CN106120405B - Terylene fibre/cotton fibre mixed union wet method transfer printing method - Google Patents
Terylene fibre/cotton fibre mixed union wet method transfer printing method Download PDFInfo
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- CN106120405B CN106120405B CN201610593673.1A CN201610593673A CN106120405B CN 106120405 B CN106120405 B CN 106120405B CN 201610593673 A CN201610593673 A CN 201610593673A CN 106120405 B CN106120405 B CN 106120405B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5292—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
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- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/004—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using dispersed dyes
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- D06P3/008—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using reactive dyes
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- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8223—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
- D06P3/8238—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye
- D06P3/8252—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye using dispersed and reactive dyes
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Abstract
The invention discloses a kind of terylene fibre/cotton fibre mixed union wet method transfer printing methods, have follow steps: printing thin film is 1. made;2. the terylene fibre/cotton fibre mixed union soaked;3. the terylene fibre/cotton fibre mixed union of wetting is fit together with printing thin film, into transfer device roll compacting, make the clear patterns on printing thin film is transferred to terylene fibre/cotton fibre mixed union surface;Color development is evaporated 4. introducing continous way rapid steamer and carrying out two-part, carries out conventional washing, drying after rapid steamer out.The present invention is by selecting suitable mill base and pretreatment fluid, suitable disperse dyes and reactive dye are especially added in mill base, using same paste printing, and optimize and evaporate technique, so as to realize the wet transfer printing of terylene fibre/cotton fibre mixed union, not only color is saturated plentiful, decalcomania remarkable fluency, and product quality is controllable, soft, fastness is good, up to 3-4 grades or more.
Description
Technical field
The invention belongs to printing in textiles technical fields, and in particular to a kind of terylene fibre/cotton fibre mixed union wet process
Method for transfer printing.
Background technique
Dacron generally uses disperse dyes stamp in acid condition, and cotton fabric generally uses reactive dye in alkalinity
Under the conditions of stamp, production technology is very mature, occupies significant proportion in China's printing in textiles.But polyester fiber/cotton
Fiber woven fabric can not carry out stamp using single disperse dyes or reactive dye, and it is one of fine otherwise can only to go up dye
Dimension, and another fiber shows money or valuables one carries unintentionally, and cloth cover is caused to become fried dough twist color, and seriously affect the presentation quality of printed articles.
For the terylene fibre/cotton fibre mixed union above problem, it is fine using pigment printing print terylene to have document report
The problem of dimension/cotton fiber union, although this method is able to solve polyester fiber and cotton fiber while painting, but there are hands
The problems such as sense is hard, fastness is poor, and common flower pattern is also suitable only in terms of flower pattern expressive force, it is multiple that gradual change, moire etc. can not be showed
Miscellaneous effect.
Summary of the invention
The purpose of the present invention is to solve the above problem, and providing one kind, not only color saturation is plentiful, decalcomania is smooth certainly
So, and soft, the good terylene fibre/cotton fibre mixed union wet method transfer printing method of fastness.
Realizing the technical solution of above-mentioned purpose of the present invention is: a kind of terylene fibre/cotton fibre mixed union wet process transfer print
Flower method, has follow steps:
1. utilizing prepared mill base, flower pattern is printed on to the film by coating by the roller on intaglio press
On, printing thin film is made;
The padding in slot of pretreatment fluid is filled 2. terylene fibre/cotton fibre mixed union is introduced into, 10~30 DEG C one of room temperature
Immersing and rolling pads the speed of service of pressure and padding machine by control to control the aqueous of terylene fibre/cotton fibre mixed union
Rate is 70%~100%, the terylene fibre/cotton fibre mixed union soaked;
3. 1. printing thin film that the terylene fibre/cotton fibre mixed union of 2. wetting that step obtains and step are obtained pastes
It is combined, into transfer device roll compacting, is pressed by the speed of service and transfer that control terylene fibre/cotton fibre mixed union
Power, make the clear patterns on printing thin film is transferred to terylene fibre/cotton fibre mixed union surface;Out after transfer device, wash
Synthetic fibre fiber/cotton fiber union is separated with printing thin film, by the independent clot of film after transfer, terylene fibre/cotton fibre mixed friendship
Woven fabric then passes through tensionless dryer drying;
4. 3. terylene fibre/cotton fibre mixed union that step obtains is introduced continous way rapid steamer to carry out evaporating color development,
And temperature and time is evaporated according to two-part strict control according to the technological requirements, to ensure disperse dyes and polyester fiber, activity
Dyestuff sufficiently reacts with cotton fiber, carries out conventional washing, drying after rapid steamer out.
Above-mentioned steps 1. described in mill base be formulated by the component of following weight percentage: disperse dyes 3%~15%,
Reactive dye 3%~15%, sodium carbonate 2%~5%, sodium hydroxide 0.1%~1%, dispersing agent 5%~10%, thickener 20%~40%, non-silicon
Defoaming agent 0.5%~1%, wetting agent 0.5%~1%, remaining is water.
The type of disperse dyes and reactive dye is particularly significant for the present invention.
For disperse dyes, the present invention claims be the high S type disperse dyes of fastness to sublimation or SE type dispersion
Dyestuff, preferably fastness to sublimation be higher while alkali resistance also stronger SE type disperse dyes.
For reactive dye, the present invention claims be heat curing type reactive dye resistant to high temperature.Dispersing agent it is main at
It is divided into yin/nonionic surfactant, thickener is modified guar gum or modified starch thickener or sodium alginate thickener, profit
The main component of humectant is Siloxane-Oxyalkylene Copolymers polymer.
Above-mentioned steps 1. described in roller be electric carving chromium plating roller, carving depth be 4~7.
Above-mentioned steps 2. described in pretreatment fluid be formulated by the component of following weight percentage: thickener 0.5%~
3%, preventing agent 1%~3%, chelated dispersants 1%~3%, non-silicon defoaming agent 0.5%~1% are restored, remaining is water.
Above-mentioned thickener is sodium alginate thickener, and the main component for restoring preventing agent is m-nitrobenzene sodium sulfonate, chelating dispersion
The main component of agent is anionic surfactant.
Above-mentioned steps 2. described in pressure of padding be 0.2~0.6MPa, the speed of service of padding machine is 5~15m/min.
Above-mentioned steps 3. described in terylene fibre/cotton fibre mixed union the speed of service be 5~15m/min, transfer
Pressure is 0.5~1MPa.
Above-mentioned steps 4. described in two-part in first segment evaporate temperature be 150~170 DEG C, evaporate the time be 8~
20min, it is 101~105 DEG C that second segment, which evaporates temperature, and evaporating the time is 6~12min.
The good effect that the present invention has: the present invention is by selecting suitable mill base and pretreatment fluid, especially in color
Suitable disperse dyes and reactive dye are added in slurry, using same paste printing, and optimizes and evaporates technique, so as to realize terylene
Fiber/cotton fiber union wet transfer printing, not only color is saturated plentiful, decalcomania remarkable fluency, but also product
Quality controllable, soft, fastness is good, up to 3-4 grades or more.
Specific embodiment
(embodiment 1)
The terylene fibre/cotton fibre mixed union wet method transfer printing method of the present embodiment has follow steps:
1. flower pattern is carved on version cylinder according to depth difference, according to flower pattern needs using prepared mill base, by recessed
Flower pattern is printed on the film by coating by printing machine, and printing thin film is made.
The mill base that the present embodiment uses is formulated by the component of following weight percentage: disperse dyes 12%, reactive dye
6%, sodium carbonate 2.5%, sodium hydroxide 0.3%, dispersing agent 5%, thickener 30%, non-silicon defoaming agent 0.5%, wetting agent 0.5% and water
43.2%。
Wherein, disperse dyes are contaminated using the high alkali resistant dispersion of HA type of Peng Lai Jia Xin dye chemical industry limited liability company
Material;Reactive dye using Shanghai Argus Textile Chemical Co., Ltd. heat curing type reactive dye;What dispersing agent used
It is dispersing agent T, derives from Changzhou Hui Lan commerce and trade Co., Ltd, main component is yin/nonionic surfactant;Thickener uses
Be Gum-14, derive from sun,moon and star commerce and trade Co., Ltd, main component is modified guar gum;What non-silicon defoaming agent used
It is DM-7401, derives from dolantin chemical company, main component is nonionic surfactant;Wetting agent is using HR-
8060, Hong Rui Chemical Co., Ltd. is derived from, main component is Siloxane-Oxyalkylene Copolymers polymer.
2. terylene fibre/cotton fibre mixed union is introduced into padding in slot for the pretreatment fluid for filling that temperature is 18 DEG C, one
Immersing and rolling, it is 0.6MPa that pressure is padded in control, and the speed of service of padding machine is 10m/min, terylene fibre/cotton fibre mixed after roll compacting
The moisture content of union is 90%, the terylene fibre/cotton fibre mixed union soaked.
The pretreatment fluid that the present embodiment uses is formulated by the component of following weight percentage: thickener 3.5%, also place where troops were originally stationed
Only agent 4%, chelated dispersants 1%, non-silicon defoaming agent 0.5% and water 91%.
Wherein, thickener is using sodium alginate;The HT-305 that preventing agent uses is restored, closes safe chemical industry from Jinzhou City
Co., Ltd, main component are m-nitrobenzene sodium sulfonate;Chelated dispersants derive from the refined essence of Shanghai good fortune using SQ-113
Thin Chemical Co., Ltd., main component are anionic surfactant;Non-silicon defoaming agent is derived from using DM-7401
Dolantin chemical company, main component are nonionic surfactant.
3. 1. printing thin film that the terylene fibre/cotton fibre mixed union of 2. wetting that step obtains and step are obtained pastes
It is combined, into transfer device roll compacting, the speed of service for controlling terylene fibre/cotton fibre mixed union is 10m/min, transfer
Pressure is 1.0MPa, and make the clear patterns on printing thin film is transferred to terylene fibre/cotton fibre mixed union surface;It transfers out
After device, terylene fibre/cotton fibre mixed union is separated with printing thin film, by the independent clot of film after transfer, polyester fiber/
Cotton fiber union then passes through tensionless dryer drying.
It is evaporated 4. 3. terylene fibre/cotton fibre mixed union that step obtains is introduced continous way rapid steamer and carries out two-part
Color development, it is 170 DEG C × 12min that first segment, which evaporates technique, enters disperse dyes inside polyester fiber;Second segment evaporates technique
102 DEG C × 10min, reactive dye is made sufficiently to react with cotton fiber, carries out conventional washing, drying after rapid steamer out.
Through detecting, the terylene fibre/cotton fibre mixed union fastness of the present embodiment is up to 3-4 grades or more, and feel is soft
Soft, color is saturated plentiful, decalcomania remarkable fluency.
Claims (4)
1. a kind of terylene fibre/cotton fibre mixed union wet method transfer printing method, it is characterised in that the following steps are included:
1. utilizing prepared mill base, flower pattern is printed on the film by coating by the roller on intaglio press, is made
At printing thin film;The mill base is formulated by the component of following weight percentage: disperse dyes 3%~15%, reactive dye
3%~15%, sodium carbonate 2%~5%, sodium hydroxide 0.1%~1%, dispersing agent 5%~10%, thickener 20%~40%, non-silicon defoaming agent
0.5%~1%, wetting agent 0.5%~1%, remaining is water;
The padding in slot of pretreatment fluid is filled 2. terylene fibre/cotton fibre mixed union is introduced into, 10~30 DEG C of one immersing and rolling is led to
Cross control pad the speed of service of pressure and padding machine to control the moisture content of terylene fibre/cotton fibre mixed union be 70%~
100%, the terylene fibre/cotton fibre mixed union soaked;The pretreatment fluid is distributed by the group of following weight percentage
It makes: thickener 0.5%~3%, reduction preventing agent 1%~3%, chelated dispersants 1%~3%, non-silicon defoaming agent 0.5%~1%, remaining
For water;
3. 1. printing thin film that the terylene fibre/cotton fibre mixed union of 2. wetting that step obtains is obtained with step is fitted in
Together, made into transfer device roll compacting by controlling the speed of service and transfer pressure of terylene fibre/cotton fibre mixed union
Clear patterns on printing thin film are transferred to terylene fibre/cotton fibre mixed union surface;Out after transfer device, terylene is fine
Dimension/cotton fiber union is separated with printing thin film, terylene fibre/cotton fibre mixed to knit by the independent clot of film after transfer
Object then passes through tensionless dryer drying;
4. 3. terylene fibre/cotton fibre mixed union that step obtains is introduced continous way rapid steamer to carry out evaporating color development, and root
It requires to evaporate temperature and time according to two-part strict control according to technique, to ensure disperse dyes and polyester fiber, reactive dye
It sufficiently reacts with cotton fiber, carries out conventional washing, drying after rapid steamer out.
2. terylene fibre/cotton fibre mixed union wet method transfer printing method according to claim 1, it is characterised in that:
Above-mentioned steps 1. in, disperse dyes be SE type disperse dyes, above-mentioned reactive dye be heat curing type reactive dye, dispersing agent it is main
Ingredient is yin/nonionic surfactant, and thickener is to be modified guar gum or modified starch thickener or sodium alginate thickener,
The main component of wetting agent is Siloxane-Oxyalkylene Copolymers polymer.
3. terylene fibre/cotton fibre mixed union wet method transfer printing method according to claim 1, it is characterised in that:
Above-mentioned steps 3. in, thickener be sodium alginate thickener, restore preventing agent main component be m-nitrobenzene sodium sulfonate, chelating dispersion
The main component of agent is anionic surfactant.
4. special according to claim 1 to terylene fibre/cotton fibre mixed union wet method transfer printing method described in one of 3
Sign is: above-mentioned steps 4. described in two-part in first segment evaporate temperature be 150~170 DEG C, evaporate the time be 8~
20min, it is 101~105 DEG C that second segment, which evaporates temperature, and evaporating the time is 6~12min.
Priority Applications (2)
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CN201610593673.1A CN106120405B (en) | 2016-07-26 | 2016-07-26 | Terylene fibre/cotton fibre mixed union wet method transfer printing method |
PCT/CN2016/106389 WO2018018800A1 (en) | 2016-07-26 | 2016-11-18 | Method for wet transfer printing of polyester fiber/cotton fiber union fabric |
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CN201610593673.1A CN106120405B (en) | 2016-07-26 | 2016-07-26 | Terylene fibre/cotton fibre mixed union wet method transfer printing method |
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CN106120405B true CN106120405B (en) | 2019-11-01 |
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CN105951484B (en) * | 2016-05-24 | 2019-07-12 | 常州旭荣针织印染有限公司 | Wool fabric wet method transfer printing method |
CN106120405B (en) * | 2016-07-26 | 2019-11-01 | 常州旭荣针织印染有限公司 | Terylene fibre/cotton fibre mixed union wet method transfer printing method |
CN106868895A (en) * | 2017-02-24 | 2017-06-20 | 常州旭荣针织印染有限公司 | Cellulose base fiber fabric wet transfer printing padding liquid and its compound method |
CN107083698B (en) * | 2017-04-07 | 2021-05-25 | 常州旭荣针织印染有限公司 | Padding liquid for wet transfer printing of chinlon fabric and its compounding process |
FR3067368B1 (en) * | 2017-06-08 | 2019-07-26 | Tam | METHOD FOR PRINTING A TEXTILE BY TRANSFER |
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