CN103342773B - Crosslinked vinyl acetate-acrylic emulsion for digital color inkjet ink-absorbing coating and preparation method thereof - Google Patents
Crosslinked vinyl acetate-acrylic emulsion for digital color inkjet ink-absorbing coating and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a crosslinked vinyl acetate-acrylic emulsion for a digital color inkjet ink-absorbing coating and a preparation method thereof. The crosslinked vinyl acetate-acrylic emulsion is composed of the following components in parts by weight: 15-28 parts of vinyl acetate, 3.1-12.4 parts of acrylic monomer, 0.9-9.3 parts of methacrylic monomer, 0.03-1.5 parts of crosslinking monomer, 0.3-1.5 parts of emulsifier, 1.5-3 parts of protective adhesive, 0.03-0.3 part of initiator, 0.03-0.3 part of pH regulator and the balance of water, totaling 100 parts. Compared with the prior art, the vinyl acetate-acrylic emulsion has greatly higher stability; and when the vinyl acetate-acrylic emulsion independently forms a film, the vinyl acetate-acrylic emulsion film has the advantages of high transparency, high toughness, high shock resistance and excellent water resistance. The digital color inkjet ink-absorbing coating prepared by the vinyl acetate-acrylic emulsion has the advantages of excellent water resistance, bright printing color and no fading.
Description
Technical field
The present invention relates to digital printing coating sizing agent field, be specifically related to a kind of digital colorful spray ink-absorbed coated layer cross linking type methyl acrylate and vinyl acetate emulsion and preparation method thereof.
Background technology
Color jet-ink digital printing paper is as the direct supporting body of color jet-ink ink, and the quality of quality to image quality of its quality has decisive role, and determines that the gordian technique of ink-jet paper quality is the ink-absorbed coated layer of paper.The ink-absorbed coated layer of ink-jet paper mainly comprises the compositions such as pigment, sizing agent, laking agent, whitening agent, and wherein, the effect as the sizing agent of external phase is mutually bonded pigment and other components, and be evenly dispersed on paper.Qualified sizing agent can under the prerequisite not affecting color representation, improve the stability of vanish system, give the good water tolerance of ink-jet paper and wet fastness, in prior art, the sizing agent for digital colorful spray paper and coating uses polyvinyl alcohol (PVA) mostly, but, be used alone polyvinyl alcohol as sizing agent, the viscosity of coating system is wayward, is unfavorable for the coating waste water of ink-jet paper, and the wet fastness of coating is not good yet.One or more in the use vinyl acetate-ethylene copolymer also had, aqueous polyurethane, benzene emulsion, pure-acrylic emulsion are as sizing agent, but its cost also improves a lot.
Minority uses vinylformic acid as function monomer; polyvinyl alcohol 1788 is as protecting glue; but due to acrylic acid existence; easily crosslinking reaction is there is between high-molecular polyvinyl alcohol chain; stability of emulsion is declined; system viscosity increases gradually, causes the viscosity of system wayward, is unfavorable for using of later stage emulsion on the contrary.
Summary of the invention
Goal of the invention: the object of the invention is to make up the deficiencies in the prior art, provide a kind of digital colorful spray ink-absorbed coated layer cross linking type methyl acrylate and vinyl acetate emulsion, another object of the present invention there is provided the preparation method of digital colorful spray ink-absorbed coated layer cross linking type methyl acrylate and vinyl acetate emulsion.
Technical scheme: a kind of digital colorful spray ink-absorbed coated layer cross linking type methyl acrylate and vinyl acetate emulsion; be made up of each component of the following parts by weight accounting for emulsion total amount: vinyl acetate 15 ~ 28 parts; acrylic monomer 3.1 ~ 12.4 parts; methacrylic monomers 0.9 ~ 9.3 part, cross-linking monomer 0.03 ~ 1.5 part, emulsifying agent 0.3 ~ 1.5 part; protecting glue 1.5 ~ 3 parts; initiator 0.03 ~ 0.3 part, PH conditioning agent 0.03 ~ 0.3 part, adds water to 100 parts.
As preferably, acrylic monomer is one or more in vinylformic acid, methyl acrylate, ethyl propenoate, n-butyl acrylate, isobutyl acrylate, Octyl acrylate, Isooctyl acrylate monomer.
As preferably, methacrylic monomers is one or more mixing in methacrylic acid, methyl methacrylate, β-dimethyl-aminoethylmethacrylate, n-BMA.
As preferably, cross-linking monomer is one or more mixing in N hydroxymethyl acrylamide, N-methoxymethyl propenamide, N-isopropoxymethyl acrylamide, N-butoxymethyl acrylamide, the different butoxymethyl acrylamide of N-, the pungent oxygen Methacrylamide of N-, N-carboxylic methoxymethyl propenamide, vinylformic acid-2-hydroxyl ethyl ester, 2-hydroxypropyl acrylate, ethyl acrylate, methacrylic acid-2-ethylhexyl, 2-hydroxyethyl methacrylate, Hydroxypropyl methacrylate.
As preferably, emulsifying agent is the mixture of anionic emulsifier and nonionic emulsifier; Anionic emulsifier is one or more in sodium lauryl sulphate, sodium laurylsulfonate, Sodium dodecylbenzene sulfonate; Nonionic emulsifier is one or more in OP-10, NP-10, TX-10, OP-20.
As preferably, protecting glue is one or more mixtures in Natvosol, polyvinyl alcohol 1788, polyvinyl alcohol 1799.
As preferably, initiator is Potassium Persulphate or ammonium persulphate.
As preferably, PH conditioning agent is Sodium phosphate dibasic or sodium bicarbonate.
A preparation method for digital colorful spray ink-absorbed coated layer cross linking type methyl acrylate and vinyl acetate emulsion, comprises the steps:
1) preparation of monomer mixed solution: obtain monomer mixed solution after vinyl acetate, acrylic monomer, methacrylic monomers, cross-linking monomer proportionally being mixed with the water of 80% weight fraction, for subsequent use;
2) preparation of pre-emulsion: get step 1) in obtain 10 ~ 50% of monomer mixed solution weight to mix with emulsifying agent, conditioning agent and protecting glue, under 500 ~ 1000rpm rotating speed, make pre-emulsion;
3) initiator is used remaining water dissolution, forms initiator solution, then join step 2 by 20 ~ 50% of initiator solution weight) in the pre-emulsion that obtains;
4) by step 3) pre-emulsion be heated to 70 ~ 75 DEG C, 100 ~ 300rpm stir under start polymerization;
5) when step 4) in pre-emulsion have blue light to produce, when reflux condensing tube does not obviously reflux, start the monomer mixed solution slowly dripping remaining 40-90%, within 2 ~ 5 hours, dropwise, and, within every and a half hours, add remaining initiator solution therebetween, keep system temperature to be 70 ~ 75 DEG C, after whole monomer mixed solution and whole initiator solution add, 30 minutes are incubated at 70 ~ 75 DEG C, then, be warming up to 80 ~ 85 DEG C of insulations 30 minutes, form emulsion;
6) by step 5) in after the emulsion that obtains is cooled to 50 DEG C, with 200 order filter-cloth filterings, namely obtain cross linking type methyl acrylate and vinyl acetate emulsion.
Beneficial effect: compared to the prior art, during the independent film forming of this acrylate and vinyl acetate emulsion, film transparency is high, flexible in the present invention, and shock resistance is strong, and water resistance is excellent.The digital colorful spray ink-absorbed coated layer adopting this acrylate and vinyl acetate emulsion to prepare has excellent water tolerance, and prints bright in luster, meets water and does not fade.
Embodiment
In the present invention, acrylic monomer is one or more in vinylformic acid, methyl acrylate, ethyl propenoate, n-butyl acrylate, isobutyl acrylate, Octyl acrylate, Isooctyl acrylate monomer.
Methacrylic monomers is one or more mixing in methacrylic acid, methyl methacrylate, β-dimethyl-aminoethylmethacrylate, n-BMA.
Cross-linking monomer is one or more mixing in N hydroxymethyl acrylamide, N-methoxymethyl propenamide, N-isopropoxymethyl acrylamide, N-butoxymethyl acrylamide, the different butoxymethyl acrylamide of N-, the pungent oxygen Methacrylamide of N-, N-carboxylic methoxymethyl propenamide, vinylformic acid-2-hydroxyl ethyl ester, 2-hydroxypropyl acrylate, ethyl acrylate, methacrylic acid-2-ethylhexyl, 2-hydroxyethyl methacrylate, Hydroxypropyl methacrylate.
Emulsifying agent is the mixture of anionic emulsifier and nonionic emulsifier; Anionic emulsifier is one or more in sodium lauryl sulphate, sodium laurylsulfonate, Sodium dodecylbenzene sulfonate; Nonionic emulsifier is one or more in OP-10, NP-10, TX-10, OP-20.
Protecting glue is one or more mixtures in Natvosol, polyvinyl alcohol 1788, polyvinyl alcohol 1799.
Embodiment 1
A kind of digital colorful spray ink-absorbed coated layer cross linking type methyl acrylate and vinyl acetate emulsion, is made up of each component of the following parts by weight accounting for emulsion total amount: vinyl acetate 15 parts; 3.1 parts, vinylformic acid; Methacrylic acid 0.9 part; N hydroxymethyl acrylamide 0.03 part, sodium lauryl sulphate and 0.3 part, OP-10 mixture; Polyvinyl alcohol 17881.5 parts; Ammonium persulphate 0.03 part; Sodium phosphate dibasic 0.03 part, adds water 79.11 parts.
The preparation method of above-mentioned digital colorful spray ink-absorbed coated layer cross linking type methyl acrylate and vinyl acetate emulsion, comprises the steps:
1) preparation of monomer mixed solution: by vinyl acetate, vinylformic acid, methacrylic acid, N hydroxymethyl acrylamide according to aforementioned proportion and 80% water mixing after obtain monomer mixed solution, for subsequent use;
2) preparation of pre-emulsion: get step 1) in obtain 10% of monomer mixed solution weight to mix with sodium lauryl sulphate and OP-10 mixture, Sodium phosphate dibasic and polyvinyl alcohol 1788, under 500rpm rotating speed, make pre-emulsion;
3) by the water dissolution of remaining for initiator 20%, form initiator solution, then join step 2 by 20% of initiator solution weight) in the pre-emulsion that obtains;
4) by step 3) pre-emulsion be heated to 70 DEG C, 100rpm stir under start polymerization;
5) when step 4) in pre-emulsion have blue light to produce, when reflux condensing tube does not obviously reflux, start the monomer mixed solution slowly dripping remaining 90%, within 2 hours, dropwise, and, within every and a half hours, add remaining initiator solution therebetween, keep system temperature to be 70 DEG C, after whole monomer mixed solution and whole initiator solution add, 30 minutes are incubated at 70 DEG C, then, be warming up to 80 DEG C of insulations 30 minutes, form emulsion;
6) by step 5) in after the emulsion that obtains is cooled to 50 DEG C, with 200 order filter-cloth filterings, namely obtain cross linking type methyl acrylate and vinyl acetate emulsion.
The stability of emulsion that the present invention obtains improves a lot, during the independent film forming of this acrylate and vinyl acetate emulsion, film transparency is high, flexible, shock resistance is strong, and water resistance is excellent, and the digital colorful spray ink-absorbed coated layer adopting this acrylate and vinyl acetate emulsion to prepare has excellent water tolerance, and print bright in luster, not fugitive color.
Embodiment 2:
A kind of digital colorful spray ink-absorbed coated layer cross linking type methyl acrylate and vinyl acetate emulsion, be made up of each component of the following parts by weight accounting for emulsion total amount: vinyl acetate 28 parts, methyl acrylate 12.4 parts, methyl methacrylate 9.3 parts, N-isopropoxymethyl acrylamide 1.5 parts, sodium laurylsulfonate and 1.5 parts, NP-10 mixture, Natvosol 3 parts, Potassium Persulphate 0.3 part, Sodium phosphate dibasic 0.3 part, adds water 43.7 parts.
The preparation method of above-mentioned digital colorful spray ink-absorbed coated layer cross linking type methyl acrylate and vinyl acetate emulsion, comprises the steps:
1) preparation of monomer mixed solution: vinyl acetate, methyl acrylate, methyl methacrylate, N-isopropoxymethyl acrylamide are obtained monomer mixed solution after proportionally mixing with the water of 80% weight fraction, for subsequent use;
2) preparation of pre-emulsion: get step 1) in obtain 50% of monomer mixed solution weight to mix with emulsifying agent, pH adjusting agent and protecting glue, under 500 ~ 1000rpm rotating speed, make pre-emulsion;
3) initiator is used remaining water dissolution, forms initiator solution, then join step 2 by 50% of initiator solution weight) in the pre-emulsion that obtains;
4) by step 3) pre-emulsion be heated to 75 DEG C, 300rpm stir under start polymerization;
5) when step 4) in pre-emulsion have blue light to produce, when reflux condensing tube does not obviously reflux, start the monomer mixed solution slowly dripping remaining 50%, within 5 hours, dropwise, and, within every and a half hours, add remaining initiator solution therebetween, keep system temperature to be 75 DEG C, after whole monomer mixed solution and whole initiator solution add, 30 minutes are incubated at 75 DEG C, then, be warming up to 85 DEG C of insulations 30 minutes, form emulsion;
6) by step 5) in after the emulsion that obtains is cooled to 50 DEG C, with 200 order filter-cloth filterings, namely obtain cross linking type methyl acrylate and vinyl acetate emulsion.
The stability of emulsion that the present invention obtains improves a lot, during the independent film forming of this acrylate and vinyl acetate emulsion, film transparency is high, flexible, shock resistance is strong, and water resistance is excellent, and the digital colorful spray ink-absorbed coated layer adopting this acrylate and vinyl acetate emulsion to prepare has excellent water tolerance, and print bright in luster, not fugitive color.
Embodiment 3:
A kind of digital colorful spray ink-absorbed coated layer cross linking type methyl acrylate and vinyl acetate emulsion, be made up of each component of the following parts by weight accounting for emulsion total amount: vinyl acetate 20 parts, ethyl propenoate 10 parts, β-dimethyl-aminoethylmethacrylate 5 parts, N-isopropoxymethyl acrylamide 1 part, Sodium dodecylbenzene sulfonate and 1 part, OP-20 mixture, polyvinyl alcohol 17992 parts, ammonium persulphate 0.1 part, sodium bicarbonate 0.1 part, adds moisture content.
A preparation method for above-mentioned digital colorful spray ink-absorbed coated layer cross linking type methyl acrylate and vinyl acetate emulsion, comprises the steps:
1) preparation of monomer mixed solution: vinyl acetate, ethyl propenoate, β-dimethyl-aminoethylmethacrylate, N-isopropoxymethyl acrylamide are obtained monomer mixed solution after proportionally mixing with the water of 80% weight fraction, for subsequent use;
2) preparation of pre-emulsion: get step 1) in obtain 30% of monomer mixed solution weight to mix with Sodium dodecylbenzene sulfonate and OP-20 mixture, ammonium persulphate and polyvinyl alcohol 1799, under 600rpm rotating speed, make pre-emulsion;
3) initiator is used remaining water dissolution, forms initiator solution, then join step 2 by 30% of initiator solution weight) in the pre-emulsion that obtains;
4) by step 3) pre-emulsion be heated to 72 DEG C, 200rpm stir under start polymerization;
5) when step 4) in pre-emulsion have blue light to produce, when reflux condensing tube does not obviously reflux, start the monomer mixed solution slowly dripping remaining 70%, within 3 hours, dropwise, and, within every and a half hours, add remaining initiator solution therebetween, keep system temperature to be 72 DEG C, after whole monomer mixed solution and whole initiator solution add, 30 minutes are incubated at 72 DEG C, then, be warming up to 82 DEG C of insulations 30 minutes, form emulsion;
6) by step 5) in after the emulsion that obtains is cooled to 50 DEG C, with 200 order filter-cloth filterings, namely obtain cross linking type methyl acrylate and vinyl acetate emulsion.
Embodiment 4:
Embodiment 4 is roughly the same with embodiment 1, difference be the Acrylic Acid Monomer in embodiment 4 used be n-butyl acrylate.
Embodiment 5:
Embodiment 5 is roughly the same with embodiment 1, and difference is the cross-linking monomer in embodiment 5 is the pungent oxygen Methacrylamide of N-.
Embodiment 6:
Embodiment 6 is roughly the same with embodiment 1, and difference is the methacrylic acid monomer in embodiment 6 is n-BMA.
In order to prove beneficial effect of the present invention further, provide following specific experiment example, specifically in table 1, table 2:
Cross linking type methyl acrylate and vinyl acetate emulsion in Example 1 is prepared into digital colorful spray blotting coating by following technique.
1) coating raw material and proportioning
Table 1 coating raw material and proportioning
2) preparation technology
First water, whitening agent, laking agent are added in high-speed stirring still (HSDD) in proportion and stir evenly, add silicon-dioxide, after high speed dispersion added after 30 minutes, add polyvinyl alcohol solution and cross linking type methyl acrylate and vinyl acetate emulsion, high speed dispersion 45 minutes, filters, and leaves standstill froth breaking stand-by.
3) above-mentionedly digital colorful spray blotting coating is prepared, the Dampler Ace material surface doing primary coat process is coated with 60g standard lines rod, place after coating and dry 5 minutes under 105 DEG C of conditions in an oven, after cooling, use dye printhead machine prints red, yellow, blue, black four look color lumps, respectively test color density, water-resistant coating and image waterfastness.Specific as follows:
Table 2 coating apparatus and test condition
Table 3 test result
Claims (2)
1. a digital colorful spray ink-absorbed coated layer cross linking type methyl acrylate and vinyl acetate emulsion, it is characterized in that: be made up of each component of following parts by weight: vinyl acetate 15 ~ 28 parts, acrylic monomer 3.1 ~ 12.4 parts, methacrylic monomers 5 ~ 9.3 parts, cross-linking monomer 0.03 ~ 1.5 part, emulsifying agent 1 ~ 1.5 part, protecting glue 1.5 ~ 2 parts, initiator 0.03 ~ 0.1 part, PH conditioning agent 0.03 ~ 0.1 part, adds water to gross weight 100 parts;
Described acrylic monomer is one or more in vinylformic acid, methyl acrylate, ethyl propenoate, n-butyl acrylate, isobutyl acrylate, Octyl acrylate, Isooctyl acrylate monomer;
Described methacrylic monomers is one or more mixing in β-dimethyl-aminoethylmethacrylate, n-BMA;
Described cross-linking monomer is one or more mixing in N-methoxymethyl propenamide, N-isopropoxymethyl acrylamide, N-butoxymethyl acrylamide, the different butoxymethyl acrylamide of N-, the pungent oxygen Methacrylamide of N-, N-carboxylic methoxymethyl propenamide, vinylformic acid-2-hydroxyl ethyl ester, 2-hydroxypropyl acrylate, ethyl acrylate, methacrylic acid-2-ethylhexyl, 2-hydroxyethyl methacrylate, Hydroxypropyl methacrylate;
Described emulsifying agent is the mixture of anionic emulsifier and nonionic emulsifier; Anionic emulsifier is one or more in sodium laurylsulfonate, Sodium dodecylbenzene sulfonate; Nonionic emulsifier is one or more in OP-10, NP-10, OP-20;
Described protecting glue is one or more mixtures in Natvosol, polyvinyl alcohol 1799;
Described initiator is ammonium persulphate;
Described PH conditioning agent is sodium bicarbonate.
2. a preparation method for digital colorful spray ink-absorbed coated layer cross linking type methyl acrylate and vinyl acetate emulsion according to claim 1, is characterized in that: comprise the steps:
1) preparation of monomer mixed solution: obtain monomer mixed solution after vinyl acetate, acrylic monomer, methacrylic monomers, cross-linking monomer proportionally being mixed with the water of 80% weight fraction, for subsequent use;
2) preparation of pre-emulsion: get step 1) in obtain 10 ~ 50% of monomer mixed solution weight to mix with emulsifying agent, pH adjusting agent and protecting glue, under 500 ~ 1000rpm rotating speed, make pre-emulsion;
3) initiator is used remaining water dissolution, forms initiator solution, then join step 2 by 20 ~ 50% of initiator solution weight) in the pre-emulsion that obtains;
4) by step 3) pre-emulsion be heated to 70 ~ 75 DEG C, 100 ~ 300rpm stir under start polymerization;
5) when step 4) in pre-emulsion have blue light to produce, when reflux condensing tube does not obviously reflux, start the monomer mixed solution slowly dripping remaining 40-90%, within 2 ~ 5 hours, dropwise, and, within every and a half hours, add remaining initiator solution therebetween, keep system temperature to be 70 ~ 75 DEG C, after whole monomer mixed solution and whole initiator solution add, 30 minutes are incubated at 70 ~ 75 DEG C, then, be warming up to 80 ~ 85 DEG C of insulations 30 minutes, form emulsion;
6) by step 5) in after the emulsion that obtains is cooled to 50 DEG C, with 200 order filter-cloth filterings, namely obtain cross linking type methyl acrylate and vinyl acetate emulsion.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906278A (en) * | 2010-08-12 | 2010-12-08 | 华南理工大学 | Single-component polyvinylacetate binding agent and preparation method thereof |
| CN102153971A (en) * | 2011-01-25 | 2011-08-17 | 北京高盟新材料股份有限公司 | Waterborne aluminium foil adhesive and preparation method thereof |
| CN102731728A (en) * | 2012-07-06 | 2012-10-17 | 江苏格美高科技发展有限公司 | Adhesive for digital inkjet printing ink-absorption coating and preparation method thereof |
-
2013
- 2013-06-21 CN CN201310251345.XA patent/CN103342773B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906278A (en) * | 2010-08-12 | 2010-12-08 | 华南理工大学 | Single-component polyvinylacetate binding agent and preparation method thereof |
| CN102153971A (en) * | 2011-01-25 | 2011-08-17 | 北京高盟新材料股份有限公司 | Waterborne aluminium foil adhesive and preparation method thereof |
| CN102731728A (en) * | 2012-07-06 | 2012-10-17 | 江苏格美高科技发展有限公司 | Adhesive for digital inkjet printing ink-absorption coating and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 聚醋酸乙烯酯乳液的耐水性改性研究进展;吴伟剑;《化学与黏合》;20060930;第28卷(第5期);第346页左栏2共聚改性 * |
| 自交联型聚醋酸乙烯酯乳液的室温制备;刘玉梅;《中国胶粘剂》;20050730;第14卷(第7期);前言，第10页右栏2.4交联单体N-羟甲基丙烯酰胺用量的影响 * |
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