CN1308544C - Digital ink jet fabric-treating process - Google Patents

Digital ink jet fabric-treating process Download PDF

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Publication number
CN1308544C
CN1308544C CNB2005100401101A CN200510040110A CN1308544C CN 1308544 C CN1308544 C CN 1308544C CN B2005100401101 A CNB2005100401101 A CN B2005100401101A CN 200510040110 A CN200510040110 A CN 200510040110A CN 1308544 C CN1308544 C CN 1308544C
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China
Prior art keywords
fabric
cationic
ink
treatment
ink jet
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Expired - Fee Related
Application number
CNB2005100401101A
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Chinese (zh)
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CN1707017A (en
Inventor
房宽峻
田安丽
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Jiangnan University
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Jiangnan University
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Priority to CNB2005100401101A priority Critical patent/CN1308544C/en
Publication of CN1707017A publication Critical patent/CN1707017A/en
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Expired - Fee Related legal-status Critical Current
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Abstract

The present invention relates to a digital ink jet printing fabric treating process belonging to the scientific and technical field of textiles. The present invention provides a textile pretreatment process used for a digital ink jet printing technology of aqueous pigment ink, which is suitable for fabrics, such as cotton, hemp, real silk, dacron, polyester cotton, acrylon, etc., and can make the aqueous pigment ink for treated fabrics carry out ink jet printing on a digital ink jet printing machine. A printing product with clear patterns, brilliant colors, good washing fastness, friction fastness and light fastness can be obtained as long as the proper heat treatment is carried out on the fabrics after printing.

Description

A kind of treatment process of digital ink jet fabric
Technical field
A kind of treatment process of digital ink jet fabric belongs to textile science and technical field.
Background technology
Digital ink jet printing technology is a kind of brand-new printing in textiles technology, and development in recent years is very fast, has obtained practical application.Compare with traditional printing technique, this technology need not plate-making, and is simple to operate, has stamp fineness height, no dye loss, advantage such as pollution-free.
Digital inking printing mainly is divided into two classes with ink, i.e. dye-type and color type.Type of dye ink is divided into three kinds of DISPERSE DYES, ACID DYES and REACTIVE DYES etc., and textile inkjet printing mainly uses type of dye ink at present.The major defect of dye ink is: (1) does not have versatility, different fibers need use different dye inks, need use reactive dye ink as cellulose fibre, protein fibre uses acid dye ink, polyester fiber uses DISPERSE DYES ink or the like, and need washer jet and pipeline, troublesome poeration when changing ink.(2) fastness to light of decalcomania is poor because ink-jet printed be a kind of noncontact stamp mode, the dyestuff great majority rest on fabric face, and exist with molecular state, easily by photooxidation.(3) in order to promote the reaction of dyestuff and fiber, improve COLOR FASTNESS, except needs fabric is carried out decatize behind the stamp or bakes to handle making dyestuff anchors on the fiber, also need to wash, soap boiling and back arrangement, removing on the fiber the not dyestuff of set, and make the washing shrinkage, fabric width etc. of fabric reach requirement.Therefore, dye ink is complex process, waste water resource and the energy not only, and have environmental pollution to a certain degree.These drawbacks limit of dye ink the performance of digital ink-jet fabric printing technique advantage, seriously hamper the development and the application of this technology.
Paint ink has versatility, can carry out stamp to any fabric in principle, but in actual applications, the water imbibition of some fabric, armful water-based etc. are relatively poor, and the easy imbibition of decalcomania is painted bright-coloured inadequately, therefore, need carry out certain processing, to satisfy ink-jet printed requirement to it.It is to be noted, adopt the pre-treatment and the pre-treatment of adopting the dye ink PRINTED FABRIC and inequality of the PRINTED FABRIC of paint ink, the former only need add a little auxiliary, substantially do not influence feel, only need carry out suitable heat treatment can obtain the good stamp product of COLOR FASTNESS in ink-jet printed end back, and dye ink must or bake reaching the purpose of fixation by decatize, and also needs washing, oven dry after the fixation.
Summary of the invention
The purpose of this invention is to provide a kind of textile processing technology that is used for the color type tax stamp ink digital ink jet, this technology is applicable to common fabrics such as cotton, fiber crops, real silk, terylene, polyester-cotton blend, acrylic fibers, make it can on ink-jet decorating machine, carry out the ink-jet printed of paint ink, only need after stamp finishes that fabric is carried out suitable heat treatment and just obtain clear patterns, bright in luster, have the stamp product of good washing, friction and light fastness.
Because different organizational structure of fabrics differences, pre-treatment impurity removal process difference, its water imbibition, embrace a water-based and also have nothing in common with each other, therefore, the imbibition carrying out can producing when ink-jet printed to a certain degree reduces the definition of image.For PRINTED FABRIC, obtain decalcomania clearly, just must carry out certain pre-treatment to fabric, make ink on fabric, not produce imbibition or diffusion.Therefore, the invention provides treatment process, can make fabric obtain meticulous, digital printing pattern clearly by this technology at different fabrics.
Because the quality difference of fabric, absorption, reflection to light also have than big difference, this is not quite similar with regard to causing the performance of same color on different fibers, therefore, in practical operation, also need difference according to textile properties, carry out the adjustment of color, saturation degree, make the solid colour that shows on the color of decalcomania and the computer monitor.
The heat-treat condition of fabric should be determined according to the fibre property of forming fabric behind the stamp.Should reduce heat treatment temperature satisfying under the condition of color fastness as far as possible, shorten the processing time.About fabric heat-treat condition and the image adjustment mode that the present invention relates to is described as follows:
1. the fabric that the present invention relates to comprises that natural fabric is as common fabrics such as cotton, fiber crops, real silk, wool and synthetic fiber terylene, acrylic fibers.
2. treatment process of the present invention is meant and uses treatment fluid that fabric is adopted flood, pads, coating or spray-on process are handled, and the liquid carrying rate of fabric is 40-110% after handling, the fabric drying after will handling then or dry.The prescription of this treatment fluid is because of the difference of fabric types difference to some extent.
3. treatment fluid of the present invention is the aqueous solution of thickener and/or cationic auxiliary, one of component wherein is a thickener, comprise sodium alginate, carboxymethyl cellulose, polyvinyl alcohol, polyacrylic acid, polyacrylate, polyacrylamide, polyethylene glycol, starch, dextrin, guar gum, gum Arabic etc., the equal water soluble of these compounds.Can select to use one or more mixing wherein, in the 0-2% scope that do not coexist of its consumption according to fabric types.
4. another component of treatment fluid of the present invention is a cationic auxiliary, mainly containing cation fatty acid derivatives class softener is trihydroxyethyl methylsulfuric acid ester quat, the silicone based softener of CATION is the hydroxy amino silicone oil emulsion, the cationic dyes color-fixing agent is the dicyandiamide formaldehyde resin, cationic surfactant is a dodecyl front three ammonium chloride, dodecyl front three ammonium bromide, cetyl front three ammonium chloride, cetyl front three ammonium bromide, dodecyl benzyl dimethyl ammonium chloride, benzyltriethylammoinium chloride, cationic low molecular compound or cationic high-molecular compound are polyacrylamide.Can select to use wherein one or more.The selection of cationic auxiliary determines that according to the requirement of vividness, fastness and the feel of ink-jet printed pattern its consumption is in the 0%-2% scope.
5. the heat-treat condition of ink-jet printed back of the present invention fabric is 90-180 ℃ dries or bakes 0.5-5min, also can heat-treat with alternate manners such as the hot transfer of blanket.
Beneficial effect of the present invention: the invention provides a kind of textiles pre-treatment process that is used for the aqueous pigment ink Digital ink jet printing technology, be applicable to fabrics such as cotton, fiber crops, real silk, terylene, polyester-cotton blend, acrylic fibers, can make the fabric use paint ink after the processing on the digital inking printing machine, carry out ink-jet printed, only need behind the stamp that fabric is carried out suitable heat treatment and just can obtain clear patterns, bright in luster, have the stamp product of good washing, friction and light fastness.
The specific embodiment
Describe the present invention below in conjunction with embodiment, but the present invention is in no way limited to examples of implementation.
Embodiment 1
Water-based is good, pattern is difficult for imbibition because cotton, wool fabric is embraced, and therefore can directly carry out ink-jet printed.It should be noted that during stamp because this kind fabric is relatively poor to the reflection of light ability, should carry out the adjusting of colour vividness at the image processing method face.Improve the vividness and the color depth of pattern, can handle with following prescription for the treatment of liquid:
Cationic dyes color-fixing agent 1%
Water 99%
Technological process: fabric rolls (pick-up 70%) back oven dry soaking two through two, carries out ink-jet printedly, and stamp finishes back 150 ℃ and bakes 3min and get finished product.
Embodiment 2
The water imbibition of dacron is relatively poor, and the directly ink-jet printed easy generation imbibition of use paint ink can be handled with following treatment fluid:
Polyvinyl alcohol 1%
Polyethylene glycol 0.2%
Cetyl front three ammonium chloride 0.3%
Water 98.5%
Technological process: fabric rolls (pick-up 50%) back oven dry soaking two through two, carry out ink-jet printed, then 180 ℃ of HEAT SETTING 30 seconds finished product.
Because the reflective of terylene is better, therefore, pattern generally need not carry out special treatment.Fabric is behind digital inking printing, and the hot transfer of available blanket formula can obtain feel preferably in 150 ℃ of roll-in 1min.
Embodiment 3
Though the water imbibition of real silk fabric is good, its armful water-based is relatively poor, and available following treatment fluid is handled:
Polyacrylic thickener 2%
Water 98%
Technological process: fabric is through drying after the coating, carries out ink-jet printedly, and 130 ℃ bake 3min and get finished product afterwards.
The fineness of real silk fabric is better, and image is generally based on outstanding stereovision when therefore ink-jet printed.After digital inking printing finished, the hot transfer of also available blanket formula can obtain feel preferably in 110 ℃ of roll-in 1min.
Embodiment 4
Prescription for the treatment of liquid:
Polyacrylamide 1.5%
Trihydroxyethyl methylsulfuric acid ester quat 1%
Water 97.5%
Adopt above treatment fluid to pad to linen, pick-up is 80%, oven dry.Adjust the image vividness before the stamp, carry out digital inking printing, bake 3.5min in 150 ℃ then.
Embodiment 5
Treatment formulations:
Polyethylene glycol 1%
Polyacrylamide 1%
Water 98%
Adopt above treatment fluid to handle to acrylic fabric, technological process is as follows:
Fabric through two soak two roll (pick-up 50%) oven dry after, carry out ink-jet printed, finish the back in 180 ℃ of HEAT SETTING 30 seconds finished product.
Embodiment 6
Prescription for the treatment of liquid:
Starch 1.5%
Benzyltriethylammoinium chloride 1%
Water 97.5%
For polyester-cotton fabric, to handle with above-mentioned treatment fluid, technological process is as follows:
Fabric through two soak two roll (pick-up 70%), oven dry after, carry out ink-jet printed, stamp finish the back 180 ℃ of HEAT SETTING 30 seconds final finished product.
Embodiment 7
Prescription for the treatment of liquid and technology are with embodiment 1, and the hot transfer of blanket formula is adopted in post processing, can improve the PRINTED FABRIC feel.
Embodiment 8
Prescription for the treatment of liquid and technology are with embodiment 4, and the hot transfer of blanket formula is adopted in post processing, can improve the PRINTED FABRIC feel.
Embodiment 9
Prescription for the treatment of liquid and technology are with embodiment 5, and the hot transfer of blanket formula is adopted in post processing, can improve the PRINTED FABRIC feel.
Embodiment 10
Prescription for the treatment of liquid and technology adopt the hot transfer of blanket formula to handle with embodiment 6 after the HEAT SETTING, can improve the PRINTED FABRIC feel.

Claims (4)

1. the treatment process of a digital ink jet fabric, it is characterized in that handling with treatment fluid through the fabric of general pre-treatment, the use paint ink carries out digital inking printing then, again through drying or bake post processing, treatment fluid is the aqueous solution of thickener and/or cationic auxiliary, its mass percent consists of: thickener 0-2%, and cationic auxiliary 0%-2%, all the other are water;
Described thickener is one or more in sodium alginate, carboxymethyl cellulose, polyvinyl alcohol, polyacrylic acid, polyacrylate, polyacrylamide, polyethylene glycol, starch, dextrin, guar gum, the gum Arabic;
Described cationic auxiliary is one or more in cation fatty acid derivatives class softener, the silicone based softener of CATION, cationic dyes color-fixing agent, cationic surfactant, cationic low molecular compound or the cationic high-molecular compound.
2. treatment process according to claim 1, it is characterized in that cation fatty acid derivatives class softener is a trihydroxyethyl methylsulfuric acid ester quat, the silicone based softener of CATION is the hydroxy amino silicone oil emulsion, the cationic dyes color-fixing agent is the dicyandiamide formaldehyde resin, cationic surfactant is a dodecyl front three ammonium chloride, dodecyl front three ammonium bromide, cetyl front three ammonium chloride, cetyl front three ammonium bromide, dodecyl benzyl dimethyl ammonium chloride, benzyltriethylammoinium chloride, cationic low molecular compound or cationic high-molecular compound are polyacrylamide.
3. treatment process according to claim 1, it is characterized in that with flood, pad, coating or spray-on process handle fabric, the liquid carrying rate of handling the back fabric is 40-110%, the fabric drying after will handling then or dry.
4. treatment process according to claim 1 is characterized in that 0.5-5min is dried or baked to the fabric after ink-jet printed at 90-180 ℃, or uses the hot transfer of blanket to heat-treat.
CNB2005100401101A 2005-05-18 2005-05-18 Digital ink jet fabric-treating process Expired - Fee Related CN1308544C (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN1308544C true CN1308544C (en) 2007-04-04

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