized in that, specifically comprise the following steps: get the anti-strike-through of ink and use deionized water to be diluted to solid content for 5g/L, then 40 DEG C are heated to, aerosil nano particle is added in the ratio of 0.5g/L, stir under 800rpm stand-by as work body lotion, cloth padding machine is arranged in leaching one mode of rolling, it is 70% that pick-up controls, then cloth specimen is dried 5min under the temperature condition of 100 DEG C, then setting bakes 3min at 170 DEG C of temperature.
6. the application method of the anti-strike-through of a kind of painting canvas inkjet printing ink according to claim 5, is characterized in that, the median size 10nm of described aerosil nanometer.
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| CN201510069169.7A CN104725577A (en) | 2015-02-11 | 2015-02-11 | Ink seepage glue for canvas inkjet printing as well as preparation method and application method thereof |
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| CN201510069169.7A CN104725577A (en) | 2015-02-11 | 2015-02-11 | Ink seepage glue for canvas inkjet printing as well as preparation method and application method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107793513A (en) * | 2017-10-25 | 2018-03-13 | 杭州海维特化工科技有限公司 | A kind of woodgrained paper coating adhesive emulsion available for numerial code spray drawing and preparation method thereof |
| CN111966858A (en) * | 2020-08-25 | 2020-11-20 | 北京雅昌艺术影像有限公司 | Picture volume rating grading evaluation method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001081486A2 (en) * | 2000-04-24 | 2001-11-01 | Avery Dennison Corporation | Acrylic emulsion coating for films, paper and rubber |
| CN103290674A (en) * | 2012-02-28 | 2013-09-11 | 明仁精细化工（嘉兴）有限公司 | Treatment method and treatment liquid for preparing fluoride-free super-hydrophobic cotton fabric |
| CN104031204A (en) * | 2014-06-06 | 2014-09-10 | 陕西科技大学 | Preparation method of cationic fluorine-containing polyacrylate soap-free emulsion |
| CN104191852A (en) * | 2014-09-01 | 2014-12-10 | 江苏格美高科技发展有限公司 | Ink-jet oil painting canvas and manufacturing method thereof |
-
2015
- 2015-02-11 CN CN201510069169.7A patent/CN104725577A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001081486A2 (en) * | 2000-04-24 | 2001-11-01 | Avery Dennison Corporation | Acrylic emulsion coating for films, paper and rubber |
| CN103290674A (en) * | 2012-02-28 | 2013-09-11 | 明仁精细化工（嘉兴）有限公司 | Treatment method and treatment liquid for preparing fluoride-free super-hydrophobic cotton fabric |
| CN104031204A (en) * | 2014-06-06 | 2014-09-10 | 陕西科技大学 | Preparation method of cationic fluorine-containing polyacrylate soap-free emulsion |
| CN104191852A (en) * | 2014-09-01 | 2014-12-10 | 江苏格美高科技发展有限公司 | Ink-jet oil painting canvas and manufacturing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李刚辉 等: "阳离子氟碳无皂乳液的制备及其在表面施胶中的应用", 《纸和造纸》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107793513A (en) * | 2017-10-25 | 2018-03-13 | 杭州海维特化工科技有限公司 | A kind of woodgrained paper coating adhesive emulsion available for numerial code spray drawing and preparation method thereof |
| CN111966858A (en) * | 2020-08-25 | 2020-11-20 | 北京雅昌艺术影像有限公司 | Picture volume rating grading evaluation method |
| CN111966858B (en) * | 2020-08-25 | 2022-04-15 | 雅昌文化(集团)有限公司 | Picture volume rating grading evaluation method |
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Application publication date: 20150624 |