CN104877419A - Gouache and acrylic painting pigment and method for manufacturing same - Google Patents

Gouache and acrylic painting pigment and method for manufacturing same Download PDF

Info

Publication number
CN104877419A
CN104877419A CN201510280245.9A CN201510280245A CN104877419A CN 104877419 A CN104877419 A CN 104877419A CN 201510280245 A CN201510280245 A CN 201510280245A CN 104877419 A CN104877419 A CN 104877419A
Authority
CN
China
Prior art keywords
parts
powder
gouache
acrylic emulsion
acrylic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201510280245.9A
Other languages
Chinese (zh)
Other versions
CN104877419B (en
Inventor
刘其通
何莉娜
梁立军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hebei Qingzhu painting material technology Co.,Ltd.
Original Assignee
Hebei Qing Zhuhua Material Science And Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hebei Qing Zhuhua Material Science And Technology Ltd filed Critical Hebei Qing Zhuhua Material Science And Technology Ltd
Priority to CN201510280245.9A priority Critical patent/CN104877419B/en
Publication of CN104877419A publication Critical patent/CN104877419A/en
Application granted granted Critical
Publication of CN104877419B publication Critical patent/CN104877419B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/06Artists' paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

Abstract

The invention provides gouache and acrylic painting pigment. A pH (potential of hydrogen) value of the gouache and acrylic painting pigment is 7-8. The gouache and acrylic painting pigment comprises, by weight, 10-15 parts of toner, 0.3-0.5 part of wetting agents, 0.02-0.05 part of preservatives, 30-40 parts of water, 5-15 parts of peach gum liquid, 25-35 parts of acrylic emulsion, 10-15 parts of alkali swelling type thickeners and 5-10 parts of fillers. The gouache and acrylic painting pigment has the advantages that the peach gum liquid and the acrylic emulsion are jointly used as adhesive, protective films can be formed after the peach gum liquid and the acrylic emulsion are dried, accordingly, the gouache and acrylic painting pigment is excellent in color retention, dry and wet colors of the obtained pigment are consistent with one another, cracking can be prevented, and the gouache and acrylic painting pigment is waterproof; systems are thickened by the alkali swelling type thickeners, thick effects can be realized by electrostatic repulsion by means of salt formation, accordingly, the painting smoothness of products can be improved, and dry and wet color difference can be reduced.

Description

A kind of powder third drawing pigment and preparation method thereof
Technical field
The present invention relates to pigment art, particularly a kind of powder third drawing pigment and preparation method thereof.
Background technology
Pigment is used to painted powdery substance.It does not dissolve in the media such as water, grease, resin or organic solvent, but can disperse in these media equably and medium can be made painted, and has certain opacifying power.The pigment basic demand particle of the fine arts is fine and smooth, bright-colored, sustained look.Existing fine arts pigment comprises gouache color, acrylic paints, watercolors etc.
Wherein, gouache color is a kind of comparatively general pigment for painting.Gouache color is add white powder in watercolors at first, makes color opaque and the product innovation obtained.Gouache color is opaque, easily revises.Gouache color is generally prepared from by starting material such as toner, a large amount of weighting material, wetting agent, sanitas and bonding agents.Wherein, by using a large amount of weighting agents that pigment can be made to obtain higher concentration and opaque sense.Gouache color in wet, has higher saturation ratio, and dry after, because the effect of powder and color tarnish, saturation ratio is sent out and is significantly reduced.And the raising of pigment lightness is by dilution, adds powder or realize containing the light colour that opaque pigment is more, therefore its Drought-wet change is larger.
Due to, gouache color in use easily occurs that dry wet aberration is comparatively large, paints not smooth, and burnt hair obfuscation after dry, occur the problems such as dry and cracked, therefore researchist explores various new pigment one after another.
Summary of the invention
The technical problem that the present invention solves is to provide a kind of powder third drawing pigment, and drawing is smooth, without dry wet aberration, not dry and cracked, and has water resistance.
The invention discloses a kind of powder third drawing pigment, its pH value is 7 ~ 8, comprises the component of following weight part:
Toner 10 ~ 15 parts;
Wetting agent 0.3 ~ 0.5 part;
Sanitas 0.02 ~ 0.05 part;
30 ~ 40 parts, water;
Peach colloidal solution 5 ~ 15 parts;
ACRYLIC EMULSION 25 ~ 35 parts;
Alkali swelling type thickening material 10 ~ 15 parts;
5 ~ 10 parts, weighting material.
Preferably, described alkali swelling type thickening material is water-soluble acrylic ester multipolymer.
Preferably, the mass ratio of described peach colloidal solution and ACRYLIC EMULSION is 1:2 ~ 5.
Preferably, comprising: described alkali swelling type thickening material 12 ~ 14 parts.
Preferably, comprising: peach colloidal solution 8 ~ 12 parts.
Preferably, comprising: ACRYLIC EMULSION 30 ~ 33 parts.
The invention also discloses a kind of preparation method of powder third drawing pigment, comprise the following steps:
By 10 ~ 15 parts of toners, 0.3 ~ 0.5 part of wetting agent, 0.02 ~ 0.05 portion of sanitas and 30 ~ 40 parts of water mixed grindings evenly, obtain color;
After 5 ~ 15 parts of peach colloidal solutions and 25 ~ 35 parts of ACRYLIC EMULSION mixing, add 10 ~ 15 parts of alkali swelling type thickening materials, with alkali adjust ph to 7 ~ 8, be uniformly dispersed, obtain bonding agent;
Described color, bonding agent and 5 ~ 10 parts of weighting materials are mixed, obtains powder third drawing pigment.
Preferably, also comprise, described peach colloidal solution obtains through following methods:
Peach gum is carried out thermostatically heating, stirs, form peach colloidal solution.
Preferably, the temperature of described heating is 70 ~ 100 DEG C.
Preferably, the fineness after described grinding is less than 35 microns.
Compared with prior art, the invention provides a kind of powder third drawing pigment, its pH value is 7 ~ 8, comprises the component of following weight part: toner 10 ~ 15 parts; Wetting agent 0.3 ~ 0.5 part; Sanitas 0.02 ~ 0.05 part; 30 ~ 40 parts, water; Peach colloidal solution 5 ~ 15 parts; ACRYLIC EMULSION 25 ~ 35 parts; Alkali swelling type thickening material 10 ~ 15 parts; 5 ~ 10 parts, weighting material.The present invention jointly as tackiness agent using peach colloidal solution and ACRYLIC EMULSION, forms protective membrane after drying, has good tint retention, makes the dry wet color of pigment that obtains consistent, there will not be dry and cracked phenomenon simultaneously, possess water resistance.Secondly, the present invention additionally uses alkali swelling type thickening material and carries out thickening to system, and by salify, electrostatic repulsion reaches dense thick effect, thus improves the drawing fluency of product, reduces dry wet aberration.
Accompanying drawing explanation
Fig. 1 represents that the present invention prepares the schematic flow sheet of powder third drawing pigment.
Embodiment
In order to understand the present invention further, below in conjunction with embodiment, the preferred embodiment of the invention is described, but should be appreciated that these describe just for further illustrating the features and advantages of the present invention, instead of limiting to the claimed invention.
The embodiment of the invention discloses a kind of powder third drawing pigment, its pH value is 7 ~ 8, comprises the component of following weight part:
Toner 10 ~ 15 parts;
Wetting agent 0.3 ~ 0.5 part;
Sanitas 0.02 ~ 0.05 part;
30 ~ 40 parts, water;
Peach colloidal solution 5 ~ 15 parts;
ACRYLIC EMULSION 25 ~ 35 parts;
Alkali swelling type thickening material 10 ~ 15 parts;
5 ~ 10 parts, weighting material.
In the present invention, utilize the compound action of toner, wetting agent, sanitas, water, peach colloidal solution, ACRYLIC EMULSION, alkali swelling type thickening material and weighting material, obtain powder third drawing pigment, which overcome the color of gouache color and the defect of fluency aspect, while remaining opaque sense, improve the fluency of pigment drawing, and its dry wet color is consistent, there will not be dry and cracked and dry after to be a bit darkish in color the phenomenon of burnt hair, good waterproof performance.Powder third drawing pigment pH value of the present invention is 7 ~ 8.
According to the present invention, the kind of the present invention to described toner, wetting agent and sanitas is not particularly limited, identical with existing gouache color, and described toner, wetting agent and sanitas all can be bought by market and obtain.The addition of described toner is 10 ~ 15 weight parts, is preferably 12 ~ 14 parts.The addition of described wetting agent is 0.3 ~ 0.5 weight part, and the addition of described sanitas is 0.02 ~ 0.05 weight part.
Described toner, wetting agent, sanitas and water form color, are the one-tenth color part of powder third drawing pigment.The addition of water is 30 ~ 40 weight parts, is preferably 33 ~ 38 weight parts.
According to the present invention, described peach colloidal solution and ACRYLIC EMULSION are tackiness agent, both actings in conjunction, and after mixing with color, thickening material and weighting agent, play bond effect.After described peach colloidal solution and ACRYLIC EMULSION join whole system, the moisture evaporation first in ACRYLIC EMULSION, latex particle bead is tightly packed, and water and water-soluble substances are filled between the space of latex particle; Along with the continuous volatilization of moisture; the protective layer of polymer particle surface absorption is destroyed; gap is more and more less; until formation kapillary; capillary action forces acrylic particles to be out of shape, and progressively polymer beads becomes oblique square dodecahedron by spherical, until intergranular interface disappears; the last polymkeric substance end of the chain spreads mutually, forms continuous print polymer coating film.Peach colloidal solution promotes the film forming of ACRYLIC EMULSION.The transparent coating of this layer containing a large amount of hydrophobic grouping, makes pigment have excellent water-repellancy and tint retention.
Described peach colloidal solution and ACRYLIC EMULSION have similar viscosity, can mutually merge.The source of the present invention to peach colloidal solution and ACRYLIC EMULSION does not have particular requirement, commercially available prod.Described peach colloidal solution is preferably prepared in accordance with the following methods:
Peach gum is carried out thermostatically heating, stirs, form peach colloidal solution.
The temperature of described heating is preferably 70 ~ 100 DEG C, is more preferably 80 ~ 85 DEG C.Comparatively suitable range of viscosities is obtained in order to make peach colloidal solution, in whipping process, preferred employing six palintrope leaf open turbine oar, such stirs flow pattern is radial flow, can be that boundary forms upper and lower two cycling streams from paddle when there being baffle plate, mild shearing force effectively can ensure the molecular structure that peach gum is comparatively complete, in order to obtain can with the range of viscosities of the blended coupling of ACRYLIC EMULSION.
The addition of described peach colloidal solution is 5 ~ 15 weight parts, is preferably 8 ~ 12 weight parts.The addition of described ACRYLIC EMULSION is 25 ~ 35 weight parts, is preferably 30 ~ 33 weight parts.The mass ratio of described peach colloidal solution and ACRYLIC EMULSION is preferably 1:2 ~ 5, is more preferably 1:3.
According to the present invention, described powder third drawing pigment also comprises alkali swelling type thickening material, and it is alkali-soluble emulsion, is preferably water-soluble acrylic ester multipolymer.Described alkali swelling type thickening material has the curling linear structure of long-chain, with a considerable amount of carboxyl on its macromolecular chain.Under alkaline environment, these converting carboxylate groups salifies, under salification, due to the electrostatic repulsion of negative charge between neighbored carboxyl groups, polymkeric substance is extended, thus system density is increased, the expansion of molecular chain simultaneously causes the hydrodynamic size of polymkeric substance to increase, thus turn increase winding and the resistance to flow of molecule, make integral system have the effect of thickness.The addition of described swelling property alkali swelling type thickening material is 10 ~ 15 weight parts, is preferably 12 ~ 14 weight parts.
According to the present invention, described powder third drawing pigment also comprises weighting material, the addition of described weighting material is 5 ~ 10 and weight part, the present invention interacts by adopting alkali swelling property thickening material and adhesion agent, decrease the addition of weighting material, thus not easily there is dry wet aberration, not easily there is burnt hair obfuscation phenomenon after dry, be conducive to the fluency improving drawing.The weighting material that the present invention adopts is consistent with the weighting material that existing gouache color adopts, commercially available prod.
The invention also discloses a kind of preparation method of powder third drawing pigment, comprise the following steps:
By 10 ~ 15 parts of toners, 0.3 ~ 0.5 part of wetting agent, 0.02 ~ 0.05 portion of sanitas and 30 ~ 40 parts of water mixed grindings evenly, obtain color;
After 5 ~ 15 parts of peach colloidal solutions and 25 ~ 35 parts of ACRYLIC EMULSION mixing, add 10 ~ 15 parts of alkali swelling type thickening materials, with alkali adjust ph to 7 ~ 8, be uniformly dispersed, obtain bonding agent;
Described color, bonding agent and 5 ~ 10 parts of weighting materials are mixed, obtains powder third drawing pigment.
In the present invention, with toner, wetting agent, sanitas, water, peach colloidal solution, ACRYLIC EMULSION, alkali swelling type thickening material and weighting material for raw material, the source of each raw material described, character and addition are identical with technique scheme, are not again repeating.
Fig. 1 represents that the present invention prepares the schematic flow sheet of powder third drawing pigment.
In the present invention, color and tackiness agent is first prepared.
By 10 ~ 15 parts of toners, 0.3 ~ 0.5 part of wetting agent, 0.02 ~ 0.05 portion of sanitas and 30 ~ 40 parts of water mixed grindings evenly, obtain color.Fineness after described grinding is preferably less than 35 microns.
After 5 ~ 15 parts of peach colloidal solutions and 25 ~ 35 parts of ACRYLIC EMULSION mixing, add 10 ~ 15 parts of alkali swelling type thickening materials, with alkali adjust ph to 7 ~ 8, be uniformly dispersed, obtain bonding agent.Described alkali is preferably trolamine, ammoniacal liquor, Monoethanolamine MEA BASF or sodium hydroxide.Acting as of described alkali makes alkali swelling type thickening material salify.Described alkali swelling type thickening material has the curling linear structure of long-chain, with a considerable amount of carboxyl on its macromolecular chain.Under alkaline environment, these converting carboxylate groups salifies, under salification, due to the electrostatic repulsion of negative charge between neighbored carboxyl groups, polymkeric substance is extended, thus system density is increased, the expansion of molecular chain simultaneously causes the hydrodynamic size of polymkeric substance to increase, thus turn increase winding and the resistance to flow of molecule, make integral system have the effect of thickness.
Described peach colloidal solution is preferably prepared in accordance with the following methods:
Peach gum is carried out thermostatically heating, stirs, form peach colloidal solution.
The temperature of described heating is preferably 70 ~ 100 DEG C, is more preferably 80 ~ 85 DEG C.The present invention is not particularly limited for pressure when stirring, normal pressure.Comparatively suitable range of viscosities is obtained in order to make peach colloidal solution, in whipping process, preferred employing six palintrope leaf open turbine oar, such stirs flow pattern is radial flow, can be that boundary forms upper and lower two cycling streams from paddle when there being baffle plate, mild shearing force effectively can ensure the molecular structure that peach gum is comparatively complete, in order to obtain can with the range of viscosities of the blended coupling of ACRYLIC EMULSION.
Described dispersion process preferably utilizes high speed dispersor to disperse.
After obtaining color and tackiness agent, described color, bonding agent and 5 ~ 10 parts of weighting materials are mixed, obtains powder third drawing pigment.Described mixing preferably utilizes low-speed agitator to stir, and then grinds further through three-roll grinder.
Powder third drawing pigment of the present invention, its pH value is 7 ~ 8, comprises the component of following weight part: toner 10 ~ 15 parts; Wetting agent 0.3 ~ 0.5 part; Sanitas 0.02 ~ 0.05 part; 30 ~ 40 parts, water; Peach colloidal solution 5 ~ 15 parts; ACRYLIC EMULSION 25 ~ 35 parts; Alkali swelling type thickening material 10 ~ 15 parts; 5 ~ 10 parts, weighting material.The present invention jointly as tackiness agent using peach colloidal solution and ACRYLIC EMULSION, forms protective membrane after drying, has good tint retention, makes the dry wet color of pigment that obtains consistent, there will not be dry and cracked phenomenon simultaneously, possess water resistance.Secondly, the present invention additionally uses alkali swelling type thickening material and carries out thickening to system, and by salify, electrostatic repulsion reaches dense thick effect, thus improves the drawing fluency of product, reduces dry wet aberration.
In order to understand the present invention further, be described in detail to powder third drawing pigment provided by the invention and preparation method thereof below in conjunction with embodiment, protection scope of the present invention is not limited by the following examples.
Embodiment 1
10 parts of toners, 0.3 part of wetting agent, 0.05 portion of sanitas and 30 parts of water are mixed, utilizes three-roll grinder to grind.Obtain color.
By peach gum thermostatically heating under 80 DEG C of conditions, continue stirring 2 hours, form peach colloidal solution.
By 5 parts of peach colloidal solutions and 25 parts of ACRYLIC EMULSION mixing, add 10 parts of alkali swelling type thickening materials, add trolamine adjust ph to 7.8, utilize high speed dispersor to be uniformly dispersed, obtain tackiness agent.
The color obtained and tackiness agent are mixed and adds 5 parts of weighting materials, again go up three-roll grinder and mill evenly, obtain powder third drawing pigment.
Embodiment 2
15 parts of toners, 0.5 part of wetting agent, 0.02 portion of sanitas and 40 parts of water are mixed, utilizes three-roll grinder to grind.Obtain color.
By peach gum thermostatically heating under 80 DEG C of conditions, continue stirring 2 hours, form peach colloidal solution.
By 15 parts of peach colloidal solutions and 35 parts of ACRYLIC EMULSION mixing, add 15 parts of alkali swelling type thickening materials, add trolamine adjust ph to 7.5, utilize high speed dispersor to be uniformly dispersed, obtain tackiness agent.
The color obtained and tackiness agent are mixed and adds 5 parts of weighting materials, again go up three-roll grinder and mill evenly, obtain powder third drawing pigment.
Embodiment 3
13 parts of toners, 0.4 part of wetting agent, 0.03 portion of sanitas and 35 parts of water are mixed, utilizes three-roll grinder to grind.Obtain color.
By peach gum thermostatically heating under 85 DEG C of conditions, continue stirring 5 hours, form peach colloidal solution.
By 10 parts of peach colloidal solutions and 30 parts of ACRYLIC EMULSION mixing, add 12 parts of alkali swelling type thickening materials, add trolamine adjust ph to 8, utilize high speed dispersor to be uniformly dispersed, obtain tackiness agent.
The color obtained and tackiness agent are mixed and adds 5 parts of weighting materials, again go up three-roll grinder and mill evenly, obtain powder third drawing pigment.
Embodiment 4
15 parts of toners, 0.3 part of wetting agent, 0.02 portion of sanitas and 35 parts of water are mixed, utilizes three-roll grinder to grind.Obtain color.
By peach gum thermostatically heating under 90 DEG C of conditions, continue stirring 4 hours, form peach colloidal solution.
By 10 parts of peach colloidal solutions and 30 parts of ACRYLIC EMULSION mixing, add 10 parts of alkali swelling type thickening materials, add trolamine adjust ph to 7, utilize high speed dispersor to be uniformly dispersed, obtain tackiness agent.
The color obtained and tackiness agent are mixed and adds 5 parts of weighting materials, again go up three-roll grinder and mill evenly, obtain powder third drawing pigment.
Comparative example 1
Commercially available gouache color.
Water-repellancy:
Use platypelloid type design pen, powder third drawing pigment to be coated onto on coating paper 3 times.By obtained film after at room temperature dry 1 hour, use the spuit of 1mL capacity, above-mentioned film drips tap water, and ambient temperatare puts 6 hours, observes the state of film.Film do not find change time as A, find film produce crack, decolouring and/or water droplet trace time as C.
Chromatism test:
Get a certain amount of pigment under dry wet different states, observe colour-change.
Fluency is tested:
Use platypelloid type design pen, pigment to be coated onto on coating paper 3 times.Observe pen touch.
The performance perameter of powder third drawing pigment prepared by table 1 embodiment 1 ~ 4
The explanation of above embodiment just understands method of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improve and modify and also fall in the protection domain of the claims in the present invention.
To the above-mentioned explanation of the disclosed embodiments, professional and technical personnel in the field are realized or uses the present invention.To be apparent for those skilled in the art to the multiple amendment of these embodiments, General Principle as defined herein can without departing from the spirit or scope of the present invention, realize in other embodiments.Therefore, the present invention can not be restricted to these embodiments shown in this article, but will meet the widest scope consistent with principle disclosed herein and features of novelty.

Claims (10)

1. powder third drawing pigment, its pH value is 7 ~ 8, comprises the component of following weight part:
Toner 10 ~ 15 parts;
Wetting agent 0.3 ~ 0.5 part;
Sanitas 0.02 ~ 0.05 part;
30 ~ 40 parts, water;
Peach colloidal solution 5 ~ 15 parts;
ACRYLIC EMULSION 25 ~ 35 parts;
Alkali swelling type thickening material 10 ~ 15 parts;
5 ~ 10 parts, weighting material.
2. powder third drawing pigment according to claim 1, is characterized in that, described alkali swelling type thickening material is water-soluble acrylic ester multipolymer.
3. powder third drawing pigment according to claim 2, is characterized in that, the mass ratio of described peach colloidal solution and ACRYLIC EMULSION is 1:2 ~ 5.
4. powder third drawing pigment according to claims 1 to 3 any one, is characterized in that, comprising: described alkali swelling type thickening material 12 ~ 14 parts.
5. powder third drawing pigment according to claim 4, is characterized in that, comprising: peach colloidal solution 8 ~ 12 parts.
6. powder third drawing pigment according to claim 5, is characterized in that, comprising: ACRYLIC EMULSION 30 ~ 33 parts.
7. a preparation method for powder third drawing pigment, comprises the following steps:
By 10 ~ 15 parts of toners, 0.3 ~ 0.5 part of wetting agent, 0.02 ~ 0.05 portion of sanitas and 30 ~ 40 parts of water mixed grindings evenly, obtain color;
After 5 ~ 15 parts of peach colloidal solutions and 25 ~ 35 parts of ACRYLIC EMULSION mixing, add 10 ~ 15 parts of alkali swelling type thickening materials, with alkali adjust ph to 7 ~ 8, be uniformly dispersed, obtain bonding agent;
Described color, bonding agent and 5 ~ 10 parts of weighting materials are mixed, obtains powder third drawing pigment.
8. preparation method according to claim 7, is characterized in that, also comprises, and described peach colloidal solution obtains through following methods:
Peach gum is carried out thermostatically heating, stirs, form peach colloidal solution.
9. preparation method according to claim 8, is characterized in that, the temperature of described heating is 70 ~ 100 DEG C.
10. preparation method according to claim 7, is characterized in that, the fineness after described grinding is less than 35 microns.
CN201510280245.9A 2015-05-27 2015-05-27 Gouache and acrylic painting pigment and method for manufacturing same Active CN104877419B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510280245.9A CN104877419B (en) 2015-05-27 2015-05-27 Gouache and acrylic painting pigment and method for manufacturing same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510280245.9A CN104877419B (en) 2015-05-27 2015-05-27 Gouache and acrylic painting pigment and method for manufacturing same

Publications (2)

Publication Number Publication Date
CN104877419A true CN104877419A (en) 2015-09-02
CN104877419B CN104877419B (en) 2017-03-22

Family

ID=53945112

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510280245.9A Active CN104877419B (en) 2015-05-27 2015-05-27 Gouache and acrylic painting pigment and method for manufacturing same

Country Status (1)

Country Link
CN (1) CN104877419B (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106554683A (en) * 2016-11-21 2017-04-05 郑州源冉生物技术有限公司 A kind of compound propylene material of drawing
CN106590408A (en) * 2016-11-22 2017-04-26 赖禄波 Crack resistant coating and preparation method thereof
CN106752389A (en) * 2017-01-20 2017-05-31 河北青竹画材科技有限公司 A kind of oiliness drawing pen and preparation method thereof
CN106752220A (en) * 2016-11-21 2017-05-31 郑州源冉生物技术有限公司 A kind of art painting compound propylene material and preparation method thereof
CN107603309A (en) * 2017-09-29 2018-01-19 江苏工程职业技术学院 A kind of formaldehydeless art painting sole pigment and its preparation technology
CN108192400A (en) * 2017-12-19 2018-06-22 宋吕阳光 A kind of pigment of drawing and preparation method thereof
CN108285710A (en) * 2018-02-09 2018-07-17 上海马利画材销售有限公司 A kind of color compositions and preparation method thereof and purposes
CN108587283A (en) * 2018-05-21 2018-09-28 张丽娟 A kind of oil painting drawing pigment of strong adhesive force and preparation method thereof
CN111334108A (en) * 2020-04-24 2020-06-26 河北青竹画材科技有限公司 Solid acrylic painting pigment and preparation method thereof
CN116790145A (en) * 2022-10-21 2023-09-22 广州市美帮祈富文仪有限公司 Preparation method of high-chroma anti-dry-crack gouache painting pigment and pigment thereof
CN116814104A (en) * 2022-10-21 2023-09-29 广州市美帮祈富文仪有限公司 Preparation method of pseudo-classic repair effect acrylic painting pigment and pigment thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101225251A (en) * 2007-12-26 2008-07-23 宋健 Art stacking acrylic paints containing nano-pigment and method for manufacturing same
CN101624488A (en) * 2008-07-10 2010-01-13 宁波松鹤文具有限公司 Writing-painting material with stereoscopic effect and preparation method thereof
JP2012144709A (en) * 2010-12-20 2012-08-02 Sakura Color Products Corp Water color pigment composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101225251A (en) * 2007-12-26 2008-07-23 宋健 Art stacking acrylic paints containing nano-pigment and method for manufacturing same
CN101624488A (en) * 2008-07-10 2010-01-13 宁波松鹤文具有限公司 Writing-painting material with stereoscopic effect and preparation method thereof
JP2012144709A (en) * 2010-12-20 2012-08-02 Sakura Color Products Corp Water color pigment composition

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106752220A (en) * 2016-11-21 2017-05-31 郑州源冉生物技术有限公司 A kind of art painting compound propylene material and preparation method thereof
CN106554683A (en) * 2016-11-21 2017-04-05 郑州源冉生物技术有限公司 A kind of compound propylene material of drawing
CN106590408A (en) * 2016-11-22 2017-04-26 赖禄波 Crack resistant coating and preparation method thereof
CN106752389B (en) * 2017-01-20 2020-03-06 河北青竹画材科技有限公司 Oily drawing pen and preparation method thereof
CN106752389A (en) * 2017-01-20 2017-05-31 河北青竹画材科技有限公司 A kind of oiliness drawing pen and preparation method thereof
CN107603309A (en) * 2017-09-29 2018-01-19 江苏工程职业技术学院 A kind of formaldehydeless art painting sole pigment and its preparation technology
CN108192400A (en) * 2017-12-19 2018-06-22 宋吕阳光 A kind of pigment of drawing and preparation method thereof
CN108285710A (en) * 2018-02-09 2018-07-17 上海马利画材销售有限公司 A kind of color compositions and preparation method thereof and purposes
CN108285710B (en) * 2018-02-09 2020-05-01 上海马利画材销售有限公司 Pigment composition and preparation method and application thereof
CN108587283A (en) * 2018-05-21 2018-09-28 张丽娟 A kind of oil painting drawing pigment of strong adhesive force and preparation method thereof
CN111334108A (en) * 2020-04-24 2020-06-26 河北青竹画材科技有限公司 Solid acrylic painting pigment and preparation method thereof
CN116790145A (en) * 2022-10-21 2023-09-22 广州市美帮祈富文仪有限公司 Preparation method of high-chroma anti-dry-crack gouache painting pigment and pigment thereof
CN116814104A (en) * 2022-10-21 2023-09-29 广州市美帮祈富文仪有限公司 Preparation method of pseudo-classic repair effect acrylic painting pigment and pigment thereof

Also Published As

Publication number Publication date
CN104877419B (en) 2017-03-22

Similar Documents

Publication Publication Date Title
CN104877419A (en) Gouache and acrylic painting pigment and method for manufacturing same
US4585815A (en) Stencil printing ink
CN102382515B (en) Environment-friendly, strong acid-resistant, strong base-resistant and steaming-resistant ink and preparation method
CN102964914B (en) Water-based narrow coated paper flexible printing ink and method for preparing same
CN104099807A (en) Formula and preparation method for high gloss color ink-jet printing paper coating
CN111748270B (en) Coating for projection screen and preparation method thereof
CN110204966A (en) A kind of environment-friendly water-based coating fluid and preparation method thereof enhancing digital printing ink adhesion
CN111500133A (en) Sand-in-water multicolor paint and preparation method thereof
CN105176170A (en) Water-based acrylic painting pigment and preparation method thereof
CN105838173B (en) A kind of water paint and preparation method thereof, application method
CN102501674A (en) Glossy waterproof polypropylene photo paper applicable for aqueous ink and its preparation method
CN103820046A (en) Film applicable to ink-jet printer and manufacturing method of film
CN104271681B (en) Aqueous painting material composition
CN104371411B (en) A kind of hydrate colour ink-jet printing media and production method thereof
CN107459867A (en) A kind of aqueous polyurethane compound oil ink of super-high solid content low viscosity
CN112341923A (en) Water-based color modifier and preparation method thereof
CN114761495A (en) Water-soluble sheet-like coloring material, water-soluble sheet-like coloring material set, and pigment set
US20170088714A1 (en) Coated silver colored colorant
CN104669811B (en) Ink-jet printing photo film and preparation method thereof
Klöckl Handbook of Colorants Chemistry: In Painting, Art and Inks
CN101993635A (en) Erasable ink and preparation method thereof
JPH0119705B2 (en)
CN1887982A (en) Waterproof neutral ink with nanometer level pigment and its prepn
TWI831504B (en) Binder components for water-based ink and water-based ink
CN110684395B (en) Structural color ink and preparation method and application thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
EXSB Decision made by sipo to initiate substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CP01 Change in the name or title of a patent holder
CP01 Change in the name or title of a patent holder

Address after: No. 1, Qingzhu Road, Hengde Industrial Park, Hengshui City, Hebei Province

Patentee after: Hebei Qingzhu painting material technology Co.,Ltd.

Address before: No. 1, Qingzhu Road, Hengde Industrial Park, Hengshui City, Hebei Province

Patentee before: HEBEI CHINJOO ART PIGMENT Co.,Ltd.