CN101225251A - Art stacking acrylic paints containing nano-pigment and method for manufacturing same - Google Patents
Art stacking acrylic paints containing nano-pigment and method for manufacturing same Download PDFInfo
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- CN101225251A CN101225251A CNA2007103024328A CN200710302432A CN101225251A CN 101225251 A CN101225251 A CN 101225251A CN A2007103024328 A CNA2007103024328 A CN A2007103024328A CN 200710302432 A CN200710302432 A CN 200710302432A CN 101225251 A CN101225251 A CN 101225251A
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Abstract
The invention relates to art accumulated acrylic paints with nano-pigment and the preparation method, belonging to technical field of painting things. First the hydroxyethylcellulose and the gum arabic are put into distilled water and then the bond glue can be obtained after swelling and heating. Then the bond glue is added in sodium benzoate, the nano-graining paste, the polyacrylic acid latex and aqueous polyurethane emulsion and then blended evenly to obtain sizing agent after adding powder pigment and calcium carbonate. The sizing agent can be obtained after grinding. The preparation method utilizes the polypropylene latex to make art accumulated acrylic paints together with the aqueous polyurethane emulsion. The paints can cause solid accumulated result painting by oil painting knife or paintbrush. The art accumulated acrylic paints with nano-pigment has the advantages of good service performance, bright color, good weather resisting property and strong chemical durability, so can meet the high requirement of the artist for art accumulated acrylic paints.
Description
Technical field
The present invention relates to a kind of art stacking acrylic paints and manufacture method thereof that contains nano dye, specifically belong to the painting supply technical field.
Background technology
In prior art, in art stacking acrylic paints product in the past, because the pigment raw material that uses is an insoluble or insoluble, its particle diameter is bigger, generally is the macrobead or the little agglomerate of 20-100 micron.Though can be when product is made in allotment through grinding with binding agent, common pigments particle redispersion with after polymerization, but efficient and effect are unsatisfactory, granules of pigments particle diameter in the finished product still reaches 10-40um, the stacking acrylic paints finished product that causes traditional fine arts to be used shows the dimness of drawing color color and luster owing to dispersive granules of pigments in the matrix is relatively large, saturation ratio is poor, the picture skin texture is more coarse, and the physical stability of product itself is poor, influences product appearance and shelf-life.
The common pigments grain diameter is big, color and luster is dull, the problem of physical stability difference though use soluble dye imitating element raw material can solve.But for the drawing art painting, the perviousness of dyestuff and chemical instability have caused the critical defect of product again.Dyestuff not dried can the generation when solvent is arranged to the picture infiltration causes variable color on the painting process surface with the solvent perviousness, this is that graphics art man is undesirable.This phenomenon of osmosis can influence or run counter to the artist and create the expression of thought on works; In addition, the poor chemical stability of dyestuff can make the color variable color under the factor effect such as humidity in oxygen, the air, fade in illumination, air, and works can lose original artistic charm and value, preserves the life-span also to shorten greatly.
Summary of the invention
The objective of the invention is to overcome above-mentioned weak point, thereby provide a kind of art stacking acrylic paints and manufacture method thereof that contains nano dye, when it had not only possessed good usability and bright-coloured bright color but also possessed excellent high-weatherability and chemical stability; Satisfied the high request of artist to art stacking acrylic paints;
Main solution of the present invention is achieved in that
The present invention is a kind of contain nano dye art stacking acrylic paints formula rate according to the mass fraction: the present invention comprises following component:
Nano dye (slurry) 1-5 part
Common pigments (powder) 5-25 part
Polyacrylic acid emulsion (solid content 65 ± 2%) 40-60 part
Aqueous polyurethane yogurt liquid (solid content 35 ± 2%) 5-15 part
Gum arabic 1-8 part
Natvosol 1-8 part
Lime carbonate 10-30 part
Sodium Benzoate 0.2-1 part
Distilled water 5-20 part
Earlier Natvosol and gum arabic are sprinkled in the distilled water, are made into the tackiness agent glue through swelling, heating; In the tackiness agent glue, add phenylformic acid again and receive, nano dye (slurry), the polypropylene emulsion, aqueous polyurethane emulsion stirs, and the back adds pigment (powder), lime carbonate stirs evenly and is coarse particles; Coarse particles gets product through grinding.
The manufacture method that the present invention is a kind of to contain the art stacking acrylic paints of nano dye adopts following processing step: formula rate according to the mass fraction:
The present invention gets nano dye (slurry) 1-5 part, common pigments (powder) 5-30 part, polyacrylic acid emulsion (solid content 65 ± 2%) 40-60 part, aqueous polyurethane yogurt liquid (solid content 35 ± 2%) 5-15 part, gum arabic 1-8 part, Natvosol 1-8 part, lime carbonate 10-30 part, Sodium Benzoate 0.2-1 part, distilled water 5-20 part;
1, get Natvosol 1-8 part and gum arabic 1-8 part and be sprinkled in formula ratio distilled water 5-20 part, swelling 6-12 hour, be heated to 80～90 ℃, 30～60 minutes heat-up times, be made into the tackiness agent glue;
2, add phenylformic acid again in above-mentioned tackiness agent glue and receive 0.2-1 part, nano dye (slurry) 1-5 part, polypropylene emulsion 40-60 part, aqueous polyurethane emulsion 5-15 part are stirred to and evenly are mixed liquor;
3, add pigment (powder) 5-30 part at above-mentioned mixed liquor, restir 1～2 hour, lime carbonate 10-30 part is stirred to the even slurry that is in the adding prescription then;
4, will slightly mix pigment slurry and be added in the three-roll grinder hopper, grind 3-5 time through three-roll grinder; Regulate roller gap distance, stand-off distance is 45～50 μ m between two rollers of grinding adjusting for the first time; Stand-off distance is 20～30 μ m between two rollers of grinding adjusting for the second time; Third and fourth, grind to regulate that stand-off distance is 10-15 μ m between two rollers for five times; Roller adopts the recirculated water cooling, and the mill base material fineness after the grinding is below 10 μ m;
5, the mill base material feed liquid through grinding flows in the material storage barrel, gets product.
Described roller cooling temperature is 38～42 ℃;
Described nano dye (slurry) is one or more composite in nano titanium oxide, nano-calcium carbonate, the nano-sized iron oxide.The particle diameter of described nano dye is the 20-100 nanometer.
Described pigment (powder) is one or more composite in titanium dioxide, the ferric oxide.
Compared with the prior art the present invention has the following advantages:
The present invention has overcome the defective of existing product, when the prepared product of prescription that provides and manufacture method had not only possessed good usability and bright-coloured bright color but also possessed excellent high-weatherability and chemical stability; Satisfied the high request of artist to art stacking acrylic paints.
Scattered nano dye colorant slurry use the nano dye raw material to be the commercial goods in the present invention's prescription, for can be directly used in prescription.The particle diameter of nano dye is the 20-100 nanometer.This superfine particle is because the increase greatly of surface-area, and the surface atom chemical bond is unsettled and have special surface effects and a volume effect.These effects cause the change of superfine pigment particles physicals and surface chemistry.The nano dye particle embodies outstanding quality of colour, and bright in colour bright, color is saturated strong, and tinting strength is extremely strong, and has kept water-fast, fast light, the weatherable characteristic of common pigments.Its surface-area increases greatly, and surface energy increases greatly, sterically hindered increase.Sterically hindered increase can make all particulates in the matrix comprise that pigment itself suspends, so the physical stability of product increases.
The nano dye of production domesticization is relatively still expensive, all uses nano dye to make art stacking acrylic paints and will cause product cost to be increased sharply.Use a small amount of nano dye instead of part common pigments raw material in the present invention's prescription, the product of making has reached and has improved use properties and effect, but the Financial cost of not obvious increase product.
But the present invention utilizes the polypropylene emulsion of high solid content to cooperate aqueous polyurethane emulsion to make art stacking acrylic paints, the pigment of this accumulation type produces spatial in the time of can painting with oil painting cutter or paintbrush and piles up effect, and general art painting accumulation effect is very not obvious.
Embodiment
Following the present invention will be further described in conjunction with the embodiments:
Embodiment one: the manufacture method that the present invention is a kind of to contain the art stacking acrylic paints of nano dye adopts following processing step: formula rate according to the mass fraction:
The present invention gets nano dye (slurry) and gets 2.5 parts of nano titanium oxides, 10 parts of common pigments (powder) titanium dioxide, 15 parts in lime carbonate, 45 parts of polyacrylic acid emulsions (solid content 65 ± 2%), 10 parts of aqueous polyurethane yogurt liquid (solid content 35 ± 2%), 2 parts of gum arabics, 4 parts of Natvosols, 0.2 part of Sodium Benzoate, 10 parts of distilled water.
At first get 2 parts of 4 parts of Natvosols and gum arabics and be sprinkled in 10 parts of the formula ratio distilled water, swelling 6 hours is heated to 80 ℃, 30 minutes heat-up times, is made into the tackiness agent glue; Add phenylformic acid again and receive 0.2 part in above-mentioned tackiness agent glue, nano dye (slurry) is got 2.5 parts of nano titanium oxides, 45 parts of polypropylene emulsions, and aqueous polyurethane emulsion is stirred to for 10 parts and evenly is mixed liquor; In above-mentioned mixed liquor, add 10 parts of pigment powder titanium dioxide, 15 parts in lime carbonate, restir 1 hour is stirred to evenly for slightly mixing slurry; To slightly mix pigment slurry and be added in the three-roll grinder hopper, the speed ratio of three-roll grinder three rollers is by 1: 2: 4 (26: 70: 145 rev/mins of rotating speeds), roller diameter 650mm; Regulate the width in roller slit by handwheel; Grind 5 times through three-roll grinder; Stand-off distance is 45 μ m between two rollers of grinding adjusting for the first time; Stand-off distance is 20 μ m between two rollers of grinding adjusting for the second time; Third and fourth, grind to regulate that stand-off distance is 12 μ m between two rollers for five times; Roller adopts the recirculated water cooling, and the roller cooling temperature is 38 ℃, and the mill base material fineness after the grinding is below 10 μ m; Mill base material feed liquid through grinding flows in the material storage barrel, gets product.
Embodiment two: the manufacture method that the present invention is a kind of to contain the art stacking acrylic paints of nano dye adopts following processing step: formula rate according to the mass fraction:
The present invention gets nano dye (slurry) and gets 3.5 parts of 1.5 parts of nano titanium oxides and nano-calcium carbonates, 12 parts of common pigments (powder) titanium dioxide, 20 parts in lime carbonate, 46 parts of polyacrylic acid emulsions (solid content 65 ± 2%), 10 parts of aqueous polyurethane yogurt liquid (solid content 35 ± 2%), 3 parts of gum arabics, 3 parts of Natvosols, 0.3 part of Sodium Benzoate, 12 parts of distilled water;
At first get 3 parts of 3 parts of Natvosols and gum arabics and be sprinkled in 12 parts of the formula ratio distilled water, swelling 8 hours is heated to 85 ℃, 40 minutes heat-up times, is made into the tackiness agent glue; Add phenylformic acid again and receive 0.3 part in above-mentioned tackiness agent glue, nano dye (slurry) is got 3.5 parts of 1.5 parts of nano titanium oxides and nano-calcium carbonates, 46 parts of polypropylene emulsions, and aqueous polyurethane emulsion is stirred to for 10 parts and evenly is mixed liquor; In above-mentioned mixed liquor, add 12 parts of pigment powder titanium dioxide, 20 parts in lime carbonate, restir 1.5 hours, being stirred to evenly is slurry; To slightly mix pigment slurry and be added in the three-roll grinder hopper, the speed ratio of three-roll grinder three rollers is by 1: 2: 4 (26: 70: 145 rev/mins of rotating speeds), roller diameter 650mm; Regulate the width in roller slit by handwheel; Grind 5 times through three-roll grinder; Stand-off distance is 48 μ m between two rollers of grinding adjusting for the first time; Stand-off distance is 25 μ m between two rollers of grinding adjusting for the second time; Third and fourth, grind to regulate that stand-off distance is 12 μ m between two rollers for five times; Roller adopts the recirculated water cooling, and the roller cooling temperature is 40 ℃, and the mill base material fineness after the grinding is below 10 μ m; Mill base material feed liquid through grinding flows in the material storage barrel, gets product.
Embodiment three: the manufacture method that the present invention is a kind of to contain the art stacking acrylic paints of nano dye adopts following processing step: formula rate according to the mass fraction:
The present invention gets nano dye (slurry) and gets 1.5 parts of nano-sized iron oxides, common pigments (powder) is got 7.5 parts of ferric oxide, 30 parts in lime carbonate, 44 parts of polyacrylic acid emulsions (solid content 65 ± 2%), 12 parts of aqueous polyurethane yogurt liquid (solid content 35 ± 2%), 4 parts of gum arabics, 4 parts of Natvosols, 0.4 part of Sodium Benzoate, 15 parts of distilled water;
At first get 4 parts of 4 parts of Natvosols and gum arabics and be sprinkled in 15 parts of the formula ratio distilled water, swelling 10 hours is heated to 90 ℃, 45 minutes heat-up times, is made into the tackiness agent glue; Add phenylformic acid again and receive 0.4 part in above-mentioned tackiness agent glue, nano dye (slurry) is got 1.5 parts of nano-sized iron oxides, 44 parts of polypropylene emulsions, and aqueous polyurethane emulsion is stirred to for 12 parts and evenly is mixed liquor; In above-mentioned mixed liquor, add pigment (powder) and get 7.5 parts of ferric oxide, stirred 1.5 hours, and then adding lime carbonate is stirred to evenly for slightly mixing slurry for 30 parts; To slightly mix slurry and be added in the three-roll grinder hopper, the speed ratio of three-roll grinder three rollers is by 1: 2: 4 (26: 70: 145 rev/mins of rotating speeds), roller diameter 650mm; Regulate the width in roller slit by handwheel; Grind 5 times through three-roll grinder; Stand-off distance is 50 μ m between two rollers of grinding adjusting for the first time; Stand-off distance is 30 μ m between two rollers of grinding adjusting for the second time; Third and fourth, grind to regulate that stand-off distance is 12 μ m between two rollers for five times; Roller adopts the recirculated water cooling, and the roller cooling temperature is 42 ℃, and the mill base material fineness after the grinding is below 10 μ m; Mill base material feed liquid through grinding flows in the material storage barrel, gets product.
Mixing equipment of the present invention adopts general stirrer, and formula material is all purchased by market.
Claims (5)
1. an art stacking acrylic paints that contains nano dye is characterized in that comprising following component, and formula rate is by umber:
Nano dye slurry 1-5 part
Pigment powder 5-25 part
Polyacrylic acid emulsion 40-60 part
Aqueous polyurethane yogurt liquid 5-15 part
Gum arabic 1-8 part
Natvosol 1-8 part
Lime carbonate 10-30 part
Sodium Benzoate 0.2-1 part
Distilled water 5-20 part
Earlier Natvosol and gum arabic are sprinkled in the distilled water, are made into the tackiness agent glue through swelling, heating; In the tackiness agent glue, add phenylformic acid again and receive, the nano dye slurry, the polypropylene emulsion, aqueous polyurethane emulsion stirs, and the back adds the pigment powder, lime carbonate stirs evenly and is slurry; Slurry gets product through grinding.
2. a kind of manufacture method that contains the art stacking acrylic paints of nano dye according to claim 1 is characterized in that adopting following processing step: formula rate is by umber:
(1), get Natvosol 1-8 part and gum arabic 1-8 part is sprinkled in distilled water 5-20 part, swelling 6-12 hour, be heated to 80～90 ℃, 30～60 minutes heat-up times, be made into the tackiness agent glue;
(2), in above-mentioned tackiness agent glue, add phenylformic acid again and receive 0.2-1 part, nano dye slurry 1-5 part, polypropylene emulsion 40-60 part, aqueous polyurethane emulsion 5-15 part are stirred to and evenly are mixed liquor;
(3), add pigment powder 5-30 part, restir 1～2 hour adds lime carbonate 10-30 part then and is stirred to and evenly is coarse particles at above-mentioned mixed liquor;
(4), the coarse fodder slurry is added in the three-roll grinder hopper, through three-roll grinder grinding 3-5 time; Roller adopts the recirculated water cooling, and the mill base material fineness after the grinding is below 10 μ m;
(5), the mill base material feed liquid through grinding flows in the material storage barrel, get product.
3. a kind of manufacture method that contains the art stacking acrylic paints of nano dye according to claim 2 is regulated roller gap distance when it is characterized in that described grinding, grind for the first time to regulate that stand-off distance is 45～50 μ m between two rollers; Stand-off distance is 20～30 μ m between two rollers of grinding adjusting for the second time; Third and fourth, grind to regulate that stand-off distance is 10-15 μ m between two rollers for five times.
4. a kind of manufacture method that contains the art stacking acrylic paints of nano dye according to claim 2 is characterized in that described roller cooling temperature is 38～42 ℃.
5. a kind of manufacture method that contains the art stacking acrylic paints of nano dye according to claim 2, the particle diameter that it is characterized in that described nano dye is the 20-100 nanometer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007103024328A CN101225251A (en) | 2007-12-26 | 2007-12-26 | Art stacking acrylic paints containing nano-pigment and method for manufacturing same |
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| Application Number | Priority Date | Filing Date | Title |
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| CNA2007103024328A CN101225251A (en) | 2007-12-26 | 2007-12-26 | Art stacking acrylic paints containing nano-pigment and method for manufacturing same |
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| CN101225251A true CN101225251A (en) | 2008-07-23 |
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| CN103108925A (en) * | 2010-09-08 | 2013-05-15 | 樱花彩色产品株式会社 | Aqueous painting material composition |
| CN104194542A (en) * | 2014-08-21 | 2014-12-10 | 宁波高新区康大美术新材料有限公司 | Molding paste for drawing |
| CN104877419A (en) * | 2015-05-27 | 2015-09-02 | 河北青竹画材科技有限公司 | Gouache and acrylic painting pigment and method for manufacturing same |
| CN105176170A (en) * | 2015-10-30 | 2015-12-23 | 河北青竹画材科技有限公司 | Water-based acrylic painting pigment and preparation method thereof |
| CN105238115A (en) * | 2014-07-10 | 2016-01-13 | 上海国韵实业有限公司 | Gouache and preparation method therefor |
| CN105566972A (en) * | 2016-01-29 | 2016-05-11 | 佛山市聚成生化技术研发有限公司 | Quick-drying acrylic paint and preparation method thereof |
| CN106147332A (en) * | 2016-07-14 | 2016-11-23 | 苏州冰心文化用品有限公司 | A kind of composite Nano acrylic paints and preparation method thereof |
| ITUB20156319A1 (en) * | 2015-12-04 | 2017-06-04 | Sergio Acerbi | COMPOSITION FOR THE REALIZATION OF PAINTING REASONS MATERIALS AND BRIGHT AS COMPONENTS OF WORKS OF ART ABSTRACT AND PROCEDURE FOR THE PRODUCTION OF THE COMPOSITION AND THE PAINTING REASONS |
| CN107189525A (en) * | 2017-07-04 | 2017-09-22 | 真彩文具股份有限公司 | Artistic oil painting stick containing nano dye and preparation method thereof |
| CN107227061A (en) * | 2017-07-24 | 2017-10-03 | 吕昕芮 | A kind of Formaldehyde-free art paint and preparation method thereof |
| CN109796860A (en) * | 2019-02-28 | 2019-05-24 | 烟台南山学院 | A kind of drawing aqueous polyurethane art painting and preparation method thereof |
| CN111454599A (en) * | 2020-05-25 | 2020-07-28 | 苏州德加画材科技有限公司 | Strong stereoscopic water-based painting pigment |
| RU2780869C1 (en) * | 2021-06-15 | 2022-10-04 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Санкт-Петербургский государственный университет промышленных технологий и дизайна (СПбГУПТД) | Pastel-based composition and method for applying the composition in interior painting |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103108925A (en) * | 2010-09-08 | 2013-05-15 | 樱花彩色产品株式会社 | Aqueous painting material composition |
| CN105238115A (en) * | 2014-07-10 | 2016-01-13 | 上海国韵实业有限公司 | Gouache and preparation method therefor |
| CN104194542A (en) * | 2014-08-21 | 2014-12-10 | 宁波高新区康大美术新材料有限公司 | Molding paste for drawing |
| CN104877419A (en) * | 2015-05-27 | 2015-09-02 | 河北青竹画材科技有限公司 | Gouache and acrylic painting pigment and method for manufacturing same |
| CN105176170B (en) * | 2015-10-30 | 2018-03-27 | 河北青竹画材科技有限公司 | A kind of aqueous acrylamide drawing pigment and preparation method thereof |
| CN105176170A (en) * | 2015-10-30 | 2015-12-23 | 河北青竹画材科技有限公司 | Water-based acrylic painting pigment and preparation method thereof |
| ITUB20156319A1 (en) * | 2015-12-04 | 2017-06-04 | Sergio Acerbi | COMPOSITION FOR THE REALIZATION OF PAINTING REASONS MATERIALS AND BRIGHT AS COMPONENTS OF WORKS OF ART ABSTRACT AND PROCEDURE FOR THE PRODUCTION OF THE COMPOSITION AND THE PAINTING REASONS |
| CN105566972A (en) * | 2016-01-29 | 2016-05-11 | 佛山市聚成生化技术研发有限公司 | Quick-drying acrylic paint and preparation method thereof |
| CN106147332A (en) * | 2016-07-14 | 2016-11-23 | 苏州冰心文化用品有限公司 | A kind of composite Nano acrylic paints and preparation method thereof |
| CN107189525A (en) * | 2017-07-04 | 2017-09-22 | 真彩文具股份有限公司 | Artistic oil painting stick containing nano dye and preparation method thereof |
| CN107227061A (en) * | 2017-07-24 | 2017-10-03 | 吕昕芮 | A kind of Formaldehyde-free art paint and preparation method thereof |
| CN109796860A (en) * | 2019-02-28 | 2019-05-24 | 烟台南山学院 | A kind of drawing aqueous polyurethane art painting and preparation method thereof |
| CN111454599A (en) * | 2020-05-25 | 2020-07-28 | 苏州德加画材科技有限公司 | Strong stereoscopic water-based painting pigment |
| RU2780869C1 (en) * | 2021-06-15 | 2022-10-04 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Санкт-Петербургский государственный университет промышленных технологий и дизайна (СПбГУПТД) | Pastel-based composition and method for applying the composition in interior painting |
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Open date: 20080723 |