CN105733360A - Permeable ink applicable to ceramic surface printing - Google Patents
Permeable ink applicable to ceramic surface printing Download PDFInfo
- Publication number
- CN105733360A CN105733360A CN201610177717.2A CN201610177717A CN105733360A CN 105733360 A CN105733360 A CN 105733360A CN 201610177717 A CN201610177717 A CN 201610177717A CN 105733360 A CN105733360 A CN 105733360A
- Authority
- CN
- China
- Prior art keywords
- ceramic surface
- ruthenium
- surface printing
- parts
- infiltration ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
Abstract
The invention discloses permeable ink applicable to ceramic surface printing and relates to the technical field of architectural ceramic decoration. The permeable ink applicable to ceramic surface printing consists of the following components in parts by weight: 30-75 parts of ruthenium metal organic compound, 20-75 parts of solvent, 0.1-4 parts of penetrant and 0.1-4 parts of complexing agent. The permeable ink applicable to ceramic surface printing disclosed by the invention can be directly sprayed to the ceramic surface by an inkjet printer, the ink has pure color, the permeation depth can reach 1.7-2.8mm, and a glaze penetrating decoration effect with high resolution and strong stereoscopic impression is realized.
Description
Technical field
The present invention relates to Prospect of Decoration Technology in Building Ceramics field, particularly relate to a kind of can be used for ceramic surface print
Infiltration ink.
Background technology
From ceramic ink jet printing technology universal since, Full-glazed tile is with its glaze pattern texture-rich, texture
The advantages such as design easy exploiting, gradually carve up the polished bricks market share, once deeply blue or green by ceramic industry and consumer
Look at.But, As time goes on, Full-glazed tile product homogeneity, the shortcoming such as the most wear-resisting the most gradually expose.
Oozing the appearance of colored ink, the development for polished bricks provides a new opportunity.Though tradition polished bricks wearability
Far above Full-glazed tile, but there is the deadly defect that pattern is deficient, and ooze colored ink by application, throwing can be made
Light brick presents and entirely throws the pattern grain decorating effect that glaze compares favourably.
Abroad, Italy is U.S. high began to research and development from 2003 and oozes colored ink.In recent years, through independent research,
Colored ink product is also oozed releasing one after another in Ming Dynasty's science and technology and the domestic enterprise such as Mai Ruisi.The Guangzhou in June, 2015
In ceramic industry exhibition, oozing colored ink and receive much concern, the enterprise such as Ming Dynasty's science and technology, Mai Ruisi, Dow opens up the most one after another
Go out to ooze colored ink and relevant tile product.
At present, in infiltration ink application process, generally redness is permeated ink and superposes with blue infiltration ink
Printing and substitute black, but this superposition printing can cause infiltration ink color development the purest, length of penetration is inadequate,
Length of penetration typically only has 0.5-1.0mm, affects the decorative effect of pattern texture.
Summary of the invention
For solve above-mentioned technical problem, the invention provides a kind of have ooze colored effect, can be used for spraying black
Color can be used for the infiltration ink that ceramic surface prints, and concrete scheme is as follows:
A kind of infiltration ink that can be used for ceramic surface printing, is made up of following parts by weight ingredient:
Preferably, described ruthenium metallo-organic compound is oil-soluble to have isomerization or have unsaturated double-bond
Organic carboxyl acid ruthenium salt compound.
Further, described organic carboxyl acid ruthenium salt compound is by can the solubility ruthenium salt of color development and organic carboxyl acid
Reacting by heating is prepared from.
Further, described solubility ruthenium salt is in ruthenium trichloride, acetic acid ruthenium and nitrosyl nitric acid ruthenium
At least one.
Further, described organic carboxyl acid is selected from C4～C18At least organic carboxyl acid with a carboxyl.
Preferably, described ruthenium metallo-organic compound one in aphthenic acids ruthenium or isooctyl acid ruthenium.
Preferably, described penetrating agent be in nonionic surfactant or anion surfactant at least
A kind of.
Preferably, described penetrating agent is selected from fatty alcohol-polyoxyethylene ether, OPEO, nonyl
At least one in phenol polyethenoxy ether and phosphate compounds.
Preferably, described solvent is selected from chloroform, dichloromethane, ethyl acetate, butyl acetate, just
At least one in butanol, normal hexane, normal heptane, methyl tertiary butyl ether(MTBE), diisopropyl ether and isobutanol.
Preferably, described chelating agent is selected from disodiumedetate (EDTA), diethanolamine, three ethanol
At least one in amine.
The preparation method of the above-mentioned infiltration ink that can be used for ceramic surface printing is as follows:
1) the metal-organic preparation of ruthenium: can solubility ruthenium salt and the organic carboxyl acid of color development press ruthenium ion and
The mol ratio 1:2-3 mixing of carboxyl, reacting by heating, it is prepared as oil-soluble organic carboxyl acid ruthenium salt compound；
2) solvent, penetrating agent and chelating agent are sufficiently mixed through high-speed stirred, are slowly added to organic carboxyl acid ruthenium salt
Compound, high-speed stirred prepares mixed liquid；
3) secondary grinds: by step 2) gained mixes that liquid carries out ball milling, sand milling grinds, and obtain black can
The infiltration ink printed for ceramic surface.
The infiltration ink that can be used for ceramic surface printing of present invention offer can be by ink-jet printer by this ink
Being directly injected to ceramic surface, ink color development is pure, and length of penetration is up to 1.7-2.8mm, and presents point
Resolution is high and third dimension is strong oozes colored decorative effect.
Detailed description of the invention
In order to more fully understand the technology contents of the present invention, below in conjunction with the specific embodiment technology to the present invention
Scheme is further described and illustrates.
Embodiment 1
Ruthenium trichloride is mixed with aphthenic acids 1:3 in molar ratio, stirring reaction at a temperature of 120 ± 5 DEG C, system
Standby one-tenth aphthenic acids ruthenium；
After 61.4 parts of normal hexane, 1.5 parts of fatty alcohol-polyoxyethylene ether and 1.1 parts of triethanolamine high-speed stirred,
Being slowly added 36 parts of aphthenic acids rutheniums, high-speed stirred prepares mixed liquid；
Gained mixing liquid and carries out ball milling and sand milling grinding, the ceramic surface that can be used for preparing black prints
Infiltration ink.
Embodiment 2
Ruthenium trichloride is mixed with aphthenic acids 1:3 in molar ratio, stirring reaction at a temperature of 120 ± 5 DEG C, system
Standby one-tenth aphthenic acids ruthenium；
After 41.7 parts of normal hexane, 1.8 parts of fatty alcohol-polyoxyethylene ether and 1.5 parts of triethanolamine high-speed stirred,
Being slowly added 55 parts of aphthenic acids rutheniums, high-speed stirred prepares mixed liquid；
Gained mixing liquid and carries out ball milling and sand milling grinding, the ceramic surface that can be used for preparing black prints
Infiltration ink.
Embodiment 3
Acetic acid ruthenium is mixed with aphthenic acids 1:2.5 in molar ratio, stirring reaction at a temperature of 110 ± 5 DEG C, system
Standby one-tenth aphthenic acids ruthenium；
After 20 parts of dichloromethane, 1.8 parts of NPEs and 0.1 part of diethanolamine high-speed stirred,
Being slowly added 30 parts of aphthenic acids rutheniums, high-speed stirred prepares mixed liquid；
Gained mixing liquid and carries out ball milling and sand milling grinding, the ceramic surface that can be used for preparing black prints
Infiltration ink.
Embodiment 4
Nitrosyl nitric acid ruthenium is mixed with aphthenic acids 1:2 in molar ratio, stirring reaction at a temperature of 160 ± 5 DEG C,
It is prepared as aphthenic acids ruthenium；
After 75 parts of ethyl acetate, 4 parts of OPEOs and 3 parts of EDTA high-speed stirred, slowly
Adding 75 parts of aphthenic acids rutheniums, high-speed stirred prepares mixed liquid；
Gained mixing liquid and carries out ball milling and sand milling grinding, the ceramic surface that can be used for preparing black prints
Infiltration ink.
Embodiment 5
Ruthenium trichloride is mixed with isooctyl acid 1:3 in molar ratio, stirring reaction at a temperature of 120 ± 5 DEG C, system
Standby one-tenth isooctyl acid ruthenium；
After 47.2 parts of n-butyl alcohol, 1.6 parts of alkylphenol polyoxyethylene and 1.2 parts of triethanolamine high-speed stirred,
Being slowly added 50 parts of isooctyl acid rutheniums, high-speed stirred prepares mixed liquid；
Gained mixing liquid and carries out ball milling and sand milling grinding, the ceramic surface that can be used for preparing black prints
Infiltration ink.
Embodiment 6
Ruthenium trichloride is mixed with isooctyl acid 1:3 in molar ratio, stirring reaction at a temperature of 120 ± 5 DEG C, system
Standby one-tenth isooctyl acid ruthenium；
By 57.5 parts of ethyl acetate, 1.6 parts of fatty alcohol-polyoxyethylene ether and 0.9 part of triethanolamine high-speed stirred
After, it being slowly added 40 parts of isooctyl acid rutheniums, high-speed stirred prepares mixed liquid；
Gained mixing liquid and carries out ball milling and sand milling grinding, the ceramic surface that can be used for preparing black prints
Infiltration ink.
Embodiment 7
Acetic acid ruthenium is mixed with isooctyl acid 1:2.5 in molar ratio, stirring reaction at a temperature of 110 ± 5 DEG C, system
Standby one-tenth isooctyl acid ruthenium；
After 20 parts of dichloromethane, 1.8 parts of NPEs and 0.1 part of diethanolamine high-speed stirred,
Being slowly added 75 parts of isooctyl acid rutheniums, high-speed stirred prepares mixed liquid；
Gained mixing liquid and carries out ball milling and sand milling grinding, the ceramic surface that can be used for preparing black prints
Infiltration ink.
Embodiment 8
Nitrosyl nitric acid ruthenium is mixed with isooctyl acid 1:2 in molar ratio, stirring reaction at a temperature of 160 ± 5 DEG C,
It is prepared as isooctyl acid ruthenium；
After 75 parts of ethyl acetate, 4 parts of OPEOs and 3 parts of EDTA high-speed stirred, slowly
Adding 30 parts of isooctyl acid rutheniums, high-speed stirred prepares mixed liquid；
Gained mixing liquid and carries out ball milling and sand milling grinding, the ceramic surface that can be used for preparing black prints
Infiltration ink.
Embodiment 9
Ruthenium trichloride is mixed with aphthenic acids 1:2.5 in molar ratio, stirring reaction at a temperature of 160 ± 5 DEG C,
It is prepared as aphthenic acids ruthenium；
By 35 parts of ethyl acetate, 20 parts of butyl acetates, 10 parts of methyl tertiary butyl ether(MTBE)s, 1 part of fatty alcohol polyoxy
After vinyl Ether, 1 part of OPEO and 1 part of EDTA high-speed stirred, it is slowly added 50 parts of cycloalkanes
Acid ruthenium, high-speed stirred prepares mixed liquid；
Gained mixing liquid and carries out ball milling and sand milling grinding, the ceramic surface that can be used for preparing black prints
Infiltration ink.
Embodiment 10
Ruthenium trichloride is mixed with isooctyl acid 1:2.5 in molar ratio, stirring reaction at a temperature of 160 ± 5 DEG C,
It is prepared as isooctyl acid ruthenium；
By 15 parts of ethyl acetate, 40 parts of butyl acetates, 10 parts of methyl tertiary butyl ether(MTBE)s, 1 part of fatty alcohol polyoxy
After vinyl Ether, 0.5 part of OPEO and 1 part of EDTA high-speed stirred, be slowly added 50 parts different
Octanoic acid ruthenium, high-speed stirred prepares mixed liquid；
Gained mixing liquid and carries out ball milling and sand milling grinding, the ceramic surface that can be used for preparing black prints
Infiltration ink.
That above example 1-10 is prepared can be used for the infiltration ink employing ceramic ink jet that ceramic surface prints
Printing technology respectively paint application in Ceramic Tiles, the Ceramic Tiles made is carried out the ink bleed degree of depth (unit:
Mm) detection, result is as shown in table 1:
Table 1
The above only further illustrates the technology contents of the present invention with embodiment, in order to reader is easier to
Understand, but do not represent embodiments of the present invention and be only limitted to this, any technology done according to the present invention extend or
Recreation, is all protected by the present invention.
Claims (10)
1. one kind can be used for the infiltration ink that ceramic surface prints, it is characterised in that by following parts by weight ingredient
Composition:
The infiltration ink that can be used for ceramic surface printing the most according to claim 1, it is characterised in that
Described ruthenium metallo-organic compound is the oil-soluble organic carboxyl acid ruthenium having isomerization or having unsaturated double-bond
Salt compound.
The infiltration ink that can be used for ceramic surface printing the most according to claim 2, it is characterised in that
Described organic carboxyl acid ruthenium salt compound by can color development the preparation of solubility ruthenium salt and organic carboxyl acid reacting by heating and
Become.
The infiltration ink that can be used for ceramic surface printing the most according to claim 3, it is characterised in that
At least one in ruthenium trichloride, acetic acid ruthenium and nitrosyl nitric acid ruthenium of described solubility ruthenium salt.
The infiltration ink that can be used for ceramic surface printing the most according to claim 3, it is characterised in that
Described organic carboxyl acid is selected from C4～C18At least organic carboxyl acid with a carboxyl.
The infiltration ink that can be used for ceramic surface printing the most according to claim 5, it is characterised in that
Described ruthenium metallo-organic compound one in aphthenic acids ruthenium or isooctyl acid ruthenium.
The infiltration ink that can be used for ceramic surface printing the most according to claim 1, it is characterised in that
Described penetrating agent is at least one in nonionic surfactant or anion surfactant.
The infiltration ink that can be used for ceramic surface printing the most according to claim 7, it is characterised in that
Described penetrating agent is selected from fatty alcohol-polyoxyethylene ether, OPEO, NPE
With at least one in phosphate compounds.
The infiltration ink that can be used for ceramic surface printing the most according to claim 1, it is characterised in that
Described solvent selected from chloroform, dichloromethane, ethyl acetate, butyl acetate, n-butyl alcohol, normal hexane,
At least one in normal heptane, methyl tertiary butyl ether(MTBE), diisopropyl ether and isobutanol.
The infiltration ink that can be used for ceramic surface printing the most according to claim 1, it is characterised in that
At least one in disodiumedetate, diethanolamine, triethanolamine of described chelating agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610177717.2A CN105733360A (en) | 2016-03-24 | 2016-03-24 | Permeable ink applicable to ceramic surface printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610177717.2A CN105733360A (en) | 2016-03-24 | 2016-03-24 | Permeable ink applicable to ceramic surface printing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105733360A true CN105733360A (en) | 2016-07-06 |
Family
ID=56251446
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610177717.2A Pending CN105733360A (en) | 2016-03-24 | 2016-03-24 | Permeable ink applicable to ceramic surface printing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105733360A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634216A (en) * | 2016-12-29 | 2017-05-10 | 中科院广州化学有限公司南雄材料生产基地 | Storage-stable high-weatherability aqueous ceramic pattern penetration ink and preparation method thereof |
| CN109206978A (en) * | 2018-08-01 | 2019-01-15 | 中山大学 | A kind of ceramic ink jet printing seeps the preparation method of flower ink with black |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01318044A (en) * | 1988-06-16 | 1989-12-22 | Tanaka Kikinzoku Kogyo Kk | Preparation of ruthenium resinate |
| CN101037349A (en) * | 2006-03-13 | 2007-09-19 | 梁桐灿 | Black pattern permeating glaze |
| CN104591801A (en) * | 2015-01-26 | 2015-05-06 | 佛山市东鹏陶瓷有限公司 | Manufacturing method of ceramic tile mud blank with concave-convex textures |
| CN105219153A (en) * | 2015-10-12 | 2016-01-06 | 佛山市明朝科技开发有限公司 | A kind of oozing spends ceramic ink permeation and preparation method thereof |
-
2016
- 2016-03-24 CN CN201610177717.2A patent/CN105733360A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01318044A (en) * | 1988-06-16 | 1989-12-22 | Tanaka Kikinzoku Kogyo Kk | Preparation of ruthenium resinate |
| CN101037349A (en) * | 2006-03-13 | 2007-09-19 | 梁桐灿 | Black pattern permeating glaze |
| CN104591801A (en) * | 2015-01-26 | 2015-05-06 | 佛山市东鹏陶瓷有限公司 | Manufacturing method of ceramic tile mud blank with concave-convex textures |
| CN105219153A (en) * | 2015-10-12 | 2016-01-06 | 佛山市明朝科技开发有限公司 | A kind of oozing spends ceramic ink permeation and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 俞康泰: "《现代陶瓷色釉料与装饰技术手册》", 31 May 1999, 武汉工业大学出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634216A (en) * | 2016-12-29 | 2017-05-10 | 中科院广州化学有限公司南雄材料生产基地 | Storage-stable high-weatherability aqueous ceramic pattern penetration ink and preparation method thereof |
| CN106634216B (en) * | 2016-12-29 | 2020-04-17 | 中科院广州化学有限公司南雄材料生产基地 | High-weather-resistance water-based ceramic pattern-penetrating ink with stable storage and preparation method thereof |
| CN109206978A (en) * | 2018-08-01 | 2019-01-15 | 中山大学 | A kind of ceramic ink jet printing seeps the preparation method of flower ink with black |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105670386A (en) | Ink for color-penetrated ceramics and preparation method of ink for color-penetrated ceramics | |
| CN105219153A (en) | A kind of oozing spends ceramic ink permeation and preparation method thereof | |
| CN105175027B (en) | A kind of ceramics with three-dimensional decorative effect and preparation method thereof | |
| CN103965687B (en) | A kind of have ceramic ink of sagging effect and preparation method thereof | |
| CN104761952B (en) | The ceramic ink jet printing ink and method of a kind of adjustable penetration depth | |
| CN104403419A (en) | Glass ink for ink-jet printing and preparation method of glass ink | |
| CN102249741A (en) | Ceramic penetration glaze suitable for spray ink printing and method for using same to produce ceramic tiles | |
| CN105733360A (en) | Permeable ink applicable to ceramic surface printing | |
| CN106518170A (en) | A ceramic brick pattern penetrating method | |
| CN106189501A (en) | A kind of praseodymium yellow color ceramic ink jet oozes colored ink and preparation method thereof | |
| CN106046939A (en) | Novel ceramic ink-jet ink and production process thereof | |
| CN103937327B (en) | A kind of Water-soluble ceramic ink | |
| CN105907178B (en) | A kind of ceramic ink jet printing is with pushing glaze ink aside | |
| CN109535837B (en) | Ceramic ink capable of improving color development effect of cobalt-containing ink and preparation method and use method thereof | |
| CN105778625A (en) | Preparation method of ceramic penetration printing ink | |
| CN105838145A (en) | Ceramic spray coating composite and preparation method thereof | |
| CN106800423A (en) | A kind of preparation method for oozing colored ceramic tile | |
| US20220282105A1 (en) | Inkjet inks for ceramic tile decoration | |
| CN109504179A (en) | A kind of matte effect ink and preparation method thereof for Ceramic glaze | |
| CN105838144B (en) | A kind of pink ceramic ink jet infiltration caul-fat ink | |
| CN108929592A (en) | A kind of white infiltration caul-fat ink and preparation method thereof for ceramic ink jet printing | |
| CN108250839A (en) | The preparation method of hydrophobic inorganic powder and ceramic ink jet printing ink | |
| CN109021703B (en) | Bright red ceramic ink-jet pattern penetrating ink and preparation method thereof | |
| EP3931276B1 (en) | Water-based ceramic dye | |
| CN105482543B (en) | A kind of reactive dye intaglio printing ink and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160706 |