CN106189501A - A kind of praseodymium yellow color ceramic ink jet oozes colored ink and preparation method thereof - Google Patents
A kind of praseodymium yellow color ceramic ink jet oozes colored ink and preparation method thereof Download PDFInfo
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- CN106189501A CN106189501A CN201610588711.4A CN201610588711A CN106189501A CN 106189501 A CN106189501 A CN 106189501A CN 201610588711 A CN201610588711 A CN 201610588711A CN 106189501 A CN106189501 A CN 106189501A
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- Prior art keywords
- praseodymium
- yellow color
- ink jet
- colored ink
- color ceramic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/322—Pigment inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
Abstract
The open a kind of praseodymium yellow color ceramic ink jet of the present invention oozes colored ink and preparation method thereof.By mass percentage, praseodymium yellow color ceramic ink jet oozes colored ink and includes 65 ~ 75% organic praseodymium salt, 25 ~ 35% solvents and 0.1 ~ 2% auxiliary agent；Described organic praseodymium salt is carboxylic acid praseodymium.The present invention uses organic praseodymium salt to ooze colored ink to prepare praseodymium yellow color, and 1.5mm is controlled for the ink bleed degree of depth 0.1, and color development is bright-coloured, within 8 months, never degenerating, at ink 40 DEG C, viscosity is 20 25mPa s, surface tension 25 29mN/m, there is good Ink Jet Printing Performance, can use on various main flow shower nozzles.
Description
Technical field
The present invention relates to ceramic ink field, particularly relate to a kind of praseodymium yellow color ceramic ink jet and ooze colored ink and preparation side thereof
Method.
Background technology
In recent years, ink-jet technology experiencings rapid development.Ceramic ink is as the important materials of inkjet printing, at home and abroad
The research of ceramic ink is deepened continuously by ceramic industry.In Guangzhou ceramic industry exhibition in 2015, ink product is further to function
Property and special-effect stride forward.Ooze colored ink and become the bright spot of ink enterprise rollout.
First Mei Gao company of Italy carried out technological cooperation and assistance to Nobel's pottery in 2014 in Chinese market, became
Merit is proposed oozes colored ink tile product, is also ink-jet polished bricks.2015, Mei Gao company was planned, step by step to covering Na
Li Sha, east roc two domestic large-scale brand pottery enterprise cooperate, and exploitation number oozes colored ink tile product.At present, ink-jet polishing
The common following two of brickwork skill:
Technique one: in cloth → adobe, the thin material → press of secondary cloth → dry → spray is oozed colored ink+spray permeation-promoter → kiln and burnt till
→ polishing；
Technique two: cloth → press → be dried → pouring glaze → be dried → spray is oozed colored ink+spray permeation-promoter → kiln and burnt till → throw
Light.
Ooze colored ink be primarily referred to as organic metal salt be dissolved in solvent is prepared from can be on ceramic matrix the one of color development
Class ink, such ink is permeable to the degree of depth of base material 0.6-1.0mm by penetrating agent.Ooze colored ink and have following four the most excellent
Gesture: one, ceramic tile pattern third dimension is higher, superficial makings can be the finest and the smoothest true to nature, close to the texture of lithotome；Two, solve
Common ink is in a difficult problem for the color color developments such as redness, Lycoperdon polymorphum Vitt, black；Three, it makes the pattern texture of polished bricks abundanter, Mohs
Hardness has reached 5.5-6, more wear-resisting than the full throwing glaze of current trend；Four, common polished bricks wants jettisoning ceramic tile table when polishing
The raw material of face more than 1mm, and use the polishing thickness oozing the produced polished bricks of colored ink to be about 0.1-0.3mm, significantly drop
Low polishing thickness, decreases the discharge of solid waste, waste residue.
CN 104761952 A refer to use 2 ethyl hexanoic acid chromium and 2 ethyl hexanoic acid titanium to ooze colored ink to prepare yellow.
But using above method to there is problems in that the deep dimness of yellow color development, color is the most bright-coloured, makes ink color development colour gamut narrow；Two kinds
Different organic salt is different due to preparation technology, and the impurity of residual etc. can cause two kinds of salt to interact, and ultimately results in ink and holds
Easily crystallize blocking shower nozzle；The preparation of 2 ethyl hexanoic acid chromium and use can produce chromium and be unfavorable for environmental protection, and price is high.
Therefore, prior art has yet to be improved and developed.
Summary of the invention
In view of above-mentioned the deficiencies in the prior art, it is an object of the invention to provide a kind of praseodymium yellow color ceramic ink jet and ooze colored ink
And preparation method thereof, it is intended to solve existing to ooze the problems such as colored ink color is dim, colour gamut is narrow.
Technical scheme is as follows:
A kind of praseodymium yellow color ceramic ink jet oozes colored ink, wherein, by mass percentage, including 65 ~ 75% organic praseodymium salt, 25 ~ 35%
Solvent and 0.1 ~ 2% auxiliary agent；
Described organic praseodymium salt is carboxylic acid praseodymium.
Described praseodymium yellow color ceramic ink jet oozes colored ink, and wherein, described organic praseodymium salt is aphthenic acids praseodymium, isooctyl acid praseodymium, new
A kind of or any several combination in capric acid praseodymium and lauric acid praseodymium.
Described praseodymium yellow color ceramic ink jet oozes colored ink, and wherein, described solvent is in alkanes, alcohols, alcohol ethers, esters
A kind of or the most several mixture.
Described praseodymium yellow color ceramic ink jet oozes colored ink, and wherein, described solvent is hexadecane, pentadecane, undecyl alcohol, isomery
Hexadecanol, dibutyl ethylene glycol ether, TRIGLYME, iso-octyl palmitate, methyl myristate, butyl oleate, stearic acid
A kind of or the most several mixture in butyl ester, amyl stearate and isopropyl laurate.
Described praseodymium yellow color ceramic ink jet oozes colored ink, and wherein, described auxiliary agent includes lubricant, defoamer and tension adjustment
Agent.
Described praseodymium yellow color ceramic ink jet oozes colored ink, wherein, described lubricant be Tween20, Span80 or
PPG2000。
Described praseodymium yellow color ceramic ink jet oozes colored ink, and wherein, described defoamer is BYK-066N, BYK-093 or BYK-
055。
Described praseodymium yellow color ceramic ink jet oozes colored ink, wherein, described tension regulator be BYK-306, Tego-1484 or
Tego Flow 370。
Described praseodymium yellow color ceramic ink jet oozes colored ink, it is characterised in that described praseodymium yellow color ceramic ink jet ooze colored ink with
Permeation-promoter with the use of, described permeation-promoter is alcohols or acids solvent, and described alcohols is isomerous tridecanol or isononyl alcohol, described acid
Kind solvent is isooctyl acid or different n-nonanoic acid.
A kind of praseodymium yellow color ceramic ink jet oozes the preparation method of colored ink, wherein, including step:
A, organic praseodymium salt, solvent and auxiliary agent are put in enamel stirred tank according to quantity, stir 3 hours with 85 revs/min under room temperature；
B, sampling detection viscosity；
Use 1 micron of filter element to filter after C, viscosity measurements are qualified, pack after filtration.
Beneficial effect: the present invention uses organic praseodymium salt to ooze colored ink, ink bleed degree of depth 0.1-1.5mm to prepare praseodymium yellow color
Controlled, color development is bright-coloured, within 8 months, never degenerates, and at ink 40 DEG C, viscosity is 20-25mPa s, and surface tension 25-29mN/m has good
Good Ink Jet Printing Performance, can use on various main flow shower nozzles.
Detailed description of the invention
The present invention provides a kind of praseodymium yellow color ceramic ink jet to ooze colored ink and preparation method thereof, for making the purpose of the present invention, skill
Art scheme and effect are clearer, clear and definite, and the present invention is described in more detail below.Should be appreciated that tool described herein
Body embodiment only in order to explain the present invention, is not intended to limit the present invention.
A kind of praseodymium yellow color ceramic ink jet provided by the present invention oozes colored ink, by mass percentage, has including 65 ~ 75%
Machine praseodymium salt, 25 ~ 35% solvents and 0.1 ~ 2% auxiliary agent；Described organic praseodymium salt is carboxylic acid praseodymium.
Further, described organic praseodymium salt is preferably the one in aphthenic acids praseodymium, isooctyl acid praseodymium, neodecanoic acid praseodymium and lauric acid praseodymium
Or any several combination.
Further, a kind of or the most several mixing during described solvent is preferably alkanes, alcohols, alcohol ethers, esters
Thing.
Further, described solvent be preferably hexadecane, pentadecane, undecyl alcohol, isomery hexadecanol, dibutyl ethylene glycol ether,
TRIGLYME, iso-octyl palmitate, methyl myristate, butyl oleate, butyl stearate, amyl stearate and lauric acid
A kind of or the most several mixture in isopropyl ester.
Further, described auxiliary agent includes lubricant, defoamer and tension regulator.
Further, described lubricant is preferably Tween20, Span80 or PPG2000.
Further, described defoamer is preferably BYK-066N, BYK-093 or BYK-055.
Further, described tension regulator is preferably BYK-306, Tego-1484 or Tego Flow 370.Such as BYK-
066N, BYK-093, BYK-055, BYK-306 are derived from Bi Ke company of Germany.
The present invention also provides for a kind of praseodymium yellow color ceramic ink jet and oozes the preparation method of colored ink, and it includes step:
1), organic praseodymium salt, solvent are put in enamel stirred tank with auxiliary agent according to quantity, little with 85 revs/min of stirrings 3 under room temperature
Time；
2), sampling detection viscosity；
3), viscosity measurements qualified after use 1 micron of filter element filter, pack after filtration.
Can sampling Detection viscosity, surface tension be finally physical and chemical performance with density etc..
In the present invention, in ink composition, chromophore component is preferably one matter, it is to avoid untoward reaction between multicomponent, it is to avoid
Using raw material disadvantageous to environmental protection, organic praseodymium salt color development is more bright-coloured；Praseodymium yellow oozes colored ink not to be sent out in common fabric
Color, but by adjusting the composition of fabric, and (nano silicon oxide is with nano oxidized to add special nano material in fabric
Zirconium), utilize the characteristic strong adsorption of nano material high-specific surface area parcel to ooze colored ink, thus at high temperature parcel color development becomes
Point, the most eclipsed after burning till, color development is bright-coloured pure.
Embodiment 1(permeation-promoter is different n-nonanoic acid+Tego-1484):
Embodiment 2(permeation-promoter is isooctyl acid+Tego-1484):
Embodiment 3(permeation-promoter is isomerous tridecanol+BYK-306):
Above example application process follows the steps below:
1, color development test: by ooze colored ink by 100% gray level printing on the ceramic tile blank executing color development fabric after at 1210 DEG C
Burn till rear tested inks color development.
2, ink bleed depth experiments: ink is respectively charged into from permeation-promoter in the different passage of ink jet printer；According to formulating ash
Ink and permeation-promoter are printed on the ceramic body executing color development fabric by degree combination simultaneously；After printing completes, after dry base substrate
In 1210 DEG C calcine 70 minutes, after product is cleaved under optical microscope tested inks length of penetration.
Above two experiment conditions: ink-jet printer is new Jingtai experimental ink-jet machine, shower nozzle is Xaar1002 GS440 shower nozzle,
In above-described embodiment, the composition (by mass percentage) of color development fabric is: SiO2 70%、Al2O3 21%、Na2O 4.5%、K2O
2%、CaO 0.5%、ZrO22%, wherein in above-mentioned material, nanometer ZrO2Account for 2%, Nano-meter SiO_22Account for 3%, say, that ZrO2All
For nanometer ZrO2, and SiO2Having fraction is Nano-meter SiO_22。
It should be noted that, L* represents brightness (Luminosity), and a* represents from carmetta to green scope, b* represent from
Yellow is to blue scope, and the codomain of a* and b* is all by+127 to-128.Because being two ink channels, each passage is 0-
100%, so above-mentioned gray scale combination sum is 110%.Can be seen that the present embodiment test effect is the most bright-coloured, no from a* and b* value
Bright-coloured performance is that b* value is generally less than 35.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can
To be improved according to the above description or to convert, all these modifications and variations all should belong to the guarantor of claims of the present invention
Protect scope.
Claims (10)
1. a praseodymium yellow color ceramic ink jet oozes colored ink, it is characterised in that by mass percentage, including 65 ~ 75% organic praseodymiums
Salt, 25 ~ 35% solvents and 0.1 ~ 2% auxiliary agent；
Described organic praseodymium salt is carboxylic acid praseodymium.
Praseodymium yellow color ceramic ink jet the most according to claim 1 oozes colored ink, it is characterised in that described organic praseodymium salt is cycloalkanes
A kind of or any several combination in acid praseodymium, isooctyl acid praseodymium, neodecanoic acid praseodymium and lauric acid praseodymium.
Praseodymium yellow color ceramic ink jet the most according to claim 1 oozes colored ink, it is characterised in that described solvent be alkanes,
A kind of or the most several mixture in alcohols, alcohol ethers, esters.
Praseodymium yellow color ceramic ink jet the most according to claim 3 oozes colored ink, it is characterised in that described solvent be hexadecane,
Pentadecane, undecyl alcohol, isomery hexadecanol, dibutyl ethylene glycol ether, TRIGLYME, iso-octyl palmitate, tetradecylic acid first
A kind of or the most several mixture in ester, butyl oleate, butyl stearate, amyl stearate and isopropyl laurate.
Praseodymium yellow color ceramic ink jet the most according to claim 1 oozes colored ink, it is characterised in that described auxiliary agent includes lubrication
Agent, defoamer and tension regulator.
Praseodymium yellow color ceramic ink jet the most according to claim 5 oozes colored ink, it is characterised in that described lubricant is
Tween20, Span80 or PPG2000.
Praseodymium yellow color ceramic ink jet the most according to claim 1 oozes colored ink, it is characterised in that described defoamer is BYK-
066N, BYK-093 or BYK-055.
Praseodymium yellow color ceramic ink jet the most according to claim 1 oozes colored ink, it is characterised in that described tension regulator is
BYK-306, Tego-1484 or Tego Flow 370.
Praseodymium yellow color ceramic ink jet the most according to claim 1 oozes colored ink, it is characterised in that described praseodymium yellow color ceramic ink jet
Ooze colored ink and permeation-promoter with the use of, described permeation-promoter is alcohols or acids solvent, and described alcohols is isomerous tridecanol or different
Nonyl alcohol, described acids solvent is isooctyl acid or different n-nonanoic acid.
10. a praseodymium yellow color ceramic ink jet oozes the preparation method of colored ink, it is characterised in that include step:
A, organic praseodymium salt, solvent and auxiliary agent are put in enamel stirred tank according to quantity, stir 3 hours with 85 revs/min under room temperature；
B, sampling detection viscosity；
Use 1 micron of filter element to filter after C, viscosity measurements are qualified, pack after filtration.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610588711.4A CN106189501A (en) | 2016-07-25 | 2016-07-25 | A kind of praseodymium yellow color ceramic ink jet oozes colored ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610588711.4A CN106189501A (en) | 2016-07-25 | 2016-07-25 | A kind of praseodymium yellow color ceramic ink jet oozes colored ink and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634216A (en) * | 2016-12-29 | 2017-05-10 | 中科院广州化学有限公司南雄材料生产基地 | Storage-stable high-weatherability aqueous ceramic pattern penetration ink and preparation method thereof |
| CN106905769A (en) * | 2017-04-18 | 2017-06-30 | 青岛农业大学 | A kind of aqueous ceramic digital jet ink and preparation method thereof |
| CN106905768A (en) * | 2017-04-18 | 2017-06-30 | 青岛农业大学 | A kind of oiliness ceramics digital jet ink and preparation method thereof |
| CN107033673A (en) * | 2017-05-25 | 2017-08-11 | 佛山市三水区康立泰无机合成材料有限公司 | A kind of preparation method of inkjet printing cobalt blue ceramic ink |
| CN108276831A (en) * | 2017-12-18 | 2018-07-13 | 佛山科学技术学院 | A kind of foresythia ceramic ink jet oozes caul-fat ink |
| CN108929592A (en) * | 2018-08-06 | 2018-12-04 | 佛山科学技术学院 | A kind of white infiltration caul-fat ink and preparation method thereof for ceramic ink jet printing |
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| CN1420916A (en) * | 2000-01-07 | 2003-05-28 | 费罗公司 | Individual inks and ink set for use in color ink jet printing of glazed ceramic tiles and surfaces |
| CN104761952A (en) * | 2015-03-27 | 2015-07-08 | 广东道氏技术股份有限公司 | Ceramic inkjet printing ink with adjustable penetration depth and method thereof |
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| CN1420916A (en) * | 2000-01-07 | 2003-05-28 | 费罗公司 | Individual inks and ink set for use in color ink jet printing of glazed ceramic tiles and surfaces |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634216A (en) * | 2016-12-29 | 2017-05-10 | 中科院广州化学有限公司南雄材料生产基地 | Storage-stable high-weatherability aqueous ceramic pattern penetration ink and preparation method thereof |
| CN106634216B (en) * | 2016-12-29 | 2020-04-17 | 中科院广州化学有限公司南雄材料生产基地 | High-weather-resistance water-based ceramic pattern-penetrating ink with stable storage and preparation method thereof |
| CN106905769A (en) * | 2017-04-18 | 2017-06-30 | 青岛农业大学 | A kind of aqueous ceramic digital jet ink and preparation method thereof |
| CN106905768A (en) * | 2017-04-18 | 2017-06-30 | 青岛农业大学 | A kind of oiliness ceramics digital jet ink and preparation method thereof |
| CN107033673A (en) * | 2017-05-25 | 2017-08-11 | 佛山市三水区康立泰无机合成材料有限公司 | A kind of preparation method of inkjet printing cobalt blue ceramic ink |
| CN107033673B (en) * | 2017-05-25 | 2020-12-15 | 佛山市三水区康立泰无机合成材料有限公司 | Preparation method of cobalt blue ceramic ink for ink-jet printing |
| CN108276831A (en) * | 2017-12-18 | 2018-07-13 | 佛山科学技术学院 | A kind of foresythia ceramic ink jet oozes caul-fat ink |
| CN108929592A (en) * | 2018-08-06 | 2018-12-04 | 佛山科学技术学院 | A kind of white infiltration caul-fat ink and preparation method thereof for ceramic ink jet printing |
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Application publication date: 20161207 |