WO2018018800A1 - Method for wet transfer printing of polyester fiber/cotton fiber union fabric - Google Patents

Method for wet transfer printing of polyester fiber/cotton fiber union fabric Download PDF

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Publication number
WO2018018800A1
WO2018018800A1 PCT/CN2016/106389 CN2016106389W WO2018018800A1 WO 2018018800 A1 WO2018018800 A1 WO 2018018800A1 CN 2016106389 W CN2016106389 W CN 2016106389W WO 2018018800 A1 WO2018018800 A1 WO 2018018800A1
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Prior art keywords
cotton fiber
polyester fiber
fiber
interwoven fabric
paste
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PCT/CN2016/106389
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French (fr)
Chinese (zh)
Inventor
黄庄芳容
张国成
左凯杰
颜怀成
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黄庄芳容
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Publication of WO2018018800A1 publication Critical patent/WO2018018800A1/en

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003—Transfer printing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48—Derivatives of carbohydrates
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    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
    • D06P1/5292—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
    • D—TEXTILES; PAPER
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    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/628—Compounds containing nitrogen
    • D—TEXTILES; PAPER
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    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D—TEXTILES; PAPER
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    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/004—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using dispersed dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/008—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82—Textiles which contain different kinds of fibres
    • D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8223—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
    • D06P3/8238—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye
    • D06P3/8252—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye using dispersed and reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment

Definitions

  • the invention belongs to the technical field of textile printing, and particularly relates to a wet transfer printing method of polyester fiber/cotton fiber interwoven fabric.
  • Polyester fabrics are generally printed with disperse dyes under acidic conditions.
  • Cotton fabrics are generally printed with reactive dyes under alkaline conditions. The production process is very mature and accounts for a large proportion of textile printing in China.
  • polyester fiber/cotton fiber interwoven fabrics cannot be printed with a single disperse dye or reactive dye. Otherwise, only one of the fibers can be dyed, while the other fiber is white, which causes the fabric to become a twist, which seriously affects the printed products. Appearance Quality.
  • polyester fiber/cotton fiber interwoven fabrics In view of the above problems of polyester fiber/cotton fiber interwoven fabrics, it has been reported in the literature that the polyester printed fiber/cotton fiber interwoven fabric is coated with paint. Although this method can solve the problem of simultaneous coloring of polyester fiber and cotton fiber, there is hard feeling and fastness. Poor and other problems, and in terms of flower expression, it is only suitable for ordinary patterns, and can not express complex effects such as gradation and moiré.
  • the object of the present invention is to solve the above problems, and to provide a polyester fiber/cotton fiber interwoven fabric wet transfer printing method which is not only saturated in color, but also has a smooth and natural printing pattern, and has soft hand feeling and good fastness.
  • the technical solution for achieving the above object of the present invention is: a polyester fiber/cotton fiber interwoven fabric wet transfer printing method, which has the following steps:
  • the polyester fiber/cotton fiber interwoven fabric is introduced into the padding tank containing the pretreatment liquid, and the dip-rolling is carried out at a normal temperature of 10 to 30 ° C to control the interlacing of the polyester fiber/cotton fiber by controlling the padding pressure and the running speed of the rolling car.
  • the moisture content of the fabric is 70% to 100%, and a weaved polyester fiber/cotton fiber interwoven fabric is obtained;
  • step 3 The wet polyester fiber/cotton fiber interwoven fabric obtained in step 2 is bonded to the printing film obtained in step 1, and is pressed into the transfer device to control the running speed and transfer of the polyester fiber/cotton fiber interwoven fabric. Pressure, the pattern on the printed film is clearly transferred to the surface of the polyester fiber/cotton fiber interwoven fabric; after the transfer device, the polyester fiber/cotton fiber interwoven fabric is separated from the printed film, and the transferred film is separately rolled, polyester The fiber/cotton fiber interwoven fabric is dried by a tension-free dryer;
  • the polyester fiber/cotton fiber interwoven fabric obtained in step 3 is introduced into a continuous steaming machine for steaming and color development, and according to the process requirements, the steaming temperature and time are strictly controlled according to the two-stage method to ensure disperse dye and polyester fiber and activity.
  • the dye reacts sufficiently with the cotton fiber, and is subjected to conventional water washing and drying after being discharged from the steaming machine.
  • the color paste described in the above step 1 is prepared from the following components by weight: disperse dye 3% to 15%, reactive dye 3% to 15%, sodium carbonate 2% to 5%, sodium hydroxide 0.1% ⁇ 1%, dispersant 5% to 10%, paste 20% to 40%, non-silicone antifoaming agent 0.5% to 1%, wetting agent 0.5% to 1%, and the rest is water.
  • disperse dyes and reactive dyes are important to the present invention.
  • the present invention requires an S-type disperse dye or a SE-type disperse dye having high sublimation fastness, and is preferably a SE-type disperse dye having high sublimation fastness and alkali resistance.
  • the present invention requires a high temperature resistant thermosetting reactive dye.
  • the main component of the dispersant is an anionic/nonionic surfactant
  • the paste is a modified guar gum or a modified starch paste or a sodium alginate paste
  • the main component of the wetting agent is a polyether modified polysiloxane. Alkyl polymer.
  • the plate roll described in the above step 1 is an electrosurgical chrome plated roll having an engraving depth of 4 to 7 wires.
  • the pretreatment liquid described in the above step 2 is prepared from the following components by weight: paste 0.5% to 3%, reduction inhibitor 1% to 3%, chelating dispersant 1% to 3%, non- The silicon defoamer is 0.5% to 1%, and the rest is water.
  • the paste is a sodium alginate paste
  • the main component of the reduction inhibitor is sodium m-nitrobenzenesulfonate
  • the main component of the chelate dispersant is an anionic surfactant
  • the padding pressure described in the above step 2 is 0.2 to 0.6 MPa, and the running speed of the rolling mill is 5 to 15 m/min.
  • the running speed of the polyester fiber/cotton fiber interwoven fabric described in the above step 3 is 5 to 15 m/min, and the transfer pressure is 0.5 to 1 MPa.
  • the first stage steaming temperature in the two-stage formula described in the above step 4 is 150-170 ° C, the steaming time is 8-20 min, the second stage steaming temperature is 101-105 ° C, and the steaming time is 6-. 12min.
  • the polyester fiber/cotton fiber interwoven fabric wet transfer printing method of the present embodiment has the following steps:
  • the pattern is engraved on the plate according to the depth and depth, and the prepared color paste is used to print the pattern on the coated film by the gravure printing machine to form a printed film.
  • the color paste used in this embodiment is prepared from the following components by weight: disperse dye 12%, reactive dye 6%, sodium carbonate 2.5%, sodium hydroxide 0.3%, dispersant 5%, paste 30%, Non-silicone defoamer 0.5%, wetting agent 0.5% and water 43.2%.
  • the disperse dye is the HA type high alkali resistance type disperse dye of Penglai Jiaxin Dyestuff Chemical Co., Ltd.; the reactive dye is the thermosetting reactive dye of Shanghai Yayun Textile Chemical Co., Ltd.; the dispersant is dispersed.
  • Agent T from Changzhou Huilan Trading Co., Ltd., its main component is anionic/nonionic surfactant; the paste is Gum-14, which is derived from Riyuexing Trading Co., Ltd., whose main component is modified guar. Bean gum; non-silicon defoamer is DM-7401, which is sourced from Demei Chemical Company. Its main component is nonionic surfactant; the wetting agent is HR-8060, which is sourced from Hongrui Chemical Co., Ltd. Its main component is a polyether modified polysiloxane polymer.
  • the polyester fiber/cotton fiber interwoven fabric was introduced into the padding tank containing the pretreatment liquid with a temperature of 18 ° C.
  • the dip-rolling pressure was controlled to 0.6 MPa, and the running speed of the rolling mill was 10 m/min.
  • the moisture content of the pressed polyester fiber/cotton fiber interwoven fabric was 90%, and a wet polyester fiber/cotton fiber interwoven fabric was obtained.
  • the pretreatment liquid used in this example was prepared from the following components by weight: paste 3.5%, reduction inhibitor 4%, chelating dispersant 1%, non-silicone defoamer 0.5%, and water 91%.
  • the paste is sodium alginate
  • the HT-305 used for the reduction inhibitor is derived from Jinzhou Hetai Chemical Co., Ltd., the main component of which is sodium m-nitrobenzenesulfonate
  • the chelate dispersant is SQ-113, from Shanghai Fubin Fine Chemical Co., Ltd., its main component is anionic surfactant
  • non-silicon defoamer is DM-7401, derived from Demei Chemical Company, its main component is nonionic surface active Agent.
  • the wet polyester fiber/cotton fiber interwoven fabric obtained in step 2 is bonded to the printing film obtained in step 1, and is pressed into the transfer device to control the running speed of the polyester fiber/cotton fiber interwoven fabric to be 10 m/min.
  • the transfer pressure is 1.0 MPa, so that the pattern on the printed film is clearly transferred to the surface of the polyester fiber/cotton fiber interwoven fabric; after the transfer device is removed, the polyester fiber/cotton fiber interwoven fabric is separated from the printed film, and the transfer film is transferred.
  • the film is wound separately, and the polyester fiber/cotton fiber interwoven fabric is dried by a tension-free dryer.
  • the polyester fiber/cotton fiber interwoven fabric obtained in step 3 is introduced into a continuous steaming machine for two-stage steaming color development.
  • the first stage steaming process is 170 ° C ⁇ 12 min, so that the disperse dye enters the inside of the polyester fiber;
  • the stage steaming process is 102 ° C ⁇ 10 min, so that the reactive dye and the cotton fiber fully react, and after the steaming machine, the conventional water washing and drying are carried out.
  • the polyester fiber/cotton fiber interwoven fabric of the present embodiment has a fastness of 3-4 or more, and the hand feel is soft, the color is saturated, and the printing pattern is smooth and natural.
  • the invention can select the appropriate color paste and the pretreatment liquid, especially the suitable disperse dye and the reactive dye in the color paste, adopt the same paste printing, and optimize the steaming process, thereby realizing
  • the wet transfer printing of polyester fiber/cotton fiber interwoven fabric is not only saturated and full of color, the printing pattern is smooth and natural, but also the product quality is controllable, the hand feels soft and the fastness is good, up to 3-4 grades.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coloring (AREA)

Abstract

Disclosed is a method for wet transfer printing of a polyester fiber/cotton fiber union fabric, comprising the following steps: (1) preparing a printed film; (2) obtaining a wetted polyester fiber/cotton fiber union fabric; (3) bonding the wetted polyester fiber/cotton fiber union fabric and the printed film together, and putting the two in a transfer printing device for roll compacting, so that a pattern on the printed film is clearly transferred to the surface of the polyester fiber/cotton fiber union fabric; (4) guiding the product into a continuous ager for two-stage aging and color development, taking the product out of the ager and then routinely washing and drying same. By selecting appropriate color paste and pretreatment liquid, particularly, adding appropriate disperse dye and reactive dye to the color paste, printing in one paste, and optimizing an aging technology, the present invention can implement wet transfer printing of the polyester fiber/cotton fiber union fabric. The present invention features high color saturation and fullness, smooth and natural printed pattern, controllable product quality, soft handle, and good fastness that can reach the third to fourth level or above.

Description

涤纶纤维/棉纤维交织织物湿法转移印花方法Polyester fiber/cotton fiber interwoven fabric wet transfer printing method 技术领域Technical field
本发明属于纺织品印花技术领域，具体涉及一种涤纶纤维/棉纤维交织织物湿法转移印花方法。The invention belongs to the technical field of textile printing, and particularly relates to a wet transfer printing method of polyester fiber/cotton fiber interwoven fabric.
背景技术Background technique
涤纶织物一般采用分散染料在酸性条件下印花，棉织物一般采用活性染料在碱性条件下印花，其生产工艺均很成熟，在我国纺织品印花中占有很大比例。但是涤纶纤维/棉纤维交织织物无法采用单一的分散染料或者活性染料进行印花，否则只能上染其中一种纤维，而另一种纤维露白，导致布面成为麻花色，而严重影响印花制品的外观质量。Polyester fabrics are generally printed with disperse dyes under acidic conditions. Cotton fabrics are generally printed with reactive dyes under alkaline conditions. The production process is very mature and accounts for a large proportion of textile printing in China. However, polyester fiber/cotton fiber interwoven fabrics cannot be printed with a single disperse dye or reactive dye. Otherwise, only one of the fibers can be dyed, while the other fiber is white, which causes the fabric to become a twist, which seriously affects the printed products. Appearance Quality.
针对涤纶纤维/棉纤维交织织物上述问题，已有文献报道采用涂料印花印涤纶纤维/棉纤维交织织物，该方法虽然能够解决涤纶纤维和棉纤维同时上色的问题，但是存在手感硬、牢度差等问题，并且在花型表现力方面也仅适合普通花型，无法表现渐变、云纹等复杂效果。In view of the above problems of polyester fiber/cotton fiber interwoven fabrics, it has been reported in the literature that the polyester printed fiber/cotton fiber interwoven fabric is coated with paint. Although this method can solve the problem of simultaneous coloring of polyester fiber and cotton fiber, there is hard feeling and fastness. Poor and other problems, and in terms of flower expression, it is only suitable for ordinary patterns, and can not express complex effects such as gradation and moiré.
发明内容Summary of the invention
本发明的目的在于解决上述问题，提供一种不仅颜色饱和丰满、印花图案流畅自然，而且手感柔软、牢度良好的涤纶纤维/棉纤维交织织物湿法转移印花方法。The object of the present invention is to solve the above problems, and to provide a polyester fiber/cotton fiber interwoven fabric wet transfer printing method which is not only saturated in color, but also has a smooth and natural printing pattern, and has soft hand feeling and good fastness.
实现本发明上述目的的技术方案是：一种涤纶纤维/棉纤维交织织物湿法转移印花方法，具有以下步骤：The technical solution for achieving the above object of the present invention is: a polyester fiber/cotton fiber interwoven fabric wet transfer printing method, which has the following steps:
①利用配制好的色浆，通过凹版印刷机上的版辊将花型印制在经过涂层的薄膜上，制成印花薄膜；1 using the prepared color paste, printing the pattern on the coated film through the plate roller on the gravure printing machine to form a printed film;
②将涤纶纤维/棉纤维交织织物引入盛有预处理液的浸轧槽中，常温10～30℃一浸一轧，通过控制浸轧压力以及轧车的运行速度来控制涤纶纤维/棉纤维交织织物的含水率为70％～100％，得到润湿的涤纶纤维/棉纤维交织织物；2 The polyester fiber/cotton fiber interwoven fabric is introduced into the padding tank containing the pretreatment liquid, and the dip-rolling is carried out at a normal temperature of 10 to 30 ° C to control the interlacing of the polyester fiber/cotton fiber by controlling the padding pressure and the running speed of the rolling car. The moisture content of the fabric is 70% to 100%, and a weaved polyester fiber/cotton fiber interwoven fabric is obtained;
③将步骤②得到的润湿的涤纶纤维/棉纤维交织织物与步骤①得到的印花薄膜贴合在一起，进入转印装置轧压，通过控制涤纶纤维/棉纤维交织织物的运行速度及转印压力，使印花薄膜上的图案清晰的转移到涤纶纤维/棉纤维交织织物表面；出转印装置后，涤纶纤维/棉纤维交织织物与印花薄膜分离，将转印后的薄膜单独打卷，涤纶纤维/棉纤维交织织物则经过无张力烘干机烘干； 3 The wet polyester fiber/cotton fiber interwoven fabric obtained in step 2 is bonded to the printing film obtained in step 1, and is pressed into the transfer device to control the running speed and transfer of the polyester fiber/cotton fiber interwoven fabric. Pressure, the pattern on the printed film is clearly transferred to the surface of the polyester fiber/cotton fiber interwoven fabric; after the transfer device, the polyester fiber/cotton fiber interwoven fabric is separated from the printed film, and the transferred film is separately rolled, polyester The fiber/cotton fiber interwoven fabric is dried by a tension-free dryer;
④将步骤③得到的涤纶纤维/棉纤维交织织物引入连续式蒸化机进行蒸化发色，并根据工艺要求按照两段式严格控制蒸化温度及时间，以确保分散染料与涤纶纤维、活性染料与棉纤维充分发生反应，出蒸化机后进行常规的水洗、烘干。4 The polyester fiber/cotton fiber interwoven fabric obtained in step 3 is introduced into a continuous steaming machine for steaming and color development, and according to the process requirements, the steaming temperature and time are strictly controlled according to the two-stage method to ensure disperse dye and polyester fiber and activity. The dye reacts sufficiently with the cotton fiber, and is subjected to conventional water washing and drying after being discharged from the steaming machine.
上述步骤①中所述的色浆由下述重量百分比的组分配制而成：分散染料3％～15％、活性染料3％～15％、碳酸钠2％～5％、氢氧化钠0.1％～1％、分散剂5％～10％、糊料20％～40％、非硅消泡剂0.5％～1％、润湿剂0.5％～1％，其余为水。The color paste described in the above step 1 is prepared from the following components by weight: disperse dye 3% to 15%, reactive dye 3% to 15%, sodium carbonate 2% to 5%, sodium hydroxide 0.1% ~1%, dispersant 5% to 10%, paste 20% to 40%, non-silicone antifoaming agent 0.5% to 1%, wetting agent 0.5% to 1%, and the rest is water.
分散染料和活性染料的种类对于本发明而言十分重要。The types of disperse dyes and reactive dyes are important to the present invention.
对于分散染料而言，本发明要求的是耐升华牢度高的S型分散染料或者SE型分散染料，优选为耐升华牢度较高的同时耐碱性也较强的SE型分散染料。For the disperse dye, the present invention requires an S-type disperse dye or a SE-type disperse dye having high sublimation fastness, and is preferably a SE-type disperse dye having high sublimation fastness and alkali resistance.
对于活性染料而言，本发明要求的是耐高温的热固型活性染料。分散剂的主要成分为阴/非离子表面活性剂，糊料为改性瓜尔豆胶或者改性淀粉糊料或者海藻酸钠糊料，润湿剂的主要成分为聚醚改性聚硅氧烷聚合物。For reactive dyes, the present invention requires a high temperature resistant thermosetting reactive dye. The main component of the dispersant is an anionic/nonionic surfactant, the paste is a modified guar gum or a modified starch paste or a sodium alginate paste, and the main component of the wetting agent is a polyether modified polysiloxane. Alkyl polymer.
上述步骤①中所述的版辊为电雕镀铬版辊，雕刻深度为4～7丝。The plate roll described in the above step 1 is an electrosurgical chrome plated roll having an engraving depth of 4 to 7 wires.
上述步骤②中所述的预处理液由下述重量百分比的组分配制而成：糊料0.5％～3％、还原防止剂1％～3％、螯合分散剂1％～3％、非硅消泡剂0.5％～1％，其余为水。The pretreatment liquid described in the above step 2 is prepared from the following components by weight: paste 0.5% to 3%, reduction inhibitor 1% to 3%, chelating dispersant 1% to 3%, non- The silicon defoamer is 0.5% to 1%, and the rest is water.
上述糊料为海藻酸钠糊料，还原防止剂的主要成分为间硝基苯磺酸钠，螯合分散剂的主要成分为阴离子表面活性剂。The paste is a sodium alginate paste, the main component of the reduction inhibitor is sodium m-nitrobenzenesulfonate, and the main component of the chelate dispersant is an anionic surfactant.
上述步骤②中所述的浸轧压力为0.2～0.6MPa，轧车的运行速度为5～15m/min。The padding pressure described in the above step 2 is 0.2 to 0.6 MPa, and the running speed of the rolling mill is 5 to 15 m/min.
上述步骤③中所述的涤纶纤维/棉纤维交织织物的运行速度为5～15m/min，转印压力为0.5～1MPa。The running speed of the polyester fiber/cotton fiber interwoven fabric described in the above step 3 is 5 to 15 m/min, and the transfer pressure is 0.5 to 1 MPa.
上述步骤④中所述的两段式中的第一段蒸化温度为150～170℃，蒸化时间为8～20min，第二段蒸化温度为101～105℃，蒸化时间为6～12min。The first stage steaming temperature in the two-stage formula described in the above step 4 is 150-170 ° C, the steaming time is 8-20 min, the second stage steaming temperature is 101-105 ° C, and the steaming time is 6-. 12min.
具体实施方式detailed description
(实施例1)(Example 1)
本实施例的涤纶纤维/棉纤维交织织物湿法转移印花方法具有以下步骤：The polyester fiber/cotton fiber interwoven fabric wet transfer printing method of the present embodiment has the following steps:
①根据花型需要，将花型按照深浅不同雕刻在版筒上，利用配制好的色浆，通过凹版印刷机将花型印制在经过涂层的薄膜上，制成印花薄膜。1 According to the flower pattern, the pattern is engraved on the plate according to the depth and depth, and the prepared color paste is used to print the pattern on the coated film by the gravure printing machine to form a printed film.
本实施例采用的色浆由下述重量百分比的组分配制而成：分散染料12％、活性染料6％、碳酸钠2.5％、氢氧化钠0.3％、分散剂5％、糊料30％、非硅消泡剂0.5％、润湿剂0.5％以及水43.2％。 The color paste used in this embodiment is prepared from the following components by weight: disperse dye 12%, reactive dye 6%, sodium carbonate 2.5%, sodium hydroxide 0.3%, dispersant 5%, paste 30%, Non-silicone defoamer 0.5%, wetting agent 0.5% and water 43.2%.
其中，分散染料采用的是蓬莱嘉信染料化工股份有限公司的HA型高耐碱型分散染料；活性染料采用的是上海雅运纺织化工股份有限公司的热固型活性染料；分散剂采用的是分散剂T，来源于常州惠蓝商贸有限公司，其主要成分为阴/非离子表面活性剂；糊料采用的是Gum-14，来源于日月星商贸有限公司，其主要成分为改性瓜尔豆胶；非硅消泡剂采用的是DM-7401，来源于德美化工公司，其主要成分为非离子表面活性剂；润湿剂采用的是HR-8060，来源于鸿瑞化工有限公司，其主要成分为聚醚改性聚硅氧烷聚合物。Among them, the disperse dye is the HA type high alkali resistance type disperse dye of Penglai Jiaxin Dyestuff Chemical Co., Ltd.; the reactive dye is the thermosetting reactive dye of Shanghai Yayun Textile Chemical Co., Ltd.; the dispersant is dispersed. Agent T, from Changzhou Huilan Trading Co., Ltd., its main component is anionic/nonionic surfactant; the paste is Gum-14, which is derived from Riyuexing Trading Co., Ltd., whose main component is modified guar. Bean gum; non-silicon defoamer is DM-7401, which is sourced from Demei Chemical Company. Its main component is nonionic surfactant; the wetting agent is HR-8060, which is sourced from Hongrui Chemical Co., Ltd. Its main component is a polyether modified polysiloxane polymer.
②将涤纶纤维/棉纤维交织织物引入盛有温度为18℃的预处理液的浸轧槽中，一浸一轧，控制浸轧压力为0.6MPa，轧车的运行速度为10m/min，经轧压后的涤纶纤维/棉纤维交织织物的含水率为90％，得到润湿的涤纶纤维/棉纤维交织织物。2 The polyester fiber/cotton fiber interwoven fabric was introduced into the padding tank containing the pretreatment liquid with a temperature of 18 ° C. The dip-rolling pressure was controlled to 0.6 MPa, and the running speed of the rolling mill was 10 m/min. The moisture content of the pressed polyester fiber/cotton fiber interwoven fabric was 90%, and a wet polyester fiber/cotton fiber interwoven fabric was obtained.
本实施例采用的预处理液由下述重量百分比的组分配制而成：糊料3.5％、还原防止剂4％、螯合分散剂1％、非硅消泡剂0.5％以及水91％。The pretreatment liquid used in this example was prepared from the following components by weight: paste 3.5%, reduction inhibitor 4%, chelating dispersant 1%, non-silicone defoamer 0.5%, and water 91%.
其中，糊料采用的是海藻酸钠；还原防止剂采用的HT-305，来源于晋州市合泰化工有限公司，其主要成分为间硝基苯磺酸钠；螯合分散剂采用的是SQ-113，来源于上海福彬精细化工有限公司，其主要成分为阴离子表面活性剂；非硅消泡剂采用的是DM-7401，来源于德美化工公司，其主要成分为非离子表面活性剂。Among them, the paste is sodium alginate; the HT-305 used for the reduction inhibitor is derived from Jinzhou Hetai Chemical Co., Ltd., the main component of which is sodium m-nitrobenzenesulfonate; the chelate dispersant is SQ-113, from Shanghai Fubin Fine Chemical Co., Ltd., its main component is anionic surfactant; non-silicon defoamer is DM-7401, derived from Demei Chemical Company, its main component is nonionic surface active Agent.
③将步骤②得到的润湿的涤纶纤维/棉纤维交织织物与步骤①得到的印花薄膜贴合在一起，进入转印装置轧压，控制涤纶纤维/棉纤维交织织物的运行速度为10m/min，转印压力为1.0MPa，使印花薄膜上的图案清晰的转移到涤纶纤维/棉纤维交织织物表面；出转印装置后，涤纶纤维/棉纤维交织织物与印花薄膜分离，将转印后的薄膜单独打卷，涤纶纤维/棉纤维交织织物则经过无张力烘干机烘干。3 The wet polyester fiber/cotton fiber interwoven fabric obtained in step 2 is bonded to the printing film obtained in step 1, and is pressed into the transfer device to control the running speed of the polyester fiber/cotton fiber interwoven fabric to be 10 m/min. The transfer pressure is 1.0 MPa, so that the pattern on the printed film is clearly transferred to the surface of the polyester fiber/cotton fiber interwoven fabric; after the transfer device is removed, the polyester fiber/cotton fiber interwoven fabric is separated from the printed film, and the transfer film is transferred. The film is wound separately, and the polyester fiber/cotton fiber interwoven fabric is dried by a tension-free dryer.
④将步骤③得到的涤纶纤维/棉纤维交织织物引入连续式蒸化机进行两段式蒸化发色，第一段蒸化工艺为170℃×12min，使分散染料进入涤纶纤维内部；第二段蒸化工艺为102℃×10min，使活性染料与棉纤维充分发生反应，出蒸化机后进行常规的水洗、烘干。4 The polyester fiber/cotton fiber interwoven fabric obtained in step 3 is introduced into a continuous steaming machine for two-stage steaming color development. The first stage steaming process is 170 ° C × 12 min, so that the disperse dye enters the inside of the polyester fiber; The stage steaming process is 102 ° C × 10 min, so that the reactive dye and the cotton fiber fully react, and after the steaming machine, the conventional water washing and drying are carried out.
经检测，本实施例的涤纶纤维/棉纤维交织织物牢度可达3-4级以上，而且手感柔软、颜色饱和丰满、印花图案流畅自然。After testing, the polyester fiber/cotton fiber interwoven fabric of the present embodiment has a fastness of 3-4 or more, and the hand feel is soft, the color is saturated, and the printing pattern is smooth and natural.
工业应用性Industrial applicability
本发明具有的积极效果：本发明通过选择合适的色浆以及预处理液，尤其是在色浆中加入合适的分散染料和活性染料，采用同浆印花，并优化蒸化工艺，从而能够实 现涤纶纤维/棉纤维交织织物的湿法转移印花，不仅颜色饱和丰满、印花图案流畅自然，而且产品质量可控，手感柔软，牢度良好，可达3-4级以上。 The positive effect of the invention: the invention can select the appropriate color paste and the pretreatment liquid, especially the suitable disperse dye and the reactive dye in the color paste, adopt the same paste printing, and optimize the steaming process, thereby realizing The wet transfer printing of polyester fiber/cotton fiber interwoven fabric is not only saturated and full of color, the printing pattern is smooth and natural, but also the product quality is controllable, the hand feels soft and the fastness is good, up to 3-4 grades.

Claims (6)

  1. 一种涤纶纤维/棉纤维交织织物湿法转移印花方法，其特征在于包括以下步骤：A polyester fiber/cotton fiber interwoven fabric wet transfer printing method characterized by comprising the following steps:
    ①利用配制好的色浆，通过凹版印刷机上的版辊将花型印制在经过涂层的薄膜上，制成印花薄膜；1 using the prepared color paste, printing the pattern on the coated film through the plate roller on the gravure printing machine to form a printed film;
    ②将涤纶纤维/棉纤维交织织物引入盛有预处理液的浸轧槽中，常温10～30℃一浸一轧，通过控制浸轧压力以及轧车的运行速度来控制涤纶纤维/棉纤维交织织物的含水率为70％～100％，得到润湿的涤纶纤维/棉纤维交织织物；2 The polyester fiber/cotton fiber interwoven fabric is introduced into the padding tank containing the pretreatment liquid, and the dip-rolling is carried out at a normal temperature of 10 to 30 ° C to control the interlacing of the polyester fiber/cotton fiber by controlling the padding pressure and the running speed of the rolling car. The moisture content of the fabric is 70% to 100%, and a weaved polyester fiber/cotton fiber interwoven fabric is obtained;
    ③将步骤②得到的润湿的涤纶纤维/棉纤维交织织物与步骤①得到的印花薄膜贴合在一起，进入转印装置轧压，通过控制涤纶纤维/棉纤维交织织物的运行速度及转印压力，使印花薄膜上的图案清晰的转移到涤纶纤维/棉纤维交织织物表面；出转印装置后，涤纶纤维/棉纤维交织织物与印花薄膜分离，将转印后的薄膜单独打卷，涤纶纤维/棉纤维交织织物则经过无张力烘干机烘干；3 The wet polyester fiber/cotton fiber interwoven fabric obtained in step 2 is bonded to the printing film obtained in step 1, and is pressed into the transfer device to control the running speed and transfer of the polyester fiber/cotton fiber interwoven fabric. Pressure, the pattern on the printed film is clearly transferred to the surface of the polyester fiber/cotton fiber interwoven fabric; after the transfer device, the polyester fiber/cotton fiber interwoven fabric is separated from the printed film, and the transferred film is separately rolled, polyester The fiber/cotton fiber interwoven fabric is dried by a tension-free dryer;
    ④将步骤③得到的涤纶纤维/棉纤维交织织物引入连续式蒸化机进行蒸化发色，并根据工艺要求按照两段式严格控制蒸化温度及时间，以确保分散染料与涤纶纤维、活性染料与棉纤维充分发生反应，出蒸化机后进行常规的水洗、烘干。4 The polyester fiber/cotton fiber interwoven fabric obtained in step 3 is introduced into a continuous steaming machine for steaming and color development, and according to the process requirements, the steaming temperature and time are strictly controlled according to the two-stage method to ensure disperse dye and polyester fiber and activity. The dye reacts sufficiently with the cotton fiber, and is subjected to conventional water washing and drying after being discharged from the steaming machine.
  2. 根据权利要求1所述的涤纶纤维/棉纤维交织织物湿法转移印花方法，其特征在于：上述步骤①中所述的色浆由下述重量百分比的组分配制而成：分散染料3％～15％、活性染料3％～15％、碳酸钠2％～5％、氢氧化钠0.1％～1％、分散剂5％～10％、糊料20％～40％、非硅消泡剂0.5％～1％、润湿剂0.5％～1％，其余为水。The polyester fiber/cotton fiber interwoven fabric wet transfer printing method according to claim 1, wherein the color paste described in the above step 1 is prepared from the following components by weight: disperse dye 3%~ 15%, reactive dye 3% to 15%, sodium carbonate 2% to 5%, sodium hydroxide 0.1% to 1%, dispersant 5% to 10%, paste 20% to 40%, non-silicon defoamer 0.5 % ~ 1%, wetting agent 0.5% ~ 1%, the rest is water.
  3. 根据权利要求1所述的涤纶纤维/棉纤维交织织物湿法转移印花方法，其特征在于：上述分散染料为SE型分散染料，上述活性染料为热固型活性染料，分散剂的主要成分为阴/非离子表面活性剂，糊料为改性瓜尔豆胶或者改性淀粉糊料或者海藻酸钠糊料，润湿剂的主要成分为聚醚改性聚硅氧烷聚合物。The polyester fiber/cotton fiber interwoven fabric wet transfer printing method according to claim 1, wherein the disperse dye is a SE type disperse dye, the reactive dye is a thermosetting reactive dye, and the main component of the dispersant is a yin. / Nonionic surfactant, the paste is a modified guar gum or a modified starch paste or a sodium alginate paste, and the main component of the wetting agent is a polyether modified polysiloxane polymer.
  4. 根据权利要求1至3之一所述的涤纶纤维/棉纤维交织织物湿法转移印花方法，其特征在于：上述步骤②中所述的预处理液由下述重量百分比的组分配制而成：糊料0.5％～3％、还原防止剂1％～3％、螯合分散剂1％～3％、非硅消泡剂0.5％～1％，其余为水。The polyester fiber/cotton fiber interwoven fabric wet transfer printing method according to any one of claims 1 to 3, wherein the pretreatment liquid described in the above step 2 is prepared from the following weight percentage components: The paste is 0.5% to 3%, the reduction inhibitor is 1% to 3%, the chelating dispersant is 1% to 3%, and the non-silicone antifoaming agent is 0.5% to 1%, and the rest is water.
  5. 根据权利要求4所述的涤纶纤维/棉纤维交织织物湿法转移印花方法，其特征在于：上述糊料为海藻酸钠糊料，还原防止剂的主要成分为间硝基苯磺酸钠，螯合分散剂的主要成分为阴离子表面活性剂。 The polyester fiber/cotton fiber interwoven fabric wet transfer printing method according to claim 4, wherein the paste is a sodium alginate paste, and the main component of the reduction inhibitor is sodium m-nitrobenzenesulfonate. The main component of the dispersant is an anionic surfactant.
  6. 根据权利要求1至5之一所述的涤纶纤维/棉纤维交织织物湿法转移印花方法，其特征在于：上述步骤④中所述的两段式中的第一段蒸化温度为150～170℃，蒸化时间为8～20min，第二段蒸化温度为101～105℃，蒸化时间为6～12min。 The polyester fiber/cotton fiber interwoven fabric wet transfer printing method according to any one of claims 1 to 5, wherein the first stage of the two-stage steaming temperature in the above step 4 is 150 to 170 °C, steaming time is 8 ~ 20min, the second stage steaming temperature is 101 ~ 105 ° C, steaming time is 6 ~ 12min.
PCT/CN2016/106389 2016-07-26 2016-11-18 Method for wet transfer printing of polyester fiber/cotton fiber union fabric WO2018018800A1 (en)

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CN108867119A (en) * 2018-07-10 2018-11-23 桐乡盛利得纺织有限公司 The production technology and its production equipment of grained cloth, grained cloth
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CN108867119A (en) * 2018-07-10 2018-11-23 桐乡盛利得纺织有限公司 The production technology and its production equipment of grained cloth, grained cloth
CN112609448A (en) * 2020-12-03 2021-04-06 绵阳佳禧印染有限责任公司 Fabric capable of repelling mosquitoes lastingly and preparation method thereof
CN112411213A (en) * 2020-12-08 2021-02-26 浙江灏宇科技有限公司 Processing method of polyester fabric penetration printing
CN113174766A (en) * 2021-05-13 2021-07-27 浙江秋露服饰有限公司 Dyeing process of polyester interlaced yarn
CN114318901A (en) * 2021-12-07 2022-04-12 郎溪远华纺织有限公司 After-finishing process of high-precision rotary screen printing fabric
CN114351478A (en) * 2021-12-14 2022-04-15 皇宝（石狮）实业有限公司 Polyester-cotton stretch fabric high-color-fastness low-water printing and dyeing process
CN114892423A (en) * 2022-06-15 2022-08-12 江苏泰慕士针纺科技股份有限公司 Thermal transfer digital printing process of natural fiber composite fabric
CN115637548A (en) * 2022-10-26 2023-01-24 鲁泰纺织股份有限公司 Production process of washable laser carved fabric
CN115613375A (en) * 2022-10-31 2023-01-17 广州市盛勤实业有限公司 Paint printing process for synthetic fiber and blended fabric

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