CN106905768A - A kind of oiliness ceramics digital jet ink and preparation method thereof - Google Patents
A kind of oiliness ceramics digital jet ink and preparation method thereof Download PDFInfo
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- CN106905768A CN106905768A CN201710253637.5A CN201710253637A CN106905768A CN 106905768 A CN106905768 A CN 106905768A CN 201710253637 A CN201710253637 A CN 201710253637A CN 106905768 A CN106905768 A CN 106905768A
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- oiliness
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/322—Pigment inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention provides a kind of oiliness ceramics digital jet ink and preparation method thereof, to overcome the defect existing for existing oiliness ceramics digital jet ink.To achieve the above object, the present invention is that, with hydro carbons mixed solvent, fatty acid ester solvent, ethers defoamer, amine inorganic material lubricant, coupling agent, hyper-dispersant, anti-settling agent, levelling agent, pigment is mixed for component.The present invention has low production cost, reduction production consumption；Simple production process, color is presented stabilization；Stable performance, sol solutionses are stable in properties, the advantages of storage when long without precipitation.
Description
Technical field
The present invention relates to a kind of ceramic digital jet ink, more particularly to a kind of oiliness ceramics digital jet ink and its system
Preparation Method.
Background technology
The scope that ceramic ink jet printing technology is applied is more and more wider, and the development of ceramic ink is also carried out rapidly.Pottery
Porcelain inkjet technology is that ceramic ink is directly printed into glaze paint or ceramic idiosome by printer to carry out incrustation
A kind of method, it has many advantages, such as compared with former ceramic surface decoration technique, its good decorating effect can
To realize the individual character manufacturing of product and design, the advantages of be also suitable for the batch production of high efficiency and time conservation.
Surfactant, ceramic powder (colorant, colouring agent), bonding agent, solvent, dispersant and other auxiliary materials are to constitute
The important component of ceramic jet ink.There is no strong agglomerate to have between the particle for making the ceramic jet ink of synthesis fine
Stability it is narrow it is necessary to ensure the particle size distribution of ink, his grain graininess is less than 1 nanometer.By solvent etc. its
The influence of its material is small：In order that each performance such as the viscosity of ceramic jet ink, surface tension is not easy changing with temperature
Become and change, require to control the dry time during experiment, the carrier on acceptor is received solvent from beating
The ceramic powders sprayed on print machine, and be attached to ceramic powders are stable and firm on the carrier of acceptor.
The oiliness ceramics digital jet ink for producing on the market at present has costly, preparation technology more complicated, most
It is important that the macroscopic property of the ink of synthesis is relatively unstable, it is impossible to enough to deposit for a long time, and the colour generation of colouring agent is imitated
It is really poor, the low shortcoming of solid content.
The content of the invention
It is an object of the invention to provide a kind of oiliness ceramics digital jet ink and preparation method thereof, to overcome existing oiliness
Defect existing for ceramic digital jet ink.
To achieve the above object, the present invention is the fatty acid ester solvent with hydro carbons mixed solvent, ethers defoamer, amine without
Machine material lubricant, coupling agent, hyper-dispersant, anti-settling agent, levelling agent, pigment each component is mixed, and each component weight portion is：
7 parts -16 parts of hydro carbons mixed solvent
1 part -7 parts of fatty acid ester solvent
0.01 part -0.03 part of ethers defoamer
0.2 part of amine inorganic material lubricant
0.1 part -0.2 part of coupling agent
0.5 part -3 parts of hyper-dispersant
0.1 part -0.2 part of anti-settling agent
0.01 part -0.05 part of levelling agent
8 parts -12 parts of pigment
By hydro carbons mixed solvent, fatty acid ester solvent, ethers defoamer, amine inorganic material lubricant, coupling agent is ultra-dispersed
Agent, anti-settling agent, levelling agent, pigment composition is mixed evenly with 2000 turns of sand mill grinding 5 hours to granularity 100- in proportion
200nm or so, tests its viscosity and surface tension, and each parameter reaches following standard：Granularity is 100-200nm, and surface tension is
30-40mN/m, viscosity is 20-30cps, Gu containing being 30%, high temperature resistant is 1300-1500 DEG C, and stability is tested for heat（60℃）
72h is without layering and precipitates, and obtains final product the aqueous ceramic digital jet ink.Wherein, pigment is cobalt blue dye, reddish brown pigment, praseodymium yellow
Pigment any one；
Hydro carbons mixed solvent is that alkanes or 12 carbon linear alkene classes any one and aromatic hydrocarbons miscible agent is mixed；Ethers disappears
Infusion is any one in alkylbenzene ethers defoamer, polyethers defoamer, poly alkyl ether class defoamer；Amine inorganic material
Lubricant be acrylic amide inorganic material lubricant or erucyl amide class inorganic material lubricant any one.
The present invention has following distinguishing feature：
(1) the oiliness ceramics digital jet ink, low production cost, reduction production consumption are invented；
(2) the oiliness ceramics digital jet ink simple production process is invented, color is presented stabilization；
(3) the oiliness ceramics digital jet ink stable performance is invented, sol solutionses are stable in properties, and storage is without precipitation when long.
Specific embodiment：
With specific embodiment, the present invention is further illustrated below, but the present invention is not limited by following embodiments.
Embodiment 1：
A kind of oiliness ceramics digital jet ink, it is made up of the raw material of following weight portion：7 parts of alkanes mixed solvent, aromatic hydrocarbons
3 parts of class mixed solvent, 1 part of fatty acid ester solvent, 0.01 part of alkylbenzene ethers defoamer, acrylic amide inorganic material lubrication
0.2 part of agent, 0.2 part of coupling agent, 0.5 part of hyper-dispersant, 0.1 part of anti-settling agent, 0.05 part of levelling agent, 8 parts of cobalt blue dye；
By alkanes mixed solvent, aromatic hydrocarbons mixed solvent, fatty acid ester solvent, alkylbenzene ethers defoamer, Allylamines
Inorganic material lubricant, coupling agent, hyper-dispersant, anti-settling agent, levelling agent, cobalt blue dye mixture is mixed evenly in proportion uses sand
The grinding 5 hours of 2000 turns of grinding machine tests its viscosity and surface tension to granularity 100nm or so, and each parameter reaches following standard：Grain
It is 100nm to spend, and surface tension is 30 mN/m, and viscosity is 20cps, Gu containing being 30%, high temperature resistant is 1300 DEG C, and stability is real for heat
Test（60℃）72h is without layering and precipitates, and obtains final product the aqueous ceramic digital jet ink.
Embodiment 2：
A kind of oiliness ceramics digital jet ink, it is made up of the raw material of following weight portion：10 parts of alkanes mixed solvent, aromatic hydrocarbons
3 parts of class mixed solvent, 7 parts of fatty acid ester solvent, 0.03 part of polyethers defoamer, acrylic amide inorganic material lubricant
0.2 part, 0.2 part of coupling agent, 3 parts of hyper-dispersant, 0.2 part of anti-settling agent, 0.03 part of levelling agent, 11 parts of reddish brown pigment；
By hydro carbons mixed solvent, fatty acid ester solvent, ethers defoamer, amine inorganic material lubricant, coupling agent is ultra-dispersed
Agent, anti-settling agent, levelling agent, reddish brown pigment composition is mixed evenly with 2000 turns of sand mill grinding 5 hours to granularity in proportion
150nm or so, tests its viscosity and surface tension, and each parameter reaches following standard：Granularity is 150nm, and surface tension is 35mN/
M, viscosity is 25cps, Gu containing being 30%, high temperature resistant is 1400 DEG C, and stability is tested for heat（60℃）72h is without layering and precipitates, i.e.,
Obtain the aqueous ceramic digital jet ink.
Embodiment 3：
A kind of oiliness ceramics digital jet ink, it is made up of the raw material of following weight portion：12 10 parts of carbon linear alkene solvents, virtue
4 parts of hydro carbons mixed solvent, 3 parts of fatty acid ester solvent, 0.01 part of poly alkyl ether class defoamer, erucyl amide class inorganic material
0.2 part of lubricant, 0.2 part of coupling agent, 1 part of hyper-dispersant, 0.2 part of anti-settling agent, 0.05 part of levelling agent, 12 parts of praseodymium yellow pigments；
By 12 carbon linear alkene solvents, aromatic hydrocarbons mixed solvent, fatty acid ester solvent, poly alkyl ether class defoamer, erucic acid acyl
Amine inorganic material lubricant, coupling agent, hyper-dispersant, anti-settling agent, levelling agent, praseodymium yellow pigments mixture is mixed evenly in proportion
With sand mill, 2000 turns are ground 5 hours to granularity, and 200nm or so tests its viscosity and surface tension, and each parameter is reached such as subscript
It is accurate：Granularity is 200nm, and surface tension is 40mN/m, and viscosity is 30cps, Gu containing being 30%, high temperature resistant is 1500 DEG C, and stability is
Heat experiment（60℃）72h is without layering and precipitates, and obtains final product the aqueous ceramic digital jet ink.
Claims (9)
1. a kind of oiliness ceramics digital jet ink, it is made up of the raw material of following weight portion：7 parts -16 parts of hydro carbons mixed solvent,
1 part -7 parts of fatty acid ester solvent, 0.01 part -0.03 part of ethers defoamer, 0.2 part of amine inorganic material lubricant, coupling agent
0.1 part -0.2 part, 0.5 part -3 parts of hyper-dispersant, 0.1 part -0.2 part of anti-settling agent, 0.01 part -0.05 part of levelling agent, 8 parts of pigment -
12 parts.
2. according to claim 1 oiliness ceramics digital jet ink, it is characterised in that：The pigment is cobalt blue dye, red
Brown pigment, praseodymium yellow pigments any one.
3. according to claim 1 oiliness ceramics digital jet ink, it is characterised in that：The wherein hydro carbons mixed solvent is
Alkanes or 12 carbon linear alkene classes any one and aromatic hydrocarbon solvent is mixed.
4. according to claim 1 oiliness ceramics digital jet ink, it is characterised in that：The ethers defoamer is alkylbenzene
Any one in ethers defoamer, polyethers defoamer, poly alkyl ether class defoamer.
5. according to claim 1 oiliness ceramics digital jet ink, it is characterised in that：The amine inorganic material lubricant
For acrylic amide inorganic material lubricant or erucyl amide class inorganic material lubricant any one.
6. according to claim any one of 1-5 oiliness ceramics digital jet ink, it is characterised in that：It is by following weight portion
Raw material composition：7 parts of alkanes mixed solvent, 3 parts of aromatic hydrocarbons mixed solvent, 1 part of fatty acid ester solvent, alkylbenzene ethers disappears
0.01 part of infusion, 0.2 part of acrylic amide inorganic material lubricant, 0.2 part of coupling agent, 0.5 part of hyper-dispersant, anti-settling agent 0.1
Part, 0.05 part of levelling agent, 8 parts of cobalt blue dye.
7. the preparation method of a kind of oiliness ceramics digital jet ink, it is characterised in that：By hydro carbons mixed solvent, fatty acid ester
Solvent, ethers defoamer, amine inorganic material lubricant, coupling agent, hyper-dispersant, anti-settling agent, levelling agent, pigment composition is pressed
Ratio is mixed evenly is ground 5 hours with sand mill, is tested its each parameter and is met standard.
8. the preparation method of a kind of oiliness ceramics digital jet ink according to claim 7, it is characterised in that：The sand
Mill speed is 2000 turns/min.
9. the preparation method of a kind of oiliness ceramics digital jet ink according to claim 7, it is characterised in that：It is described each
Parameter reaches following standard：Granularity is 100-200nm, and surface tension is 30-40mN/m, and viscosity is 20-30cps, Gu contain be
30%, high temperature resistant is 1300-1500 DEG C, and stability is tested for heat（60℃）72h is without layering and precipitates.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710253637.5A CN106905768A (en) | 2017-04-18 | 2017-04-18 | A kind of oiliness ceramics digital jet ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710253637.5A CN106905768A (en) | 2017-04-18 | 2017-04-18 | A kind of oiliness ceramics digital jet ink and preparation method thereof |
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| CN106905768A true CN106905768A (en) | 2017-06-30 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116161987A (en) * | 2023-04-21 | 2023-05-26 | 佛山市东鹏陶瓷有限公司 | Composite decorative porcelain product and preparation method thereof |
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| CN102432340A (en) * | 2011-09-02 | 2012-05-02 | 景德镇陶瓷学院 | Method for preparing zirconium silicate-based ceramic pigment by nonhydrolytic sol-gel process |
| CN102964920A (en) * | 2012-11-27 | 2013-03-13 | 广东道氏技术股份有限公司 | Ink for ceramic ink-jet printing and method for preparing same |
| CN104004412A (en) * | 2014-06-13 | 2014-08-27 | 上海第二工业大学 | Blue ink for ceramic ink-jet printing and preparation method thereof |
| CN106009897A (en) * | 2016-05-17 | 2016-10-12 | 佛山市高明区海帝陶瓷原料有限公司 | Preparation method of blue ceramic ink |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116161987A (en) * | 2023-04-21 | 2023-05-26 | 佛山市东鹏陶瓷有限公司 | Composite decorative porcelain product and preparation method thereof |
| CN116161987B (en) * | 2023-04-21 | 2024-01-05 | 佛山市东鹏陶瓷有限公司 | Composite decorative porcelain product and preparation method thereof |
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Application publication date: 20170630 |
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