CN101845246B - Easily scrubbed graffiti art watercolor paint and preparation method - Google Patents
Easily scrubbed graffiti art watercolor paint and preparation method Download PDFInfo
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- CN101845246B CN101845246B CN2010102046054A CN201010204605A CN101845246B CN 101845246 B CN101845246 B CN 101845246B CN 2010102046054 A CN2010102046054 A CN 2010102046054A CN 201010204605 A CN201010204605 A CN 201010204605A CN 101845246 B CN101845246 B CN 101845246B
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Abstract
The invention relates to easily scrubbed graffiti art watercolor paint and a preparation method. The preparation method comprises the following steps of: heating and boiling deionized water, then stopping heating, adding glycerine and solution of Kathon, and stirring to dissolve the mixture; adding polyvinyl alcohol with low degree of alcoholysis, stirring to dissolve the mixture to obtain the mixed solution, then adding solution of polyacrylamide, and uniformly stirring the mixed solution to obtain the viscose; adding lithopone and pigment powder into the viscose, and uniformly stirring the mixed solution to obtain the crude slurry; and adding the crude slurry into a hopper of a three-roll grinder, and allowing the crude slurry to flow into a grinding roller and grinding the crude slurry to obtain the color pigment slurry, and allowing the color pigment slurry to flow into a storage barrel to obtain the finished product. The easily scrubbed graffiti art watercolor paint has bright color and powder texture, and film forming property, and is difficult to permeate from the surface, and is easy to be scrubbed by cold and hot water; and in addition, non-sugar-derived material, namely polyvinyl alcohol with the low degree of alcoholysis is used in a formula, and the paint is difficult to be used by the microorganism, such as mycete, compared with the traditional paint which uses the sugar-derived material, such as water soluble starch, Arabic gum and peach gum, and the shelf life thereof is obviously prolonged.
Description
Technical field
The present invention relates to a kind of pigment graffiti art pigment and method of manufacture of easy scouring, specifically belong to the painting supply technical field.
Background technology
Along with social progress and Economic development; In important commemoration day and east, west Holiday; In order to increase happy atmosphere or showing personality; Adolescent likes on glass door and window, indoor wall, on the furniture drawing caricature, writing lucky blessing language with the lucid and lively art painting beautiful in colour arbitrarily performance graffiti art of following one's inclinations.Be worth regrettably: the art painting that has such as traditional watercolor, gouache color, also clean than being easier to water, but since their penetrating quality, the color that be easy on metope, the light color furniture surface stays difficult scouring; Art painting that has such as acrylic paints, dry back difficulty are dissolved in water and strong adhesion and are difficult to clean.These defectives cause people that graffiti art is difficult to accept.
Summary of the invention
The objective of the invention is to overcome above-mentioned weak point; Thereby a kind of pigment graffiti art pigment and method of manufacture of easy scouring are provided, and the product of processing had both had distinct color and opaque sense, had film-forming properties again; Be difficult for cleaning with the hot water or cold water easily from surface seepage.In addition, used non-sugared source property material polyvinyl alcohol with low alcoholysis level in the prescription, traditional art painting of sugared source property material that uses than tradition such as water soluble starch, gum arabic, peach gum is difficult for being utilized by mikrobes such as moulds, and shelf-life obviously prolongs.
According to technical scheme provided by the invention, a kind of pigment graffiti art pigment of easy scouring, comprise following component: its formula rate is counted by weight:
Polyvinyl alcohol with low alcoholysis level 10-20 part
SEPIGEL 305 (PAM) solution (solid content 20%) 2-8 part
Lithopone 20-40 part
Pigment powder 10-30 part
Glycerine 6-10 part
Card pine (Kathon) solution 0.1-0.5 part
Deionized water 30-45 part
With deionized water heating, boil 10 minutes microbicidels after, stop heating, put and be chilled to 60-65 ℃, add glycerine, card pine (Kathon) solution, stirring and dissolving is a solution; Add polyvinyl alcohol with low alcoholysis level, stirring makes and is dissolved as mixing solutions fully; In above-mentioned mixing solutions, add SEPIGEL 305 (PAM) solution (solid content 20%) again, be stirred into viscose; In viscose, add lithopone, pigment powder, stir coarse particles; Above-mentioned coarse particles is added to flow to grind on the roller in the hopper of three-roll grinder and grinds, grind back mill base materials flow and go in the Goods storage pail, get product.
The method of manufacture of the pigment graffiti art pigment of a kind of easy scouring of the present invention, characteristic are to adopt following process step: its formula rate is counted by weight:
1. earlier with the heating of deionized water 30-45 part, boil 10 minutes microbicidels after, stop heating, put and be chilled to 60-65 ℃ and add glycerine 6-10 part, card pine (Kathon) solution 0.1-0.5 part, stirring and dissolving is a solution;
2. add polyvinyl alcohol with low alcoholysis level 10-20 part, stirring makes and is dissolved as mixing solutions fully;
3. in above-mentioned mixing solutions, add SEPIGEL 305 (PAM) solution (solid content 20%) 2-8 part again, be stirred into viscose;
4. in viscose, add lithopone 20-40 part, pigment powder 10-30 part, stir coarse particles;
5. above-mentioned coarse particles is added in the hopper of three-roll grinder, grinds 3-5 quality slurry through three-roll grinder, three-roll grinder roller diameter 650mm, three roller speed are 26: 70: 145 (r.p.m).Regulate the width in roller slit through handwheel; Regulate roller gap distance during grinding, stand-off distance is 45～50 μ m between two rollers of grinding adjusting for the first time; Stand-off distance is 20～30 μ m between two rollers of grinding adjusting for the second time; Third and fourth, grind to regulate that stand-off distance is respectively 10～15 μ m between two rollers for five times; The fineness of the mill base material after the grinding is below 15 μ m;
6. go in the material storage barrel through the mill base materials flow of grinding, get product.
Polyvinyl alcohol with low alcoholysis level is like 1788,1988,2088 glue pastes as watercolor graffiti art pigment among the present invention, and film forming properties is good, is easy to be dissolved in cold water, processes watercolor graffiti art pigment and behind scribble, is difficult for using scrub water easily at surface seepage.Though high alcoholysis degree Z 150PH is also good like 1799,1899,2099 film-forming propertiess, is dissolved in the hot water more than 95 ℃,, do not adopt among the present invention program so be difficult for using scrub water.
SEPIGEL 305 among the present invention (PAM) solution is associative thickener, in aqueous systems, forms reticulated structure through bridging action and polyvinyl alcohol with low alcoholysis level linear polymeric, plays thickening effectiveness.How much regulated the low-shearing power viscosity of system according to consumption; Thereby select and kept the desirable balance between viscosity, flow leveling; Make the Z 150PH glue after the thickening can become the soft paste shape that preparation graffiti art pigment needs; It is good to make the graffiti art pigment of processing sprawl leveling characteristics again, it is very important concerning graffiti art pigment to sprawl leveling characteristics, because its smooth degree when having determined scribble.
Lithopone is a weighting agent among the present invention, plays the opaque effect of pigment graffiti art pigment, also helps pigment to play the covering effect simultaneously.
The loose commodity of card Kathon by name among the present invention; Commercially available is the solution of actives total content 1.5% (weight percent); Actives is the two a mixture of 2-methyl-4-isothiazoline-3-ketone and 5-chloro-2-methyl-4-isothiazoline-3-ketone, suppresses mikrobe, prevents to go mouldy, become sour.
Glycerine plays moisture-keeping function among the present invention
The commercially available specification Z 150PH 1788,1988,2088 of polyvinyl alcohol with low alcoholysis level according to the invention all can use; SEPIGEL 305 commercial goods name PAM, the aqueous solution has multiple solid content, and it is 20% (percentage ratio meter by weight) that the present invention's employing contains the solid amount of fruit; Pigment powder such as ultramarine etc. are commercially available common pigments powder, can be to select one or more pigment raw material powder to mix by the toning requirement.
Compared with present technology the present invention has the following advantages:
Product of the present invention had both had distinct color and opaque sense, had film-forming properties again, was difficult for cleaning with the hot water or cold water easily from surface seepage.In addition, used non-sugared source property material polyvinyl alcohol with low alcoholysis level in the prescription, traditional art painting of sugared source property material that uses than tradition such as water soluble starch, gum arabic, peach gum is difficult for being utilized by mikrobes such as moulds, and shelf-life obviously prolongs.
Embodiment
Following the present invention will combine embodiment to further describe:
Embodiment one: the pigment graffiti art pigment of a kind of easy scouring of the present invention, and comprise following component: its formula rate is counted by weight:
10 parts of polyvinyl alcohol with low alcoholysis level
8 parts of SEPIGEL 305 (PAM) solution (solid content 20%)
40 parts of lithopones
10 parts in ultramarine (pigment powder)
6 parts of glycerine
0.1 part of card pine (Kathon) solution
30 parts of deionized waters
The method of manufacture of the pigment graffiti art pigment of a kind of easy scouring of the present invention, adopt following process step: its formula rate is counted by weight:
1. earlier with 30 parts of heating of deionized water, boil 10 minutes microbicidels after, stop heating, put and be chilled to 60-65 ℃ and add 6 parts of glycerine, 0.1 part of card pine (Kathon) solution, stirring and dissolving is a solution;
2. add 10 parts of polyvinyl alcohol with low alcoholysis level, stirring makes and is dissolved as mixing solutions fully;
3. in above-mentioned mixing solutions, add 8 parts of SEPIGEL 305 (PAM) solution (solid content 20%) again, be stirred into viscose;
4. in viscose, add 40 parts of lithopones, 10 parts in ultramarine (pigment powder), stir coarse particles;
5. above-mentioned coarse particles is added in the hopper of three-roll grinder, grinds 3 quality slurries through three-roll grinder, three-roll grinder roller diameter 650mm, three roller speed are 26: 70: 145 (r.p.m).Regulate the width in roller slit through handwheel; Regulate roller gap distance during grinding, stand-off distance is 45 μ m between two rollers of grinding adjusting for the first time; Stand-off distance is 20 μ m between two rollers of grinding adjusting for the second time; Stand-off distance is respectively 10～15 μ m between two rollers of grinding adjusting for the third time; The fineness of the mill base material after the grinding is below 15 μ m;
6. go in the material storage barrel through the mill base materials flow of grinding, get product.
Embodiment two: the pigment graffiti art pigment of a kind of easy scouring of the present invention, and comprise following component: its formula rate is counted by weight:
20 parts of polyvinyl alcohol with low alcoholysis level
2 parts of SEPIGEL 305 (PAM) solution (solid content 20%)
20 parts of lithopones
26 parts of red iron oxides (pigment powder)
4 parts of yellow oxide of iron (pigment powder)
10 parts of glycerine
0.5 part of card pine (Kathon) solution
45 parts of deionized waters
The method of manufacture of the pigment graffiti art pigment of a kind of easy scouring of the present invention, adopt following process step: its formula rate is counted by weight:
1. earlier with 45 parts of heating of deionized water, boil 10 minutes microbicidels after, stop heating, put and be chilled to 60-65 ℃ and add 10 parts of glycerine, 0.5 part of card pine (Kathon) solution, stirring and dissolving is a solution;
2. add 20 parts of polyvinyl alcohol with low alcoholysis level, stirring makes and is dissolved as mixing solutions fully;
3. in above-mentioned mixing solutions, add 2 parts of SEPIGEL 305 (PAM) solution (solid content 20%) again, be stirred into viscose;
4. in viscose, add 20 parts of lithopones, 26 parts of red iron oxides (pigment powder), 4 parts of yellow oxide of iron (pigment powder), stir coarse particles;
5. above-mentioned coarse particles is added in the hopper of three-roll grinder, grinds 3-5 quality slurry through three-roll grinder, three-roll grinder roller diameter 650mm, three roller speed are 26: 70: 145 (r.p.m).Regulate the width in roller slit through handwheel; Regulate roller gap distance during grinding, stand-off distance is 50 μ m between two rollers of grinding adjusting for the first time; Stand-off distance is 30 μ m between two rollers of grinding adjusting for the second time; Third and fourth, grind to regulate that stand-off distance is respectively 15 μ m between two rollers for five times; The fineness of the mill base material after the grinding is below 15 μ m;
6. go in the material storage barrel through the mill base materials flow of grinding, get product.
Embodiment three: the pigment graffiti art pigment of a kind of easy scouring of the present invention, and comprise following component: its formula rate is counted by weight:
15 parts of polyvinyl alcohol with low alcoholysis level
4.5 parts of SEPIGEL 305 (PAM) solution (solid content 20%)
35 parts of lithopones
15 parts of phthalocyanine greens (pigment powder)
8 parts of glycerine
0.3 part of card pine (Kathon) solution
40 parts of deionized waters
The method of manufacture of the pigment graffiti art pigment of a kind of easy scouring of the present invention, adopt following process step: its formula rate is counted by weight:
1. earlier with 40 parts of heating of deionized water, boil 10 minutes microbicidels after, stop heating, put and be chilled to 60-65 ℃ and add 8 parts of glycerine, 0.3 part of card pine (Kathon) solution, stirring and dissolving is a solution;
2. add 15 parts of polyvinyl alcohol with low alcoholysis level, stirring makes and is dissolved as mixing solutions fully;
3. in above-mentioned mixing solutions, add 4.5 parts of SEPIGEL 305 (PAM) solution (solid content 20%) again, be stirred into viscose;
4. in viscose, add 35 parts of lithopones, 15 parts of phthalocyanine greens (pigment powder), stir coarse particles;
5. above-mentioned coarse particles is added in the hopper of three-roll grinder, grinds 3 quality slurries through three-roll grinder, three-roll grinder roller diameter 650mm, three roller speed are 26: 70: 145 (r.p.m).Regulate the width in roller slit through handwheel; Regulate roller gap distance during grinding, stand-off distance is 45 μ m between two rollers of grinding adjusting for the first time; Stand-off distance is 20 μ m between two rollers of grinding adjusting for the second time; Stand-off distance is respectively 15 μ m between two rollers of grinding adjusting for the third time; The fineness of the mill base material after the grinding is below 15 μ m;
6. go in the material storage barrel through the mill base materials flow of grinding, get product.
Mix whipping device among the present invention and adopt general stirrer, mixing speed is 90-120 rev/min, and formula material is all purchased by market.
Claims (3)
1. pigment graffiti art pigment of be prone to cleaning, it is characterized in that: comprise following component: its formula rate is counted by weight:
With deionized water heating, boil 10 minutes microbicidels after, stop heating, put and be chilled to 60-65 ℃ and add glycerine, block loose solution, stirring and dissolving is a solution; Add polyvinyl alcohol with low alcoholysis level, stirring makes and is dissolved as mixing solutions fully; In above-mentioned mixing solutions, add polyacrylamide solution again, be stirred into viscose; In viscose, add lithopone, pigment powder, stir coarse particles; Above-mentioned coarse particles is added to flow to grind on the roller in the hopper of three-roll grinder and grinds, grind back mill base materials flow and go in the Goods storage pail, get product;
Said polyvinyl alcohol with low alcoholysis level specification is Z 150PH 1788, Z 150PH 1988, Z 150PH 2088.
2. the method for manufacture of the pigment graffiti art pigment of a kind of easy scouring as claimed in claim 1, it is characterized in that: adopt following process step, its formula rate is counted by weight:
(1), earlier with the heating of deionized water 30-45 part, boil 10 minutes microbicidels after, stop heating, put and be chilled to 60-65 ℃ and add glycerine 6-10 part, block loose solution 0.1-0.5 part, stirring and dissolving is a solution;
(2), in above-mentioned solution, add polyvinyl alcohol with low alcoholysis level 10-20 part, stir to make and be dissolved as mixing solutions fully; Said polyvinyl alcohol with low alcoholysis level specification is Z 150PH 1788, Z 150PH 1988, Z 150PH 2088;
(3), in above-mentioned mixing solutions, add polyacrylamide solution 2-8 part again, be stirred into viscose; (4), in above-mentioned viscose, add lithopone 20-40 part, pigment powder 10-30 part, stir coarse particles;
(5), above-mentioned coarse particles is added in the hopper of three-roll grinder, grind 3-5 quality slurry, regulate roller gap distance during grinding, grind for the first time that stand-off distance is 45～50 μ m between adjusting two rollers through three-roll grinder; Stand-off distance is 20～30 μ m between two rollers of grinding adjusting for the second time; Third and fourth, grind to regulate that stand-off distance is respectively 10～15 μ m between two rollers for five times;
(6), go in the material storage barrel, get product through the mill base materials flow of grinding.
3. the method for manufacture of the pigment graffiti art pigment of a kind of easy scouring as claimed in claim 2, it is characterized in that: the fineness of the mill base feed liquid after the said grinding is below 15 μ m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102046054A CN101845246B (en) | 2010-06-10 | 2010-06-10 | Easily scrubbed graffiti art watercolor paint and preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102046054A CN101845246B (en) | 2010-06-10 | 2010-06-10 | Easily scrubbed graffiti art watercolor paint and preparation method |
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| CN101845246B true CN101845246B (en) | 2012-01-18 |
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| CN105733331B (en) * | 2016-05-09 | 2018-07-24 | 南昌航空大学 | A kind of preparation method of the dextrin base without rear thickening property advertisement paint |
| CN110305535A (en) * | 2019-06-18 | 2019-10-08 | 宿迁嘉禾塑料金属制品有限公司 | A kind of PVA collodion pigment that do not fade |
| CN112852202A (en) * | 2021-01-13 | 2021-05-28 | 宿迁艾朋文化用品有限公司 | Novel pigment capable of washing hands and finger painting and preparation method thereof |
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| CN1164694C (en) * | 2002-01-29 | 2004-09-01 | 吴雯菲 | Composite compounding agent for amphiphilic active pigment |
| JP4841966B2 (en) * | 2006-02-16 | 2011-12-21 | 株式会社サクラクレパス | Erasable colorant composition |
| CN101215437B (en) * | 2008-01-18 | 2010-06-09 | 宁波康大美术用品有限公司 | Nano composite painting canvas paint |
| CN101451029A (en) * | 2008-12-30 | 2009-06-10 | 上海乐美文具有限公司 | Stripping type painting glue |
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