CN106758373A - A kind of digit printing transfer printing process - Google Patents
A kind of digit printing transfer printing process Download PDFInfo
- Publication number
- CN106758373A CN106758373A CN201611162626.8A CN201611162626A CN106758373A CN 106758373 A CN106758373 A CN 106758373A CN 201611162626 A CN201611162626 A CN 201611162626A CN 106758373 A CN106758373 A CN 106758373A
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- Prior art keywords
- printing
- reactive dye
- digit
- fabric
- transfer printing
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5292—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of digit printing transfer printing process, comprise the following steps:(1) starching:Fabric is pre-processed with slurry;(2) stamp:The direct spray printing of reactive dye intaglio printing ink to PET film is formed into pattern, then the pattern in PET film is transferred to the fabric after starching;(3) evaporate.Digit printing transfer printing process of the present invention, the direct spray printing of reactive dye intaglio printing ink that will be prepared to PET film forms pattern, then the pattern in PET film is transferred into the fabric after starching, simple to operate, and printing quality is good, and pattern is exquisite.
Description
Technical field
The present invention relates to garment industry, and in particular to a kind of digit printing transfer printing process.
Background technology
Pigment or dye print on paper, rubber or other carriers, then bat printing prints to title transfer on commodity to be printed
Flower, but the bat printing technology for printing and meaning and make carrier with knitted fabric and textile is shifted for narrow sense.Transfer printing is mainly used in polyester fiber
On product, with the raising of trans-printing art, in nylon, acrylonitrile, cotton, fiber crops are also widely used on woolen knitwear.Transfer printing
The diversified forms such as fabric (cloth) point wet method, dry method, steaming process, vacuum method, hot method.Transfer printing method can accurately reproduce figure
Case, is easy to mechanization production, and process is simple, and especially stamp aftertreatment technology is simpler than traditional dyeing and finishing and stamp feel and print
Dye is identical, thus has the gesture for progressively substituting old method stamp greatly.But traditional dyeing and finishing method is still used mostly in most of printing and dyeing mills of China
Carry out, only a small number of production units are produced using transfer printing.Digit printing printing technique is divided to two kinds, and a kind of number is directly
Stamp, is, by means such as scanner, digital camera, digital cameras, to be input into digital form the pattern of stamp is needed
Computer, forms required pattern, then control spray drawing machine dyestuff by special RIP softwares by patterning software system editing and processing
(activity, acid, dispersion) directly spray printing, on textile, forms printing in textiles.Another kind is thermal transfer printing, with containing point
Class dyestuff and the printing-ink impressing pattern on paper are dissipated, during then calico paper storage with standby stamp, fabric is passed through heat and is turned
Printing machine is moved, transfer paper and non-stamp is sticked together face-to-face, by machine under conditions of about 210 DEG C, so, transfer
Dye sublimation on paper is simultaneously transferred on fabric, completes stamp.Digital ink-jet fabric printing technique and Conventional decal technology phase
Than digit printing high precision, can realize individual electronic business consumption without plate-making batch flexibly by internet, go out sample
Reappearance is high, and floor space saves labour less, simple to operate, and order speed is fast, and product quality is high, and production lot is unrestricted,
The advantages of production process low energy consumption, directly facilitate the development of " textile of green " and " green manufacturing ".Thus, its appearance is complete
It is complete to have reformed idea of the people on textile production, sale and consumption, the generation of 21 century textile industry technological revolution will be turned into
Table, promotes textile to be strided forward to ecology, digitlization, functionalization and personalization, realizes the sustainable development of textile industry.Shortcoming
Spray printing speed many compared to slow with Conventional decal machine, ink it is relatively costly, be not suitable for large batch of production.Following development
It is to be drawn a design using timesaving digital printer, small lot batch manufacture, then Conventional decal machine of arranging in pairs or groups is produced in enormous quantities, from
And effectively produce, obtain more golden eggs.Digital jet printing is a system engineering, is related to cad technique, network service skill
The frontier science and technology such as art, precise machine machining and fine chemical technology, are the tradition such as information technology and machinery, weaving and chemical industry
The product of technological incorporation.The production process of digit printing be exactly briefly by various digitlization means such as:Scanning, digital phase
The various digitlization patterns input computer that piece, image or computing mechanism deal with, then processed by computer color splitting printing system
Afterwards, various dedicated dyes (activity, dispersion, acid main coating) are directly sprayed by its sprayed printed system by special RIP softwares
Print on various fabrics or other media, then it is various high-precision needed for after processing, being obtained on various weaving face fabrics
The Printing of degree.The invention provides a kind of digit printing transfer printing process, printing quality is high, pollution is few.
The content of the invention
For above shortcomings in the prior art, the technical problems to be solved by the invention are to provide a kind of digital print
Flower transfer printing process.
The present invention seeks to what is be achieved through the following technical solutions:
A kind of digit printing transfer printing process, comprises the following steps:
(1) starching:Fabric is pre-processed with slurry;
(2) stamp:The direct spray printing of reactive dye intaglio printing ink to PET film is formed into pattern, then the pattern in PET film is turned
Print to the fabric after starching;
(3) evaporate.
Reactive dye intaglio printing ink in the step (2) is prepared from by the raw material of following weight percentage:
Reactive dye 28-32%, binder 22-28%, organic solvent 12-28%, dimethicone 0.3-0.5% are balance of
Water.
Preferably, described reactive dye are K-type reactive dye, M types reactive dye or p-type reactive dye.
Preferably, described organic solvent is acetone, ethyl acetate, propyl acetate, butyl acetate, ethanol, 1,2- the third two
One or more of mixture in alcohol, 1,3- propane diols, butanol, toluene.
It is highly preferred that described organic solvent is mixed by ethanol, 1,2-PD, 1,3-PD, the ethanol,
1,2- propane diols, the mass ratio of 1,3- propane diols are (1-3):(1-3):(1-3).
Preferably, described binder is in sodium carboxymethyl starch, hydroxypropul starch, CMS, sodium alginate
One or more of mixture.
It is highly preferred that described binder is by 40-60wt% sodium carboxymethyl starches and 40-60wt% hydroxypropul starch groups
Into.
The reactive dye intaglio printing ink comprises the following steps preparation:By organic solvent, water, binder, dimethicone
And reactive dye, it is uniformly mixed, obtain mill base;By the mill base, it is placed in ball mill and grinds.
Preferably, the slurry in the step (1) includes that the raw material of following weight percentage is prepared from:
Printing gum 1-5%, reserve salt 0.5-2%, glauber salt 1-5%, urea 6-10%, sodium bicarbonate 1-3%, balance of water.
The preparation method of the slurry is:By water, printing gum, reserve salt, glauber salt, urea and sodium bicarbonate, stirring is mixed
Close uniform.
Preferably, the step (3) evaporates 95-110 DEG C of temperature, time 6-9 minutes.
Preferably, the fabric is formed by 40-60wt% strings and 40-60wt% Europe root weaving yarns.
Preferably, the string includes Modal fibre, cotton fiber, bamboo fibre, flax fiber;
The Europe root yarn includes terylene, nylon, artificial silk, mulberry silk.
Digit printing transfer printing process of the present invention, the direct spray printing of reactive dye intaglio printing ink that will be prepared to PET film shape
Into pattern, then the pattern in PET film is transferred to the fabric after starching, simple to operate, printing quality is good, pattern essence
Cause.
Specific embodiment
Each raw material introduction of embodiment:
Reactive dye are K-type reactive dye, the model K-2G's produced using Jiangsu Shenxin Dyeing Material Chemical Co., Ltd
Active Red Dye.
Hydroxypropul starch, No. CAS:9049-76-7, the hydroxypropyl produced using Luohe HR Chemical Industry Co., Ltd. is formed sediment
Powder.
Sodium carboxymethyl starch, No. CAS:9063-38-1, can prepare or be commercially available, and be had using swallow Xinghua, Hebei work
The sodium carboxymethyl starch of limit company production.
Dimethicone, No. CAS:63148-62-9.
Ethanol, No. CAS:64-17-5.
1,2-PD, No. CAS:57-55-6.
1,3-PD, No. CAS:504-63-2.
Printing gum refers to be added in print paste the macromolecular compound that can play thickening power.Printing gum is being added to
Before print paste, be generally dissolved in water or in water abundant swelling and scattered hydrophilic macromolecule stiff colloidal solution or
It is oil/water type or when water/oil type emulsion thickening is modulated into print paste, a part of dyestuff is dissolved in water, and another part dyestuff is then
In dissolving, adsorb or being dispersed in the former paste of stamp.Composition printing gum is the key component of print paste, and it decides that stamp is operated
Performance, surface tinctorial yield, finish of decorative pattern profile of dyestuff etc..
In embodiment, printing gum selects thickener DGT-6, the specific number using the production of Shanghai Di Ling Chemical Co., Ltd.s
Active starching thickener DGT-6.Reserve salt uses m-nitrobenzene sodium sulfonate, No. CAS:127-68-4, it is specific to use Shangyu city Hai Li
The reservehao S of Chemical Co., Ltd.'s production.Glauber salt, No. CAS:7757-82-6, is produced using Shandong Lu Qiu salinization Co., Ltd
Model
Primes, granularity is the glauber salt of the mesh of crystallite 400.Urea, No. CAS:57-13-6, using the Anhui Huaihe River limited public affairs of share
Take charge of the industrial urea of production.Sodium bicarbonate, No. CAS:144-55-8, use Weifang Hai Zhiyuan Chemical Co., Ltd.s produce granularity for
The industrial grade saleratus of 120-170 mesh.Fabric:Warp thread is that flax fiber (uses flax fiber, a diameter of 7.0 μm, fiber number is
155dtex), weft yarn is terylene Europe root yarn (using terylene Europe root yarn, a diameter of 14.55 μm, fiber number is 180dtex), using normal
Rule technique weaving obtains base fabric, and wherein warp count is 12/cm, and weft count is 14/cm.
Embodiment 1
Digit printing transfer printing process (that is, weaving face fabric number transfer printing process), comprises the following steps:
(1) starching:Fabric is soaked with slurry, temperature is 60 DEG C, and the time is 30min, then dried at 100 DEG C;
(2) stamp:The flower pattern for designing is used numerial code spray drawing stamp, numerial code spray drawing is the figure that will be processed by digitizing technique
As being input to computer, by after computer color separation in printing system (CAD) editing and processing, then spray printing is controlled by special-purpose software (RIP)
The direct spray printing of reactive dye intaglio printing ink to PET film is formed pattern by system, is made transfer printing PET film;Again by starching
Fabric afterwards sends into padding machine pressurization, 160 DEG C of temperature, 3 minutes time, the fabric after starching with transfer printing PET film simultaneously
On obtain decalcomania, the reactive dye intaglio printing ink rate of transform is 96%;
(3) evaporate:100 DEG C of temperature is evaporated, 8 minutes time, the printcloth of embodiment 1 is obtained.
Slurry in the step (1) includes that the raw material of following weight percentage is prepared from:Thickener DGT-62%, resist printing
Salt S1%, glauber salt 2%, urea 8%, sodium bicarbonate 2%, water 85%.
The preparation method of slurry is:In order to thickener DGT-6 is sequentially added in water, reservehao S, glauber salt, urea is small
Soda, a kind of lower raw material is added after every sample raw material beats, and PH to 8.5 is adjusted with tertiary sodium phosphate, checks slurry without obvious
After grain, then place 2 hours, allow each raw material to be well mixed, it is ensured that slurry has good homogeneity.
The reactive dye intaglio printing ink, is prepared from by the raw material of following weight percentage:K-type reactive dye 30%,
Sodium carboxymethyl starch 12%, hydroxypropul starch 12%, organic solvent 15%, dimethicone 0.4%, deionized water 30.6%.
Described organic solvent is 1 according to mass ratio by ethanol, 1,2- propane diols, 1,3- propane diols:1:1 mixes.
The preparation method of reactive dye intaglio printing ink, it comprises the steps:
(1) mill base is prepared:First organic solvent and deionized water are placed in mixer, 8min is stirred, in 30 degree of temperature, rotating speed
Binder is slowly added at 300 revs/min, until binder is completely dissolved, adds dimethicone to stir 8min as defoamer,
K-type reactive dye are added, mixer rotating speed brings up to 1300 revs/min, stirs 40 minutes, control viscosity to 900 centipoises, i.e., 40
Degree.
(2) mill base grinding:By the mill base obtained by step (1), it is placed in ball mill and grinds, keep grinding 48 hours, makes color
Slurry fineness controls viscosity to 80 seconds, i.e., Zang Shi 2# glasss, 30 degree to 0.6 micron.
Embodiment 2
It is substantially the same manner as Example 1, differ only in, wherein reactive dye intaglio printing ink, by the original of following weight percentage
Material is prepared from:K-type reactive dye 30%, sodium carboxymethyl starch 24%, organic solvent 15%, dimethicone 0.4%, go from
Sub- water 30.6%, described organic solvent is 1 according to mass ratio by ethanol, 1,2-PD, 1,3-PD:1:1 mixing and
Into.Obtain the printcloth of embodiment 2.The reactive dye intaglio printing ink rate of transform is 92%.
Embodiment 3
It is substantially the same manner as Example 1, differ only in, wherein reactive dye intaglio printing ink, by the original of following weight percentage
Material is prepared from:K-type reactive dye 30%, hydroxypropul starch 24%, organic solvent 15%, dimethicone 0.4%, deionization
Water 30.6%, described organic solvent is 1 according to mass ratio by ethanol, 1,2-PD, 1,3-PD:1:1 mixes.
Obtain the printcloth of embodiment 3.
The reactive dye intaglio printing ink rate of transform is 91%.
Embodiment 4
It is substantially the same manner as Example 1, differ only in, the reactive dye intaglio printing ink, by the original of following weight percentage
Material is prepared from:K-type reactive dye 30%, sodium carboxymethyl starch 12%, hydroxypropul starch 12%, organic solvent 15%, diformazan
Base silicone oil 0.4%, deionized water 30.6%.Described organic solvent is 1 according to mass ratio by ethanol and 1,2- propane diols:1 mixes
Conjunction is formed.
Obtain the printcloth of embodiment 4.The reactive dye intaglio printing ink rate of transform is 93%.
Embodiment 5
It is substantially the same manner as Example 1, differ only in, the reactive dye intaglio printing ink, by the original of following weight percentage
Material is prepared from:K-type reactive dye 30%, sodium carboxymethyl starch 12%, hydroxypropul starch 12%, organic solvent 15%, diformazan
Base silicone oil 0.4%, deionized water 30.6%.Described organic solvent is 1 according to mass ratio by ethanol and 1,3- propane diols:1 mixes
Conjunction is formed.Obtain the printcloth of embodiment 5.The reactive dye intaglio printing ink rate of transform is 93%.
Embodiment 6
It is substantially the same manner as Example 1, differ only in, the reactive dye intaglio printing ink, by the original of following weight percentage
Material is prepared from:K-type reactive dye 30%, sodium carboxymethyl starch 12%, hydroxypropul starch 12%, organic solvent 15%, diformazan
Base silicone oil 0.4%, deionized water 30.6%.Described organic solvent is by 1,2- propane diols and 1,3- propane diols according to mass ratio
It is 1:1 mixes.Obtain the printcloth of embodiment 6.The reactive dye intaglio printing ink rate of transform is 92%.
Test case 1
Quality test is carried out to printcloth obtained in embodiment 1-6, can significantly be found out, (the sodium carboxymethyl starch of embodiment 1
Compounded with hydroxypropul starch) printcloth quality is obtained than embodiment 2-3 (single originals in sodium carboxymethyl starch and hydroxypropul starch
Material) jeans quality it is more excellent.Embodiment 1 (ethanol, 1,2- propane diols, 1,3- propane diols compounding) is obtained printcloth mass ratio
The jeans quality of embodiment 4-6 (any the two compounding in ethanol, 1,2- propane diols, 1,3- propane diols) is more excellent.
Embodiment 1 (sodium carboxymethyl starch and hydroxypropul starch compound) the reactive dye intaglio printing ink rate of transform is apparently higher than reality
Apply a 2-3 (single raw material in sodium carboxymethyl starch and hydroxypropul starch).Embodiment 1 (ethanol, 1- propyl alcohol, 2- propyl alcohol compounding) is living
Property the dye intaglio printing ink rate of transform apparently higher than embodiment 4-6 (in ethanol, 1- propyl alcohol, 2- propyl alcohol any the two compounding) cowboy
Trousers quality is more excellent.
Claims (6)
1. a kind of digit printing transfer printing process, comprises the following steps:
(1) starching:Fabric is pre-processed with slurry;
(2) stamp:The direct spray printing of reactive dye intaglio printing ink to PET film is formed into pattern, then the pattern in PET film is turned
Print to the fabric after starching;
(3) evaporate;
Reactive dye intaglio printing ink in the step (2) is prepared from by the raw material of following weight percentage:
Reactive dye 28-32%, binder 22-28%, organic solvent 12-28%, dimethicone 0.3-0.5% are balance of
Water;
Described organic solvent is mixed by ethanol, 1,2-PD, 1,3-PD, the ethanol, 1,2-PD, 1,
The mass ratio of ammediol is (1-3):(1-3):(1-3).
2. digit printing transfer printing process as claimed in claim 1, it is characterised in that described binder is by 40-60wt% carboxylic first
Base sodium starch and 40-60wt% hydroxypropul starch are constituted.
3. digit printing transfer printing process as claimed in claim 1 or 2, it is characterised in that reactive dye intaglio printing ink includes following
It is prepared by step:By organic solvent, water, binder, dimethicone and reactive dye, it is uniformly mixed, obtains mill base;By institute
Mill base is stated, is placed in ball mill and is ground.
4. digit printing transfer printing process as claimed in claim 1 or 2, it is characterised in that the slurry in the step (1) includes
The raw material of following weight percentage is prepared from:Printing gum 1-5%, reserve salt 0.5-2%, glauber salt 1-5%, urea 6-
10%, sodium bicarbonate 1-3%, balance of water.
5. digit printing transfer printing process as claimed in claim 4, it is characterised in that the preparation method of the slurry is:By water,
Printing gum, reserve salt, glauber salt, urea and sodium bicarbonate, are uniformly mixed.
6. digit printing transfer printing process as claimed in claim 1 or 2, it is characterised in that the fabric is by 40-60wt% plants
Fiber and 40-60wt% Europe root weaving yarns are formed.
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CN201611162626.8A CN106758373A (en) | 2016-12-15 | 2016-12-15 | A kind of digit printing transfer printing process |
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CN201611162626.8A CN106758373A (en) | 2016-12-15 | 2016-12-15 | A kind of digit printing transfer printing process |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108004815A (en) * | 2017-12-12 | 2018-05-08 | 东莞市财盛硅胶转印材料有限公司 | Silica gel ink is used in transfer |
CN108505369A (en) * | 2017-07-28 | 2018-09-07 | 海宁百越贸易有限公司 | The printing method of cotton fabric after improvement |
CN114775307A (en) * | 2022-05-25 | 2022-07-22 | 绍兴高肯数码纺织有限公司 | Green environment-friendly digital printing process |
-
2016
- 2016-12-15 CN CN201611162626.8A patent/CN106758373A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108505369A (en) * | 2017-07-28 | 2018-09-07 | 海宁百越贸易有限公司 | The printing method of cotton fabric after improvement |
CN108004815A (en) * | 2017-12-12 | 2018-05-08 | 东莞市财盛硅胶转印材料有限公司 | Silica gel ink is used in transfer |
CN114775307A (en) * | 2022-05-25 | 2022-07-22 | 绍兴高肯数码纺织有限公司 | Green environment-friendly digital printing process |
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Application publication date: 20170531 |