CN105482543B - A kind of reactive dye intaglio printing ink and preparation method thereof - Google Patents

A kind of reactive dye intaglio printing ink and preparation method thereof Download PDF

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Publication number
CN105482543B
CN105482543B CN201610035280.9A CN201610035280A CN105482543B CN 105482543 B CN105482543 B CN 105482543B CN 201610035280 A CN201610035280 A CN 201610035280A CN 105482543 B CN105482543 B CN 105482543B
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CN
China
Prior art keywords
reactive dye
intaglio printing
printing ink
organic solvent
ink
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Expired - Fee Related
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CN201610035280.9A
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Chinese (zh)
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CN105482543A (en
Inventor
袁娟
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Hunan Yingkun Ink Chemical Product Co., Ltd.
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HUNAN YINGKUN INK CHEMICAL PRODUCT CO Ltd
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Priority to CN201610035280.9A priority Critical patent/CN105482543B/en
Priority to CN201810587122.3A priority patent/CN108976897A/en
Publication of CN105482543A publication Critical patent/CN105482543A/en
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Publication of CN105482543B publication Critical patent/CN105482543B/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/14—Printing inks based on carbohydrates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48—Derivatives of carbohydrates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
    • D06P1/5292—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Textile Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a kind of reactive dye intaglio printing inks, are prepared by the raw material of following weight percentage：Reactive dye 25 35%, binder 20 30%, organic solvent 10 30%, antifoaming agent 0.3 0.5%, surplus is water.Reactive dye intaglio printing ink of the present invention is due to mainly using deionized water and organic solvent to make solvent, so that ink and Special Film printing adaptability are good, and the reactive dye on Special Film are printed in hygrometric state with splendid metastatic, it is suitable for the cold shifting process of wet method, it prepares simply, cost is relatively low.

Description

A kind of reactive dye intaglio printing ink and preparation method thereof
Technical field
The present invention relates to chemical ink fields, and in particular to a kind of reactive dye intaglio printing ink and preparation method thereof.
Background technology
The method that dyestuff carries out stamp to textile fabric is broadly divided into three categories in dyeing at present, and one kind is up to ten The dye paste PLATE SCREAM PRINTING or rotary scream printing of several chromatographys；It is another kind of be dye ink transfer printing (including thermal transfer printing and Cold-transfer printing)；Also one kind is that dye ink is ink-jet printed.
Dye paste PLATE SCREAM PRINTING or rotary scream printing are a kind of traditional printing methods, have technological process shorter, produce The advantages that processing cost is relatively low, but there is also the variations of decalcomania color hierarchy not to enrich, some dye fixing rates are not high, water Loose colour is more during washing, they washing when largely enter in rinsing solution, cause discharge of wastewater exceeded, at the same these not by Dyestuff that fixation is fallen even can also stain printed textile in vain, cause printed textile product there are quality problems etc. to lack Point.
Dye ink transfer printing is a kind of novel printing method, at present mainly include disperse dyes to dacron, To the cold-transfer printing of cotton fabric, they become with decalcomania color hierarchy for the thermal transfer printing of nylon fabric and reactive dye Change abundant, less energy consumption during dye fixing, dye fixing rate is higher, and loose colour is less in water-washing process, it is possible to reduce discharge of wastewater, together When these are not greatly reduced the white ground contamination of printed textile by the dyestuff that fixation is fallen, so as to reduce printed textile Product quality problem the advantages that.
Ink used in traditional activated wet transfer printing has disadvantages that such as perishable, concentration is not high, can only printing paper Deng.It is unlikely to deteriorate because the invention is a kind of, concentration is high, the reactive dye intaglio printing ink demand of environmental protection is increasingly urgent.
Invention content
The first technical problem to be solved by the present invention be to provide it is a kind of be unlikely to deteriorate, concentration is high, the reactive dye of environmental protection Gravure ink.
The second technical problem to be solved by the present invention is to provide a kind of method for preparing the reactive dye intaglio printing ink.
The present invention seeks to what is be achieved through the following technical solutions：
The present invention provides a kind of reactive dye intaglio printing inks, are prepared by the raw material of following weight percentage：Activity Dyestuff 25-35%, binder 20-30%, organic solvent 10-30%, antifoaming agent 0.3-0.5%, surplus are water.
Preferably, the reactive dye are K-type reactive dye, M types reactive dye or p-type reactive dye.
Preferably, the binder is selected from oxidized starch, acidified starch, cationic starch, hydroxyethyl starch, starch vinegar One or more mixtures in acid esters, starch phosphate, dialdehyde starch, crosslinked starch, carboxymethyl starch, sodium alginate.
It is highly preferred that the binder is by 40-60wt% sodium carboxymethyl starches and 40-60wt% hydroxyethyl starch groups Into.
Preferably, the organic solvent is selected from toluene, ketone system organic solvent (such as acetone, methyl ethyl ketone, methyl-isobutyl Ketone etc.), ester system organic solvent (such as methyl acetate, ethyl acetate, n-propyl acetate, n-butyl acetate, isobutyl acetate etc.), Alcohol system organic solvent (such as methanol, ethyl alcohol, butanol etc.), it is one or more in hydrocarbon system solvent (toluene, hexahydrotoluene etc.) Mixture.
It is highly preferred that the organic solvent is ethyl alcohol.
Preferably, the antifoaming agent is selected from dimethyl silicone polymer, cyclomethicone, amino silicone, poly- methyl One or more mixtures in phenyl siloxane.
The present invention also provides the preparation methods of the reactive dye intaglio printing ink, include the following steps：
(1) mill base is prepared：It by organic solvent, water, binder, antifoaming agent and reactive dye, is uniformly mixed, obtains color Slurry；
(2) mill base is ground：By the mill base, it is placed in ball mill and grinds.
Compared with prior art, the present invention with following remarkable advantage：
1st, due to mainly deionized water and organic solvent being used to make solvent so that ink and Special Film printing adaptability are good It is good；
2nd, the present invention is not only the gravure ink of high quality, and be printed in the reactive dye on Special Film in hygrometric state With splendid metastatic, it is suitable for the cold shifting process of wet method；
3rd, it prepares simply, cost is relatively low.
Specific embodiment
Each raw material introduction of embodiment：
Reactive dye are K-type reactive dye, using the model K- of Jiangsu Shenxin Dyeing Material Chemical Co., Ltd's production The active light yellow dye of 6G.
Hydroxyethyl starch, No. CAS：9005-27-0, using the model kono of Xi'an Kang Nuo Chemical Co., Ltd.s production Hydroxyethyl starch.
Sodium carboxymethyl starch, No. CAS：9063-38-1 can be prepared or is commercially available, and be had using swallow Xinghua, Hebei work The sodium carboxymethyl starch of limit company production.
Antifoaming agent use dimethyl silicone polymer, No. CAS：63148-62-9.
Organic solvent use ethyl alcohol, No. CAS：64-17-5.
Embodiment 1
Reactive dye intaglio printing ink is prepared by the raw material of following weight percentage：K-type reactive dye 30%, carboxylic first Base sodium starch 12%, hydroxyethyl starch 12%, ethyl alcohol 15%, dimethyl silicone polymer 0.4%, deionized water 30.6%.
The preparation method of reactive dye intaglio printing ink, includes the following steps：
(1) mill base is prepared：First ethyl alcohol and deionized water are placed in blender, 8min is stirred, in 30 degree of temperature, rotating speed Binder is slowly added at 300 revs/min, until binder is completely dissolved, dimethyl silicone polymer is added in and is stirred as antifoaming agent 8min adds K-type reactive dye, and blender rotating speed is increased to 1300 revs/min, stirs 40 minutes, and control viscosity is to 900 lis Pool, i.e., 40 degree.
(2) mill base is ground：It by the mill base obtained by step (1), is placed in ball mill and grinds, keep grinding 48 hours, make color Fineness is starched to 0.6 micron, control viscosity was to 80 seconds, i.e., Zang Shi 2# glasss, 30 degree.
Embodiment 2
Reactive dye intaglio printing ink is prepared by the raw material of following weight percentage：K-type reactive dye 30%, carboxylic first Base sodium starch 24%, ethyl alcohol 15%, dimethyl silicone polymer 0.4%, deionized water 30.6%.
Reactive dye intaglio printing ink is prepared as described in Example 1.
Embodiment 3
Reactive dye intaglio printing ink is prepared by the raw material of following weight percentage：K-type reactive dye 30%, hydroxyl second Base starch 24%, ethyl alcohol 15%, dimethyl silicone polymer 0.4%, deionized water 30.6%.
Reactive dye intaglio printing ink is prepared as described in Example 1.
Test case 1
The reactive dye intaglio printing ink prepared using embodiment 1-3 carries out stamp to jeans.Specifically printing technology is： Designed flower pattern using numerial code spray drawing stamp, numerial code spray drawing is will to be input to calculating by the image that digitizing technique is handled Machine contaminates activity after computer color separation in printing system (CAD) editing and processing, then by special-purpose software (RIP) control sprayed printed system Expect that the direct spray printing of gravure ink forms pattern to PET film, transfer printing PET film is made；The white embryo cloth after starching (is adopted again The yarn count 24 × 24 produced with Hua Weibu industry Co., Ltd of Changyi City, density 68 × 63,140g/m2, the cotton of breadth 63-105 Embryo cloth) with transfer printing PET film it is sent into padding machine pressurization, 160 DEG C of temperature, 3 minutes time, in the white embryo cloth after starching simultaneously Obtain decalcomania.Concrete outcome is shown in Table 1：
Table 1：Jeans technical parameter result
Embodiment 1 Embodiment 2 Embodiment 3
Degree of fixation 94% 86% 84%
K/S values 1.8 1.4 1.3
Washing color fastness 5 grades 4 grades 4 grades
Colour fastness to rubbing 5 grades 4 grades 3 grades
Can significantly it be found out by table 1, jeans matter is made in embodiment 1 (sodium carboxymethyl starch and hydroxyethyl starch compounding) Amount is more excellent than the jeans quality of embodiment 2-3 (single raw material in sodium carboxymethyl starch and hydroxyethyl starch).

Claims (3)

1. a kind of reactive dye intaglio printing ink is prepared by the raw material of following weight percentage：Reactive dye 25-35%, even Splicing 20-30%, organic solvent 10-30%, antifoaming agent 0.3-0.5%, surplus are water；
The binder is made of 40-60wt% sodium carboxymethyl starches and 40-60wt% hydroxyethyl starch；
The reactive dye are K-type reactive dye, M types reactive dye or p-type reactive dye；
The organic solvent is ethyl alcohol.
2. reactive dye intaglio printing ink as described in claim 1, which is characterized in that the antifoaming agent is selected from poly dimethyl silicon One or more mixtures in oxygen alkane, cyclomethicone, amino silicone, polymethylphenylsiloxane.
3. the preparation method of reactive dye intaglio printing ink as described in any one of claim 1-2, which is characterized in that including following Step：
(1) it by organic solvent, water, binder, antifoaming agent and reactive dye, is uniformly mixed, obtains mill base；
(2) it by the mill base, is placed in ball mill and grinds.
CN201610035280.9A 2016-01-19 2016-01-19 A kind of reactive dye intaglio printing ink and preparation method thereof Expired - Fee Related CN105482543B (en)

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CN201810587122.3A CN108976897A (en) 2016-01-19 2016-01-19 A kind of jeans printing technology

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CN107868513A (en) * 2017-12-08 2018-04-03 马鞍山虹润彩印有限责任公司 A kind of flame-proof antibiotic ink for plastic printing

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101104756A (en) * 2007-07-24 2008-01-16 王勇 Reactive dye intaglio printing ink and preparation method thereof

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CN102304862B (en) * 2011-07-15 2013-03-20 北京印月明印染新技术有限公司 Printing technology for pure cotton or polyester-cotton jean

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Publication number Priority date Publication date Assignee Title
CN101104756A (en) * 2007-07-24 2008-01-16 王勇 Reactive dye intaglio printing ink and preparation method thereof

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Effective date of registration: 20180604

Address after: 415000 2 Road, 8 Industrial Zone, Xin'an community, Dongjiang street, Wuling, Changde, Hunan

Applicant after: Hunan Yingkun Ink Chemical Product Co., Ltd.

Address before: 201107 T158 twenty-second, 1-30 Lane 88, min Bei Road, Minhang District, Shanghai.

Applicant before: Shanghai Wanjing Textile Technology Co., Ltd.

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Granted publication date: 20180710

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