CN109897464A - A kind of printable transfer non-silicon separated type material - Google Patents
A kind of printable transfer non-silicon separated type material Download PDFInfo
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- CN109897464A CN109897464A CN201910181021.0A CN201910181021A CN109897464A CN 109897464 A CN109897464 A CN 109897464A CN 201910181021 A CN201910181021 A CN 201910181021A CN 109897464 A CN109897464 A CN 109897464A
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Abstract
A kind of printable transfer non-silicon separated type material disclosed by the invention including non-silicon release layer and is coated on the semi-solid preparation transfer ink of the release layer surface of the non-silicon；The non-silicon release layer by the material of following parts by weight through mixing, extrusion, dry: fluorine-containing ester copolymer 40-60 parts of ethylene-vinyl imines-acrylic acid；Plexiglass 20-25；15-25 parts of polyethyleneimine；10-15 parts of diluent；3-5 parts of auxiliary agent.Non-silicon separated type material disclosed by the invention will not cause silicon to pollute due to not siliceous ingredient, and when transfer will not leave behind residue, and off-type force is adjustable；Be coated with semi-solid preparation transfer ink additionally, due to non-silicon separated type material surface, therefore non-silicon separated type material disclosed by the invention has the function of printing transfer, and the semi-solid preparation ink of surface coating can after transfer all solidstate again, ink adhesion is strong, and transfer fastness is good.
Description
Technical field
The present invention relates to separated type material field, in particular to a kind of printable transfer non-silicon separated type material.
Background technique
Transfer is a kind of material played after transfer with substrate film release effect, traditional release material with separated type material
Material is generally siliceous separated type material, such as silicone oil, OP wax.Although siliceous separated type material can be configured to the release of different peeling forces
Layer, and using effect is preferable, but subsequent as being easy in printing technology at printing interface there are residue, and remaining siliceous material
Material easily causes silicon to pollute, and when operator uses siliceous separated type material, residue containing silicon, which is easily transferred to stick surface, to be caused
Subsequent transferring effect.In addition, existing separated type material is intended only as a peeling layer in transfer film, and siliceous separated type material table
Face tension is low, is not able to satisfy the requirement of surface printing, therefore does not have individually printing and transfer function.
Summary of the invention
In view of the above-mentioned deficiencies in the prior art, the technical problem to be solved by the present invention is that providing a kind of printable turn
Print non-silicon separated type material.
In order to solve the above technical problems, the technical solution adopted by the present invention is that: a kind of printable release material of transfer non-silicon
Material including non-silicon release layer and is coated on the semi-solid preparation transfer ink of the release layer surface of the non-silicon；The non-silicon release layer by
The material of following parts by weight through mixing, extrusion, dry: fluorine-containing ester copolymer 40-60 parts of ethylene-vinyl imines-acrylic acid；
Plexiglass 20-25；15-25 parts of polyethyleneimine；10-15 parts of diluent；3-5 parts of auxiliary agent.
Preferably, the ethylene-vinyl imines-fluorine-containing ester copolymer of acrylic acid is the preparation method comprises the following steps: under vacuum conditions
The water of 100-150 parts by weight and the fluorine-containing organic solvent of 150-200 parts by weight are added into autoclave, then is separately added into 75-80
The molecular weight regulator of the fluorine-containing ester monomer of parts by weight of acrylic acid, the aziridine monomer of 40-60 parts by weight and 1.2-2.0 parts by weight
Tetrachloromethane, while stirring is warming up to 60-70 DEG C, then imports the vinyl monomer of 25-30 parts by weight, adjusting polymerization pressure is 0.8-
The initiator ammonium persulfate of 3-5 parts by weight is added after 2.2MPa, ethylene-vinyl imines-the third is obtained by filtration in cooling after keeping the temperature 3-4h
The fluorine-containing ester copolymer of olefin(e) acid；The fluorine-containing ester copolymer number average molecular weight of ethylene-vinyl imines-acrylic acid is 30000-35000.
Preferably, the plexiglass number-average molecular weight is 20000-30000.
Preferably, the polyethyleneimine is linear, low density polymer, number-average molecular weight 10000-20000.
Preferably, the diluent is propylene glycol monomethyl ether, and the auxiliary agent is dispersing agent, wetting agent and toughener
It is one or more.
Preferably, the semi-solid preparation transfer ink includes following components by weight: epoxy acrylic resin 50-60
Part；15-25 parts of acrylate monomer；1-2 parts of cation light initiator；3-5 parts of free radical photo-initiation；6-8 parts of pigment；Solvent
30-45 parts；0.5-1 parts of levelling agent；0.1-0.2 parts of defoaming agent；0.5-1.5 parts of antistatic agent.
Preferably, the acrylate monomer is propylene glycol diacrylate, hexanediyl ester, pentanediol two
One of acrylate, butanediol diacrylate are a variety of.
Preferably, the cation light initiator is one of diazonium salt, alkyl sulfosalt, sulfonyloxy ketone or more
Kind, the free radical photo-initiation is one of dialkyl group oxygroup acetophenone, alpha-hydroxyalkyl benzophenone, α-amine alkyl phenones or more
Kind.
Preferably, the solvent is the one or more of ethyl acetate, butyl acetate, ethyl alcohol or isopropanol.
Preferably, the levelling agent is acrylate leveling agent, and the pigment is organic pigment.
The beneficial effects of the present invention are: fluorine-containing using plexiglass and ethylene-vinyl imines-acrylic acid
The blending and modifying of ester copolymer forms the release layer material of non-silicon, due to not siliceous ingredient, therefore silicon will not be caused to pollute, when transfer not
Residue can be left, and off-type force is adjustable；Because being coated with semi-solid preparation transfer ink, therefore this hair in the release layer surface of non-silicon
Bright disclosed non-silicon separated type material has the function of printing transfer, and the semi-solid preparation ink that is coated with of surface can after transfer Quan Gu again
Change, ink adhesion is strong, and transfer fastness is good.
Specific embodiment
The present invention will be further described in detail below with reference to the embodiments, to enable those skilled in the art referring to specification
Text can be implemented accordingly.
It should be appreciated that such as " having ", "comprising" and " comprising " term used herein are not precluded one or more
The presence or addition of a other elements or combinations thereof.
A kind of printable transfer non-silicon separated type material disclosed by the invention, including non-silicon release layer and be coated on described non-
The semi-solid preparation transfer ink of the release layer surface of silicon；The non-silicon release layer is by the material of following parts by weight through mixing, extrusion, drying
It forms: fluorine-containing ester copolymer 40-60 parts of ethylene-vinyl imines-acrylic acid；Plexiglass 20-25；Polyethylene
15-25 parts of imines；10-15 parts of diluent；3-5 parts of auxiliary agent.Wherein the non-silicon release layer uses polymethyl methacrylate tree
Rouge and ethylene-vinyl imines-acrylic acid fluorine-containing ester copolymer blending and modifying have good off-type force；In addition polyethyleneimine
Amine is a kind of typical water soluble polymer cation type polymer surfactant, can be by being adsorbed on around other polymers
Prevent its flocculation and a kind of good non-silicon mould release, the table of non-silicon separated type material can be reduced by being added in system
Face tension makes it have printable function.
Further, the ethylene-vinyl imines-fluorine-containing ester copolymer of acrylic acid the preparation method comprises the following steps: under vacuum conditions to
The water of 100-150 parts by weight and the fluorine-containing organic solvent of 150-200 parts by weight are added in autoclave, then is separately added into 75-80 weight
Measure the fluorine-containing ester monomer of part acrylic acid, the aziridine monomer of 40-60 parts by weight and the molecular weight regulator four of 1.2-2.0 parts by weight
Chloromethanes, while stirring is warming up to 60-70 DEG C, then imports the vinyl monomer of 25-30 parts by weight, adjusting polymerization pressure is 0.8-
The initiator ammonium persulfate of 3-5 parts by weight is added after 2.2MPa, ethylene-vinyl imines-the third is obtained by filtration in cooling after keeping the temperature 3-4h
The fluorine-containing ester copolymer of olefin(e) acid；The fluorine-containing ester copolymer number average molecular weight of ethylene-vinyl imines-acrylic acid is 30000-35000.
By introducing the fluorine-containing ester monomer of acrylic acid in ethylene and ethyleneimine copolymer, the fluorine component of introducing can improve release material
Alkaline-resisting, the water-fast and solvent resistance of material.
Wherein, the plexiglass number-average molecular weight is 20000-30000；The polyethyleneimine is
Linear, low density polymer, number-average molecular weight 10000-20000；The diluent is propylene glycol monomethyl ether, described to help
Agent is the one or more of dispersing agent, wetting agent and toughener, keeps separated type material mixed-forming more uniform by the way that auxiliary agent is added.
Using the plexiglass and polyethyleneimine of different proportion, ethylene-vinyl imines-acrylic acid fluorinated ester copolymerization
The non-silicon release layer of the available different off-type forces of object.
Wherein, the non-silicon release layer is the preparation method is as follows: by above-mentioned raw materials with 1000- under the conditions of 50-60 DEG C
The revolving speed of 1500r/min stirs evenly 1-2h and obtains mixture, then mixture is squeezed out by lamination extruder and is coated on poly-
Membrane of lipoprotein substrate surface forms non-silicon release layer after toasted.
Further, the semi-solid preparation transfer ink includes following components by weight: 50-60 parts of epoxy acrylic resin；
15-25 parts of acrylate monomer；1-2 parts of cation light initiator；3-5 parts of free radical photo-initiation；6-8 parts of pigment；Solvent 30-
45 parts；0.5-1 parts of levelling agent；0.1-0.2 parts of defoaming agent；0.5-1.5 parts of antistatic agent.
Wherein, the acrylate monomer is propylene glycol diacrylate, hexanediyl ester, two propylene of pentanediol
One of acid esters, butanediol diacrylate are a variety of, and the acrylate monomer is good UV curing monomer, solidification
Property and dilution property it is more preferable, reactivity is high, and viscosity is low, excellent storage stability, and level of residual monomers is few after photocuring, and ink is attached after solidification
Put forth effort by force, transfer fastness is good；The cation light initiator is one of diazonium salt, alkyl sulfosalt, sulfonyloxy ketone
Or it is a variety of；The free radical photo-initiation is one of dialkyl group oxygroup acetophenone, alpha-hydroxyalkyl benzophenone, α-amine alkyl phenones
Or it is a variety of；The solvent is the one or more of ethyl acetate, butyl acetate, ethyl alcohol or isopropanol, and the levelling agent is propylene
Acid esters levelling agent, the pigment are organic pigment.The uniformity of ink system, antistatic agent can be improved in levelling agent and defoaming agent
The deleterious charge of ink solidification rear surface can be reduced, pigment can assign ink different colors, and draw using free radical light
Hair agent and cation light initiator can make the transfer ink for being coated on the release layer surface of non-silicon first carry out portion under ultraviolet light
Divide and be formed by curing semi-solid preparation coating, after removing ultraviolet light after transfer, after transfer ink is transferred to other interfaces, in cation
Continue to solidify under photoinitiator effect, until forming all solidstate coating.
Wherein, the transfer ink is the preparation method comprises the following steps: the raw material is uniformly mixed under 2000-2500r/min revolving speed
Ink mixture is obtained, then ink mixture is sprayed at the release layer surface of non-silicon using coating machine, and be 250- with wavelength
The ultraviolet light 3-5min of 280nm forms semi-solid preparation coating.In use, the non-silicon separated type material for being coated with transfer ink is turning
After print, solidification can be continued after the semi-solid preparation coating transfer to other interfaces on surface until all solidstate.
It is exemplified below out specific embodiment and test performance:
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed
With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily
Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited
In specific details.
Claims (10)
1. a kind of printable transfer non-silicon separated type material, which is characterized in that including non-silicon release layer and be coated on the non-silicon
The semi-solid preparation transfer ink of release layer surface；The non-silicon release layer by following parts by weight material through mixing, extrusion, drying and
At: fluorine-containing ester copolymer 40-60 parts of ethylene-vinyl imines-acrylic acid；Plexiglass 20-25；Polyethyleneimine
15-25 parts of amine；10-15 parts of diluent；3-5 parts of auxiliary agent.
2. printable transfer non-silicon separated type material according to claim 1, which is characterized in that the ethylene-vinyl is sub-
The fluorine-containing ester copolymer of amine-acrylic acid the preparation method comprises the following steps: under vacuum conditions into autoclave be added 100-150 parts by weight water and
The fluorine-containing organic solvent of 150-200 parts by weight, then it is separately added into the fluorine-containing ester monomer of 75-80 parts by weight of acrylic acid, 40-60 parts by weight
Aziridine monomer and 1.2-2.0 parts by weight molecular weight regulator tetrachloromethane, while stirring is warming up to 60-70 DEG C, then
The vinyl monomer of 25-30 parts by weight is imported, the initiator over cure that 3-5 parts by weight are added after polymerization pressure is 0.8-2.2MPa is adjusted
Sour ammonium, ethylene-vinyl imines-fluorine-containing ester copolymer of acrylic acid is obtained by filtration in cooling after keeping the temperature 3-4h；The ethylene-vinyl is sub-
The fluorine-containing ester copolymer number average molecular weight of amine-acrylic acid is 30000-35000.
3. printable transfer non-silicon separated type material according to claim 1, which is characterized in that the polymethylacrylic acid
Late resin number-average molecular weight is 20000-30000.
4. printable transfer non-silicon separated type material according to claim 1, which is characterized in that the polyethyleneimine is
Linear, low density polymer, number-average molecular weight 10000-20000.
5. printable transfer non-silicon separated type material according to claim 1, which is characterized in that the diluent is
Propylene glycol monomethyl ether, the auxiliary agent are the one or more of dispersing agent, wetting agent and toughener.
6. printable transfer non-silicon separated type material according to claim 1, which is characterized in that the semi-solid preparation transfer oil
Ink includes following components by weight: 50-60 parts of epoxy acrylic resin；15-25 parts of acrylate monomer；Cationic photopolymerization causes
1-2 parts of agent；3-5 parts of free radical photo-initiation；6-8 parts of pigment；30-45 parts of solvent；0.5-1 parts of levelling agent；Defoaming agent 0.1-0.2
Part；0.5-1.5 parts of antistatic agent.
7. printable transfer non-silicon separated type material according to claim 6, which is characterized in that the acrylate monomer
For one of propylene glycol diacrylate, hexanediyl ester, Diacrylate, butanediol diacrylate
Or it is a variety of.
8. printable transfer non-silicon separated type material according to claim 6, which is characterized in that the cationic photopolymerization causes
Agent is one of diazonium salt, alkyl sulfosalt, sulfonyloxy ketone or a variety of, and the free radical photo-initiation is dialkyl group oxygroup
One of acetophenone, alpha-hydroxyalkyl benzophenone, α-amine alkyl phenones are a variety of.
9. printable transfer non-silicon separated type material according to claim 6, which is characterized in that the solvent is acetic acid second
Ester, butyl acetate, ethyl alcohol or isopropanol it is one or more.
10. printable transfer non-silicon separated type material according to claim 6, which is characterized in that the levelling agent is third
Olefin(e) acid ester levelling agent, the pigment are organic pigment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910181021.0A CN109897464B (en) | 2019-03-11 | 2019-03-11 | Non-silicon release material for printable transfer printing |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910181021.0A CN109897464B (en) | 2019-03-11 | 2019-03-11 | Non-silicon release material for printable transfer printing |
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| CN109897464B CN109897464B (en) | 2021-08-06 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110903588A (en) * | 2019-12-02 | 2020-03-24 | 苏州泰仑电子材料有限公司 | Low-silicon transfer silica gel pressure-sensitive adhesive protective film |
| CN110922858A (en) * | 2019-12-02 | 2020-03-27 | 苏州泰仑电子材料有限公司 | Environment-friendly emulsion type low-transfer high-temperature-resistant protective film |
| CN110949028A (en) * | 2019-11-18 | 2020-04-03 | 东莞市信彩包装有限公司 | Printing method for strengthening sprayed code adhesive force on gloss oil surface |
| CN112373214A (en) * | 2020-09-17 | 2021-02-19 | 上海当纳利印刷有限公司 | Glue film mixture for ink-jet proofing and film coating scheme |
| CN113088193A (en) * | 2021-04-13 | 2021-07-09 | 海南必凯水性新材料有限公司 | Environment-friendly water-based release agent and preparation method thereof |
| CN113693038A (en) * | 2021-07-27 | 2021-11-26 | 界首市汇珠渔具有限公司 | Production process method of paillette thermoprint plastic bionic bait |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110949028A (en) * | 2019-11-18 | 2020-04-03 | 东莞市信彩包装有限公司 | Printing method for strengthening sprayed code adhesive force on gloss oil surface |
| CN110903588A (en) * | 2019-12-02 | 2020-03-24 | 苏州泰仑电子材料有限公司 | Low-silicon transfer silica gel pressure-sensitive adhesive protective film |
| CN110922858A (en) * | 2019-12-02 | 2020-03-27 | 苏州泰仑电子材料有限公司 | Environment-friendly emulsion type low-transfer high-temperature-resistant protective film |
| CN112373214A (en) * | 2020-09-17 | 2021-02-19 | 上海当纳利印刷有限公司 | Glue film mixture for ink-jet proofing and film coating scheme |
| CN113088193A (en) * | 2021-04-13 | 2021-07-09 | 海南必凯水性新材料有限公司 | Environment-friendly water-based release agent and preparation method thereof |
| CN113088193B (en) * | 2021-04-13 | 2022-06-28 | 海南必凯水性新材料有限公司 | Environment-friendly water-based release agent and preparation method thereof |
| CN113693038A (en) * | 2021-07-27 | 2021-11-26 | 界首市汇珠渔具有限公司 | Production process method of paillette thermoprint plastic bionic bait |
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| CN109897464B (en) | 2021-08-06 |
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