CN112080173A - High-temperature-resistant inorganic inkjet ink and application thereof - Google Patents
High-temperature-resistant inorganic inkjet ink and application thereof Download PDFInfo
- Publication number
- CN112080173A CN112080173A CN202010967771.3A CN202010967771A CN112080173A CN 112080173 A CN112080173 A CN 112080173A CN 202010967771 A CN202010967771 A CN 202010967771A CN 112080173 A CN112080173 A CN 112080173A
- Authority
- CN
- China
- Prior art keywords
- temperature
- ink
- inorganic
- color paste
- resistant inorganic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0011—Pre-treatment or treatment during printing of the recording material, e.g. heating, irradiating
- B41M5/0017—Application of ink-fixing material, e.g. mordant, precipitating agent, on the substrate prior to printing, e.g. by ink-jet printing, coating or spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0023—Digital printing methods characterised by the inks used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/0047—Digital printing on surfaces other than ordinary paper by ink-jet printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Thermal Sciences (AREA)
- Toxicology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention provides high-temperature-resistant inorganic ink-jet ink which is prepared by mixing high-temperature inorganic color paste, an ink solvent, organic silicon resin and a surface leveling agent, wherein the high-temperature inorganic color paste is prepared by mixing inorganic toner, a dispersing agent, a color paste solvent and an auxiliary agent. The invention provides high-temperature-resistant inorganic ink-jet ink, a preparation method and an application method thereof, so that when patterns are printed on the surface of a high-temperature-resistant product, an ink-jet process can be adopted, the traditional process is abandoned, the production of complex patterns becomes possible, and the added value of the product is increased for manufacturers.
Description
Technical Field
The invention relates to the technical field of chemical pigments, in particular to high-temperature (300 ℃) resistant inorganic ink-jet ink and application thereof, wherein the inorganic ink-jet ink is applied to printing on products or product packages of industries needing high temperature resistance, such as small household appliances, building materials and the like by adopting a spraying process, and comprises the following steps: kitchen utensils, irons, hair clips, and the like.
Background
In the prior art, patterns on products or product packages in industries requiring high temperature resistance, such as small household appliances, building materials and the like, are usually printed by screen printing, gravure printing or embossing. In any case, the process is complex, the printing of a plurality of patterns is required, the requirements on equipment and operators are very high, the realization is difficult, and the quality stability of the printed patterns is difficult to ensure.
Therefore, it is very costly to produce complicated color patterns on products requiring high temperature resistance, or it is difficult to mass-produce them, and it is impossible to industrialize them, and it is only possible to print some simple patterns by the screen printing process.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention aims to provide a novel high-temperature-resistant printing method and material, which can ensure that the color of a printed pattern is not changed in a high-temperature environment of 300 ℃, and the printed pattern has no toxic or harmful volatilization in the high-temperature environment of 300 ℃.
In order to solve the problems, the technical scheme adopted by the invention is as follows:
the high-temperature-resistant inorganic ink-jet ink is formed by mixing high-temperature inorganic color paste, an ink solvent, organic silicon resin and a surface leveling agent, wherein the high-temperature inorganic color paste is formed by mixing an inorganic toner, a dispersing agent, a color paste solvent and an auxiliary agent.
Preferably, the high-temperature inorganic color paste is prepared by the following method:
mixing the inorganic toner, the dispersant and the color paste solvent, and uniformly dispersing to form a high-temperature inorganic color paste raw material mixture;
firstly, stirring the high-temperature inorganic color paste raw material mixture for 1 hour by using an emulsifying machine to form emulsion, and then putting the emulsion into a nano sand mill for grinding, thereby converting the emulsion into uniformly and stably dispersed color paste, so that the inorganic color powder is in a stable suspension state in the color paste, and the stable period exceeds 6 months;
the emulsifying machine is a vertical emulsifying machine, and the stirring speed during emulsification is 900 revolutions per minute; the nano grinder is a horizontal sand grinder, zirconium beads with the diameter of 0.3-0.6mm are adopted, and the filling amount of the zirconium beads is 3-4 kg; the zirconium beads are ground for 6 to 12 hours at the rotating speed of 2550 revolutions, the average particle size of inorganic toner particles in the color paste after grinding is less than 200nm, and the viscosity of the high-temperature inorganic color paste is between 5 and 30 centipoises.
Preferably, in the high-temperature inorganic color paste, the content of the inorganic color powder is 20-50% by mass.
Preferably, the inorganic toner comprises titanium chromium brown, iron oxide red, cobalt blue and copper complex black which are mixed according to a required proportion; the dispersant is a polymer dispersant of polyester; the color paste solvent is one or a mixture of several of diethylene glycol diethyl ether, diethylene glycol methyl ethyl ether, n-propanol, isopropanol, alcohol, NME, diethylene glycol butyl ether and ethylene glycol.
Preferably, the dispersant is a polymeric dispersant of a polyester.
Preferably, the color paste solvent is one or a mixture of two of diethylene glycol diethyl ether and diethylene glycol methyl ethyl ether.
Preferably, in the high-temperature-resistant inorganic ink-jet ink, the mass percentage of the high-temperature-resistant inorganic color paste is 20-40%.
Preferably, the ink solvent is one or more of diethylene glycol diethyl ether, diethylene glycol methyl ethyl ether, isopropanol and n-propanol.
Preferably, the surface leveling agent is one or a mixture of BYK-3500, BYK-377 and EFKA-3034.
The pattern printed by the high-temperature-resistant inorganic ink-jet ink comprises: the high-temperature-resistant inorganic ink-jet printing ink is uniformly coated on a priming paint layer on the surface of a high-temperature-resistant material, is used for ink-jet ink pattern layer formed on the surface of the priming paint layer by ink-jet printing of the high-temperature-resistant inorganic ink-jet ink, and is uniformly coated on a transparent finish paint layer on the surface of the ink pattern.
The thickness of the primer layer is 10-15 microns, so that a pattern can be fixed on the surface of the high-temperature resistant material, and the pattern is generally transparent and white; the film thickness of the dried ink-jet ink pattern layer is controlled to be below 5-10 microns, and obvious convex-concave feeling cannot be generated; the thickness of the transparent finish paint layer is 5-10 microns, the protection of the surface of the pattern is increased, and the total thickness of the primer layer, the ink-jet ink pattern layer and the transparent finish paint layer is 20-30 microns.
The method for ink-jet printing by adopting the high-temperature-resistant inorganic ink-jet ink comprises the following steps:
spraying white paint or transparent varnish: baking at 70-80 deg.C for 5-10 min;
digital jet printing of high-temperature inorganic ink: baking at 70-80 deg.C for 5 min;
spraying gloss oil: baking at 70-80 deg.C for 6 min, and drying;
then the product enters a tunnel furnace at 260 ℃ and 280 ℃ for 10 minutes to finish the final shaping of the product.
Compared with the prior art, the invention has the beneficial effects that:
the invention emulsifies and grinds the color paste raw material mixture, so that the inorganic toner is ground into particles with the particle size of below 200 nanometers, the color paste is uniformly dispersed, the inorganic toner in the color paste is in a stable suspension state, and the stabilization period at least exceeds 6 months. Because the ink has good uniformity and high stability, when patterns are printed on the surface of a high-temperature resistant product, an ink-jet process can be adopted, the traditional high-cost process is abandoned, the production of complex patterns becomes possible, and the added value of the product is increased for manufacturers.
Drawings
FIG. 1 is a schematic cross-sectional view of a pattern according to an embodiment of the present invention,
fig. 2 is an ink-jet printed pattern on an aluminum plate in an embodiment of the present invention.
Detailed Description
The principles and features of this invention are described below in conjunction with examples which are set forth to illustrate, but are not to be construed to limit the scope of the invention.
The embodiment provides a high-temperature-resistant inorganic inkjet ink which is formed by mixing high-temperature inorganic color paste, an ink solvent, organic silicon resin and a surface leveling agent, wherein the high-temperature inorganic color paste is formed by mixing an inorganic toner, a dispersing agent and a color paste solvent. The high-temperature inorganic color paste is prepared from 20-40% by mass of an ink solvent which is one or a mixture of diethylene glycol diethyl ether, diethylene glycol methyl ethyl ether, isopropanol and n-propanol, and the surface leveling agent is one or a mixture of BYK-346, BYK-348, BYK-350, BYK-377 and EFKA-3034.
The core of the invention is the preparation of the high-temperature inorganic color paste. The preparation process of the high-temperature inorganic color paste comprises the following steps:
mixing the inorganic toner, the dispersant and the color paste solvent, and uniformly dispersing to form a high-temperature inorganic color paste raw material mixture;
firstly, stirring the high-temperature inorganic color paste raw material mixture for 1 hour by using an emulsifying machine to form emulsion, and then putting the emulsion into a nano sand mill for grinding, thereby converting the emulsion into uniformly and stably dispersed color paste, so that the inorganic color powder is in a stable suspension state in the color paste, and the stable period exceeds 6 months;
the emulsifying machine is a vertical emulsifying machine, and the stirring speed during emulsification is 900 revolutions per minute; the nano grinder is a horizontal sand grinder, zirconium beads with the diameter of 0.3-0.6mm are adopted, and the filling amount of the zirconium beads is 3-4 kg; the zirconium beads are ground for 6 to 12 hours at the rotating speed of 2550 revolutions, the average particle size of inorganic toner particles in the color paste after grinding is less than 200nm, and the viscosity of the high-temperature inorganic color paste is between 5 and 30 centipoises.
Wherein the inorganic toner is 20-50% by mass. The inorganic toner is prepared by mixing titanium chromium brown, iron oxide red, cobalt blue and copper complex black according to a proportion determined by the color to be presented. Namely: the color is different by mixing the four colors of the titanium chromium brown, the iron oxide red, the cobalt blue and the copper complex black according to the proportion. The dispersant is a polymeric dispersant for polyester. The color paste solvent is one or a mixture of two of diethylene glycol diethyl ether and diethylene glycol methyl ethyl ether.
The application method of the high-temperature-resistant inorganic ink-jet ink is to prepare a pattern through ink-jet printing. As shown in fig. 1, the prepared pattern includes: the high-temperature-resistant inorganic ink-jet printing ink comprises a priming paint layer 2 uniformly coated on the surface of a high-temperature-resistant material 1, an ink-jet ink pattern layer 3 formed on the surface of the priming paint layer by adopting the high-temperature-resistant inorganic ink-jet ink and a transparent finish paint layer 4 uniformly coated on the surface of the ink pattern. The thickness of the primer layer 2 is 10-15 microns, so that a pattern can be fixed on the surface of the high-temperature resistant material 1, and the pattern is generally transparent and white; the film thickness of the dried ink-jet ink pattern layer 3 is controlled to be below 5-10 microns, and obvious convex-concave feeling cannot be generated; the thickness of the transparent finish paint layer 4 is 5-10 microns, the protection of the surface of the pattern is increased, and the total thickness of the primer layer 2, the ink-jet ink pattern layer 3 and the transparent finish paint layer 4 is 20-30 microns.
The preparation method of the pattern comprises the following steps:
1. spraying white paint: baking at 70-80 deg.C for 5-10 min;
2. digital jet printing of high-temperature inorganic ink: baking at 70-80 deg.C for 5 min;
3. spraying gloss oil: baking at 70-80 deg.C for 6 min, and drying;
4. then the product enters a tunnel furnace at 260 ℃ and 280 ℃ for 10 minutes to finish the final shaping of the product.
The patterns prepared in this example were subjected to performance testing, which required the following criteria:
1. the glossiness is 40-60/45 degrees;
2. the film thickness of the finished product is 20-30 microns;
3. the wear resistance is different according to different industries, generally, under the condition of 200 ℃ temperature, 880 load bearing is carried out, and the test is more than 2000 times;
4. the hundred-grid 3m adhesive tape is completely free from fading;
5. and in butanone test, 880g of load is repeated for 100 times without fading and dropping.
The pattern prepared in this example was tested to meet the above criteria. Specifically, the high-temperature-resistant inorganic inkjet ink has the viscosity of 3-20cp and the tension of 20-40, is tried on inkjet printing heads such as epson, konica, seiko, Ricoh, Xaar, Kyocera, toshiba and the like, and inkjet printed patterns do not change color at the temperature of 300 ℃ for 1 hour, and have no toxic and harmful gas emission and no pungent odor. The color decay is required to be no more than 20% in 5 years outdoors.
In addition, as shown in fig. 2, the pattern printed by the high temperature resistant inorganic inkjet ink of the present embodiment by using the inkjet printing method on the surface of the aluminum plate is unchanged in color when 1 hour is in a high temperature environment of 270 ℃.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like made within the spirit and principle of the present invention should be included in the scope of the present invention.
Claims (10)
1. The high-temperature-resistant inorganic ink-jet ink is characterized by being prepared by mixing high-temperature inorganic color paste, an ink solvent, organic silicon resin and a surface leveling agent, wherein the high-temperature inorganic color paste is prepared by mixing an inorganic toner, a dispersing agent, a color paste solvent and an auxiliary agent.
2. The high-temperature-resistant inorganic inkjet ink according to claim 1, wherein the high-temperature-resistant inorganic color paste is prepared by the following method:
mixing the inorganic toner, the dispersant and the color paste solvent, and uniformly dispersing to form a high-temperature inorganic color paste raw material mixture;
firstly, stirring the high-temperature inorganic color paste raw material mixture for 1 hour by using an emulsifying machine to form emulsion, and then putting the emulsion into a nano sand mill for grinding, thereby converting the emulsion into uniformly and stably dispersed color paste, so that the inorganic color powder is in a stable suspension state in the color paste, and the stable period exceeds 6 months;
the emulsifying machine is a vertical emulsifying machine, and the stirring speed during emulsification is 900 revolutions per minute; the nano grinder is a horizontal sand grinder, zirconium beads with the diameter of 0.3-0.6mm are adopted, and the filling amount of the zirconium beads is 3-4 kg; the zirconium beads are ground for 6 to 12 hours at the rotating speed of 2550 revolutions, the average particle size of inorganic toner particles in the color paste after grinding is less than 200nm, and the viscosity of the high-temperature inorganic color paste is between 5 and 30 centipoises.
3. The high-temperature-resistant inorganic inkjet ink according to claim 2, wherein the inorganic toner is contained in the high-temperature inorganic color paste in an amount of 20 to 50% by mass.
4. The high temperature resistant inorganic inkjet ink according to claim 3, wherein the inorganic toner comprises chrome brown, red iron oxide, cobalt blue and copper complex black mixed in a desired ratio; the dispersant is a polymer dispersant of polyester; the color paste solvent is one or a mixture of several of diethylene glycol diethyl ether, diethylene glycol methyl ethyl ether, n-propanol, isopropanol, alcohol, NME, diethylene glycol butyl ether and ethylene glycol.
5. The high-temperature-resistant inorganic inkjet ink according to claim 1, wherein the high-temperature-resistant inorganic inkjet ink contains 20 to 40 mass% of the high-temperature-resistant inorganic color paste.
6. The high temperature resistant inorganic inkjet ink according to claim 1, wherein the ink solvent is one or more of diethylene glycol diethyl ether, diethylene glycol methyl ethyl ether, isopropyl alcohol, and n-propyl alcohol.
7. The high temperature resistant inorganic inkjet ink according to claim 1, wherein the surface leveling agent is one or more of BYK-3500, BYK-377, and EFKA-3034.
8. A design printed with the high temperature resistant inorganic ink jet ink of any one of claims 1 to 7, comprising: the high-temperature-resistant inorganic ink-jet printing ink is uniformly coated on a priming paint layer on the surface of a high-temperature-resistant material, is used for ink-jet ink pattern layer formed on the surface of the priming paint layer by ink-jet printing of the high-temperature-resistant inorganic ink-jet ink, and is uniformly coated on a transparent finish paint layer on the surface of the ink pattern.
9. The pattern of claim 8, wherein the primer layer has a thickness of 10-15 μm, and is capable of fixing the pattern on the surface of the refractory material, and has a transparent color and a white color; the film thickness of the dried ink-jet ink pattern layer is controlled to be below 5-10 microns, and obvious convex-concave feeling cannot be generated; the thickness of the transparent finish paint layer is 5-10 microns, the protection of the surface of the pattern is increased, and the total thickness of the primer layer, the ink-jet ink pattern layer and the transparent finish paint layer is 20-30 microns.
10. A method for preparing a pattern according to claim 8 or 9, comprising the steps of:
spraying white paint or transparent varnish: baking at 70-80 deg.C for 5-10 min;
digital jet printing of high-temperature inorganic ink: baking at 70-80 deg.C for 5 min;
spraying gloss oil: baking at 70-80 deg.C for 6 min, and drying;
then the product enters a tunnel furnace at 260 ℃ and 280 ℃ for 10 minutes to finish the final shaping of the product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010967771.3A CN112080173A (en) | 2020-09-15 | 2020-09-15 | High-temperature-resistant inorganic inkjet ink and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010967771.3A CN112080173A (en) | 2020-09-15 | 2020-09-15 | High-temperature-resistant inorganic inkjet ink and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112080173A true CN112080173A (en) | 2020-12-15 |
Family
ID=73737153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010967771.3A Pending CN112080173A (en) | 2020-09-15 | 2020-09-15 | High-temperature-resistant inorganic inkjet ink and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112080173A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113637356A (en) * | 2021-08-06 | 2021-11-12 | 佛山市迈瑞思科技有限公司 | Ink-jet printing ink for aluminum plate and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1616241A (en) * | 2004-12-06 | 2005-05-18 | 王宇明 | Metal printing plate and its producing method |
| CN101063014A (en) * | 2006-04-28 | 2007-10-31 | 中国科学院化学研究所 | Abrasion resistant ink used for ink-ejecting direct plate-making technology and preparation method thereof |
| CN101891984A (en) * | 2010-03-04 | 2010-11-24 | 珠海保税区天然宝杰数码科技材料有限公司 | Printing ink combination, printing ink and method for forming image on ceramic surface |
| CN105086617A (en) * | 2015-08-04 | 2015-11-25 | 山东布瑞特油墨有限公司 | Water-based inner printing ink coated with PE and PP and preparation method thereof |
-
2020
- 2020-09-15 CN CN202010967771.3A patent/CN112080173A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1616241A (en) * | 2004-12-06 | 2005-05-18 | 王宇明 | Metal printing plate and its producing method |
| CN101063014A (en) * | 2006-04-28 | 2007-10-31 | 中国科学院化学研究所 | Abrasion resistant ink used for ink-ejecting direct plate-making technology and preparation method thereof |
| CN101891984A (en) * | 2010-03-04 | 2010-11-24 | 珠海保税区天然宝杰数码科技材料有限公司 | Printing ink combination, printing ink and method for forming image on ceramic surface |
| CN105086617A (en) * | 2015-08-04 | 2015-11-25 | 山东布瑞特油墨有限公司 | Water-based inner printing ink coated with PE and PP and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张齐生等: "《胶合板生产技术问答》", 31 October 1981, 林业部林产工业设计研究院 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113637356A (en) * | 2021-08-06 | 2021-11-12 | 佛山市迈瑞思科技有限公司 | Ink-jet printing ink for aluminum plate and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103911024B (en) | Glass pigment micro powder, dispersion liquid, ink-jet ink and forming method thereof | |
| CN109651883B (en) | Black ceramic ink and preparation method thereof | |
| CN106833113B (en) | Ink suitable for glass hot bending forming and application of ink in mobile phone | |
| CN107033672B (en) | High-temperature-resistant ceramic bright red ink and preparation method thereof | |
| CN105482513A (en) | Method for modification and dispersion of glass powder and pigment for ink and high-temperature-resistant ink | |
| CN109337439A (en) | A kind of environment-friendly type high chroma art ink and preparation method thereof | |
| CN105504981A (en) | Water-based ink for intaglio printing process of aluminum foil and preparation method of water-based ink | |
| CN109852142B (en) | Preparation method of coating ink for small-particle-size ceramic ink-jet printing | |
| CN110804340A (en) | Single-component silk-screen printing ink for treatment-free PET (polyethylene terephthalate) material | |
| CN112080173A (en) | High-temperature-resistant inorganic inkjet ink and application thereof | |
| CN105038393A (en) | High-temperature-resistant ink and preparation method thereof | |
| CN108560267B (en) | Aqueous temperature-sensitive color-changing printing treating agent for synthetic leather and preparation method and application thereof | |
| CN106147401A (en) | A kind of preparation method of heat-sensitive colour-changing ink | |
| CN101320229B (en) | Colorful ink powder and preparation method thereof | |
| CN112048212B (en) | Preparation method of resin-based carbon ribbon printing ink | |
| CN112011217A (en) | High-concentration water-based preprinting ink and preparation method thereof | |
| CN103952033B (en) | A kind of general ink and preparation method thereof and using method | |
| CN108300230A (en) | One kind is for substituting mute film water environmental friendly materials of PET and preparation method thereof | |
| CN107163684A (en) | A kind of ceramic white ink and preparation method thereof | |
| CN111205698A (en) | High-temperature sintering type glass printing ink and preparation method thereof | |
| CN110305485A (en) | A kind of digital printing silica gel and preparation method thereof | |
| CN106905768A (en) | A kind of oiliness ceramics digital jet ink and preparation method thereof | |
| CN110922808A (en) | Modified permanent yellow pigment and preparation method and application thereof | |
| CN110804338A (en) | Blue pigment for water-based ink and preparation method thereof | |
| CN110041753A (en) | A kind of gravure water-based ink of the printing of the fine definition on aluminium paper |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20201215 |
|
| RJ01 | Rejection of invention patent application after publication |