CN105951484B - Wool fabric wet method transfer printing method - Google Patents
Wool fabric wet method transfer printing method Download PDFInfo
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- CN105951484B CN105951484B CN201610350014.5A CN201610350014A CN105951484B CN 105951484 B CN105951484 B CN 105951484B CN 201610350014 A CN201610350014 A CN 201610350014A CN 105951484 B CN105951484 B CN 105951484B
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- Prior art keywords
- wool fabric
- wool
- thin film
- printing
- transfer
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/39—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/14—Wool
- D06P3/16—Wool using acid dyes
Abstract
The invention discloses a kind of wool fabric wet method transfer printing methods, comprising the following steps: 1. utilizes prepared mill base, flower pattern is printed on the film by coating by the roller on intaglio press, printing thin film is made;The padding in slot of pretreatment fluid is filled 2. wool fabric is introduced into, 10~30 DEG C of one immersing and rolling of room temperature, the wool fabric soaked;3. 1. printing thin film that the wool fabric of 2. wetting that step obtains is obtained with step is fit together, into transfer device roll compacting, make the clear patterns on printing thin film is transferred to wool fabric surface;4. 3. wool fabric that step obtains is introduced continous way rapid steamer to carry out evaporating color development, conventional washing, drying are carried out after rapid steamer out.The present invention is by selecting suitable mill base and pretreatment fluid, and so as to realize the wet transfer printing of wool fabric, and flower pattern fineness is high, and decalcomania clear and natural, fastness is up to 3-4 grades or more.
Description
Technical field
The invention belongs to printing in textiles technical fields, and in particular to a kind of wool fabric wet method transfer printing method.
Background technique
Traditional wool fabric printing method generally comprises circle/PLATE SCREAM PRINTING, digital ink-jet printed and heat transfer printing.
Since wool fabric surface villus is long, network blocking is easily caused using circle/PLATE SCREAM PRINTING, reduction can only be taken in this way
Mesh number reduces color paste viscosity and improves, generally more rough so as to cause the flower pattern printed off, and is unable to complete careful flower pattern
Stamp, and stamp flaw caused by network blocking still not can avoid in producing.
Although digital ink-jet printed the problem of being able to solve flower pattern fineness, the villus of fabric surface are still easy to make
It is blocked at spray head, not only influences product quality, also cause production cost greatly improves (spray head price is too high).
Heat Transfer Printing can effectively solve the problem that the above problem, but there are fastness poor, organic solvent residual and height
The lower wool of temperature is easily driven plain to lose the disadvantages of wool product intrinsic lint sense.
Chinese patent literature CN101105006A discloses a kind of natural fiber and polyamide fibre wet method transfer printing method, this article
The acid dye inks for offering use include following components and weight ratio: acid dyes 15~20%, the polyamide resin as binder
Rouge 20~30%, ethyl alcohol 50~64%, defoaming agent 0.3~0.5%, levelling agent 0.3~0.5% as solvent;What the document used
Maceration extract includes following components and weight ratio: thickener 1~10%, surfactant 1~10%, as cosolvent glycerol 1~3%,
Alkaline agent 3~5%, remaining is water.Applicant has found by a large number of experiments: using the acid dye inks and maceration extract of the document
Carry out wet transfer printing to natural fibers such as silk, nylon has preferable effect really, but carries out to wool fabric wet
Method transfer printing is ineffective, and fastness is poor, the unintelligible nature of decalcomania.
Summary of the invention
The purpose of the present invention is to solve the above problem, provide a kind of fastness preferably, the wool of decalcomania clear and natural
Fabric wet method for transfer printing.
Realizing the technical solution of the object of the invention is: a kind of wool fabric wet method transfer printing method, comprising the following steps:
1. utilizing prepared mill base, flower pattern is printed on to the film by coating by the roller on intaglio press
On, printing thin film is made;
The padding in slot of pretreatment fluid is filled 2. wool fabric is introduced into, 10~30 DEG C of one immersing and rolling of room temperature passes through control
Pad the speed of service of pressure and padding machine control the moisture content of wool fabric be 50%~70%, the wool soaked is knitted
Object;
3. 1. printing thin film that the wool fabric of 2. wetting that step obtains is obtained with step is fit together, into turn
Printing equipment sets roll compacting, by controlling the speed of service and transfer pressure of wool fabric, makes the transfer of the clear patterns on printing thin film
To wool fabric surface;Out after transfer device, wool fabric is separated with printing thin film, by the independent clot of film after transfer, sheep
It is woolen then by tensionless dryer dry;
4. 3. wool fabric that step obtains is introduced continous way rapid steamer to carry out evaporating color development, and tight according to the technological requirements
Temperature and time is evaporated in lattice control, to ensure that acid dyes sufficiently reacts with wool fiber, carries out after rapid steamer out conventional
Washing, drying.
Above-mentioned steps 1. described in mill base be formulated by the component of following weight percentage: acid dyes 5%~25%,
Dispersing agent 5%~10%, thickener 20%~40%, non-silicon defoaming agent 0.5%~1%, wetting agent 0.5%~1%, remaining is water.
Above-mentioned acid dyes is nanoscale acid dyes, and the main component of dispersing agent is yin/nonionic surfactant, paste
Material is modified guar gum, and the main component of wetting agent is Siloxane-Oxyalkylene Copolymers polymer.
Above-mentioned steps 1. described in roller be electric carving roller, carving depth be 4~7.
Above-mentioned steps 2. described in pretreatment fluid be formulated by the component of following weight percentage: organic acid 2%~
5%, thickener 0.5%~3%, wool Toner 1%~3%, chelated dispersants 1%~3%, non-silicon defoaming agent 0.5%~1%, remaining is
Water.
The main component of above-mentioned organic acid is anionic polymer polymer, and thickener is modified guar gum, wool colouring
The main component of agent is sulfonamide macromolecule polyalcohol, and the main component of chelated dispersants is anionic surfactant.
Above-mentioned steps 2. described in pressure of padding be 0.2~0.6MPa, the speed of service of padding machine is 5~15m/min.
Above-mentioned steps 3. described in wool fabric the speed of service be 5~15m/min, transfer pressure be 0.5~1MPa.
Above-mentioned steps 4. described in rapid steamer be continous way rapid steamer, evaporate temperature be 101~105 DEG C, evaporate the time
For 30~60min.
The good effect that the present invention has: the present invention is by selecting suitable mill base and pretreatment fluid, so as to reality
The wet transfer printing of existing wool fabric, and flower pattern fineness is high, and decalcomania clear and natural, fastness is up to 3-4 grades or more.
Specific embodiment
(embodiment 1)
The wool fabric wet method transfer printing method of the present embodiment has follow steps:
1. flower pattern is carved on version cylinder according to depth difference, according to flower pattern needs using prepared mill base, by recessed
Flower pattern is printed on the film by coating by printing machine, and printing thin film is made.
The mill base that the present embodiment uses is formulated by the component of following weight percentage: acid dyes 15%, dispersing agent
6%, thickener 30%, non-silicon defoaming agent 0.5%, wetting agent 0.5% and water 48%.
Wherein, acid dyes derives from Huntsman company using nanoscale acid dyes;Dispersing agent using
Dispersing agent T, derives from Changzhou Hui Lan commerce and trade Co., Ltd, and main component is yin/nonionic surfactant;What thickener used
It is Gum-14, derives from sun,moon and star commerce and trade Co., Ltd, main component is modified guar gum;Non-silicon defoaming agent using
DM-7401, derives from dolantin chemical company, and main component is nonionic surfactant;Wetting agent is using HR-
8060, Hong Rui Chemical Co., Ltd. is derived from, main component is Siloxane-Oxyalkylene Copolymers polymer.
2. wool fabric to be introduced into padding in slot for the pretreatment fluid for filling that temperature is 15 DEG C, an immersing and rolling, control is padded
Pressure is 0.3MPa, and the speed of service of padding machine is 8m/min, and the moisture content of the wool fabric after roll compacting is 60%, is soaked
Wool fabric.
The pretreatment fluid that the present embodiment uses is formulated by the component of following weight percentage: organic acid 2.5%, thickener
2%, wool Toner 3%, chelated dispersants 1%, non-silicon defoaming agent 0.5% and water 91%.
Wherein, organic acid derives from dolantin chemical company using DM-2725, and main component is anion high score
Sub- polymer;Thickener derives from sun,moon and star commerce and trade Co., Ltd using Gum-14, and main component is modified cluster bean
Glue;Wool Toner derives from Shanghai Fang Ke Chemical Co., Ltd. using spinning section energy E, and main component is that sulfonamide is big
Molecularly Imprinted Polymer;Chelated dispersants derive from Shanghai Fu Bin Fine Chemical Co., Ltd, main component using SQ-113
For anionic surfactant;Non-silicon defoaming agent derives from dolantin chemical company using DM-7401, and main component is
Nonionic surfactant.
3. 1. printing thin film that the wool fabric of 2. wetting that step obtains is obtained with step is fit together, into turn
Printing equipment sets roll compacting, and the speed of service for controlling wool fabric is 8m/min, and transfer pressure 0.6MPa makes the pattern on printing thin film
Clearly it is transferred to wool fabric surface;Out after transfer device, wool fabric is separated with printing thin film, by the film list after transfer
Only clot, wool fabric then pass through tensionless dryer drying.
4. 3. wool fabric that step obtains is introduced continous way rapid steamer to carry out evaporating color development, evaporating technique is 102 DEG C
× 45min carries out conventional washing, drying to ensure that acid dyes sufficiently reacts with wool fiber out after rapid steamer.
Through detecting, the wool fabric fastness of the present embodiment is up to 3-4 grades or more, and decalcomania clear and natural.
Claims (3)
1. a kind of wool fabric wet method transfer printing method, it is characterised in that the following steps are included:
1. utilizing prepared mill base, flower pattern is printed on the film by coating by the roller on intaglio press, is made
At printing thin film;The mill base is formulated by the component of following weight percentage: acid dyes 5%~25%, dispersing agent 5%
~10%, thickener 20%~40%, non-silicon defoaming agent 0.5%~1%, wetting agent 0.5%~1%, remaining is water;
The padding in slot of pretreatment fluid is filled 2. wool fabric is introduced into, 10~30 DEG C of one immersing and rolling of room temperature is padded by control
Pressure and the speed of service of padding machine are 50%~70% come the moisture content for controlling wool fabric, the wool fabric soaked;Institute
The pretreatment fluid stated is formulated by the component of following weight percentage: organic acid 2%~5%, thickener 0.5%~3%, wool colouring
Agent 1%~3%, chelated dispersants 1%~3%, non-silicon defoaming agent 0.5%~1%, remaining is water;
3. 1. printing thin film that the wool fabric of 2. wetting that step obtains is obtained with step is fit together, filled into transfer
Roll compacting is set, by controlling the speed of service and transfer pressure of wool fabric, make the clear patterns on printing thin film is transferred to sheep
Woolen surface;Out after transfer device, wool fabric is separated with printing thin film, and by the independent clot of film after transfer, wool is knitted
Object then passes through tensionless dryer drying;
4. 3. wool fabric that step obtains is introduced continous way rapid steamer to carry out evaporating color development, and stringent control according to the technological requirements
System evaporates temperature and time, to ensure that acid dyes sufficiently reacts with wool fiber, carries out conventional water after rapid steamer out
It washes, dry.
2. wool fabric wet method transfer printing method according to claim 1, it is characterised in that: above-mentioned acid dyes is to receive
Meter level acid dyes, the main component of dispersing agent are yin/nonionic surfactant, and thickener is modified guar gum, wetting agent
Main component be Siloxane-Oxyalkylene Copolymers polymer.
3. wool fabric wet method transfer printing method according to claim 1, it is characterised in that: above-mentioned organic acid it is main
Ingredient is anionic polymer polymer, and thickener is modified guar gum, and the main component of wool Toner is that sulfonamide divides greatly
Sub- polymer, the main component of chelated dispersants are anionic surfactant.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610350014.5A CN105951484B (en) | 2016-05-24 | 2016-05-24 | Wool fabric wet method transfer printing method |
PCT/CN2016/106392 WO2017201989A1 (en) | 2016-05-24 | 2016-11-18 | Wet transfer printing method for wool fabric |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610350014.5A CN105951484B (en) | 2016-05-24 | 2016-05-24 | Wool fabric wet method transfer printing method |
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Publication Number | Publication Date |
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CN105951484A CN105951484A (en) | 2016-09-21 |
CN105951484B true CN105951484B (en) | 2019-07-12 |
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CN201610350014.5A Active CN105951484B (en) | 2016-05-24 | 2016-05-24 | Wool fabric wet method transfer printing method |
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CN (1) | CN105951484B (en) |
WO (1) | WO2017201989A1 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105951484B (en) * | 2016-05-24 | 2019-07-12 | 常州旭荣针织印染有限公司 | Wool fabric wet method transfer printing method |
CN106120405B (en) * | 2016-07-26 | 2019-11-01 | 常州旭荣针织印染有限公司 | Terylene fibre/cotton fibre mixed union wet method transfer printing method |
CN107083698B (en) * | 2017-04-07 | 2021-05-25 | 常州旭荣针织印染有限公司 | Padding liquid for wet transfer printing of chinlon fabric and its compounding process |
CN109024059B (en) * | 2018-07-27 | 2021-03-05 | 西安工程大学 | Processing method of wool short fiber wet felt |
CN113529329B (en) * | 2021-07-23 | 2023-02-24 | 河南凯华万洋新型建材有限公司 | Rock wool board plastic cutting production line |
CN114619778B (en) * | 2022-03-24 | 2023-09-22 | 绍兴泽瑞数控印花科技有限公司 | Wet transfer printing process and printing equipment for textile fabrics |
CN115559139A (en) * | 2022-09-16 | 2023-01-03 | 绍兴鸿瑞数字科技有限公司 | Non-steaming and non-washing transfer printing pretreatment process for pure cotton fabric |
Family Cites Families (11)
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DK520587D0 (en) * | 1987-10-05 | 1987-10-05 | Dansk Transfertryk | PROCEDURE FOR TRANSFER PRINTING A TEXTILE AND PATTERNS FOR USE BY THE PROCEDURE |
CN100560859C (en) * | 2007-07-24 | 2009-11-18 | 常州涵源新印花有限公司 | Natural fabric and polyamide fibre wet method transfer printing method |
TW201100605A (en) * | 2009-06-18 | 2011-01-01 | Full Color Co Ltd | Wet transfer printing method applied in cloth material |
CN102161850B (en) * | 2011-05-24 | 2013-12-04 | 常州涵源新印花有限公司 | Fabric pattern transfer ink and preparation method thereof |
CN102677492B (en) * | 2011-09-08 | 2014-02-19 | 沈翰宇 | Heat transfer digital printing method for natural fibers and regenerated cellulose fibers |
CN102926238A (en) * | 2012-11-16 | 2013-02-13 | 刘静 | Transfer method of fur quilt pattern |
CN102926237B (en) * | 2012-11-16 | 2014-08-13 | 常州涵源新印花有限公司 | Wetting liquid for fabric pattern transfer |
CN103015240B (en) * | 2012-12-21 | 2014-07-23 | 江苏鑫泰纺织有限公司 | Wet transfer printing method for nylon wool electrostatic flocking cloth |
CN105951484B (en) * | 2016-05-24 | 2019-07-12 | 常州旭荣针织印染有限公司 | Wool fabric wet method transfer printing method |
CN106012594B (en) * | 2016-06-24 | 2019-03-15 | 常州旭荣针织印染有限公司 | Milk protein fiber/cotton fiber union wet method transfer printing method |
CN106120405B (en) * | 2016-07-26 | 2019-11-01 | 常州旭荣针织印染有限公司 | Terylene fibre/cotton fibre mixed union wet method transfer printing method |
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2016
- 2016-05-24 CN CN201610350014.5A patent/CN105951484B/en active Active
- 2016-11-18 WO PCT/CN2016/106392 patent/WO2017201989A1/en active Application Filing
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WO2017201989A1 (en) | 2017-11-30 |
CN105951484A (en) | 2016-09-21 |
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