CN106555364A - A kind of high glaze is water-fast printing paper and preparation method thereof - Google Patents
A kind of high glaze is water-fast printing paper and preparation method thereof Download PDFInfo
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- CN106555364A CN106555364A CN201611065262.1A CN201611065262A CN106555364A CN 106555364 A CN106555364 A CN 106555364A CN 201611065262 A CN201611065262 A CN 201611065262A CN 106555364 A CN106555364 A CN 106555364A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/12—Defoamers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/32—Bleaching agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/40—Cover layers; Layers separated from substrate by imaging layer; Protective layers; Layers applied before imaging
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of water-fast printing paper of high glaze, including ink absorbing layer, glazing layer, body paper and back coating；Its preparation method is as follows：Ink-absorbed coated layer liquid and preparation method thereof；Glazing coating liquid preparing process；Back of the body coating layer liquid preparing process；Printing paper preparation technology that high glaze is water-fast.The high glaze printing paper of present invention production, its glossiness can be to more than 80%, much larger than the printing paper of on market 40 60% glossiness, there is scraping and wiping resistance performance simultaneously, printing paper case hardness reaches 7 grades, because backside coating polymer emulsion, acts on buffer action and Anti-curling, backside surface tension force is less than 25 dynes, and water cannot be in surface spreading.Flatness reaches leaching membrane paper level.Blotting rate of drying is fast, reaches the i.e. dry effect of machine, goes out 2 minutes rates of drying of machine compared with leaching membrane paper printing paper and greatly promote.
Description
Technical field
Technical field is new material technology field, and application is output image area, and in particular to Yi Zhonggao
Gloss is water-fast printing paper and preparation method thereof.
Background technology
2012 film manufacturing enterprise of Nian9Yue China giants --- Chinese Lekai film group closes the last item in Nanjing
Colour film production line, indicate that China's digital ink-jet printing technique has replaced conventional silver halide substantially in image output industry
Export technique.
Ink jet printed photographic paper is the print media material in digital ink-jet printing technique, be by by coating liquid in base
Material surface forms.The species of printing paper mainly has film stationery printing paper and casting to apply class printing paper, wherein film stationery phase in the market
Paper is that, by ink-absorbed coated layer coating liquid on leaching membrane paper, its ink-absorbed coated layer is mainly nano silicon and aluminum oxide, and casting is applied
Printing paper is that ink-absorbed coated layer is coated in the preferable paper surface of gas permeability, and being attached to when coating fluid is half-dried on minute surface cylinder is carried out
It is further dried and is prepared from.
Film stationery printing paper has water-tolerant, and flatness is high, and back side of paper is completely hydrophobic, and output color is true to nature bright-coloured,
The advantages of being adapted to long-term preservation, but its surface gloss is relatively low, prints slow drying speed, and surface is also easy to produce cut and stays
Fingerprint, and then affect to print color appearance and preservation.
Casting applies class printing paper, and glossiness is high, prints rate of drying soon, and case hardness is high, and color is true to nature bright-coloured, but as which is adopted
It is base material with stationery, it is water-fast relatively poor, easily crimp, affect long-term preservation application.
Number of patent application is：201210186881.1, patent name is：Nanoscale high-gloss cast coated paper is used in printing, and this is special
The printing nanoscale high-gloss cast coated paper that profit is provided, is molded by first drying, is obtained without the need for supercalendering, but which is saturating
Gas, the surface gloss of product and scratch resistant performance etc. be not good enough.
Number of patent application is：201210187158.5, patent name is：Novel environment friendly bloom cast-coated paper made of paper is regenerated, should
Patent is using recycled writing paper as cast coated base paper, you can obtain the easily peelable cast-coated paper of high glaze, energy-conserving and environment-protective, but the suction of its product
Black rate of drying and print resolution are relatively low.
The content of the invention
Goal of the invention：The present invention provides water-fast printing paper of a kind of high glaze and preparation method thereof.
Technical scheme：A kind of high glaze is water-fast printing paper, including ink absorbing layer, glazing layer, body paper and back coating；Body paper is applied for casting
Body paper, body paper grammes per square metre scope 60-260 gram/m；
The ink absorbing layer masking liquid is made up of each component of following parts by weight：
Water 50-70 parts；
Color fixing agent 3-7 parts；
Defoamer 0.1-0.5 parts；
Brightening agent 0.1-0.5 parts；
Poly-vinyl alcohol solution（15%）5-10 parts；
Coated layer 12-18 parts；
Polymer emulsion 10-15 parts；
The ink absorbing layer is applied in formula of liquid：
The color fixing agent is quaternary ammonium salt aldehyde-free colour stabilizer, and quaternized reactive fixing agent or quaternized high polymer are without aldehyde fixation
One kind in agent；
The defoamer is polyethers defoamer：Tributyl phosphate, dimethyl silicone polymer, in polysiloxane defoaming agent
Kind；
The brightening agent is diphenyl ethylene derivatives, is its disulfonic acid sodium salt, sodium salt, one kind of six sulfonate sodiums；
The glazing layer masking liquid is made up of each component of following parts by weight：
Alumina gel 28-40 parts；
Water 50-70 parts；
Alcohol 0.1-1 parts；
Defoamer 0.05-0.2 parts；
Brightening agent 0.05-0.5 parts；
Ammoniacal liquor 0.05-0.5 parts；
Lubricant 0.1-1 parts；
Polymer emulsion 1-5 parts；
The glazing layer is applied in formula of liquid：
The defoamer is polyethers defoamer：Tributyl phosphate, dimethyl silicone polymer, in polysiloxane defoaming agent
Kind；
The brightening agent is diphenyl ethylene derivatives, is its disulfonic acid sodium salt, sodium salt, one kind of six sulfonate sodiums；
The lubricant be calcium stearate, polythene wax emulsion, the one kind in magnesium stearate；
The polymer emulsion be cationic styrene-acrylic emulsion, the one kind in nonionic vinyl acetate-ethylene copolymerization emulsions；
The back coating masking liquid is made up of each component of following parts by weight：
20 parts of polymer emulsion；
20 parts of opacity polymer；
60 parts of water；
The back coating is applied in formula of liquid：
The polymer emulsion be styrene acrylic copolymer dispersion liquid, the one kind in fluorine-containing pure-acrylic emulsion；
The opacity polymer is the acrylic styrene copolymer dispersion liquid of not film forming.
As optimization：The ink absorbing layer is applied in formula of liquid, the poly-vinyl alcohol solution（15%）For polyvinyl alcohol 1799,
One kind in 1788, and Kuraray FJS-1000.
As optimization：The ink absorbing layer is applied in formula of liquid, and the coated layer particle diameter is 9-15 microns, pore volume
1.4-2.0ml/g。
As optimization：The ink absorbing layer is applied in formula of liquid, and the polymer emulsion is common for nonionic vinyl acetate-ethylene
Poly- emulsion.
As optimization：The glazing layer is applied in formula of liquid, and the Alumina gel particle diameter is less than or equal to 1 micron, solid content 25-
30, pH value is more than or equal to 3.
As optimization：The glazing layer is applied in formula of liquid, and the alcohol is n-butanol, ethanol, the one kind in isopropanol.
A kind of preparation method of high glaze as mentioned is water-fast printing paper, comprises the steps：
（1）Ink-absorbed coated layer liquid and preparation method thereof：
In formula technique ratio, color fixing agent, defoamer, brightening agent, poly-vinyl alcohol solution are added separately in water, are stirred
Afterwards, silica is added, after high-speed stirred 30-90 minute, adds polymer emulsion, high-speed stirred 20-60 minute, filter, treat
With；
（2）Glazing coating liquid preparing process：
Water is added in Alumina gel first, is the 20% of water inventory, under conditions of at the uniform velocity stirring, be separately added into alcohol, defoamer increases
White agent, at a high speed dispersion 30-90 minutes, is slowly added dropwise ammoniacal liquor under the conditions of high-speed stirred, stirs 20-40 minutes, respectively slow
Lubricant and polymer emulsion are added under conditions of stirring, high-speed stirred 30-60 minute, is filtered, it is stand-by；
（3）Back of the body coating layer liquid preparing process：
Successively opacity polymer and water are added in polymer emulsion under slow stirring, are stirred；
（4）Printing paper preparation technology that high glaze is water-fast：
Ink-absorbed coated layer is coated in cast coated base paper using comma scraper doctor blade process, butt coating weight control 15-20 gram/it is flat
Square rice, the heated-air drying under the conditions of 60-100 DEG C；Using airblade coating technique by glazing layer coating liquid on ink absorbing layer,
Butt coating weight be 3-5 gram/m, in room temperature to heated-air drying under the conditions of 60 DEG C to leather hard, hot pressing to minute surface drying cylinder,
Minute surface dryer temperature is 90-120 DEG C, and platen pressure is 0.1-0.4MPa, de- cylinder after being dried completely；Using the bar coating coating back of the body
Coating layer liquid, butt coating weight 3-8 gram/m are dried under the conditions of 60-90 DEG C, as finished product.
Beneficial effect：The high glaze printing paper of present invention production, its glossiness can be to more than 80%, much larger than 40- on market
The printing paper of 60% glossiness, while having scraping and wiping resistance performance, printing paper case hardness reaches 7 grades, because backside coating polymer is newborn
Liquid, acts on buffer action and Anti-curling, and backside surface tension force is less than 25 dynes, and water cannot be in surface spreading.Flatness reaches
To leaching membrane paper level.Blotting rate of drying is fast, reaches the i.e. dry effect of machine, goes out 2 minutes rates of drying of machine compared with leaching membrane paper printing paper
Greatly promote.
The present invention passes through different coating formulas and coating process, film class printing paper and casting is applied class printing paper advantage and is mutually tied
Close, high glaze water-fast printing paper is divided into into four-layer structure, respectively back coating, paper substrate, ink absorbing layer and glazing layer.Back coating improves
The Anti-curling performance of printing paper and the hydrophobic performance at the raising printing paper back side, and then improve the overall water resistance and keeping quality of printing paper
Energy；Paper substrate adopts natural fiber paper substrate, good permeability；Ink absorbing layer as ink-absorbing medium, is improved and is produced using coated layer
The blotting rate of drying of product and print resolution；Glazing layer improves the surface of product using Alumina gel as main coating material
Glossiness and scratch resistant performance.
Specific embodiment
With reference to specific embodiment, the present invention will be described in detail.
Specific embodiment one：
A kind of high glaze is water-fast printing paper, including ink absorbing layer, glazing layer, body paper and back coating.Body paper is cast coated base paper, body paper grammes per square metre
60 grams/m of scope.
The ink absorbing layer masking liquid is made up of each component of following parts by weight：
50 parts of water；
3 parts of color fixing agent；
0.1 part of defoamer；
0.1 part of brightening agent；
Poly-vinyl alcohol solution（15%）5 parts；
12 parts of coated layer；
10 parts of polymer emulsion.
The ink absorbing layer is applied in formula of liquid：
The color fixing agent is quaternary ammonium salt aldehyde-free colour stabilizer.
The defoamer is polyethers defoamer.
The brightening agent is diphenyl ethylene derivatives, is its disulfonic acid sodium salt.
The poly-vinyl alcohol solution（15%）For polyvinyl alcohol 1799.
The coated layer particle diameter is 9 microns, pore volume 1.4ml/g.
The polymer emulsion is nonionic vinyl acetate-ethylene copolymerization emulsions.
The glazing layer masking liquid is made up of each component of following parts by weight：
28 parts of Alumina gel；
50 parts of water；
0.1 part of alcohol；
0.05 part of defoamer；
0.05 part of brightening agent；
0.05 part of ammoniacal liquor；
0.1 part of lubricant；
1 part of polymer emulsion.
The glazing layer is applied in formula of liquid：
The Alumina gel particle diameter is less than or equal to 1 micron, solid content 25, and pH value is more than or equal to 3.
The alcohol is n-butanol.
The defoamer is polyethers defoamer：Tributyl phosphate.
The brightening agent is diphenyl ethylene derivatives, is its disulfonic acid sodium salt.
The lubricant is calcium stearate.
The polymer emulsion is cationic styrene-acrylic emulsion.
The back coating masking liquid is made up of each component of following parts by weight：
20 parts of polymer emulsion；
20 parts of opacity polymer；
60 parts of water.
The back coating is applied in formula of liquid：
The polymer emulsion is styrene acrylic copolymer dispersion liquid.
The opacity polymer is the acrylic styrene copolymer dispersion liquid of not film forming.
A kind of preparation method of high glaze as mentioned is water-fast printing paper, comprises the steps：
（1）Ink-absorbed coated layer liquid and preparation method thereof：
In formula technique ratio, color fixing agent, defoamer, brightening agent, poly-vinyl alcohol solution are added separately in water, are stirred
Afterwards, silica is added, high-speed stirred added polymer emulsion after 30 minutes, and high-speed stirred 20 minutes is filtered, stand-by；
（2）Glazing coating liquid preparing process：
Water is added in Alumina gel first, is the 20% of water inventory, under conditions of at the uniform velocity stirring, be separately added into alcohol, defoamer increases
White agent, dispersion 30 minutes, are slowly added dropwise ammoniacal liquor under the conditions of high-speed stirred at a high speed, stir 20 minutes, are being slowly stirred respectively
Under the conditions of add lubricant and polymer emulsion, high-speed stirred 30 minutes is filtered, stand-by；
（3）Back of the body coating layer liquid preparing process：
Successively opacity polymer and water are added in polymer emulsion under slow stirring, are stirred；
（4）Printing paper preparation technology that high glaze is water-fast：
Ink-absorbed coated layer is coated in cast coated base paper using comma scraper doctor blade process, butt coating weight control is in 15 grams/square
Rice, the heated-air drying under the conditions of 60 DEG C；Using airblade coating technique by glazing layer coating liquid on ink absorbing layer, butt apply
Cloth amount is 3 grams/m, in room temperature to heated-air drying under the conditions of 60 DEG C to leather hard, hot pressing to minute surface drying cylinder, minute surface drying cylinder
Temperature is 90 DEG C, and platen pressure is 0.1MPa, de- cylinder after being dried completely；Using bar coating coating back of the body coating layer liquid, butt is applied
3 grams/m of cloth amount, is dried under the conditions of 60 DEG C, as finished product.
Specific embodiment two：
A kind of high glaze is water-fast printing paper, including ink absorbing layer, glazing layer, body paper and back coating.Body paper is cast coated base paper, body paper grammes per square metre
260 grams/m of scope.
The ink absorbing layer masking liquid is made up of each component of following parts by weight：
70 parts of water；
7 parts of color fixing agent；
0.5 part of defoamer；
0.5 part of brightening agent；
Poly-vinyl alcohol solution（15%）10 parts；
18 parts of coated layer；
15 parts of polymer emulsion.
The ink absorbing layer is applied in formula of liquid：
The color fixing agent is quaternized reactive fixing agent.
The defoamer is tributyl phosphate.
The brightening agent is diphenyl ethylene derivatives, is its sodium salt.
The poly-vinyl alcohol solution（15%）For polyvinyl alcohol 1788.
The coated layer particle diameter is 15 microns, pore volume 2.0ml/g.
The polymer emulsion is nonionic vinyl acetate-ethylene copolymerization emulsions.
The glazing layer masking liquid is made up of each component of following parts by weight：
40 parts of Alumina gel；
70 parts of water；
1 part of alcohol；
0.2 part of defoamer；
0.5 part of brightening agent；
0.5 part of ammoniacal liquor；
1 part of lubricant；
5 parts of polymer emulsion.
The glazing layer is applied in formula of liquid：
The Alumina gel particle diameter is less than or equal to 1 micron, solid content 30, and pH value is more than or equal to 3.
The alcohol is ethanol.
The defoamer is tributyl phosphate.
The brightening agent is diphenyl ethylene derivatives, is its six sulfonate sodium.
The lubricant is polythene wax emulsion.
The polymer emulsion be cationic styrene-acrylic emulsion, in nonionic vinyl acetate-ethylene copolymerization emulsions
Kind.
The back coating masking liquid is made up of each component of following parts by weight：
20 parts of polymer emulsion；
20 parts of opacity polymer；
60 parts of water.
The back coating is applied in formula of liquid：
The polymer emulsion is fluorine-containing pure-acrylic emulsion.
The opacity polymer is the acrylic styrene copolymer dispersion liquid of not film forming.
A kind of preparation method of high glaze as mentioned is water-fast printing paper, comprises the steps：
（1）Ink-absorbed coated layer liquid and preparation method thereof：
In formula technique ratio, color fixing agent, defoamer, brightening agent, poly-vinyl alcohol solution are added separately in water, are stirred
Afterwards, silica is added, high-speed stirred added polymer emulsion after 90 minutes, and high-speed stirred 60 minutes is filtered, stand-by；
（2）Glazing coating liquid preparing process：
Water is added in Alumina gel first, is the 20% of water inventory, under conditions of at the uniform velocity stirring, be separately added into alcohol, defoamer increases
White agent, dispersion 90 minutes, are slowly added dropwise ammoniacal liquor under the conditions of high-speed stirred at a high speed, stir 40 minutes, are being slowly stirred respectively
Under the conditions of add lubricant and polymer emulsion, high-speed stirred 60 minutes is filtered, stand-by；
（3）Back of the body coating layer liquid preparing process：
Successively opacity polymer and water are added in polymer emulsion under slow stirring, are stirred；
（4）Printing paper preparation technology that high glaze is water-fast：
Ink-absorbed coated layer is coated in cast coated base paper using comma scraper doctor blade process, butt coating weight control is in 20 grams/square
Rice, the heated-air drying under the conditions of 100 DEG C；Using airblade coating technique by glazing layer coating liquid on ink absorbing layer, butt
Coating weight is 5 grams/m, and in room temperature to heated-air drying under the conditions of 60 DEG C to leather hard, hot pressing to minute surface drying cylinder, minute surface are dried
Cylinder temperature is 120 DEG C, and platen pressure is 0.4MPa, de- cylinder after being dried completely；Using bar coating coating back of the body coating layer liquid, butt
8 grams/m of coating weight, is dried under the conditions of 90 DEG C, as finished product.
Specific embodiment three：
A kind of high glaze is water-fast printing paper, including ink absorbing layer, glazing layer, body paper and back coating.Body paper is cast coated base paper, body paper grammes per square metre
160 grams/m of scope.
The ink absorbing layer masking liquid is made up of each component of following parts by weight：
55 parts of water；
4 parts of color fixing agent；
0.3 part of defoamer；
0.2 part of brightening agent；
Poly-vinyl alcohol solution（15%）7 parts；
14 parts of coated layer；
12 parts of polymer emulsion.
The ink absorbing layer is applied in formula of liquid：
The color fixing agent is quaternized high polymer aldehyde-free colour stabilizer.
The defoamer is dimethyl silicone polymer.
The brightening agent is diphenyl ethylene derivatives, is its six sulfonate sodium.
The poly-vinyl alcohol solution（15%）For the one kind in Kuraray FJS-1000.
The coated layer particle diameter is 11 microns, pore volume 1.6ml/g.
The polymer emulsion is nonionic vinyl acetate-ethylene copolymerization emulsions.
The glazing layer masking liquid is made up of each component of following parts by weight：
33 parts of Alumina gel；
58 parts of water；
0.3 part of alcohol；
0.09 part of defoamer；
0.24 part of brightening agent；
0.27 part of ammoniacal liquor；
0.3 part of lubricant；
3 parts of polymer emulsion.
The glazing layer is applied in formula of liquid：
The Alumina gel particle diameter is less than or equal to 1 micron, solid content 27, and pH value is more than or equal to 3.
The alcohol is isopropanol.
The defoamer is dimethyl silicone polymer.
The brightening agent is diphenyl ethylene derivatives, is its sodium salt.
The lubricant is polythene wax emulsion.
The polymer emulsion be cationic styrene-acrylic emulsion, in nonionic vinyl acetate-ethylene copolymerization emulsions
Kind.
The back coating masking liquid is made up of each component of following parts by weight：
20 parts of polymer emulsion；
20 parts of opacity polymer；
60 parts of water.
The back coating is applied in formula of liquid：
The polymer emulsion is styrene acrylic copolymer dispersion liquid.
The opacity polymer is the acrylic styrene copolymer dispersion liquid of not film forming.
A kind of preparation method of high glaze as mentioned is water-fast printing paper, comprises the steps：
（1）Ink-absorbed coated layer liquid and preparation method thereof：
In formula technique ratio, color fixing agent, defoamer, brightening agent, poly-vinyl alcohol solution are added separately in water, are stirred
Afterwards, silica is added, high-speed stirred added polymer emulsion after 46 minutes, and high-speed stirred 37 minutes is filtered, stand-by；
（2）Glazing coating liquid preparing process：
Water is added in Alumina gel first, is the 20% of water inventory, under conditions of at the uniform velocity stirring, be separately added into alcohol, defoamer increases
White agent, dispersion 44 minutes, are slowly added dropwise ammoniacal liquor under the conditions of high-speed stirred at a high speed, stir 27 minutes, are being slowly stirred respectively
Under the conditions of add lubricant and polymer emulsion, high-speed stirred 42 minutes is filtered, stand-by；
（3）Back of the body coating layer liquid preparing process：
Successively opacity polymer and water are added in polymer emulsion under slow stirring, are stirred；
（4）Printing paper preparation technology that high glaze is water-fast：
Ink-absorbed coated layer is coated in cast coated base paper using comma scraper doctor blade process, butt coating weight control is in 16 grams/square
Rice, the heated-air drying under the conditions of 70 DEG C；Using airblade coating technique by glazing layer coating liquid on ink absorbing layer, butt apply
Cloth amount is 4 grams/m, in room temperature to heated-air drying under the conditions of 60 DEG C to leather hard, hot pressing to minute surface drying cylinder, minute surface drying cylinder
Temperature is 100 DEG C, and platen pressure is 0.2MPa, de- cylinder after being dried completely；Using bar coating coating back of the body coating layer liquid, butt is applied
4 grams/m of cloth amount, is dried under the conditions of 72 DEG C, as finished product.
Specific embodiment four：
A kind of high glaze is water-fast printing paper, including ink absorbing layer, glazing layer, body paper and back coating.Body paper is cast coated base paper, body paper grammes per square metre
230 grams/m of scope.
The ink absorbing layer masking liquid is made up of each component of following parts by weight：
66 parts of water；
6 parts of color fixing agent；
0.4 part of defoamer；
0.4 part of brightening agent；
Poly-vinyl alcohol solution（15%）8 parts；
17 parts of coated layer；
14 parts of polymer emulsion.
The ink absorbing layer is applied in formula of liquid：
The color fixing agent is quaternized high polymer aldehyde-free colour stabilizer.
The defoamer is dimethyl silicone polymer.
The brightening agent is diphenyl ethylene derivatives, is its disulfonic acid sodium salt.
The poly-vinyl alcohol solution（15%）For polyvinyl alcohol 1788.
The coated layer particle diameter is 13 microns, pore volume 1.9ml/g.
The polymer emulsion is nonionic vinyl acetate-ethylene copolymerization emulsions.
The glazing layer masking liquid is made up of each component of following parts by weight：
36 parts of Alumina gel；
65 parts of water；
0.8 part of alcohol；
0.18 part of defoamer；
0.43 part of brightening agent；
0.45 part of ammoniacal liquor；
0.9 part of lubricant；
4 parts of polymer emulsion.
The glazing layer is applied in formula of liquid：
The Alumina gel particle diameter is less than or equal to 1 micron, solid content 29, and pH value is more than or equal to 3.
The alcohol is isopropanol.
The defoamer is dimethyl silicone polymer.
The brightening agent is diphenyl ethylene derivatives, is its disulfonic acid sodium salt.
The lubricant is magnesium stearate.
The polymer emulsion be cationic styrene-acrylic emulsion, in nonionic vinyl acetate-ethylene copolymerization emulsions
Kind.
The back coating masking liquid is made up of each component of following parts by weight：
20 parts of polymer emulsion；
20 parts of opacity polymer；
60 parts of water.
The back coating is applied in formula of liquid：
The polymer emulsion is fluorine-containing pure-acrylic emulsion.
The opacity polymer is the acrylic styrene copolymer dispersion liquid of not film forming.
A kind of preparation method of high glaze as mentioned is water-fast printing paper, comprises the steps：
（1）Ink-absorbed coated layer liquid and preparation method thereof：
In formula technique ratio, color fixing agent, defoamer, brightening agent, poly-vinyl alcohol solution are added separately in water, are stirred
Afterwards, silica is added, high-speed stirred added polymer emulsion after 80 minutes, and high-speed stirred 50 minutes is filtered, stand-by；
（2）Glazing coating liquid preparing process：
Water is added in Alumina gel first, is the 20% of water inventory, under conditions of at the uniform velocity stirring, be separately added into alcohol, defoamer increases
White agent, dispersion 86 minutes, are slowly added dropwise ammoniacal liquor under the conditions of high-speed stirred at a high speed, stir 37 minutes, are being slowly stirred respectively
Under the conditions of add lubricant and polymer emulsion, high-speed stirred 56 minutes is filtered, stand-by；
（3）Back of the body coating layer liquid preparing process：
Successively opacity polymer and water are added in polymer emulsion under slow stirring, are stirred；
（4）Printing paper preparation technology that high glaze is water-fast：
Ink-absorbed coated layer is coated in cast coated base paper using comma scraper doctor blade process, butt coating weight control is in 18 grams/square
Rice, the heated-air drying under the conditions of 80 DEG C；Using airblade coating technique by glazing layer coating liquid on ink absorbing layer, butt apply
Cloth amount is 4 grams/m, in room temperature to heated-air drying under the conditions of 60 DEG C to leather hard, hot pressing to minute surface drying cylinder, minute surface drying cylinder
Temperature is 110 DEG C, and platen pressure is 0.3MPa, de- cylinder after being dried completely；Using bar coating coating back of the body coating layer liquid, butt is applied
6 grams/m of cloth amount, is dried under the conditions of 88 DEG C, as finished product.
The high glaze printing paper of present invention production, its glossiness can be to more than 80%, much larger than 40-60% glossiness on market
Printing paper, while having scraping and wiping resistance performance, printing paper case hardness reaches 7 grades, because backside coating polymer emulsion, makees with isolation
With acting on Anti-curling, backside surface tension force is less than 25 dynes, and water cannot be in surface spreading.Flatness reaches leaching membrane paper level.
Blotting rate of drying is fast, reaches the i.e. dry effect of machine, goes out 2 minutes rates of drying of machine compared with leaching membrane paper printing paper and greatly promote.
The present invention passes through different coating formulas and coating process, film class printing paper and casting is applied class printing paper advantage and is mutually tied
Close, high glaze water-fast printing paper is divided into into four-layer structure, respectively back coating, paper substrate, ink absorbing layer and glazing layer.Back coating improves
The Anti-curling performance of printing paper and the hydrophobic performance at the raising printing paper back side, and then improve the overall water resistance and keeping quality of printing paper
Energy；Paper substrate adopts natural fiber paper substrate, good permeability；Ink absorbing layer as ink-absorbing medium, is improved and is produced using coated layer
The blotting rate of drying of product and print resolution；Glazing layer improves the surface of product using Alumina gel as main coating material
Glossiness and scratch resistant performance.
The present invention is not limited to above-mentioned preferred forms, and anyone can show that other are various under the enlightenment of the present invention
The product of form, however, make any change in its shape or structure, it is every with skill identical or similar to the present application
Art scheme, is within the scope of the present invention.
Claims (7)
1. the water-fast printing paper of a kind of high glaze, it is characterised in that：Including ink absorbing layer, glazing layer, body paper and back coating；Body paper is applied for casting
Body paper, body paper grammes per square metre scope 60-260 gram/m；
The ink absorbing layer masking liquid is made up of each component of following parts by weight：
Water 50-70 parts；
Color fixing agent 3-7 parts；
Defoamer 0.1-0.5 parts；
Brightening agent 0.1-0.5 parts；
Poly-vinyl alcohol solution（15%）5-10 parts；
Coated layer 12-18 parts；
Polymer emulsion 10-15 parts；
The ink absorbing layer is applied in formula of liquid：
The color fixing agent is quaternary ammonium salt aldehyde-free colour stabilizer, and quaternized reactive fixing agent or quaternized high polymer are without aldehyde fixation
One kind in agent；
The defoamer is polyethers defoamer：Tributyl phosphate, dimethyl silicone polymer, in polysiloxane defoaming agent
Kind；
The brightening agent is diphenyl ethylene derivatives, is its disulfonic acid sodium salt, sodium salt, one kind of six sulfonate sodiums；
The glazing layer masking liquid is made up of each component of following parts by weight：
Alumina gel 28-40 parts；
Water 50-70 parts；
Alcohol 0.1-1 parts；
Defoamer 0.05-0.2 parts；
Brightening agent 0.05-0.5 parts；
Ammoniacal liquor 0.05-0.5 parts；
Lubricant 0.1-1 parts；
Polymer emulsion 1-5 parts；
The glazing layer is applied in formula of liquid：
The defoamer is polyethers defoamer：Tributyl phosphate, dimethyl silicone polymer, in polysiloxane defoaming agent
Kind；
The brightening agent is diphenyl ethylene derivatives, is its disulfonic acid sodium salt, sodium salt, one kind of six sulfonate sodiums；
The lubricant be calcium stearate, polythene wax emulsion, the one kind in magnesium stearate；
The polymer emulsion be cationic styrene-acrylic emulsion, the one kind in nonionic vinyl acetate-ethylene copolymerization emulsions；
The back coating masking liquid is made up of each component of following parts by weight：
20 parts of polymer emulsion；
20 parts of opacity polymer；
60 parts of water；
The back coating is applied in formula of liquid：
The polymer emulsion be styrene acrylic copolymer dispersion liquid, the one kind in fluorine-containing pure-acrylic emulsion；
The opacity polymer is the acrylic styrene copolymer dispersion liquid of not film forming.
2. the water-fast printing paper of high glaze according to claim 1, it is characterised in that：The ink absorbing layer is applied in formula of liquid, described
Poly-vinyl alcohol solution（15%）For polyvinyl alcohol 1799, the one kind in 1788, and Kuraray FJS-1000.
3. the water-fast printing paper of high glaze according to claim 1, it is characterised in that：The ink absorbing layer is applied in formula of liquid, described
Coated layer particle diameter be 9-15 microns, pore volume 1.4-2.0ml/g.
4. the water-fast printing paper of high glaze according to claim 1, it is characterised in that：The ink absorbing layer is applied in formula of liquid, described
Polymer emulsion is nonionic vinyl acetate-ethylene copolymerization emulsions.
5. the water-fast printing paper of high glaze according to claim 1, it is characterised in that：The glazing layer is applied in formula of liquid, described
Alumina gel particle diameter is less than or equal to 1 micron, solid content 25-30, and pH value is more than or equal to 3.
6. the water-fast printing paper of high glaze according to claim 1, it is characterised in that：The glazing layer is applied in formula of liquid, described
Alcohol is n-butanol, ethanol, the one kind in isopropanol.
7. the preparation method of the water-fast printing paper of a kind of high glaze as claimed in claim 1, it is characterised in that：Comprise the steps：
（1）Ink-absorbed coated layer liquid and preparation method thereof：
In formula technique ratio, color fixing agent, defoamer, brightening agent, poly-vinyl alcohol solution are added separately in water, are stirred
Afterwards, silica is added, after high-speed stirred 30-90 minute, adds polymer emulsion, high-speed stirred 20-60 minute, filter, treat
With；
（2）Glazing coating liquid preparing process：
Water is added in Alumina gel first, is the 20% of water inventory, under conditions of at the uniform velocity stirring, be separately added into alcohol, defoamer increases
White agent, at a high speed dispersion 30-90 minutes, is slowly added dropwise ammoniacal liquor under the conditions of high-speed stirred, stirs 20-40 minutes, respectively slow
Lubricant and polymer emulsion are added under conditions of stirring, high-speed stirred 30-60 minute, is filtered, it is stand-by；
（3）Back of the body coating layer liquid preparing process：
Successively opacity polymer and water are added in polymer emulsion under slow stirring, are stirred；
（4）Printing paper preparation technology that high glaze is water-fast：
Ink-absorbed coated layer is coated in cast coated base paper using comma scraper doctor blade process, butt coating weight control 15-20 gram/it is flat
Square rice, the heated-air drying under the conditions of 60-100 DEG C；Using airblade coating technique by glazing layer coating liquid on ink absorbing layer,
Butt coating weight be 3-5 gram/m, in room temperature to heated-air drying under the conditions of 60 DEG C to leather hard, hot pressing to minute surface drying cylinder,
Minute surface dryer temperature is 90-120 DEG C, and platen pressure is 0.1-0.4MPa, de- cylinder after being dried completely；Using the bar coating coating back of the body
Coating layer liquid, butt coating weight 3-8 gram/m are dried under the conditions of 60-90 DEG C, as finished product.
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| CN107604754A (en) * | 2017-08-12 | 2018-01-19 | 安徽文峰特种纸业有限公司 | A kind of preparation technology of color ink jet printed photographic paper |
| CN107674457A (en) * | 2017-08-12 | 2018-02-09 | 安徽文峰特种纸业有限公司 | A kind of preparation method of improved silica filler for photographic paper ink absorbing coating |
| CN108425287A (en) * | 2018-04-08 | 2018-08-21 | 温州创佳影像材料有限公司 | A kind of digital metal-like bloom printing paper and its production technology suitable for UV lamination glazings |
| CN108485403A (en) * | 2018-04-08 | 2018-09-04 | 温州创佳影像材料有限公司 | A kind of digital printing non-woven fabrics and its production technology |
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| CN107674457A (en) * | 2017-08-12 | 2018-02-09 | 安徽文峰特种纸业有限公司 | A kind of preparation method of improved silica filler for photographic paper ink absorbing coating |
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| CN109235123A (en) * | 2018-08-22 | 2019-01-18 | 安徽文峰特种纸业有限公司 | A kind of bloom printing paper preparation method of high print performance |
| CN109235123B (en) * | 2018-08-22 | 2021-04-06 | 安徽文峰特种纸业有限公司 | Preparation method of high-printing-performance high-gloss photographic paper |
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