CN1461704A - Thermal transfer printing ribbon, and its prodn, art - Google Patents
Thermal transfer printing ribbon, and its prodn, art Download PDFInfo
- Publication number
- CN1461704A CN1461704A CN 02115333 CN02115333A CN1461704A CN 1461704 A CN1461704 A CN 1461704A CN 02115333 CN02115333 CN 02115333 CN 02115333 A CN02115333 A CN 02115333A CN 1461704 A CN1461704 A CN 1461704A
- Authority
- CN
- China
- Prior art keywords
- adhesive
- ink coating
- wax
- heat transfer
- tape base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
A ribbon for thermal transfer is prepared through providing a ribbon substrate, preparing ink from wax-type adhesive, resin-type adhesive, pigment and assistant, coating the ink on the surface of ribbon substrate, coating the refractory material on the back of ribbon substrate, baking and cutting according needed sizes. Its preparing process is also disclosed. Its advantages are high resolution, clear print, and high resistance to wearing and moisture.
Description
Technical field
The present invention relates to the recording materials that printing technique is used, more particularly, relate to a kind of heat transfer colour ribbon and manufacturing process thereof of fine definition.
Background technology
In recent years, being applied in of heat transfer colour ribbon (Thermal Transfer Ribbon is hereinafter to be referred as TTR) develops rapidly.The advantage that adopts TTR to print is that resolution ratio writings and image higher, that print is clear, and does not resemble when work and produce noise other printers, can reduce the noise pollution to environment.
TTR is of wide application, for example can be used for factory and market print labels name board, marked price, bar code etc., also can be used for the boarding card on traffic department's printing train ticket, airport etc., also be used in office's facsimile document, the fax paper that is printed easy flavescence or fade unlike common facsimile transmission paper, thereby can long preservation.In addition, colored TTR can the printing color certificate photograph, can save the complicated processes of flushing photograph.
For the ease of the understanding of the present invention, simply introduce the operation principle of thermal transfer printer below.As shown in Figure 1, TTR is by plastics tape base 21, is coated on ink coating 22 on the tape base 21 and the heat-resisting backing layer 23 at tape base 21 back sides is constituted.Wherein the main component of ink coating 22 is adhesive and the colouring agent that is dispersed in wherein.
At normal temperatures, ink coating 22 is solid-state, sticks to plastic sheeting tape base 21 surfaces.As shown in Figure 2, when printing, thermal printing head 10 heats up because of the messenger electric current, when thermal printing head is heated to uniform temperature, TTR is last to be melted with ink coatings thermal printing head 10 contacts site, under the effect of thermal printing head pressure, the ink coating of this part fusing strips down from tape base 21, transfer on the record-paper of accepting below the TTR to print or other recording medium materials 30, thereby form literal or the image 26 printed, the ink coating at other positions that contact with thermal printing head 10 then still is not retained in the original position of TTR.
According to the operation principle of thermal transfer printer as can be known, for important materials TTR wherein, need to satisfy following the requirement:
(1), the tape base of TTR will have higher heat endurance, can not adhere to or stain thermal printing head owing to softening under the heat effect of thermal printing head; Tape base will approach simultaneously, is beneficial to accelerate when printing the fusing of ink coating, thereby improves print speed;
(2), ink coating will have suitable melt temperature scope, low-melting material is easy to fusing and helps Rapid Thermal and shift, but fusing point crosses when low, ink material can undercapacity, does not resistance to wear; Otherwise when the ink material fusing point was too high, though the strength of materials improves, ink coating was difficult to fusing when hot print, was difficult for shifting, and not only made print speed slow excessively, and the service life that can reduce thermal printing head;
(3), ink coating and accept adhesion between the recording medium material of printing and the intensity and the physical and chemical performance of ink coating material itself will meet the demands, the writing of printing and image are had resistance to wear and ability that moisture resistance is wet;
(4), the ink coating material of TTR will have sufficiently high flowability in molten state, even make the ink coating material of fusing on common recording medium, also sufficiently high levelability will be arranged, thereby the ink coating material of molten condition can flow into the recessed part in hole on print record paper surface, pit is filled up by printing ink, then formed literal or pattern edge are complete, the definition height, thus higher resolution ratio is arranged.
Present some commercially available heat transfer colour ribbon, some product quality is relatively poor, for example the ink coating on the TTR is easy to peel off, and the writing of printing and image are relatively fuzzy, definition is not enough, and the writings and image abrasion resistance properties of printing is relatively poor, easily because of frayed or fogged or the like by humidity.Especially when adopting non-special-purpose paper to accept to print, above-mentioned phenomenon is more obvious.In addition, the fusing point of some TTR ink coating is not suitable for general thermal transfer printer, and the print speed that not only slows down also influences service life of thermal printing head.
Summary of the invention
The technical problem to be solved in the present invention is that the above-mentioned defective at existing heat transfer colour ribbon has proposed a kind of new TTR ink coating prescription and manufacturing process.
Heat transfer colour ribbon of the present invention comprises tape base, is coated on the ink coating on described tape base surface and the heat-resisting backing layer at the back side, the material of described ink coating comprises adhesive, colouring agent and auxiliary agent, it is characterized in that, described adhesive comprises wax class and resinae adhesive, in described ink coating, the ratio of described wax class adhesive is that the ratio of 40-80%, described resinae adhesive is that the ratio of 5-35%, described colouring agent is that the ratio of 5-25%, described auxiliary agent is 0.1-10%.
In heat transfer colour ribbon of the present invention, the fusing point of described wax class adhesive is 50-110 ℃; The softening temperature of described resinae adhesive is that 60-130 ℃, solidification temperature are 30-70 ℃.
In heat transfer colour ribbon of the present invention, described wax class adhesive can be selected two or more from native paraffin, animals and plants wax and synthetic wax, and each wax shared ratio in ink coating is 10-50%.
In heat transfer colour ribbon of the present invention, described resinae adhesive can adopt thermoplasticity synthetic resin, can select one or more from polyethylene, polypropylene, polyvinyl chloride, polyvinyl acetate, polyvinyl alcohol, ethylene-vinyl acetate copolymer, vinyl chloride-vinyl acetate copolymer, vinyl chloride-vinyl acetate-vinyl alcohol terpolymer, epoxy resin, polyamide, polyurethane resin, Petropols, polyketone resin, polystyrene and SBR styrene butadiene rubbers.
In heat transfer colour ribbon of the present invention, described heat-resisting backing layer can be heat-resisting silicones or polyurethane material.
In heat transfer colour ribbon of the present invention, the plastic sheeting of described tape base for adopting nylon, acetate fiber, polyester, polyamide or polyethylene to make, its thickness is the 3-6 micron.
The manufacturing process of heat transfer colour ribbon of the present invention may further comprise the steps:
(1), choosing thickness is that the plastic sheeting of 3-6 micron is as tape base;
(2), the ratio of getting is the wax class adhesive of 40-80%, the resinae adhesive of 5-35%, the colouring agent of 5-25% and the auxiliary agent of 0.1-10%, makes the ink coating slurry;
(3), be coated with described ink coating slurry on the surface of tape base, coating weight is every square metre of 2-5 gram;
(4), be coated with heat-resisting backing layer, coating weight is every square metre of 0.1-1 gram at the back side of tape base;
(5), dry and cut into required size.
In described step (2), can make three types ink coating slurry, the first adopts toluene, ketone, cyclohexane and industrial naptha to make mixed solvent, wax class adhesive and resinae adhesive are dissolved in wherein, add colouring agent and auxiliary agent again, be mixed with solvent type ink coating slurry; It two is that wax class adhesive and resinae adhesive are carried out emulsification, adds colouring agent and auxiliary agent again, is mixed with emulsion-type printing ink coating slurry; It three is that the heating of wax class adhesive and resinae adhesive is melted, and adds colouring agent and auxiliary agent again, is mixed with molten printing ink paint slurry.
The TTR that adopts TTR ink coating prescription of the present invention and manufacturing process to produce has the following advantages: the image of printing has higher resolution ratio, and the writings and image of printing is clear; The writings and image of being printed has high adhesion with the recording medium of accepting printing, thereby has and resistance to wear and ability that moisture resistance is wet, and be difficult for because of wearing and tearing or fogged by humidity, thereby can long preservation; When flying print, still have good printing effect, thereby can improve the operating efficiency of printing.
Description of drawings
Fig. 1 is the enlarged diagram of heat transfer colour ribbon before printing that contacts with thermal printing head;
Fig. 2 is the enlarged diagram of heat transfer colour ribbon when printing that contacts with thermal printing head.
The specific embodiment
Below we introduce the prescription and the process for making of Transfer ribbon of the present invention in detail.
One, the used material of Transfer ribbon
As can be known from Fig. 1, TTR mainly is made of tape base 21 and ink coating 22 two parts, the formation of two sections of material is discussed respectively below and is selected foundation.
1, tape base
As the tape base material of TTR, must be not softening in 150-250 ℃ temperature range, thinner thickness is beneficial to the heat conduction.Therefore can from multiple plastic sheetings such as nylon, acetate fiber, Merlon, PEF, polypropylene, polyamide, polyester, select.But, consider from the multiple factors such as softening point, tensile strength and heat-conductive characteristic of material, be that polyester (PET) film of 2-10 micron is advisable with thickness, thickness is the most suitable tape base of being TTR of the polyester film of 3-6 micron.
2, ink coating material:
The main material that is coated in the ink coating on the tape base of TTR is adhesive and colouring agent, and adds a little auxiliary.
2-1, adhesive
The effect of adhesive in the ink coating of TTR comprises: colouring agent is bonded together, and it is bonded on the plastic sheeting; Adhesive melts during hot print, and colouring agent transferred on the recording medium of accepting printing together; On record-paper or other recording mediums, the effect of adhesive is that colouring agent is bonded on the surface of recording medium.
Therefore for adhesive following some requirement is arranged: have suitable fusing point or softening point range; Have low viscosity after heat fused, high fluidity promptly has higher melt index (Melting Index), is accepting on the paper of printing high levelability is arranged, and is clear to guarantee writing and the figure printed; Adhesive and TTR tape base have suitable adhesion strength, guarantee that ink coating can not come off from plastic sheeting at normal temperatures; Be easy to peel off totally but require ink coating to be heated when melting from tape base; Between the paper that guarantees ink coating and accept to print or other recording medium materials high adhesion strength is arranged, the ink coating of fusing is transferred on the surface of printing paper from the TTR tape base easily, and in cooling with solidify writing and the figure printed the back and have high fastness, be difficult for being worn and fog.
Above-mentioned requirements is conflicting a bit, thereby a kind of adhesive of very difficult searching can satisfy above-mentioned multiple requirement fully.For example, when requiring a kind of adhesive to have low viscosity under molten condition, then this low viscous adhesive just is difficult to that the recording medium material is had high adhesion strength.In order to accomplish to satisfy above-mentioned multiple requirement simultaneously, need in the ink coating prescription, add multiple adhesive, make performance complement between them, respectively get the chief, to reach the purpose that fully satisfies aforementioned various requirement.The adhesive material that is adopted among the present invention comprises wax and resin.
2-1-1 wax class
Selecting the adhesive of wax as the TTR ink coating, is that the wax of fusing has lower viscosity, and high melt index is promptly arranged because of it is easy to fusing, can improve the levelability of fusing ink coating, thereby improve the definition of printing writing and figure.The wax that can adopt has following several big class at present,
Native paraffin comprises paraffin, montan wax, E-wax, O-wax, microwax and ceresine;
Animals and plants wax comprises Brazil wax, sugarcane wax, shellac wax, insect wax, beeswax and rice bran wax;
Synthetic wax comprises Tissuemat E, OPE and synthesizing amide wax.
In the selection of wax, the melting range that requires wax is 50-110 ℃, can select two or more wax for use, and every kind of wax shared ratio in ink coating is 10-50%, and the total amount of wax shared ratio in ink coating is 40-80%.
2-1-2, resinae
When adopting wax to make TTR, although writing and the clear picture and the high advantage of print speed of printing are arranged as adhesive; But writing and the image printed are not firm, and antiwear property is poor, easily fogs.In order to remedy the above-mentioned weakness of wax, in the ink coating prescription of TTR, add a certain proportion of thermoplasticity synthetic resin adhesive, can improve the cementitiousness of TTR ink coating, increase the fastness and the antiwear property of printing writing and figure, thereby improve the printing effect of TTR.The thermoplastic synthetic resin adhesive that is fit to comprises polyethylene, polypropylene, polyvinyl chloride, polyvinyl acetate, polyvinyl alcohol, ethylene-vinyl acetate copolymer, vinyl chloride-vinyl acetate copolymer, vinyl chloride-vinyl acetate-vinyl alcohol terpolymer, epoxy resin, polyamide, polyurethane resin, Petropols, polyketone resin, polystyrene and SBR styrene butadiene rubbers etc.
On resin choice, the softening point temperature scope that requires selected ger-bond is 60-130 ℃, and solidification temperature is 30-70 ℃, and under the temperature that is higher than 30 ℃ of melting point resins, viscosity is low.In the selection of synthetic resin, to note the intermiscibility of it and wax.Can select one or more synthetic resin, the part by weight that various resins are added in the ink coating of TTR is 5-35%.
2-2, colouring agent
The colouring agent of selecting for use in the TTR ink coating can adopt inorganic pigment, organic pigment or dyestuff, or several dual-purpose.The colouring agent of selecting for use should guarantee that dispersing of pigments is good, will note the granularity of pigment for this reason, and tiny particle helps the intensification of color, but meticulous particle is difficult to be uniformly dispersed; Require colouring agent to have good chemical stability in addition, be difficult for decomposing.
The addition of colouring agent can influence the color and luster of printing writing and image, and the additional proportion of colouring agent is the 5-25% of ink coating solid content usually.
When being used to make black TTR, colouring agent can be selected carbon black, graphite, spirit black, nigrosine, direct black, black pigment slurry etc. for use; And when making colored TTR, can select pigment such as phthalocyanine blue, permanent bordeaux, permanent yellow for use.
2-3, auxiliary agent
Except main components such as adhesive and colouring agents and, in prescription, to add the auxiliary agent such as dispersant, antistatic additive, defoamer of proper proportion.
Two, Recipe and coating process
1, ink coating prescription
Among the present invention, the fusing point of TTR ink coating is determined in 60-90 ℃ of scope that this temperature range is fit to for the present commercially available thermal transfer printer of great majority; Consider TTR again for the viscosity of fusing printing ink and the requirement of antiwear property, the formula rate of TTR ink coating sees the following form 1 among the present invention.
The content range of various materials in the table 1-thermal transfer-printing ink ribbon ink coating
| ????No | Material category | Content in the thermal transfer-printing ink ribbon ink coating (%) |
| ????1 | Colouring agent | ????5-25 |
| ????2 | The wax class | ????50-80 |
| ????3 | Synthetic resin | ????5-35 |
| ????4 | Various auxiliary agents | ????0.1-10 |
Among the present invention, the formula rate of black ink coating sees the following form 2, comprises three embodiment in the table, and wherein the ratio of carbon black, Tissuemat E and auxiliary agent keeps 10%, 10% and 8% respectively, and all the other are every slightly to change.
Table 2-black fever Transfer ribbon ink coating prescription
| ????No | Material category | Content range in the thermal transfer-printing ink ribbon ink coating (%) | ||
| Embodiment one | Embodiment two | Embodiment three | ||
| ????1 | Carbon black | ????10 | ????10 | ????10 |
| ????2 | Brazil wax | ????45 | ????35 | ????30 |
| ????3 | Paraffin | ????20 | ????27 | ????30 |
| ????4 | Tissuemat E | ????10 | ????10 | ????10 |
| ????5 | The EVA resin | ????7 | ????10 | ????12 |
| ????6 | Various auxiliary agents | ????8 | ????8 | ????8 |
| Add up to | ????100 | ????100 | ????100 | |
Among the present invention, the formula rate of colored ink coating sees the following form 3, wherein provides prescription red, yellow, the blue ink coating.
The colored thermal transfer-printing ink ribbon ink coating formula of table 3-
| ????No | Material category | Content in the thermal transfer-printing ink ribbon ink coating (%) | ||
| Red zone | Yellow band | Blue ribbon | ||
| ????1 | Permanent bordeaux | ????10 | ????/ | ????/ |
| ????2 | Permanent yellow | ????/ | ????10 | ????/ |
| ????3 | Phthalocyanine blue | ????/ | ????/ | ????10 |
| ????4 | Brazil wax | ????45 | ????45 | ????45 |
| ????5 | Montan wax | ????10 | ????10 | ????10 |
| ????6 | Paraffin | ????15 | ????15 | ????15 |
| ????7 | Tissuemat E | ????10 | ????10 | ????10 |
| ????8 | The EVA resin | ????10 | ????10 | ????10 |
| Add up to | ????100 | ????100 | ????100 | |
2, the preparation of coating and coating process
The preparation of 2-1, slurry
According to the ink coating prescription of above-mentioned TTR, the selected adhesive material that comprises wax and resin can be made three types slurry.
First solvent-borne type slurry, the mixed solvent that adopts toluene, ketone, cyclohexane, industrial naptha etc. to form, dissolving wax and synthetic resin then are mixed with printing ink paint;
It two is emulsion-type slurries, adopt the emulsion of wax and resin to prepare printing ink paint, its biggest advantage is to avoid the pollution of organic solvent for environment, and the emulsion of wax and resin can be from market purchasing, or adopts suitable emulsion process that wax or resin material are carried out emulsification in water;
It three is molten slurries, and adhesive materials such as wax and resin are melted under heating, adds colouring agent and auxiliary agent, directly be coated with, the advantage of this method is not need organic solvent, does not also need emulsion process, can avoid environmental pollution, process is easy.
No matter adopt any technology, all will pass through equipment such as ball mill, sand mill, make colouring agent in the solution of adhesive or emulsion or disperse fully in the fused solution, make it to form uniform printing ink slurry, then on coating machine, be coated with.
The coating of 2-2, backing layer and ink coating
In order to improve the heat resistance of plastic sheeting tape base, prevent when printing that plastic sheeting is subjected to thermal softening and bonding thermal printing head will be coated with a refractory layer at the back side of plastic sheeting tape base, as shown in Figure 1, this refractory layer common name backing layer 23.The material that backing layer adopted comprises silicones, polyurethane etc., and coating weight is every square metre of 0.1-1 gram.
When the ink coating of coated heat Transfer ribbon, after printing ink slurry warp is disperseed fully, can be coated with at scraper type, counter-rotating roller coat formula, gravure or extrusion coater.The thickness of ink coating will suitably be controlled, and is advisable to be coated with the 2-5 gram on every square metre of plastic sheeting.When the slurry coating of adopting the preparation of solvent method or emulsion method, after the colour band that coats was dried in 50-100 ℃ oven dry road, rolling also cut into certain width.
The heat transfer colour ribbon that utilizes above-mentioned prescription and preparation printing ink slurry technology to be coated with, can be in 60-80 ℃ temperature range, speed with 50-250 millimeter each second (being equivalent to the 2-10 inch per second) prints, even on general paper, print, bar code of being printed or fax paper, writing and figure are clear, and the resolution ratio height has wear-resistant ability.
Claims (10)
1, a kind of heat transfer colour ribbon, comprise tape base, be coated on the ink coating on described tape base surface and the heat-resisting backing layer at the back side, the material of described ink coating comprises adhesive, colouring agent and auxiliary agent, it is characterized in that, described adhesive comprises wax class and resinae adhesive, in described ink coating, the ratio of described wax class adhesive is that the ratio of 40-80%, described resinae adhesive is that the ratio of 5-35%, described colouring agent is that the ratio of 5-25%, described auxiliary agent is 0.1-10%.
2, heat transfer colour ribbon according to claim 1 is characterized in that, the fusing point of described wax class adhesive is 50-110 ℃; The softening temperature of described resinae adhesive is that 60-130 ℃, solidification temperature are 30-70 ℃.
3, heat transfer colour ribbon according to claim 2 is characterized in that, described wax class adhesive can be selected two or more from native paraffin, animals and plants wax and synthetic wax, and each wax shared ratio in ink coating is 10-50%.
4, heat transfer colour ribbon according to claim 2, it is characterized in that, described resinae adhesive can adopt thermoplasticity synthetic resin, can select one or more from polyethylene, polypropylene, polyvinyl chloride, polyvinyl acetate, polyvinyl alcohol, ethylene-vinyl acetate copolymer, vinyl chloride-vinyl acetate copolymer, vinyl chloride-vinyl acetate-vinyl alcohol terpolymer, epoxy resin, polyamide, polyurethane resin, Petropols, polyketone resin, polystyrene and SBR styrene butadiene rubbers.
5, heat transfer colour ribbon according to claim 1 is characterized in that, described heat-resisting backing layer can be heat-resisting silicones or polyurethane material.
6, according to each described heat transfer colour ribbon among the claim 1-5, it is characterized in that, the plastic sheeting of described tape base for adopting nylon, acetate fiber, polyester, polyamide or polyethylene to make, its thickness is the 3-6 micron.
7, a kind of manufacturing process of heat transfer colour ribbon is characterized in that, may further comprise the steps:
(1), choosing thickness is that the plastic sheeting of 3-6 micron is as tape base;
(2), the ratio of getting is the wax class adhesive of 40-80%, the resinae adhesive of 5-35%, the colouring agent of 5-25% and the auxiliary agent of 0.1-10%, makes the ink coating slurry;
(3), be coated with described ink coating slurry on the surface of tape base, coating weight is every square metre of 2-5 gram;
(4), be coated with heat-resisting backing layer, coating weight is every square metre of 0.1-1 gram at the back side of tape base;
(5), dry and cut into required size.
8, manufacturing process according to claim 7, it is characterized in that, in described step (2), adopt toluene, ketone, cyclohexane and industrial naptha to make mixed solvent, wax class adhesive and resinae adhesive are dissolved in wherein, add colouring agent and auxiliary agent again, be mixed with solvent type ink coating slurry.
9, manufacturing process according to claim 7 is characterized in that, in described step (2), wax class adhesive and resinae adhesive is carried out emulsification, adds colouring agent and auxiliary agent again, is mixed with emulsion-type printing ink coating slurry.
10, manufacturing process according to claim 7 is characterized in that, in described step (2), wax class adhesive and the heating of resinae adhesive is melted, and adds colouring agent and auxiliary agent again, is mixed with molten printing ink paint slurry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02115333 CN1206112C (en) | 2002-05-30 | 2002-05-30 | Thermal transfer printing ribbon, and its prodn, art |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02115333 CN1206112C (en) | 2002-05-30 | 2002-05-30 | Thermal transfer printing ribbon, and its prodn, art |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1461704A true CN1461704A (en) | 2003-12-17 |
| CN1206112C CN1206112C (en) | 2005-06-15 |
Family
ID=29742346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02115333 Expired - Fee Related CN1206112C (en) | 2002-05-30 | 2002-05-30 | Thermal transfer printing ribbon, and its prodn, art |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1206112C (en) |
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100425456C (en) * | 2006-09-29 | 2008-10-15 | 上海凯兰达实业有限公司 | Adhesive for electrochemical aluminum paint and its preapring method |
| CN101318421B (en) * | 2007-06-08 | 2010-07-14 | 焦作市卓立烫印材料有限公司 | Leather mark ribbon |
| CN101837690A (en) * | 2010-05-31 | 2010-09-22 | 焦作市卓立烫印材料有限公司 | Mixed base bar code printing thermal transfer ribbon and preparation method thereof |
| CN101850671A (en) * | 2010-05-31 | 2010-10-06 | 杭州天地数码科技有限公司 | Mixed base thermal transfer ink ribbon coated by hot melting and production method thereof |
| CN101612843B (en) * | 2009-07-23 | 2011-06-22 | 焦作市卓立烫印材料有限公司 | Sublimation banner thermal transfer ribbons (TTR) and preparation method thereof |
| CN102189852A (en) * | 2011-04-02 | 2011-09-21 | 泉州市山水电脑耗材有限公司 | Multi-layer thermal transfer ribbon and manufacturing method thereof |
| CN102211478A (en) * | 2011-04-02 | 2011-10-12 | 泉州市山水电脑耗材有限公司 | Thermal transfer wax ribbon |
| CN102303459A (en) * | 2011-07-26 | 2012-01-04 | 大连富士山办公设备有限公司 | High-resolution thermal transfer colored tape |
| CN102642414A (en) * | 2012-04-25 | 2012-08-22 | 焦作卓林数码材料有限公司 | Sublimable thermal transfer ink ribbon and preparation method thereof |
| CN104057733A (en) * | 2014-06-28 | 2014-09-24 | 周永生 | Full-resin thermal transfer printing ribbon suitable for various print substrates |
| CN104589814A (en) * | 2013-10-30 | 2015-05-06 | 诚研科技股份有限公司 | Ink ribbon and photo printing method |
| CN104802540A (en) * | 2015-05-12 | 2015-07-29 | 卢成林 | Digital printing color tape for light-color natural fiber textiles as well as preparation method and application of digital printing color tape |
| CN105172409A (en) * | 2015-08-27 | 2015-12-23 | 鹏码实业(上海)有限公司 | Preparation method for compounded thermal transfer ribbon |
| CN106085000A (en) * | 2016-07-11 | 2016-11-09 | 鹏码实业(上海)有限公司 | A kind of heat transfer colour ribbon of high-fire resistance and preparation method thereof |
| CN106519798A (en) * | 2016-09-28 | 2017-03-22 | 苏州吉谷新材料有限公司 | Heat sublimation transfer printing ink and preparation method thereof |
| CN106566312A (en) * | 2016-11-04 | 2017-04-19 | 苏州吉谷新材料有限公司 | Anticorrosion and sterilization sublimation ink |
| CN110143068A (en) * | 2019-05-23 | 2019-08-20 | 广东可得智能科技有限公司 | A kind of printer colour band production technology |
| CN110356129A (en) * | 2019-06-18 | 2019-10-22 | 鹏码实业(上海)有限公司 | A kind of heat transfer colour ribbon and preparation method thereof |
| CN111154332A (en) * | 2020-01-22 | 2020-05-15 | 江西服装学院 | Printing ink and preparation method thereof |
| CN111499909A (en) * | 2020-05-29 | 2020-08-07 | 曲阜市玉樵夫科技有限公司 | Low-temperature-resistant high-firmness banner color band |
| CN111497474A (en) * | 2020-04-21 | 2020-08-07 | 福建鸣友新材料科技有限公司 | Special thermal transfer ribbon for portable printer and preparation method thereof |
| CN111662592A (en) * | 2020-07-16 | 2020-09-15 | 焦作卓立膜材料有限责任公司 | Antistatic flame-retardant thermal transfer printing ink for carbon ribbon and preparation method thereof |
| CN111748118A (en) * | 2020-07-22 | 2020-10-09 | 曲阜市玉樵夫科技有限公司 | Resin-based colored tape |
| US11442393B2 (en) | 2018-10-03 | 2022-09-13 | Hewlett-Packard Development Company, L.P. | Heat transfer printing |
| CN116515153A (en) * | 2023-05-15 | 2023-08-01 | 河南东方印新材料科技有限公司 | A banner color ribbon product without a primer and a production process thereof |
-
2002
- 2002-05-30 CN CN 02115333 patent/CN1206112C/en not_active Expired - Fee Related
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100425456C (en) * | 2006-09-29 | 2008-10-15 | 上海凯兰达实业有限公司 | Adhesive for electrochemical aluminum paint and its preapring method |
| CN101318421B (en) * | 2007-06-08 | 2010-07-14 | 焦作市卓立烫印材料有限公司 | Leather mark ribbon |
| CN101612843B (en) * | 2009-07-23 | 2011-06-22 | 焦作市卓立烫印材料有限公司 | Sublimation banner thermal transfer ribbons (TTR) and preparation method thereof |
| CN101850671B (en) * | 2010-05-31 | 2011-09-28 | 杭州天地数码科技有限公司 | Mixed base thermal transfer ink ribbon coated by hot melting and production method thereof |
| CN101850671A (en) * | 2010-05-31 | 2010-10-06 | 杭州天地数码科技有限公司 | Mixed base thermal transfer ink ribbon coated by hot melting and production method thereof |
| CN101837690A (en) * | 2010-05-31 | 2010-09-22 | 焦作市卓立烫印材料有限公司 | Mixed base bar code printing thermal transfer ribbon and preparation method thereof |
| CN101837690B (en) * | 2010-05-31 | 2012-08-29 | 焦作市卓立烫印材料有限公司 | Mixed base bar code printing thermal transfer ribbon and preparation method thereof |
| CN102189852A (en) * | 2011-04-02 | 2011-09-21 | 泉州市山水电脑耗材有限公司 | Multi-layer thermal transfer ribbon and manufacturing method thereof |
| CN102211478A (en) * | 2011-04-02 | 2011-10-12 | 泉州市山水电脑耗材有限公司 | Thermal transfer wax ribbon |
| CN102303459A (en) * | 2011-07-26 | 2012-01-04 | 大连富士山办公设备有限公司 | High-resolution thermal transfer colored tape |
| CN102303459B (en) * | 2011-07-26 | 2013-11-06 | 大连富士山办公设备有限公司 | High-resolution thermal transfer colored tape |
| CN102642414A (en) * | 2012-04-25 | 2012-08-22 | 焦作卓林数码材料有限公司 | Sublimable thermal transfer ink ribbon and preparation method thereof |
| CN104589814A (en) * | 2013-10-30 | 2015-05-06 | 诚研科技股份有限公司 | Ink ribbon and photo printing method |
| CN104057733A (en) * | 2014-06-28 | 2014-09-24 | 周永生 | Full-resin thermal transfer printing ribbon suitable for various print substrates |
| CN104802540A (en) * | 2015-05-12 | 2015-07-29 | 卢成林 | Digital printing color tape for light-color natural fiber textiles as well as preparation method and application of digital printing color tape |
| CN104802540B (en) * | 2015-05-12 | 2018-04-10 | 卢成林 | Light natural fiber textile digital printing colour band and preparation method and application |
| CN105172409A (en) * | 2015-08-27 | 2015-12-23 | 鹏码实业(上海)有限公司 | Preparation method for compounded thermal transfer ribbon |
| CN106085000A (en) * | 2016-07-11 | 2016-11-09 | 鹏码实业(上海)有限公司 | A kind of heat transfer colour ribbon of high-fire resistance and preparation method thereof |
| CN106519798A (en) * | 2016-09-28 | 2017-03-22 | 苏州吉谷新材料有限公司 | Heat sublimation transfer printing ink and preparation method thereof |
| CN106566312A (en) * | 2016-11-04 | 2017-04-19 | 苏州吉谷新材料有限公司 | Anticorrosion and sterilization sublimation ink |
| US11442393B2 (en) | 2018-10-03 | 2022-09-13 | Hewlett-Packard Development Company, L.P. | Heat transfer printing |
| CN110143068A (en) * | 2019-05-23 | 2019-08-20 | 广东可得智能科技有限公司 | A kind of printer colour band production technology |
| CN110356129A (en) * | 2019-06-18 | 2019-10-22 | 鹏码实业(上海)有限公司 | A kind of heat transfer colour ribbon and preparation method thereof |
| CN111154332A (en) * | 2020-01-22 | 2020-05-15 | 江西服装学院 | Printing ink and preparation method thereof |
| CN111497474A (en) * | 2020-04-21 | 2020-08-07 | 福建鸣友新材料科技有限公司 | Special thermal transfer ribbon for portable printer and preparation method thereof |
| CN111499909A (en) * | 2020-05-29 | 2020-08-07 | 曲阜市玉樵夫科技有限公司 | Low-temperature-resistant high-firmness banner color band |
| CN111662592A (en) * | 2020-07-16 | 2020-09-15 | 焦作卓立膜材料有限责任公司 | Antistatic flame-retardant thermal transfer printing ink for carbon ribbon and preparation method thereof |
| CN111748118A (en) * | 2020-07-22 | 2020-10-09 | 曲阜市玉樵夫科技有限公司 | Resin-based colored tape |
| CN116515153A (en) * | 2023-05-15 | 2023-08-01 | 河南东方印新材料科技有限公司 | A banner color ribbon product without a primer and a production process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1206112C (en) | 2005-06-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1206112C (en) | Thermal transfer printing ribbon, and its prodn, art | |
| CN101850671B (en) | Mixed base thermal transfer ink ribbon coated by hot melting and production method thereof | |
| JPH0420797B2 (en) | ||
| CN1224385A (en) | Image receptor medium | |
| US4938617A (en) | Thermal transfer ribbon with adhesion layer | |
| JPS63222892A (en) | Thermal transfer material | |
| CN115447304A (en) | Resin thermal transfer ribbon for thermal transfer printing and preparation method thereof | |
| DE60016861T2 (en) | Thermal image transfer recording material, image forming method and image carrier | |
| US5827617A (en) | Thermo-transfer ribbon | |
| JP2722466B2 (en) | Thermal transfer recording material | |
| CN1323851C (en) | Thermo-sensitive recording medium and printed object | |
| JPH0436941Y2 (en) | ||
| JP3555621B2 (en) | Image forming method | |
| JP2001322360A (en) | Melt type thermal transfer ink ribbon, printed product and printer | |
| JPH09267570A (en) | Heat transfer sheet | |
| JPS6248591A (en) | Ink ribbon for thermal fusion transfer | |
| JPS6270088A (en) | Thermal transfer ink | |
| CN117227343A (en) | Heat transfer printing sheet for friction-resistant high-resolution color patterns and preparation method thereof | |
| JP6884554B2 (en) | Thermal transfer medium | |
| US6846527B2 (en) | Thermal transfer recording media | |
| JP2971556B2 (en) | Thermal transfer ink ribbon | |
| JP2001219654A (en) | Thermal transfer recording medium and image forming method | |
| JP2001096922A (en) | Thermal transfer recording medium, image receiving sheet and image forming method using them | |
| CN115610132A (en) | Friction-resistant thermal transfer printing sheet capable of transferring high-resolution patterns and preparation method thereof | |
| WO1993001058A1 (en) | Thermal transfer ink sheet for forming color image |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050615 |