CN106758373A - A kind of digit printing transfer printing process - Google Patents

A kind of digit printing transfer printing process Download PDF

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Publication number
CN106758373A
CN106758373A CN201611162626.8A CN201611162626A CN106758373A CN 106758373 A CN106758373 A CN 106758373A CN 201611162626 A CN201611162626 A CN 201611162626A CN 106758373 A CN106758373 A CN 106758373A
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China
Prior art keywords
printing
reactive dye
digit
fabric
transfer printing
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CN201611162626.8A
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Chinese (zh)
Inventor
寿华君
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Individual
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Individual
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Priority to CN201611162626.8A priority Critical patent/CN106758373A/en
Publication of CN106758373A publication Critical patent/CN106758373A/en
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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48Derivatives of carbohydrates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5264Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
    • D06P1/5292Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003Transfer printing

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a kind of digit printing transfer printing process, comprise the following steps:(1) starching:Fabric is pre-processed with slurry;(2) stamp:The direct spray printing of reactive dye intaglio printing ink to PET film is formed into pattern, then the pattern in PET film is transferred to the fabric after starching;(3) evaporate.Digit printing transfer printing process of the present invention, the direct spray printing of reactive dye intaglio printing ink that will be prepared to PET film forms pattern, then the pattern in PET film is transferred into the fabric after starching, simple to operate, and printing quality is good, and pattern is exquisite.

Description

A kind of digit printing transfer printing process
Technical field
The present invention relates to garment industry, and in particular to a kind of digit printing transfer printing process.
Background technology
Pigment or dye print on paper, rubber or other carriers, then bat printing prints to title transfer on commodity to be printed Flower, but the bat printing technology for printing and meaning and make carrier with knitted fabric and textile is shifted for narrow sense.Transfer printing is mainly used in polyester fiber On product, with the raising of trans-printing art, in nylon, acrylonitrile, cotton, fiber crops are also widely used on woolen knitwear.Transfer printing The diversified forms such as fabric (cloth) point wet method, dry method, steaming process, vacuum method, hot method.Transfer printing method can accurately reproduce figure Case, is easy to mechanization production, and process is simple, and especially stamp aftertreatment technology is simpler than traditional dyeing and finishing and stamp feel and print Dye is identical, thus has the gesture for progressively substituting old method stamp greatly.But traditional dyeing and finishing method is still used mostly in most of printing and dyeing mills of China Carry out, only a small number of production units are produced using transfer printing.Digit printing printing technique is divided to two kinds, and a kind of number is directly Stamp, is, by means such as scanner, digital camera, digital cameras, to be input into digital form the pattern of stamp is needed Computer, forms required pattern, then control spray drawing machine dyestuff by special RIP softwares by patterning software system editing and processing (activity, acid, dispersion) directly spray printing, on textile, forms printing in textiles.Another kind is thermal transfer printing, with containing point Class dyestuff and the printing-ink impressing pattern on paper are dissipated, during then calico paper storage with standby stamp, fabric is passed through heat and is turned Printing machine is moved, transfer paper and non-stamp is sticked together face-to-face, by machine under conditions of about 210 DEG C, so, transfer Dye sublimation on paper is simultaneously transferred on fabric, completes stamp.Digital ink-jet fabric printing technique and Conventional decal technology phase Than digit printing high precision, can realize individual electronic business consumption without plate-making batch flexibly by internet, go out sample Reappearance is high, and floor space saves labour less, simple to operate, and order speed is fast, and product quality is high, and production lot is unrestricted, The advantages of production process low energy consumption, directly facilitate the development of " textile of green " and " green manufacturing ".Thus, its appearance is complete It is complete to have reformed idea of the people on textile production, sale and consumption, the generation of 21 century textile industry technological revolution will be turned into Table, promotes textile to be strided forward to ecology, digitlization, functionalization and personalization, realizes the sustainable development of textile industry.Shortcoming Spray printing speed many compared to slow with Conventional decal machine, ink it is relatively costly, be not suitable for large batch of production.Following development It is to be drawn a design using timesaving digital printer, small lot batch manufacture, then Conventional decal machine of arranging in pairs or groups is produced in enormous quantities, from And effectively produce, obtain more golden eggs.Digital jet printing is a system engineering, is related to cad technique, network service skill The frontier science and technology such as art, precise machine machining and fine chemical technology, are the tradition such as information technology and machinery, weaving and chemical industry The product of technological incorporation.The production process of digit printing be exactly briefly by various digitlization means such as:Scanning, digital phase The various digitlization patterns input computer that piece, image or computing mechanism deal with, then processed by computer color splitting printing system Afterwards, various dedicated dyes (activity, dispersion, acid main coating) are directly sprayed by its sprayed printed system by special RIP softwares Print on various fabrics or other media, then it is various high-precision needed for after processing, being obtained on various weaving face fabrics The Printing of degree.The invention provides a kind of digit printing transfer printing process, printing quality is high, pollution is few.
The content of the invention
For above shortcomings in the prior art, the technical problems to be solved by the invention are to provide a kind of digital print Flower transfer printing process.
The present invention seeks to what is be achieved through the following technical solutions:
A kind of digit printing transfer printing process, comprises the following steps:
(1) starching:Fabric is pre-processed with slurry;
(2) stamp:The direct spray printing of reactive dye intaglio printing ink to PET film is formed into pattern, then the pattern in PET film is turned Print to the fabric after starching;
(3) evaporate.
Reactive dye intaglio printing ink in the step (2) is prepared from by the raw material of following weight percentage:
Reactive dye 28-32%, binder 22-28%, organic solvent 12-28%, dimethicone 0.3-0.5% are balance of Water.
Preferably, described reactive dye are K-type reactive dye, M types reactive dye or p-type reactive dye.
Preferably, described organic solvent is acetone, ethyl acetate, propyl acetate, butyl acetate, ethanol, 1,2- the third two One or more of mixture in alcohol, 1,3- propane diols, butanol, toluene.
It is highly preferred that described organic solvent is mixed by ethanol, 1,2-PD, 1,3-PD, the ethanol, 1,2- propane diols, the mass ratio of 1,3- propane diols are (1-3):(1-3):(1-3).
Preferably, described binder is in sodium carboxymethyl starch, hydroxypropul starch, CMS, sodium alginate One or more of mixture.
It is highly preferred that described binder is by 40-60wt% sodium carboxymethyl starches and 40-60wt% hydroxypropul starch groups Into.
The reactive dye intaglio printing ink comprises the following steps preparation:By organic solvent, water, binder, dimethicone And reactive dye, it is uniformly mixed, obtain mill base;By the mill base, it is placed in ball mill and grinds.
Preferably, the slurry in the step (1) includes that the raw material of following weight percentage is prepared from:
Printing gum 1-5%, reserve salt 0.5-2%, glauber salt 1-5%, urea 6-10%, sodium bicarbonate 1-3%, balance of water.
The preparation method of the slurry is:By water, printing gum, reserve salt, glauber salt, urea and sodium bicarbonate, stirring is mixed Close uniform.
Preferably, the step (3) evaporates 95-110 DEG C of temperature, time 6-9 minutes.
Preferably, the fabric is formed by 40-60wt% strings and 40-60wt% Europe root weaving yarns.
Preferably, the string includes Modal fibre, cotton fiber, bamboo fibre, flax fiber;
The Europe root yarn includes terylene, nylon, artificial silk, mulberry silk.
Digit printing transfer printing process of the present invention, the direct spray printing of reactive dye intaglio printing ink that will be prepared to PET film shape Into pattern, then the pattern in PET film is transferred to the fabric after starching, simple to operate, printing quality is good, pattern essence Cause.
Specific embodiment
Each raw material introduction of embodiment:
Reactive dye are K-type reactive dye, the model K-2G's produced using Jiangsu Shenxin Dyeing Material Chemical Co., Ltd Active Red Dye.
Hydroxypropul starch, No. CAS:9049-76-7, the hydroxypropyl produced using Luohe HR Chemical Industry Co., Ltd. is formed sediment Powder.
Sodium carboxymethyl starch, No. CAS:9063-38-1, can prepare or be commercially available, and be had using swallow Xinghua, Hebei work The sodium carboxymethyl starch of limit company production.
Dimethicone, No. CAS:63148-62-9.
Ethanol, No. CAS:64-17-5.
1,2-PD, No. CAS:57-55-6.
1,3-PD, No. CAS:504-63-2.
Printing gum refers to be added in print paste the macromolecular compound that can play thickening power.Printing gum is being added to Before print paste, be generally dissolved in water or in water abundant swelling and scattered hydrophilic macromolecule stiff colloidal solution or It is oil/water type or when water/oil type emulsion thickening is modulated into print paste, a part of dyestuff is dissolved in water, and another part dyestuff is then In dissolving, adsorb or being dispersed in the former paste of stamp.Composition printing gum is the key component of print paste, and it decides that stamp is operated Performance, surface tinctorial yield, finish of decorative pattern profile of dyestuff etc..
In embodiment, printing gum selects thickener DGT-6, the specific number using the production of Shanghai Di Ling Chemical Co., Ltd.s Active starching thickener DGT-6.Reserve salt uses m-nitrobenzene sodium sulfonate, No. CAS:127-68-4, it is specific to use Shangyu city Hai Li The reservehao S of Chemical Co., Ltd.'s production.Glauber salt, No. CAS:7757-82-6, is produced using Shandong Lu Qiu salinization Co., Ltd Model
Primes, granularity is the glauber salt of the mesh of crystallite 400.Urea, No. CAS:57-13-6, using the Anhui Huaihe River limited public affairs of share Take charge of the industrial urea of production.Sodium bicarbonate, No. CAS:144-55-8, use Weifang Hai Zhiyuan Chemical Co., Ltd.s produce granularity for The industrial grade saleratus of 120-170 mesh.Fabric:Warp thread is that flax fiber (uses flax fiber, a diameter of 7.0 μm, fiber number is 155dtex), weft yarn is terylene Europe root yarn (using terylene Europe root yarn, a diameter of 14.55 μm, fiber number is 180dtex), using normal Rule technique weaving obtains base fabric, and wherein warp count is 12/cm, and weft count is 14/cm.
Embodiment 1
Digit printing transfer printing process (that is, weaving face fabric number transfer printing process), comprises the following steps:
(1) starching:Fabric is soaked with slurry, temperature is 60 DEG C, and the time is 30min, then dried at 100 DEG C;
(2) stamp:The flower pattern for designing is used numerial code spray drawing stamp, numerial code spray drawing is the figure that will be processed by digitizing technique As being input to computer, by after computer color separation in printing system (CAD) editing and processing, then spray printing is controlled by special-purpose software (RIP) The direct spray printing of reactive dye intaglio printing ink to PET film is formed pattern by system, is made transfer printing PET film;Again by starching Fabric afterwards sends into padding machine pressurization, 160 DEG C of temperature, 3 minutes time, the fabric after starching with transfer printing PET film simultaneously On obtain decalcomania, the reactive dye intaglio printing ink rate of transform is 96%;
(3) evaporate:100 DEG C of temperature is evaporated, 8 minutes time, the printcloth of embodiment 1 is obtained.
Slurry in the step (1) includes that the raw material of following weight percentage is prepared from:Thickener DGT-62%, resist printing Salt S1%, glauber salt 2%, urea 8%, sodium bicarbonate 2%, water 85%.
The preparation method of slurry is:In order to thickener DGT-6 is sequentially added in water, reservehao S, glauber salt, urea is small Soda, a kind of lower raw material is added after every sample raw material beats, and PH to 8.5 is adjusted with tertiary sodium phosphate, checks slurry without obvious After grain, then place 2 hours, allow each raw material to be well mixed, it is ensured that slurry has good homogeneity.
The reactive dye intaglio printing ink, is prepared from by the raw material of following weight percentage:K-type reactive dye 30%, Sodium carboxymethyl starch 12%, hydroxypropul starch 12%, organic solvent 15%, dimethicone 0.4%, deionized water 30.6%.
Described organic solvent is 1 according to mass ratio by ethanol, 1,2- propane diols, 1,3- propane diols:1:1 mixes.
The preparation method of reactive dye intaglio printing ink, it comprises the steps:
(1) mill base is prepared:First organic solvent and deionized water are placed in mixer, 8min is stirred, in 30 degree of temperature, rotating speed Binder is slowly added at 300 revs/min, until binder is completely dissolved, adds dimethicone to stir 8min as defoamer, K-type reactive dye are added, mixer rotating speed brings up to 1300 revs/min, stirs 40 minutes, control viscosity to 900 centipoises, i.e., 40 Degree.
(2) mill base grinding:By the mill base obtained by step (1), it is placed in ball mill and grinds, keep grinding 48 hours, makes color Slurry fineness controls viscosity to 80 seconds, i.e., Zang Shi 2# glasss, 30 degree to 0.6 micron.
Embodiment 2
It is substantially the same manner as Example 1, differ only in, wherein reactive dye intaglio printing ink, by the original of following weight percentage Material is prepared from:K-type reactive dye 30%, sodium carboxymethyl starch 24%, organic solvent 15%, dimethicone 0.4%, go from Sub- water 30.6%, described organic solvent is 1 according to mass ratio by ethanol, 1,2-PD, 1,3-PD:1:1 mixing and Into.Obtain the printcloth of embodiment 2.The reactive dye intaglio printing ink rate of transform is 92%.
Embodiment 3
It is substantially the same manner as Example 1, differ only in, wherein reactive dye intaglio printing ink, by the original of following weight percentage Material is prepared from:K-type reactive dye 30%, hydroxypropul starch 24%, organic solvent 15%, dimethicone 0.4%, deionization Water 30.6%, described organic solvent is 1 according to mass ratio by ethanol, 1,2-PD, 1,3-PD:1:1 mixes. Obtain the printcloth of embodiment 3.
The reactive dye intaglio printing ink rate of transform is 91%.
Embodiment 4
It is substantially the same manner as Example 1, differ only in, the reactive dye intaglio printing ink, by the original of following weight percentage Material is prepared from:K-type reactive dye 30%, sodium carboxymethyl starch 12%, hydroxypropul starch 12%, organic solvent 15%, diformazan Base silicone oil 0.4%, deionized water 30.6%.Described organic solvent is 1 according to mass ratio by ethanol and 1,2- propane diols:1 mixes Conjunction is formed.
Obtain the printcloth of embodiment 4.The reactive dye intaglio printing ink rate of transform is 93%.
Embodiment 5
It is substantially the same manner as Example 1, differ only in, the reactive dye intaglio printing ink, by the original of following weight percentage Material is prepared from:K-type reactive dye 30%, sodium carboxymethyl starch 12%, hydroxypropul starch 12%, organic solvent 15%, diformazan Base silicone oil 0.4%, deionized water 30.6%.Described organic solvent is 1 according to mass ratio by ethanol and 1,3- propane diols:1 mixes Conjunction is formed.Obtain the printcloth of embodiment 5.The reactive dye intaglio printing ink rate of transform is 93%.
Embodiment 6
It is substantially the same manner as Example 1, differ only in, the reactive dye intaglio printing ink, by the original of following weight percentage Material is prepared from:K-type reactive dye 30%, sodium carboxymethyl starch 12%, hydroxypropul starch 12%, organic solvent 15%, diformazan Base silicone oil 0.4%, deionized water 30.6%.Described organic solvent is by 1,2- propane diols and 1,3- propane diols according to mass ratio It is 1:1 mixes.Obtain the printcloth of embodiment 6.The reactive dye intaglio printing ink rate of transform is 92%.
Test case 1
Quality test is carried out to printcloth obtained in embodiment 1-6, can significantly be found out, (the sodium carboxymethyl starch of embodiment 1 Compounded with hydroxypropul starch) printcloth quality is obtained than embodiment 2-3 (single originals in sodium carboxymethyl starch and hydroxypropul starch Material) jeans quality it is more excellent.Embodiment 1 (ethanol, 1,2- propane diols, 1,3- propane diols compounding) is obtained printcloth mass ratio The jeans quality of embodiment 4-6 (any the two compounding in ethanol, 1,2- propane diols, 1,3- propane diols) is more excellent.
Embodiment 1 (sodium carboxymethyl starch and hydroxypropul starch compound) the reactive dye intaglio printing ink rate of transform is apparently higher than reality Apply a 2-3 (single raw material in sodium carboxymethyl starch and hydroxypropul starch).Embodiment 1 (ethanol, 1- propyl alcohol, 2- propyl alcohol compounding) is living Property the dye intaglio printing ink rate of transform apparently higher than embodiment 4-6 (in ethanol, 1- propyl alcohol, 2- propyl alcohol any the two compounding) cowboy Trousers quality is more excellent.

Claims (6)

1. a kind of digit printing transfer printing process, comprises the following steps:
(1) starching:Fabric is pre-processed with slurry;
(2) stamp:The direct spray printing of reactive dye intaglio printing ink to PET film is formed into pattern, then the pattern in PET film is turned Print to the fabric after starching;
(3) evaporate;
Reactive dye intaglio printing ink in the step (2) is prepared from by the raw material of following weight percentage:
Reactive dye 28-32%, binder 22-28%, organic solvent 12-28%, dimethicone 0.3-0.5% are balance of Water;
Described organic solvent is mixed by ethanol, 1,2-PD, 1,3-PD, the ethanol, 1,2-PD, 1, The mass ratio of ammediol is (1-3):(1-3):(1-3).
2. digit printing transfer printing process as claimed in claim 1, it is characterised in that described binder is by 40-60wt% carboxylic first Base sodium starch and 40-60wt% hydroxypropul starch are constituted.
3. digit printing transfer printing process as claimed in claim 1 or 2, it is characterised in that reactive dye intaglio printing ink includes following It is prepared by step:By organic solvent, water, binder, dimethicone and reactive dye, it is uniformly mixed, obtains mill base;By institute Mill base is stated, is placed in ball mill and is ground.
4. digit printing transfer printing process as claimed in claim 1 or 2, it is characterised in that the slurry in the step (1) includes The raw material of following weight percentage is prepared from:Printing gum 1-5%, reserve salt 0.5-2%, glauber salt 1-5%, urea 6- 10%, sodium bicarbonate 1-3%, balance of water.
5. digit printing transfer printing process as claimed in claim 4, it is characterised in that the preparation method of the slurry is:By water, Printing gum, reserve salt, glauber salt, urea and sodium bicarbonate, are uniformly mixed.
6. digit printing transfer printing process as claimed in claim 1 or 2, it is characterised in that the fabric is by 40-60wt% plants Fiber and 40-60wt% Europe root weaving yarns are formed.
CN201611162626.8A 2016-12-15 2016-12-15 A kind of digit printing transfer printing process Pending CN106758373A (en)

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Application Number Priority Date Filing Date Title
CN201611162626.8A CN106758373A (en) 2016-12-15 2016-12-15 A kind of digit printing transfer printing process

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108004815A (en) * 2017-12-12 2018-05-08 东莞市财盛硅胶转印材料有限公司 Silica gel ink is used in transfer
CN108505369A (en) * 2017-07-28 2018-09-07 海宁百越贸易有限公司 The printing method of cotton fabric after improvement
CN114775307A (en) * 2022-05-25 2022-07-22 绍兴高肯数码纺织有限公司 Green environment-friendly digital printing process

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108505369A (en) * 2017-07-28 2018-09-07 海宁百越贸易有限公司 The printing method of cotton fabric after improvement
CN108004815A (en) * 2017-12-12 2018-05-08 东莞市财盛硅胶转印材料有限公司 Silica gel ink is used in transfer
CN114775307A (en) * 2022-05-25 2022-07-22 绍兴高肯数码纺织有限公司 Green environment-friendly digital printing process

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Application publication date: 20170531