CN111794002A - Transfer printing method of textile - Google Patents

Transfer printing method of textile Download PDF

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Publication number
CN111794002A
CN111794002A CN202010749609.4A CN202010749609A CN111794002A CN 111794002 A CN111794002 A CN 111794002A CN 202010749609 A CN202010749609 A CN 202010749609A CN 111794002 A CN111794002 A CN 111794002A
Authority
CN
China
Prior art keywords
printing
textile
water
paper
transfer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010749609.4A
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Chinese (zh)
Inventor
谭朴顺
蒋柱
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shaoxing Keqiao Saibang Textile Co ltd
Original Assignee
Shaoxing Keqiao Saibang Textile Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shaoxing Keqiao Saibang Textile Co ltd filed Critical Shaoxing Keqiao Saibang Textile Co ltd
Priority to CN202010749609.4A priority Critical patent/CN111794002A/en
Publication of CN111794002A publication Critical patent/CN111794002A/en
Pending legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003Transfer printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/5214Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613Polyethers without nitrogen
    • D06P1/6131Addition products of hydroxyl groups-containing compounds with oxiranes
    • D06P1/6133Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651Compounds without nitrogen
    • D06P1/65106Oxygen-containing compounds
    • D06P1/65112Compounds containing aldehyde or ketone groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67316Acids

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a transfer printing method of textiles, which relates to a printing and dyeing technology and aims to solve the problems that a large amount of transfer paper is needed during printing and dyeing, the transfer paper is difficult to recycle after printing and can cause serious resource waste, and the key points of the technical scheme are as follows: s1: preparing ink, wherein the ink comprises disperse dye, a dispersing agent, a cosolvent, a preservative, a defoaming agent, a wetting agent and an organic solvent; s2: printing patterns on transfer paper which is water-soluble paper by using prepared ink through a printing roller on a gravure printing machine to prepare printing paper; s3: carrying out modification treatment and pre-swelling treatment on the textile in advance; s4: and (3) feeding the printing paper and the textile into a transfer printing machine for treatment for 20-30 seconds, and transferring the patterns onto the textile. The transfer paper can be fully utilized, and the good quality of the printed textile is ensured.

Description

Transfer printing method of textile
Technical Field
The invention relates to a printing and dyeing technology, in particular to a transfer printing method of a textile.
Background
The transfer printing is to print dye pigment on transfer printing paper, transfer printing and heat treatment to transfer the dye in the pattern to the textile and fix the dye to form the pattern. The most widely used transfer printing method is dry transfer of disperse dyes onto synthetic fiber fabrics. The method is that the disperse dye, paste powder, alcohol, benzene and other solvent are first selected and mixed with resin to form ink, and the ink is printed onto tough paper to form transfer paper. When printing, the surface of the transfer paper with patterns is overlapped with the fabric, and the fabric is hot pressed for about 1min at high temperature (220 ℃), so that the disperse dye is sublimated to be changed into gas, and the gas is transferred to the fabric from the paper. After printing, no water washing treatment is needed, so that no sewage is produced, and the effects of bright color, clear gradation and delicate flower shape can be obtained.
However, the existing ecological problem is that a large amount of transfer paper is needed during printing and dyeing, and the transfer paper is difficult to recycle after printing, which causes serious resource waste.
Therefore, a new solution is needed to solve this problem.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide a transfer printing method for a textile, which can make full use of transfer paper and ensure good quality of the printed textile.
The technical purpose of the invention is realized by the following technical scheme: a method of transfer printing a textile, comprising the steps of:
s1: preparing ink, wherein the ink comprises disperse dye, a dispersing agent, a cosolvent, a preservative, a defoaming agent, a wetting agent and an organic solvent;
s2: printing patterns on transfer paper which is water-soluble paper by using prepared ink through a printing roller on a gravure printing machine to prepare printing paper;
s3: carrying out modification treatment and pre-swelling treatment on the textile in advance;
s4: feeding the printing paper and the textile into a transfer printing machine for treatment for 20-30 seconds, and transferring the patterns onto the textile;
s5: after the printing is finished, putting the textile with the printing and the transfer paper into a first water tank, wherein the first water tank is clear water, and the water temperature in the first water tank is always kept to be higher than 85 ℃, so that the transfer paper is dissolved in the first water tank;
s6: after step S5 is completed, putting powdered sodium hydroxide into the first water pool, standing for 3-5min, then continuing to put powdered monochloroacetic acid, continuing to stand for 3-5min, and finally putting a color fixing agent, wherein the water in the first water pool is replaced after 10-15 batches of textiles are put;
s7: putting the textile in a second water tank after leaving the first water tank, wherein the second water tank is also clear water, the temperature of the water in the second water tank is normal temperature, and soaking the textile in the second water tank for 10 minutes;
s8: and taking the wet textile out of the water tank II, and performing washing, dewatering and drying work.
The invention is further configured to: the dispersing agent comprises 20-45% of fatty alcohol-polyoxyethylene ether, 20-31% of polyvinyl acetate, 5-13% of hydrochloric acid, 30-39% of formaldehyde solution and 5-12.4% of dispersing agent viscosity improver.
The invention is further configured to: the organic solvent is one or more of dimethyl carbonate, diethyl carbonate, absolute ethyl alcohol and the like.
The invention is further configured to: the transfer paper comprises water-soluble vinylon fibers, polyvinyl alcohol and waterproof emulsion, wherein the content of the waterproof emulsion is 0.5-1.6%.
The invention is further configured to: the modification treatment comprises plant fiber modification treatment and animal fiber modification treatment, wherein the plant fiber modification treatment is carried out in a chemical modification mode, and the animal fiber modification treatment is carried out in an ultrasonic modification mode.
The invention is further configured to: the dispersant viscosity improver comprises a ferrous ion salt, and the content of the ferrous ion salt in the ink is more than 5 mg/L.
In conclusion, the invention has the following beneficial effects:
the ink that obtains through the ratio, thereby make it comparatively disperse when the stamp on the transfer paper, the effect of printing and dyeing is better, secondly the ink is not dissolved in aqueous, transfer paper for water-soluble paper has certain water-resistant effect after the ratio again, make the ink print when on transfer paper from this, transfer paper can not take place damaged problem, and after the rendition to the fabrics is accomplished, transfer paper can obtain fully dissolving in hot water, make can not remain the wastepaper of transfer paper on the fabrics, and simultaneously, transfer paper can form the chemical in aqueous, thereby make the fabrics soak wherein, fixed effect and subsequent cleaning performance to the fabrics effectively strengthen, make transfer paper can form the material and come to produce protection or other more excellent effects to the fabrics, make the resource obtain make full use of.
Detailed Description
The present invention will be described in detail with reference to examples.
Example (b):
a method of transfer printing a textile, comprising the steps of:
s1: the ink is prepared and comprises disperse dye, a dispersant, a cosolvent, a preservative, a defoaming agent, a wetting agent and an organic solvent, wherein the dispersant comprises 20% of fatty alcohol-polyoxyethylene ether, 20% of polyvinyl acetate, 5% of hydrochloric acid, 30% of formaldehyde solution and 5% of a dispersant viscosity improver, the dispersant viscosity improver comprises a ferrous ion salt, the content of the ferrous ion salt in the ink is 5mg/L, and the organic solvent is one or more of dimethyl carbonate, diethyl carbonate, absolute ethyl alcohol and the like.
The ink formed by dissolving the disperse dye by the organic solvent has extremely low water content, the disperse dye can be dispersed uniformly by the dispersant, and the twist of the ink can be effectively reduced by the ferrous ion salt, so that the twist of the ink is relatively low, and the condition of overhigh concentration can not occur.
S2: printing patterns on transfer paper which is water-soluble paper by using prepared ink through a plate roller on a gravure printing machine to prepare the printing paper, wherein the transfer paper comprises water-soluble vinylon fibers, polyvinyl alcohol and waterproof emulsion, and the content of the waterproof emulsion is 0.5%.
The transfer paper is water-soluble paper, so that the transfer paper can be melted when meeting water, and the waterproof emulsion with the content of 0.5 percent is contained in the transfer paper, so that the water resistance of the transfer paper is increased to a certain degree, the transfer paper cannot be melted quickly after meeting water, and the problem of damage of the transfer paper cannot occur even if the ink with moisture is printed on the transfer paper.
S3: the textile is subjected to modification treatment and pre-swelling treatment in advance, wherein the modification treatment comprises plant fiber modification treatment and animal fiber modification treatment, the plant fiber modification treatment is carried out in a chemical modification mode, and the animal fiber modification treatment is carried out in an ultrasonic modification mode.
Through modification treatment and pre-swelling treatment, the felting property of wool fibers of the textile is improved, the good anti-wrinkle effect is achieved, and the condition that the wool fibers shrink in the subsequent processing process of the textile is avoided, so that the printed patterns on the fabric deform.
S4: and (3) feeding the printing paper and the textile into a transfer printing machine for treatment for 25 seconds, transferring the patterns onto the textile, transferring the printing patterns on the transfer paper onto the fabric through the transfer printing machine, and fixing the colors.
S5: after the printing, will have the printing and during the fabrics of transferring paper drops into pond one, be the clear water in the pond one, the water temperature keeps the state of 90 degrees centigrade all the time in the pond to make the transfer paper dissolve in pond one, the transfer paper fully dissolves in high temperature aquatic, and can not remain on the fabrics, thereby can not appear the wastepaper on the fabrics that makes people obtain.
S6: after the step S5 is completed, the first water pool is filled with powdered sodium hydroxide and then is kept still for 3min, then the powdered monochloroacetic acid is continuously filled and then is kept still for 3min, finally, the fixing agent is filled, the water in the first water pool is replaced after passing through 15 batches of textiles, the transfer paper is dissolved in the water, the carboxymethyl cellulose exists in the water and reacts with the sodium hydroxide, [ C6H7O2(OH)3] n + naoh → [ C6H7O2(OH)2ONa ] n + nH2O and then reacts with the monochloroacetic acid, [ C6H7O2(OH)2ONa ] n + nClCH2COONa → [ C6H7O2(OH)2OCH2COONa ] n + naci, the sodium carboxymethyl cellulose generated by the reaction can be used as an organic builder and a textile printing and dyeing sizing agent to be attached to the textiles, and the matching agent can effectively fix the color of the patterns on the textiles.
S7: and (3) after leaving the first water tank, putting the textile into a second water tank, wherein the second water tank is also clear water, the temperature of the water in the second water tank is normal temperature, and soaking the textile in the second water tank for standing for 10 minutes, so that the textile can be cleaned to a certain degree.
S8: and taking out the wet textile from the second water tank, and performing cleaning, dewatering and drying work, wherein when the textile is cleaned, the organic builder in the textile can be cleaned more cleanly in the cleaning process, so that people can obtain the pure textile.
The transfer printing is carried out according to the method, so that after printing is finished, the transfer paper cannot become waste, people are required to recover and treat the waste, the waste can be dissolved in water, people can peel the waste from the textile conveniently, the transfer paper can form substances to protect the textile or achieve other excellent effects, and resources are fully utilized.
The above description is only a preferred embodiment of the present invention, and the protection scope of the present invention is not limited to the above embodiments, and all technical solutions belonging to the idea of the present invention belong to the protection scope of the present invention. It should be noted that modifications and embellishments within the scope of the invention may occur to those skilled in the art without departing from the principle of the invention, and are considered to be within the scope of the invention.

Claims (6)

1. A textile transfer printing method is characterized in that: the method comprises the following steps:
s1: preparing ink, wherein the ink comprises disperse dye, a dispersing agent, a cosolvent, a preservative, a defoaming agent, a wetting agent and an organic solvent;
s2: printing patterns on transfer paper which is water-soluble paper by using prepared ink through a printing roller on a gravure printing machine to prepare printing paper;
s3: carrying out modification treatment and pre-swelling treatment on the textile in advance;
s4: feeding the printing paper and the textile into a transfer printing machine for treatment for 20-30 seconds, and transferring the patterns onto the textile;
s5: after the printing is finished, putting the textile with the printing and the transfer paper into a first water tank, wherein the first water tank is clear water, and the water temperature in the first water tank is always kept to be higher than 85 ℃, so that the transfer paper is dissolved in the first water tank;
s6: after step S5 is completed, putting powdered sodium hydroxide into the first water pool, standing for 3-5min, then continuing to put powdered monochloroacetic acid, continuing to stand for 3-5min, and finally putting a color fixing agent, wherein the water in the first water pool is replaced after 10-15 batches of textiles are put;
s7: putting the textile in a second water tank after leaving the first water tank, wherein the second water tank is also clear water, the temperature of the water in the second water tank is normal temperature, and soaking the textile in the second water tank for 10 minutes;
s8: and taking the wet textile out of the water tank II, and performing washing, dewatering and drying work.
2. A method of transfer printing a textile according to claim 1, wherein: the dispersing agent comprises 20-45% of fatty alcohol-polyoxyethylene ether, 20-31% of polyvinyl acetate, 5-13% of hydrochloric acid, 30-39% of formaldehyde solution and 5-12.4% of dispersing agent viscosity improver.
3. A method of transfer printing a textile according to claim 1, wherein: the organic solvent is one or more of dimethyl carbonate, diethyl carbonate, absolute ethyl alcohol and the like.
4. A method of transfer printing a textile according to claim 1, wherein: the transfer paper comprises water-soluble vinylon fibers, polyvinyl alcohol and waterproof emulsion, wherein the content of the waterproof emulsion is 0.5-1.6%.
5. A method of transfer printing a textile according to claim 1, wherein: the modification treatment comprises plant fiber modification treatment and animal fiber modification treatment, wherein the plant fiber modification treatment is carried out in a chemical modification mode, and the animal fiber modification treatment is carried out in an ultrasonic modification mode.
6. A method of transfer printing a textile according to claim 2, wherein: the dispersant viscosity improver comprises a ferrous ion salt, and the content of the ferrous ion salt in the ink is more than 5 mg/L.
CN202010749609.4A 2020-07-30 2020-07-30 Transfer printing method of textile Pending CN111794002A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010749609.4A CN111794002A (en) 2020-07-30 2020-07-30 Transfer printing method of textile

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010749609.4A CN111794002A (en) 2020-07-30 2020-07-30 Transfer printing method of textile

Publications (1)

Publication Number Publication Date
CN111794002A true CN111794002A (en) 2020-10-20

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CN202010749609.4A Pending CN111794002A (en) 2020-07-30 2020-07-30 Transfer printing method of textile

Country Status (1)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101974859A (en) * 2010-09-28 2011-02-16 刘静 Method for transferring pattern of textile fabric
CN102776791A (en) * 2012-08-21 2012-11-14 长胜纺织科技发展(上海)有限公司 Cold transfer decal process of disperse dyes
CN107915783A (en) * 2017-12-06 2018-04-17 浙江理工大学 A kind of method that carboxymethyl cellulose is prepared using waste paper as raw material
CN108265423A (en) * 2018-03-28 2018-07-10 浙江工贸职业技术学院 A kind of processing technology of Wenzhou embroidery embroidered cloth picture on surface
CN110528300A (en) * 2019-08-01 2019-12-03 陈桂川 A kind of preparation method of no aldehyde textile dye-Fixing agents

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101974859A (en) * 2010-09-28 2011-02-16 刘静 Method for transferring pattern of textile fabric
CN102776791A (en) * 2012-08-21 2012-11-14 长胜纺织科技发展(上海)有限公司 Cold transfer decal process of disperse dyes
CN107915783A (en) * 2017-12-06 2018-04-17 浙江理工大学 A kind of method that carboxymethyl cellulose is prepared using waste paper as raw material
CN108265423A (en) * 2018-03-28 2018-07-10 浙江工贸职业技术学院 A kind of processing technology of Wenzhou embroidery embroidered cloth picture on surface
CN110528300A (en) * 2019-08-01 2019-12-03 陈桂川 A kind of preparation method of no aldehyde textile dye-Fixing agents

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
甘文君: "《高分子化学实验原理与技术》", 31 July 2012, 电子科技大学出版社 *

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Application publication date: 20201020

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