CN102731728A - Adhesive for digital inkjet printing ink-absorption coating and preparation method thereof - Google Patents
Adhesive for digital inkjet printing ink-absorption coating and preparation method thereof Download PDFInfo
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- CN102731728A CN102731728A CN2012102331599A CN201210233159A CN102731728A CN 102731728 A CN102731728 A CN 102731728A CN 2012102331599 A CN2012102331599 A CN 2012102331599A CN 201210233159 A CN201210233159 A CN 201210233159A CN 102731728 A CN102731728 A CN 102731728A
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Abstract
The invention discloses an adhesive for a digital inkjet printing ink-absorption coating, which is prepared from soft monomers, hard monomers, an emulsifying agent, protection glue, an initiator, a pH regulating agent and water. The adhesive for the digital inkjet printing ink-absorption coating, which is prepared by the invention, has the advantages of uniform latex particle distribution, stable product quality, good compatibility and no demulsification and can be mixed with a cation system; the water resistance of a digital inkjet printing ink-absorption coating which is subsequently prepared is guaranteed; and as soon as the adhesive is put in a printing machine, the adhesive is cured immediately without placement for solidification, and the printing color is vivid.
Description
Technical field
The present invention relates to a kind of digital ink-jet and print the preparation method of ink-absorbed coated layer with tackiness agent.
Background technology
The digital color spray ink Printing is a kind of non-bump, mosaic printing technology, and ink droplet is directly injected to the specific position of dielectric surface to form image by micropore.With the traditional printing compared with techniques, it is little to have equipment volume, efficient and convenient, characteristics such as environmental protection; Compare with laser, stylus printer, heat sublimation and the silver salt picture way of output, it is low to have a cost, and colorize, digitizing are easy, characteristics such as print size is unrestricted.Therefore, with the development of digitizing technique with popularize, export such as large format display and demonstration, indoor and outdoor advertisement, high-definition picture (photo), print, draw a design, aspect such as office automation, obtained widespread use.
Ink jet printing process is that ink is sprayed with small ink droplet (nano-micrometre size) form by ink-jet printer, contacts with the print media material surface, and spreads to different directions; Absorption; Drying finally forms required image, and the ink-absorbed coated layer on image quality and print media material surface is closely bound up; Ink-absorbed coated layer has determined the situation bright in luster of print image, water-fast situation, resolving power situation, and the Application Areas of print media material etc.Print media material can be divided into the indoor vacuum material of writing by the difference of ink-absorbed coated layer; Outdoor air brushing material and Weak solvent spray-drawing material etc.; The simultaneously indoor vacuum material of writing can be divided into common high light coating again according to the difference of ink-absorbed coated layer and writes vacuum material; Common inferior light coating is write vacuum material, and inferior light waterproof (water-fast) coating is write vacuum material etc.Present technique is mainly used in indoor inferior light waterproof (water-fast) coating and writes vacuum material, and such ink-jet printing material generally is made up of ink-absorbed coated layer, bridge formation layer and base material, and wherein base material plays effects such as support, outward appearance performance and leading material Application Areas; Ink-absorbed coated layer plays absorption, fixedly ink forms the water-fast image effect of high resolving power, can improve the colour vividness of image through change figure layer, image resolution ratio and deposit weather resistance etc.; The layer of building bridge plays anastomosis, with close-coupled between ink-absorbed coated layer and the base material together, improves the firmness of doing, wet of ink-absorbed coated layer.
The novel ink-absorbed coated layer material of indoor inferior light waterproof (water-fast) coating for growing up in recent years; Its blotting mechanism is " capillary effect " mechanism---have a large amount of microporous type structures in the coating; After meeting jetting ink ink is absorbed rapidly to the micropore of coating, form image.The primary binder major part that such ink-absorbed coated layer uses is Z 150PH; Through adding MR adhesive or compositions such as linking agent and laking agent, can make coating have waterproof action, promptly on the one hand; After coating itself can not run into water, the coating phenomenon of dissolving, trickle; On the other hand, color can be because of the existence of water, and the phenomenon that fades.The advantage of coating is: blotting speed and drying rate are fast, and resolving power is high, and ink flexibility is strong etc.Though also can make coating play water-fast effect through adding the linking agent composition, crosslinking temperature or time are had high requirement, perhaps linking agent is ageing very short, and can't satisfy quick, efficient, the following machine of this material is ripe coating production requirement.Thereby seek the use that suitable MR adhesive substitutes linking agent in the industry one after another, and play cohesive action on the one hand, play water-proof effect on the other hand.Though use MR adhesive to be easier to make coating and print image to have water-fast effect; Very big influence---color whitens easily but often the color representation of image and coating weather-proof, fast light, ageing-resistant etc. had, and color becomes not bright-coloured along with change of time, the coating jaundice; Embrittlement etc.; Be that persistence is not enough, therefore, develop a kind of digital ink-jet and print the critical problem that the ink-absorbed coated layer adhesive specially becomes digital ink-jet printed material production industry.
Summary of the invention
The object of the present invention is to provide a kind of good product performance, easily manufactured digital ink-jet is printed ink-absorbed coated layer with tackiness agent and preparation method thereof.
Technical solution of the present invention is:
A kind of digital ink-jet is printed ink-absorbed coated layer and is used tackiness agent, it is characterized in that: processed by following component in percentage by weight:
Soft monomer 0.5～9.5%;
Hard monomer 16.5～33%;
Emulsifying agent 0.3～3%;
Protection glue 0.5～4%;
Initiator 0.1～0.9%;
PH regulator agent 0.1～0.4%;
Water 56～75%.
Soft monomer is one or more mix monomers in ethyl propenoate, Bing Xisuandingzhi, Octyl acrylate, the Isooctyl acrylate monomer.
Hard monomer is one or more mix monomers in vinylformic acid, methylacrylic acid, TEB 3K, vinyl acetate, the vinylbenzene.
Emulsifying agent is the mixture of anionic emulsifier and nonionic emulsifier; Said anionic emulsifier is one or more in sodium lauryl sulphate, the X 2073; Said nonionic emulsifier is one or more among OP-10, TX-10, paregal O-25, LAE-9, OP-20, the SE-10.
Protection glue is one or both mixtures in Z 150PH 1788, Z 150PH 2088, Z 150PH 2488, the Natvosol.
Initiator is a kind of in Potassium Persulphate, the ammonium persulphate.
The pH regulator agent is a kind of in Sodium phosphate, dibasic, the sodium hydrogencarbonate.
A kind of digital ink-jet is printed the preparation method of ink-absorbed coated layer with tackiness agent, it is characterized in that: comprise the following steps;
(1) will protect glue and water mixed dissolution, be prepared into protective colloid solution, and cool to normal temperature;
(2) in protective colloid solution, add emulsifying agent, pH regulator agent, after stirring and dissolving is even, adds hard monomer, soft monomer and water stirring and processes pre-emulsion;
(3) get 10～30% of pre-emulsion gross weight, logical nitrogen is removed the air in the system, stirs, be warming up to 60～70 ℃ after, add initiator solution, the system of being warming up to reacts;
(4) after waiting to reflux evenly, begin to add remaining pre-emulsion and initiator solution, the reaction times was controlled between 2～5 hours, and temperature is controlled between 70～78 ℃;
Wherein, in the step (1), the weight of water is 15～90% of the total consumption of water; The weight that adds entry in the step (2) is the 0-70% of the total consumption of water; The weight of water and be the 5-30% of the total consumption of water in the initiator solution in step (3) and the step (4); The consumption of initiator solution is the 10-40% of initiator solution gross weight in the step (3);
The weight percent of above-mentioned each component is:
Soft monomer 0.5～9.5%;
Hard monomer 16.5～33%;
Emulsifying agent 0.3～3%;
Protection glue 0.5～4%;
Initiator 0.1～0.9%;
PH regulator agent 0.1～0.4%;
Water 56～75%.
The adding mode of initiator solution is in the step (4): the initiator solution of at first leaving and taking initiator solution gross weight 10-25%; Then the initiator solution of surplus and pre-emulsion are dripped synchronously or every at a distance from 20～30min average initiator that adds surplus in system, treat that pre-emulsion dropwises after, system continues to react 10～30min; Disposable then the initiator solution of leaving and taking is joined in the reaction system; Behind reaction 10～30min, be warming up to 80～90 ℃, insulation 5～30min; Be cooled to 40～50 ℃, pH value to 5～9 of regulation system.
Beneficial effect of the present invention: the digital ink-jet printing ink-absorbed coated layer of employing the present invention preparation is evenly distributed with the latex particle of tackiness agent, and constant product quality is compatible good, can mix mutually with cationic system, not breakdown of emulsion; The digital ink-jet that has guaranteed subsequent preparation is printed the ink-absorbed coated layer water tolerance, and following machine is promptly ripe, need not to place to solidify, and prints bright in luster.
Below in conjunction with embodiment the present invention is described further.
Embodiment
Embodiment 1:
A kind of digital ink-jet is printed ink-absorbed coated layer with tackiness agent and preparation method thereof, adopts following process step:
Prescription: (being mass percent)
Ethyl propenoate 3%
Vinyl acetate 25.7%
TEB 3K 1.5%
Methylacrylic acid 1.7%
TX-10 0.3%
Sodium lauryl sulphate 0.3%
Potassium Persulphate 0.3%
Sodium phosphate, dibasic 0.2%
Z 150PH 1,788 2.8%
Water 64.2%
Process step:
Z 150PH 1788 joins in 20% the water of water inventory; In the dissolving of 85～93 ℃ of temperature condition, be prepared into protective colloid solution, cool to normal temperature after; Add TX-10, sodium lauryl sulphate, Sodium phosphate, dibasic; Stirring and dissolving evenly after, add 64% water of ethyl propenoate, vinyl acetate, TEB 3K, methylacrylic acid and water inventory, high-speed stirring is processed pre-emulsion.Get 12% of pre-emulsion, logical nitrogen is removed the air in the system, stirs; After being warming up to 65 ℃, add 25% of initiator solution (mixing solutions of Potassium Persulphate and remainder water) total amount, the system of being warming up to reacts; After waiting to reflux evenly, begin to drip remaining pre-emulsion, the time was controlled at 3.5 hours; Temperature is controlled between 74～78 ℃, leaves and takes 14% of initiator solution total amount, and remaining initiator solution and pre-emulsion are dripped synchronously.After pre-emulsion dropwised, system continued behind reaction 15min under the former temperature, disposable the initiator solution of leaving and taking was joined in the reaction system; Behind the reaction 10min, be warming up to 85 ℃, insulation 15min; Be cooled to 50 ℃, the pH value to 6 of regulation system gets product.
Embodiment 2:
A kind of digital ink-jet is printed ink-absorbed coated layer with tackiness agent and preparation method thereof, adopts following process step:
Prescription: (being mass percent)
Bing Xisuandingzhi 3%
Vinyl acetate 25.7%
TEB 3K 1.5%
Methylacrylic acid 1.7%
OP-10 0.6%
Sodium lauryl sulphate 0.3%
Potassium Persulphate 0.3%
Sodium phosphate, dibasic 0.15%
Natvosol (2% solution viscosity is 30000cP) 1%
Water 65.75%
Process step:
Natvosol is joined in 84% the water of water inventory; Stirring and dissolving is prepared into protective colloid solution; Add OP-10, sodium lauryl sulphate, Sodium phosphate, dibasic; After stirring and dissolving is even, add Bing Xisuandingzhi, vinyl acetate, TEB 3K, methylacrylic acid, high-speed stirring is processed pre-emulsion.Get 11% of pre-emulsion, logical nitrogen is removed the air in the system, stirs; After being warming up to 70 ℃, add 25% of initiator solution (mixing solutions of Potassium Persulphate and remainder water) total amount, the system of being warming up to reacts; After waiting to reflux evenly, begin to drip remaining pre-emulsion, the time was controlled at 4 hours; Temperature is controlled between 75～78 ℃, leaves and takes 14% of initiator solution total amount, on average adds remaining initiator solution every separated half a hour.After pre-emulsion dropwised, system continued behind reaction 10min under the former temperature, disposable the initiator solution of leaving and taking was joined in the reaction system; Behind the reaction 10min, be warming up to 90 ℃, insulation 10min; Be cooled to 50 ℃, the pH value to 7 of regulation system gets product.
Embodiment 3:
A kind of digital ink-jet is printed ink-absorbed coated layer with tackiness agent and preparation method thereof, adopts following process step:
Prescription: (being mass percent)
Bing Xisuandingzhi 4.5%
Isooctyl acrylate monomer 0.9%
Vinyl acetate 21.5%
Vinylformic acid 0.27%
OP-10 0.6%
Sodium lauryl sulphate 0.3%
Ammonium persulphate 0.1%
Sodium phosphate, dibasic 0.23%
Z 150PH 2,088 2.1%
Water 69.5%
Process step:
Z 150PH 2088 is joined in 86% the water of water inventory; In the dissolving of 85～93 ℃ of temperature condition, be prepared into protective colloid solution, cool to normal temperature after; Add OP-10, sodium lauryl sulphate, Sodium phosphate, dibasic; After stirring and dissolving is even, add Bing Xisuandingzhi, Isooctyl acrylate monomer, vinyl acetate, vinylformic acid, high-speed stirring is processed pre-emulsion.Get 11% of pre-emulsion, logical nitrogen is removed the air in the system, stirs; After being warming up to 70 ℃, add 23% of initiator solution (mixing solutions of Potassium Persulphate and remainder water) total amount, the system of being warming up to reacts; After waiting to reflux evenly, begin to drip remaining pre-emulsion, the time was controlled at 3.5 hours; Temperature is controlled between 74～78 ℃, leaves and takes 14% of initiator solution total amount, and remaining initiator solution and pre-emulsion are dripped synchronously.After pre-emulsion dropwised, system continued behind reaction 10min under the former temperature, disposable the initiator solution of leaving and taking was joined in the reaction system; Behind the reaction 10min, be warming up to 90 ℃, insulation 10min; Be cooled to 50 ℃, the pH value to 6 of regulation system gets product.
Claims (9)
1. a digital ink-jet is printed ink-absorbed coated layer and is used tackiness agent, it is characterized in that: processed by following component in percentage by weight:
Soft monomer 0.5～9.5%;
Hard monomer 16.5～33%;
Emulsifying agent 0.3～3%;
Protection glue 0.5～4%;
Initiator 0.1～0.9%;
PH regulator agent 0.1～0.4%;
Water 56～75%.
2. a kind of digital ink-jet according to claim 1 is printed ink-absorbed coated layer and is used tackiness agent, and it is characterized in that: soft monomer is one or more mix monomers in ethyl propenoate, Bing Xisuandingzhi, Octyl acrylate, the Isooctyl acrylate monomer.
3. a kind of digital ink-jet according to claim 1 and 2 is printed ink-absorbed coated layer and is used tackiness agent, and it is characterized in that: hard monomer is one or more mix monomers in vinylformic acid, methylacrylic acid, TEB 3K, vinyl acetate, the vinylbenzene.
4. a kind of digital ink-jet according to claim 1 and 2 is printed ink-absorbed coated layer and is used tackiness agent, and it is characterized in that: emulsifying agent is the mixture of anionic emulsifier and nonionic emulsifier; Said anionic emulsifier is one or more in sodium lauryl sulphate, the X 2073; Said nonionic emulsifier is one or more among OP-10, TX-10, paregal O-25, LAE-9, OP-20, the SE-10.
5. a kind of digital ink-jet according to claim 1 and 2 is printed ink-absorbed coated layer and used tackiness agent, it is characterized in that: protection glue is one or both mixtures in Z 150PH 1788, Z 150PH 2088, Z 150PH 2488, the Natvosol.
6. a kind of digital ink-jet according to claim 1 and 2 is printed ink-absorbed coated layer and used tackiness agent, it is characterized in that: initiator is a kind of in Potassium Persulphate, the ammonium persulphate.
7. a kind of digital ink-jet according to claim 1 and 2 is printed ink-absorbed coated layer and used tackiness agent, it is characterized in that: the pH regulator agent is a kind of in Sodium phosphate, dibasic, the sodium hydrogencarbonate.
8. a digital ink-jet is printed the preparation method of ink-absorbed coated layer with tackiness agent, it is characterized in that: comprise the following steps;
(1) will protect glue and water mixed dissolution, be prepared into protective colloid solution, and cool to normal temperature;
(2) in protective colloid solution, add emulsifying agent, pH regulator agent, after stirring and dissolving is even, adds hard monomer, soft monomer and water stirring and processes pre-emulsion;
(3) get 10～30% of pre-emulsion gross weight, logical nitrogen is removed the air in the system, stirs, be warming up to 60～70 ℃ after, add initiator solution, the system of being warming up to reacts;
(4) after waiting to reflux evenly, begin to add remaining pre-emulsion and initiator solution, the reaction times was controlled between 2～5 hours, and temperature is controlled between 70～78 ℃;
Wherein, in the step (1), the weight of water is 15～90% of the total consumption of water; The weight that adds entry in the step (2) is the 0-70% of the total consumption of water; The weight of water and be the 5-30% of the total consumption of water in the initiator solution in step (3) and the step (4); The consumption of initiator solution is the 10-40% of initiator solution gross weight in the step (3);
The weight percent of above-mentioned each component is:
Soft monomer 0.5～9.5%;
Hard monomer 16.5～33%;
Emulsifying agent 0.3～3%;
Protection glue 0.5～4%;
Initiator 0.1～0.9%;
PH regulator agent 0.1～0.4%;
Water 56～75%.
9. a kind of digital ink-jet according to claim 8 is printed the preparation method of ink-absorbed coated layer with tackiness agent; It is characterized in that: the adding mode of initiator solution is in the step (4): the initiator solution of at first leaving and taking initiator solution gross weight 10-25%; Then the initiator solution of surplus and pre-emulsion are dripped synchronously or every at a distance from 20～30min average initiator that adds surplus in system, treat that pre-emulsion dropwises after, system continues to react 10～30min; Disposable then the initiator solution of leaving and taking is joined in the reaction system; Behind reaction 10～30min, be warming up to 80～90 ℃, insulation 5～30min; Be cooled to 40～50 ℃, pH value to 5～9 of regulation system.
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| CN103319646A (en) * | 2013-06-21 | 2013-09-25 | 南通华润新材料有限公司 | Polyacrylate emulsion for highlight eco-solvent digital ink-jet recording material and preparation method thereof |
| CN103342773A (en) * | 2013-06-21 | 2013-10-09 | 南通华润新材料有限公司 | Crosslinked vinyl acetate-acrylic emulsion for digital color inkjet ink-absorbing coating and preparation method thereof |
| CN105017493A (en) * | 2014-04-15 | 2015-11-04 | 辽宁天麒科技有限公司 | Organosilicon-modified poor solvent ink-absorption coating resin, preparation method and applications thereof |
| CN105178010A (en) * | 2015-10-29 | 2015-12-23 | 吴江市畅欣宇数码纺织品贸易有限公司 | Flame-retardant canvas for painting |
| CN105365427A (en) * | 2015-12-25 | 2016-03-02 | 天津美迪亚影像材料有限公司 | Environment-friendly and medical laser printing film |
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| CN103319646A (en) * | 2013-06-21 | 2013-09-25 | 南通华润新材料有限公司 | Polyacrylate emulsion for highlight eco-solvent digital ink-jet recording material and preparation method thereof |
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| CN105017493A (en) * | 2014-04-15 | 2015-11-04 | 辽宁天麒科技有限公司 | Organosilicon-modified poor solvent ink-absorption coating resin, preparation method and applications thereof |
| CN105178010A (en) * | 2015-10-29 | 2015-12-23 | 吴江市畅欣宇数码纺织品贸易有限公司 | Flame-retardant canvas for painting |
| CN105365427A (en) * | 2015-12-25 | 2016-03-02 | 天津美迪亚影像材料有限公司 | Environment-friendly and medical laser printing film |
| CN106674433A (en) * | 2016-11-25 | 2017-05-17 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | 3d printing powder and preparation method thereof |
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| CN107793513A (en) * | 2017-10-25 | 2018-03-13 | 杭州海维特化工科技有限公司 | A kind of woodgrained paper coating adhesive emulsion available for numerial code spray drawing and preparation method thereof |
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Application publication date: 20121017 |