CN101974859B - Method for transferring pattern of textile fabric - Google Patents

Method for transferring pattern of textile fabric Download PDF

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CN101974859B
CN101974859B CN2010105195722A CN201010519572A CN101974859B CN 101974859 B CN101974859 B CN 101974859B CN 2010105195722 A CN2010105195722 A CN 2010105195722A CN 201010519572 A CN201010519572 A CN 201010519572A CN 101974859 B CN101974859 B CN 101974859B
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transfer
paper
film
fabric
printing
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CN101974859A (en
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刘静
陈期
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Changzhou Hanyuan New Printing Co Ltd
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Abstract

The invention discloses a method for transferring a pattern of a textile fabric. The method comprises the following steps of: dissolving polyoxyethylene or polypropylene oxide in water, an organic solvent or mixed solution of the water and the organic solvent, coating paper or plastic film, drying and rolling for later use, or heating the polyoxyethylene or polypropylene oxide to a molten state, coating the paper or the plastic film, and rolling after the coating for later use; printing the paper or the plastic film by utilizing dye ink or Chinese dye ink to prepare transfer paper or transfer film; attaching the printing surface of the transfer paper or transfer film to a to-be-transferred textile fabric, feeding into a transfer machine together, heating and pressing to realize printing; stripping off the transfer paper or transfer film and fixing the dye, or fixing the dye and stripping off the transfer paper or the transfer film; and washing the textile fabric and forming to finish the transfer printing. By the transfer printing method of the invention, the inherent transfer printing idea is broken through, a damping step is saved, the processing time is saved, the production cost is reduced and the difficulty of pigment printing is reduced.

Description

A kind of transfer method of fabric flower type
Technical field
The present invention relates to a kind of dyeing method of fabric, relate in particular to a kind of transfer method of fabric flower type.
Background technology
Traditional textiles thermal transfer printing method starts from late 1960s.It is that the DISPERSE DYES that will distil easily earlier are imprinted on the transfer printing base stock, and then with modes such as hot pressing, the DISPERSE DYES distillation is transferred on the fabric, forms a kind of printing method of pattern.It has, and colored type is true to nature, and technology is simple, advantage that three waste discharge is few or the like.It is only applicable to the stamp of dacron, at polyamide fibre, and acrylic fibers, and poor effect on the natural fabric.
In order to realize the TRANSFER PRINTING of natural fabric, the wet transfer printing of REACTIVE DYES and ACID DYES has obtained domestic and international many colourists' attention.Patent 200410041034.1, and patent 200510026661.2 all discloses a kind of wet transfer printing method of natural fabric separately.Patent 200710025329.3 also discloses the wet transfer printing method of a kind of natural fabric and nylon fabric.
But they all have more jointly, must be earlier that fabric to be transferred is wetting, more under pressure; Make on the lining with moisture dissolving transfer paper or the water-soluble dye on the transfer film, last or cold dome, or decatize; Or bake, dyestuff is combined with fiber, accomplish TRANSFER PRINTING.
And wet transfer printing is in implementation process, and the humidity control when fabric is wetting has suitable difficulty, because fabric variety is numerous; Thickness differs greatly; Institutional framework closely differs, and very easily because the wetting dye transfer that causes inadequately is bad, or humidity causes colored pattern to stick with paste drawbacks such as unclear too greatly.
Summary of the invention
Technical problem to be solved by this invention provides a kind of transfer method of fabric flower type and controls a difficult difficult problem with the humidity that the solution fabric wet transfer printing exists.
For solving the problems of the technologies described above; Thinking of the present invention is; Abandon wet transfer printing, adopt brand-new heat-transferring method, i.e. hot transfer printing with REACTIVE DYES or ACID DYES or cation dyes or common difficult distillation DISPERSE DYES replaces wet transfer printing; The wetting operation of fabric of wet transfer printing is abandoned in directly transfer printing on the fabric of doing.
Concrete technical scheme is following:
A kind of transfer method of fabric flower type comprises the steps:
(1) with polyethylene glycol oxide PPOX is water-soluble or the mixed solution of organic solvent or water and organic solvent that paper or plastic film are carried out coating, oven dry, clot is subsequent use; Perhaps, polyethylene glycol oxide or PPOX are heated to molten condition paper or plastic film are coated with again, coated back clot is subsequent use;
(2) utilize dye ink or dyestuff ink that paper or the plastic film that step (1) obtains carried out stamp, process transfer paper or transfer film;
(3) with the printing surface and the fabric laminating to be transferred of transfer paper or transfer film, together get into transfer machine, heating, pressurization; Under heat and pressure effect, polyethylene glycol oxide or PPOX fusion produce powerful adhesion; And the band dyestuff infiltrates in the fabric fibre realization stamp;
(4) earlier transfer paper or transfer film are peeled off, carried out the dyestuff set again; Perhaps, carry out the dyestuff set earlier, again transfer paper or transfer film are peeled off;
(5), accomplish transfer printing with the fabric processing of washing, finalize the design.
In the step (1), described organic solvent is an intensive polar solvent, comprises but is not limited to like acetonitrile carrene, dichloroethanes, toluene etc.
In the step (1), it is the solution of 1~40% (w/w) that described polyethylene glycol oxide or PPOX mixed solution water-soluble or organic solvent or water and organic solvent forms concentration.
In the step (1), polyethylene glycol oxide or PPOX are heated to 70~250 ℃ to molten condition.
In the step (1), described plastic film is PET film, BOPP film, PE film or nylon membrane.
In the step (2), described dye ink comprises following components in weight percentage: dyestuff 0.1~60% connects material 1~20%, organic solvent 20~98.9%.Wherein, dyestuff is REACTIVE DYES, ACID DYES, cation dyes or the DISPERSE DYES that are difficult for distillation; Connecting material is the polymer substance that can be dissolved in organic solvent and can form viscous solution, and it includes but not limited to polyvinyl acetal resin, vinyl chloride-vinyl acetate resin, cellulosic plastics etc.; Organic solvent is the intensive polar solvent of ability dissolving dye, and it includes but not limited to methyl alcohol, ethanol, oxolane etc.
In the step (2), described dyestuff ink comprises following components in weight percentage: dyestuff 0.1~30% connects material 1~20%, water 50~98.9%.Wherein, dyestuff is REACTIVE DYES, ACID DYES, cation dyes or the DISPERSE DYES that are difficult for distillation; Connecting material is the polymer substance that can be dissolved in water and can form viscous solution, and it includes but not limited to sodium alginate, sodium carboxymethylcellulose, CMS etc.
In the step (2), the stamp mode is intaglio plate stamp, PLATE SCREAM PRINTING, ROTARY SCREAM PRINTING, flexographic plate stamp or ink-jet printed.
Those skilled in the art can prepare corresponding dye ink or ink according to the difference of fabric fibre kind to be transferred, select the stamp mode that is fit to.For example cellulose fibre, wool, polyamide fibre, real silk fabric can be used REACTIVE DYES; Polyamide fibre, wool, real silk fabric can be used ACID DYES; Acrylic fabric can be used cation dyes; Dacron can be used DISPERSE DYES; The use of printing ink or ink is accustomed to adjustment according to shop equipment and workman; These all are technology well known in the art.Technology of the present invention is not directed against certain specific fabric or limits the prescription and the stamp mode of printing ink, ink; And being intended to change the printing and dyeing flow process of being used to, fabric that uses in the existing transfering printing process and supporting dye formulation and stamp mode thereof all are applicable to process of the present invention.
In the step (3), be heated to 70~250 ℃, be forced into 0.5~50Kg/cm 2
In the step (3), fabric to be transferred can the rolling transfer printing, can the garment piece transfer printing, and also can the ready-made clothes transfer printing.
In the step (3), transfer machine can be a pulley type, also can be flat.
In the step (3), those skilled in the art all know, and before the fabric different dyes to be transferred transfer printing, need the solution-treated through different formulations, handle the back oven dry, carry out transfer printing again.(the component urea in the mixed solution can be replaced by glycerine need to use the mixed solution wettability treatment of urea 5~15% (w/w) and sodium bicarbonate 2~5% (w/w) like: all-cotton fabric, real silk fabric with the cotton reactive dye transfer printing; Ratio range is constant); Oven dry is subsequent use again.Real silk fabric, wool fabric, RIPSTOP are with ACID DYES or reactive dye for wool or nylon during with the dedicated dye transfer printing; Need that (the component urea in the mixed solution can be replaced by glycerine with urea 5~15% (w/w) and citric acid 2~5% (w/w) mixed solution wettability treatment; Ratio range is constant), dry for standby again.Acrylic fabric needs the mixed solution wettability treatment (the component urea in the mixed solution can be replaced by glycerine, and ratio range is constant) with urea 5~15% (w/w) and citric acid 2~5% (w/w), again dry for standby during with the cation dyes transfer printing.Dacron need be used aqueous solution wettability treatment, the dry for standby of urea 1~5% (w/w).
In the step (4), dyestuff set mode has dewing cold dome, decatize or bakes.Those skilled in the art can be according to the corresponding dyestuff set of the different choice of transfer printing fabric mode; For example three kinds of set modes of REACTIVE DYES all can adopt; ACID DYES and cation dyes only can adopt the set of decatize mode; DISPERSE DYES can adopt decatize or bake the mode set, and above-mentioned dyestuff set mode all is a technology well known to those skilled in the art.
Beneficial effect: method for transfer printing of the present invention, broken through intrinsic transfer printing thinking, saved this program of dewing, saved process time, reduced production cost, reduced the dye transfer difficulty.Because be that dry type shifts, its flower shape fineness is far superior to wet transfer printing, has thoroughly solved wet method and has shifted the difficult problem that can not be applied to the ready-made clothes stamp.
The specific embodiment
According to following embodiment, can understand the present invention better.Yet, those skilled in the art will readily understand that the described concrete material proportion of embodiment, process conditions and result thereof only are used to explain the present invention, and the present invention that should also can not limit in claims to be described in detail.
Embodiment 1:
Polyethylene glycol oxide is used water-soluble, be made into 2% (w/w) solution, coat on the BOPP film with intaglio press, oven dry, rolling is subsequent use.Again with reactive black kn-b 20%, sodium alginate 5%, water 75% is made into ink by weight percentage, selects the flower type, behind the rotary screen printing machines impressing pattern, rolling.Above-mentioned printed transfer film is fitted with the all-cotton knitting cloth of wetting oven dry in advance, together get into the pulley type heat transfer machine, temperature is transferred to 120 ℃, and pressure is transferred to 15Kg/cm 2, after the transfer printing that lining is with transfer film reverse side dewing, good with plastic film wrapped again, prevent moisture loss, put into 15 ℃ of thermostatic chambers, cold dome 16 hours tears the PET film at last, postprocessing working procedures such as washes, and accomplishes TRANSFER PRINTING.
Through test, each item fastness index of the pattern behind the stamp is seen table 1, and is few with the weak effect of wet transfer printing.(GB19817-2005) (GB18401-2003), wherein light fastness is 8 grades with " national textile product basic security technical specification national standard " according to " textiles, FURNISHING FABRIC national standard ", and 1 grade the poorest, and 8 grades best.All the other are 5 grades, and 1 grade the poorest, and 5 grades best, and following form is identical.
Table 1
Figure BSA00000319706100041
Embodiment 2:
PPOX is dissolved with dichloroethanes, be made into 30% (w/w) solution, coat with the scraper type coating machine on the blank sheet of paper of 100 grams, oven dry, rolling is subsequent use.Again with weak acid red B 0.5%, polyvinyl acetal resin 10%, methyl alcohol 89.5% is made into printing ink by weight percentage, selects the flower type, behind the intaglio press impressing pattern, rolling.Above-mentioned printed transfer paper is fitted with the silk fabric of the wetting oven dry in advance of having cut out sheet, together put into flat transfer machine, temperature is transferred to 150 ℃, and pressure is transferred to 25Kg/cm 2, after the transfer printing, lining to be put into steam box with transfer paper evaporated 45 minutes, temperature is 102 ℃.At last, tear transfer paper, postprocessing working procedures such as wash, accomplish TRANSFER PRINTING.
Through test, each item fastness index of the pattern behind the stamp is seen table 2, and is few with the weak effect of wet transfer printing.
Table 2
Figure BSA00000319706100042
Embodiment 3:
Polyethylene glycol oxide is heated to 180 ℃, makes it complete fusion, the molten coating machine of reusable heat is evenly coated polyethylene glycol oxide on the PET film, and rolling is subsequent use.Buy ready-made reactive yellow ink-jet ink again, select the flower type, the rattan air brushing machine of useing force carries out ink-jet printed.Above-mentioned printed transfer film is cut into the ready-made clothes size, fits with the woollen sweater ready-made clothes of wetting oven dry in advance, put into flat transfer machine, temperature is transferred to 160 ℃, and pressure is transferred to 30Kg/cm 2, after the transfer printing, tear transfer film off, with lining with put into steam box and evaporated 60 minutes, temperature is 102 ℃.Postprocessing working procedures such as wash at last, accomplish TRANSFER PRINTING.
Through test, each item fastness index of the pattern behind the stamp is seen table 3, and is few with the weak effect of wet transfer printing.
Table 3
Embodiment 4:
PPOX is heated to 230 ℃, makes it into molten condition, the molten coating machine of reusable heat is coated on the blank sheet of paper of 100 grams, and rolling is subsequent use.Again with cationic blue x-grrl 10%, sodium alginate 5%, water 85% is made into ink by weight percentage, selects the flower type, behind the intaglio press impressing pattern, rolling.Above-mentioned printed transfer paper is fitted with the acrylic fibers lining of wetting oven dry in advance, together put into the pulley type transfer machine, temperature is transferred to 75 ℃, and pressure is transferred to 50Kg/cm 2, after the transfer printing, lining to be put into steam box with transfer paper evaporated 60 minutes, temperature is 102 ℃.At last, tear transfer paper, postprocessing working procedures such as wash, accomplish TRANSFER PRINTING.
Through test, each item fastness index of the pattern behind the stamp is seen table 4, and is few with the weak effect of wet transfer printing.
Table 4
Figure BSA00000319706100051
Embodiment 5:
With oxolane 40%, the dissolving of the mixed solution of water 60% is made into 20% (w/w) solution with polyethylene glycol oxide, coat on the nylon membrane with intaglio press, and oven dry, rolling is subsequent use.Again with disperse red 2BL 5%, CMS 5%, water 90% is made into ink by weight percentage, selects the flower type, behind the flat screen printing machine impressing pattern, rolling.Above-mentioned printed transfer film is fitted with the polyester knitting cloth of wetting oven dry in advance, together get into the pulley type heat transfer machine, temperature is transferred to 75 ℃, and pressure is transferred to 30Kg/cm 2, after the transfer printing, nylon membrane is torn off, putting into temperature is that 230 ℃ of baking ovens baked 3 minutes, washing, TRANSFER PRINTING is accomplished in typing.
Through test, each item fastness index of the pattern behind the stamp is seen table 5, and is few with the weak effect of wet transfer printing.
Table 5
Figure BSA00000319706100052

Claims (9)

1. the transfer method of a fabric flower type is characterized in that this method comprises the steps:
(1) with polyethylene glycol oxide PPOX is water-soluble or the mixed solution of organic solvent or water and organic solvent that paper or plastic film are carried out coating, oven dry, clot is subsequent use; Perhaps, polyethylene glycol oxide or PPOX are heated to molten condition paper or plastic film are coated with again, coated back clot is subsequent use;
(2) utilize dye ink or dyestuff ink that paper or the plastic film that step (1) obtains carried out stamp, process transfer paper or transfer film;
(3) with the printing surface and the fabric laminating to be transferred of transfer paper or transfer film, together get into transfer machine, heating, pressurization realize stamp;
(4) earlier transfer paper or transfer film are peeled off, carried out the dyestuff set again; Perhaps, carry out the dyestuff set earlier, again transfer paper or transfer film are peeled off;
(5), accomplish transfer printing with the fabric processing of washing, finalize the design.
2. the transfer method of fabric flower type according to claim 1 is characterized in that in the step (1), described organic solvent is acetonitrile, carrene, dichloroethanes or toluene.
3. the transfer method of fabric flower type according to claim 1; It is characterized in that in the step (1); The mixed solution of described polyethylene glycol oxide or PPOX water-soluble or organic solvent or water and organic solvent, forming concentration is the solution of 1~40% (w/w).
4. the transfer method of fabric flower type according to claim 1 is characterized in that in the step (1), and polyethylene glycol oxide or PPOX are heated to 70~250 ℃ to molten condition.
5. the transfer method of fabric flower type according to claim 1 is characterized in that in the step (1) that described plastic film is PET film, BOPP film, PE film or nylon membrane.
6. the transfer method of fabric flower type according to claim 1 is characterized in that described dye ink comprises following components in weight percentage in the step (2): dyestuff 0.1~60% connects material 1~20%, organic solvent 20~98.9%.
7. the transfer method of fabric flower type according to claim 1 is characterized in that in the step (2), described dyestuff ink comprises following components in weight percentage: dyestuff 0.1~30% connects material 1~20%, water 50~98.9%.
8. the transfer method of fabric flower type according to claim 1 is characterized in that in the step (2) that the stamp mode is intaglio plate stamp, PLATE SCREAM PRINTING, ROTARY SCREAM PRINTING, flexographic plate stamp or ink-jet printed.
9. the transfer method of fabric flower type according to claim 1 is characterized in that fabric to be transferred passes through wetting, dried in advance in the step (3); After together getting into transfer machine, be heated to 70~250 ℃, be forced into 0.5~50Kg/cm 2
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Address before: 703, room 2, building A, building No. 801, Changzhou research and education port, Changzhou science and Education City, No. 213000 middle Wu Road, Wujin District, Jiangsu, China

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CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20121114

Termination date: 20171015