CN101705626B - Textile printing method with little amount of water of cotton fabric by utilizing reactive dye - Google Patents
Textile printing method with little amount of water of cotton fabric by utilizing reactive dye Download PDFInfo
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- CN101705626B CN101705626B CN2009101546271A CN200910154627A CN101705626B CN 101705626 B CN101705626 B CN 101705626B CN 2009101546271 A CN2009101546271 A CN 2009101546271A CN 200910154627 A CN200910154627 A CN 200910154627A CN 101705626 B CN101705626 B CN 101705626B
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Abstract
The invention discloses a textile printing method with a little amount of water of cotton fabric by utilizing reactive dye. Light-colored textile printing comprises the following steps: graft modification is firstly carried out on the cotton fibre to ensure that cationic group is introduced in the cotton fibre molecules, so as to increase the adsorption rate of the anionic reactive dye to increase the dye uptake (fixing) of the reactive dye and improve color fastness; and simultaneously, synthetic thickening agent with low content of solid is adopted to be served as the rawstock of the printing paste to reduce the content of solid in the sizing agent of the color paste; fixation accelerator and softening agent are added into the color paste to further improve the color fastness of the printed fabric and improve hand feeling; and washing can be avoided after textile printing. With regard to the middle and deep-coloured textile printing: the rawstock of the print paste adopts modified sodium alginate to increase the washability, thus reducing washing time and water consumption and achieving the purpose of light washing. In the textile printing, the pattern designing, flower version manufacturing, textile printing, decatizing and after finishing processes are identical to traditional process. The invention can shorten the process of dye textile printing, save water and reduce the discharge of sewage simultaneously.
Description
Technical field
The present invention relates to the printing method of textiles, especially relate to a kind of textile printing method with little amount of water of cotton fabric by utilizing reactive dye.
Background technology
At present cotton fabric printing has two kinds of COAT PRINTING and dye printings.
COAT PRINTING is widely used, and accounts for 50～60% of whole stamp production; COAT PRINTING is mat adhesive film forming on fabric, thereby coating is anchored at the printing technology that fabric face obtains required pattern.Have simple to operately, work simplification generally need not washed behind the stamp, soaps, operation such as destarch, energy savings, advantages such as no wastewater problem.But COAT PRINTING is adhered to it on fabric by the adhesive film forming; Because the existence of adhesive; The feel of stamp (particularly large tracts of land stamp) fabric is relatively poor, and simultaneously the epithelium that partly forms at decorative pattern of adhesive exists absorption dust, yellowing, problem such as aging.
And dye printing is different with COAT PRINTING.Because dyestuff has substantivity to fiber, so the thickener that dye printing is used only need be given mill base with certain viscosity and stamp characteristic, so that dyestuff tentatively puts on fabric face with thickener.But behind stamp, need dyestuff is shifted to fibrous inside from mill base through evaporating, so on dye set.At this moment, the function of thickener is also just accomplished, and needs to remove from fabric.In addition, after stamp evaporates, also need remove exist on the fabric not on dye (set) dyestuff be loose colour.Therefore, dye printing behind stamp, also need evaporate, operation such as washing, destarch.In the dye printing, combining of chemistry takes place with fiber in dyestuff, handles through destarch again behind the stamp.Compare with COAT PRINTING, its fabric feeling and washing, fastness such as to soap, wash by rubbing with the hands better, but there is sewage handling problem in its complex process after washing, destarch, ecological environment is existed destroy.
Summary of the invention
Relatively the pluses and minuses of COAT PRINTING and dye printing are taken all factors into consideration both pros and cons, combine current high-quality, high benefit, the heavily development trend and the sustainable productive target that develops again of dyeing realization of the green production of environmental protection of requiring.The object of the present invention is to provide a kind of textile printing method with little amount of water of cotton fabric by utilizing reactive dye.With the COAT PRINTING is foundation, and dye printing is improved, and develops the novel preferably printing method of a kind of PRINTED FABRIC feel, COLOR FASTNESS and printing effect.Thereby the shortening printing technology reaches the purpose that light-water is washed or do not washed, to reduce sewage discharge.
The technical scheme of employing of the present invention has (exempting from washing, light-water developing and printing flower method) two:
One, textile printing method with little amount of water of cotton fabric by utilizing reactive dye: promptly to exempt to wash the technical scheme steps that printing method (this method is adapted to the light stamp of REACTIVE DYES consumption X≤0.5%) adopts following for cotton fabric by utilizing reactive dye:
1. cotton ripe base is fabric graft modified, dyes fixation rate on the increase dyestuff, prescription and technology:
Cotton with grafting agent 30～50g/L, under the normal temperature, two soak two, and to roll back COTTON FABRIC band liquid percentage by weight be 70～80%, 105～120 ℃, and 3～5min is dried;
2. in the dye printing mill base, adopting the synthetic thickening agent of salt tolerant is the major part in the mill base, reduces its solids content, the Essential colour slurry formula, by weight percentage:
REACTIVE DYES consumption X≤0.5%, urea 1～2%, 3～4% salt tolerant synthetic thickening agents slurry 60～70%, strengthening agent 0～5%, softener 0～5%; Ammoniacal liquor or triethanolamine 1～2% add water to 100%.
The described cotton grafting agent that uses is: molecule one end contains reactive group, can react with cotton fiber to combine; The other end contains cation group, helps anionic REACTIVE DYES and cotton fiber and draws close with covalent bonds.
Described synthetic thickening agent is polyacrylic acid or polyacrylate macromolecular compound.
Described strengthening agent to reduce loose colour, improves the COLOR FASTNESS of PRINTED FABRIC in the application of dye printing mill base.
Described softener is amido silicon oil or amodimethicone macromolecular compound, to improve the feel of fabric.
Described urea is the moisture absorption cosolvent, and being added in of it helps dyestuff and dye set from mill base to fibre migration when evaporating.
Described ammoniacal liquor or triethanolamine are alkaline agent, its adding help that dyestuff combines with fiber-reactive and on dye set, ammoniacal liquor or triethanolamine do not resemble sodium bicarbonate or soda ash and join the thickener medium viscosity and can descend simultaneously.
Two, textile printing method with little amount of water of cotton fabric by utilizing reactive dye: cotton fabric by utilizing reactive dye light-water developing and printing flower method (this method be adapted to REACTIVE DYES consumption X be 0.5～5.0% in, deep printing) technical scheme steps of employing is following:
In the printing with reactive dye mill base, adopting the modification sodium alginate is the major part in the mill base, and sodium alginate increases its washability through modification, the Essential colour slurry formula, by weight percentage:
REACTIVE DYES X is 0.5～5.0%, urea 2～4%, and 5～8% modification sodium alginates slurry 60～70%, reserve salt 1～3%, sodium bicarbonate or soda ash 2～4% add water to 100%.
Described modification sodium alginate is in sodium alginate, to add 2～3% anionic detergents, and sodium alginate can increase its washability through modification.
Described urea is the moisture absorption cosolvent, and being added in of it helps dyestuff and dye set from mill base to fibre migration when evaporating;
Described reserve salt is weak oxidant, and being added in of it prevents when evaporating that dyestuff from producing look and becoming;
Described sodium bicarbonate or soda ash are alkaline agent, its adding help that dyestuff combines with fiber-reactive and on dye set.
Comparing the beneficial effect that the present invention has with background technology is:
For light stamp; This technology makes and introduces cation group in the fiber molecule earlier with the cotton fiber graft modification, increases the adsorption rate to anion-active dye; Help REACTIVE DYES and cotton fiber and draw close with covalent bonds, make dyestuff on (set) rate of dying increase and COLOR FASTNESS improves.Be foundation with the COAT PRINTING simultaneously, dye printing is improved, adopt the main magma of low solid content synthetic thickening agent, reduce the content of slurry in the mill base as the dye printing mill base; In mill base, add strengthening agent and softener simultaneously, make the further raising of COLOR FASTNESS of PRINTED FABRIC and the improvement of feel.For in, deep printing, adopting the modification sodium alginate is the major part in the mill base, sodium alginate increases its washability through modification, and washing time and water consumption are reduced.This The Application of Technology can shorten dye printing technology, reaches using water wisely, reduces sewage discharge simultaneously.
Description of drawings
Fig. 1 is light color (dye dosage X≤0.5%) printing technology flow chart.
Fig. 2 is moderate depth (dye dosage X is 0.5～a 2%) printing technology flow chart.
Fig. 3 is dark (dye dosage X is 2～5%) printing technology flow chart.
The specific embodiment
All need behind the COTTON FABRIC dye printing to handle through washing, destarch.The purpose of washing, destarch mainly is dyestuff---the loose colour of removing the slurry on the PRINTED FABRIC and not combining with fiber.Reach and exempt from washing or light-water is washed, decatize behind stamp, dyestuff wants high to the rate of transform of fiber, reduces the loose colour on the fabric behind the stamp, to guarantee the COLOR FASTNESS of PRINTED FABRIC; Require slurry residual on the fabric the least possible simultaneously, to guarantee fabric feeling.
1. cotton fiber graft modification:
Cotton fiber is a native cellulose fibre, contains a large amount of hydroxyls in the fiber molecule and exists, and cotton fiber is after graft modification, and the introducing of cation group in the molecule increases dying (set) rate on the anion-active dye.Grafting agent molecule one end contains reactive group, can react with cotton fiber to combine; The other end contains cation group, helps anion-active dye to drawing close of fiber and reaction bonded.Thereby improve the rate of transform of dyestuff on fiber, loose colour is reduced, the PRINTED FABRIC COLOR FASTNESS is improved; Because dyestuff and interfibrous adhesion improve, the possibility of dyestuff imbibition reduces when stamp and decatize, and the stamp contour sharpness is improved.
2. dye printing mill base modulation:
The print paste modulation is a topmost part in the stamp process, and whether the mill base modulation rationally directly influences the product quality of PRINTED FABRIC.Mill base mainly is made up of colouring agent (dyestuff or coating), slurry (or thickener) and other auxiliary agents.The dye printing mill base mainly is made up of dyestuff, thickener and other auxiliary agents; And coating red ink paste used for seals slurry mainly is made up of coating, adhesive, thickener and other auxiliary agents.The solid content of slurry is low in the paint-printing colour size, can no longer wash after the stamp decatize (baking).The present invention adopts dye printing " coating " mill base concerning light stamp, its mill base mainly is made up of dyestuff, synthetic thickening agent and other auxiliary agents, after the stamp decatize on the fabric residual slurry few, to reach the purpose of exempting to wash.For in, deep printing, adopting the modification sodium alginate is the major part in the mill base, sodium alginate increases its washability through modification, washing time and water consumption is reduced, to reach the purpose that light-water is washed.
3. strengthening agent is in the application of dye printing mill base:
Dyestuff in the dye printing mill base, stamp be after decatize, greatly the part REACTIVE DYES from mill base to fibre migration and with the cotton fiber reaction and combine, remaining dyestuff can further combine and set with fiber through the strengthening agent effect in the mill base.Add the COLOR FASTNESS of strengthening agent in the stamp process with further raising fabric.
4. the application of color-fixing agent in printing with reactive dye
When the REACTIVE DYES deep printing, need further to improve the COLOR FASTNESS of fabric after the washing through fixation treatment.
Embodiment 1: light I (dye dosage X≤0.5%) stamp
(1) stamp process, as shown in Figure 1:
(2) prescription and description of the process:
1) pre-treatment (cotton fiber graft modification) prescription and technology:
The cotton grafting agent HS:30g/L that uses, two soak two rolls (room temperature, band liquid 70～80%), 105～120 ℃ of oven dry (3～5min).
Cotton is provided by Zhejiang Huachen Chemical Products Co., Ltd with grafting agent HS.
2) paste formula and explanation:
REACTIVE DYES 0.05%, urea 1%, 3～4% synthetic thickening agent slurry 70%, ammoniacal liquor 1% adds water to 100%;
Because dye dosage is low, loose colour is few after the stamp decatize, generally no longer washing, destarch.Thereby slurry is entirely with synthetic thickening agent slurry (solid content is low, good hand touch) in the mill base, and synthetic thickening agent (polyacrylic acid) soars chemicals Co., Ltd by Hangzhou and provides;
Urea be added in decatize the time moisture absorption, help dyestuff from mill base to fibre migration and set.The adding of ammoniacal liquor helps and the cotton fiber reaction bonded REACTIVE DYES under alkali condition.Ammoniacal liquor can make the synthetic thickening agent mill base thinning unlike soda ash or sodium bicarbonate simultaneously.
3) other explanation:
Other (design, the making of flower version, stamp, decatize, back arrangement) process is identical with traditional handicraft in the stamp.
Embodiment 2: light II (dye dosage X≤0.5%) stamp
(1) stamp process, as shown in Figure 1:
(2) prescription and description of the process:
1) pre-treatment (cotton fiber graft modification) prescription and technology:
The cotton grafting agent HS:40g/L that uses, two soak two rolls (room temperature, band liquid 70～80%), 105～120 ℃ of oven dry (3～5min).
Cotton is provided by Zhejiang Huachen Chemical Products Co., Ltd with grafting agent HS.
2) paste formula and explanation:
REACTIVE DYES 0.2%, urea 1.5%, 3～4% synthetic thickening agent slurry 65%, strengthening agent 2%, softener 2%; Ammoniacal liquor 2% adds water to 100%;
Because dye dosage is lower, loose colour is few after the stamp decatize, generally no longer washing, destarch.Thereby slurry is entirely with synthetic thickening agent slurry (solid content is low, good hand touch) in the mill base, and synthetic thickening agent (polyacrylic acid) soars chemicals Co., Ltd by Hangzhou and provides;
The adding of strengthening agent increases the set of dyestuff, and the adding of softener improves the feel of fabric, and strengthening agent, softener are provided by Zhejiang Huachen Chemical Products Co., Ltd;
Urea be added in decatize the time moisture absorption, help dyestuff from mill base to fibre migration and set.The adding of ammoniacal liquor helps and the cotton fiber reaction bonded REACTIVE DYES under alkali condition.Ammoniacal liquor can make the synthetic thickening agent mill base thinning unlike soda ash or sodium bicarbonate simultaneously.
3) other explanation:
Other (design, the making of flower version, stamp, decatize, back arrangement) process is identical with traditional handicraft in the stamp.
Embodiment 3: light III (dye dosage X≤0.5%) stamp
(1) stamp process, as shown in Figure 1:
(2) prescription and description of the process:
1) pre-treatment (cotton fiber graft modification) prescription and technology:
The cotton grafting agent HS:50g/L that uses, two soak two rolls (room temperature, band liquid 70～80%), 105～120 ℃ of oven dry (3～5min).
Cotton is provided by Zhejiang Huachen Chemical Products Co., Ltd with grafting agent HS.
2) paste formula and explanation:
REACTIVE DYES 0.5%, urea 2%, 3～4% synthetic thickening agent slurry 60%, strengthening agent 5%, softener 5%; Triethanolamine 2% adds water to 100%;
Same dye dosage is low, and loose colour is few after the stamp decatize, generally no longer washing, destarch.With synthetic thickening agent slurry (solid content is low, good hand touch), synthetic thickening agent (polyacrylic acid) soars chemicals Co., Ltd by Hangzhou and provides slurry entirely in the mill base;
The adding of strengthening agent increases the set (reinforce dosage with dye dosage improve) of dyestuff to fiber, and the adding of softener improves the feel of fabric, and strengthening agent, softener are provided by Zhejiang Huachen Chemical Products Co., Ltd;
Same urea be added in decatize the time moisture absorption, help dyestuff from mill base to fibre migration and set.Triethanolamine is the same with ammoniacal liquor, and its adding makes REACTIVE DYES under alkali condition, help combining with the cotton fiber reaction.Same triethanolamine (alkalescence is higher slightly than ammoniacal liquor) can not make the synthetic thickening agent mill base thinning yet.
3) other explanation:
Other (design, the making of flower version, stamp, decatize, back arrangement) process is identical with traditional handicraft in the stamp.
Embodiment 4: moderate depth I (dye dosage X is 0.5～2.0%) stamp
(1) stamp process, as shown in Figure 2:
(2) prescription and description of the process:
1) paste formula and explanation:
REACTIVE DYES 1%, urea 2%, 5～8% modification sodium alginate 70%, sodium bicarbonate 2%, reserve salt 1% adds water to 100%.
The modification sodium alginate is in the sodium alginate slurry, to add anionic detergent (like detergent 209) 2～3%, and washing agent can make serous coat wetting, expanded, makes the washing property raising of slurry.
Urea be added in decatize the time moisture absorption, help dyestuff from mill base to fibre migration and set.The adding of sodium bicarbonate makes REACTIVE DYES under alkali condition, help combining with the cotton fiber reaction.The adding of reserve salt can be avoided when decatize, possibly the look change can taking place some dyestuff.
3) light-water wash, destarch:
Because dye dosage is moderate, there is certain loose colour to exist after the stamp decatize, need generally that light-water is washed, destarch.Because slurry is a modification sodium alginate slurry in the mill base, washing, destarch are easy.Thereby washing, destarch time and water consumption are about 1/3rd of traditional handicraft.
4) other explanation:
Other (design, the making of flower version, stamp, decatize, back arrangement) process is identical with traditional handicraft in the stamp.
Embodiment 5: moderate depth II (dye dosage X is 0.5～2.0%) stamp
(1) stamp process, as shown in Figure 2:
(2) prescription and description of the process:
1) paste formula and explanation:
REACTIVE DYES 2%, urea 3%, 5～8% modification sodium alginate 65%, soda ash 2%, reserve salt 2% adds water to 100%.
The modification sodium alginate is in the sodium alginate slurry, to add anionic detergent (like washing agent 105) 3%, and washing agent can make serous coat wetting, expanded, makes the washing property raising of slurry.
Same urea be added in decatize the time moisture absorption, help dyestuff from mill base to fibre migration and set.The adding of soda ash (alkalescence is stronger than sodium bicarbonate) makes REACTIVE DYES under alkali condition, help combining with the cotton fiber reaction.The adding of reserve salt can be avoided when decatize, possibly the look change can taking place some dyestuff.
3) light-water wash, destarch:
Because dye dosage is moderate, there is certain loose colour to exist after the stamp decatize, need generally that light-water is washed, destarch.Because slurry is a modification sodium alginate slurry in the mill base, washing, destarch are easy.Thereby washing, destarch time and water consumption are about 1/3rd of traditional handicraft.
4) other explanation:
Other (design, the making of flower version, stamp, decatize, back arrangement) process is identical with traditional handicraft in the stamp.
Embodiment 6: dark I (dye dosage X is 2～5%) stamp
(1) stamp process, as shown in Figure 3:
(2) prescription and description of the process:
1) paste formula and explanation:
REACTIVE DYES 4%, urea 4%, 5～8% modification sodium alginate 60%, soda ash 3%, reserve salt 3% adds water to 100%.
The modification sodium alginate is in the sodium alginate slurry, to add anionic detergent (like washing agent 105) 3%, and washing agent can make serous coat wetting, expanded, makes the washing property raising of slurry.
Same urea be added in decatize the time moisture absorption, help dyestuff from mill base to fibre migration and set.The adding of soda ash makes REACTIVE DYES under alkali condition, help combining with the cotton fiber reaction.The adding of reserve salt can be avoided when decatize, possibly the look change can taking place some dyestuff.
3) light-water wash, destarch, fixation:
Because dye dosage is moderate, there is certain loose colour to exist after the stamp decatize, need generally that light-water is washed, destarch.Because slurry is a modification sodium alginate slurry in the mill base, washing, destarch are easy.Thereby washing, destarch time and water consumption are about 1/2nd of traditional handicraft.Because COLOR FASTNESS is not ideal enough, can improve COLOR FASTNESS for degree of depth stamp through the cationic fixing agent fixation.
4) other explanation:
Other (design, the making of flower version, stamp, decatize, back arrangement) process is identical with traditional handicraft in the stamp.
Embodiment 7: dark II (dye dosage X is 2～5%) stamp
(1) stamp process, as shown in Figure 3:
(2) prescription and description of the process:
1) paste formula and explanation:
REACTIVE DYES 5%, urea 4%, 5～8% modification sodium alginate 60%, soda ash 4%, reserve salt 3% adds water to 100%.
The modification sodium alginate is in the sodium alginate slurry, to add anionic detergent (like washing agent 105) 3%, and washing agent can make serous coat wetting, expanded, makes the washing property raising of slurry.
Same urea be added in decatize the time moisture absorption, help dyestuff from mill base to fibre migration and set.The adding of soda ash makes REACTIVE DYES under alkali condition, help combining with the cotton fiber reaction.The adding of reserve salt can be avoided when decatize, possibly the look change can taking place some dyestuff.
3) light-water wash, destarch, fixation:
Because dye dosage is moderate, there is certain loose colour to exist after the stamp decatize, need generally that light-water is washed, destarch.Because slurry is a modification sodium alginate slurry in the mill base, washing, destarch are easy.Thereby washing, destarch time and water consumption are about 1/2nd of traditional handicraft.Because COLOR FASTNESS is not ideal enough, can improve COLOR FASTNESS for degree of depth stamp through the cationic fixing agent fixation.
4) other explanation:
Other (design, the making of flower version, stamp, decatize, back arrangement) process is identical with traditional handicraft in the stamp.
Claims (5)
1. textile printing method with little amount of water of cotton fabric by utilizing reactive dye is characterized in that: the step of the cotton fabric by utilizing reactive dye light color stamp of REACTIVE DYES consumption X≤0.5% is following:
1. cotton ripe base is fabric graft modified, dyes fixation rate on the increase dyestuff, prescription and technology:
Cotton with grafting agent 30～50g/L, under the normal temperature, two soak two, and to roll back COTTON FABRIC band liquid percentage by weight be 70～80%, 105～120 ℃, and 3～5min is dried;
2. in the printing with reactive dye mill base, adopting the synthetic thickening agent of salt tolerant is the major part in the mill base, reduces its solids content, the Essential colour slurry formula, by weight percentage:
REACTIVE DYES consumption X≤0.5%, urea 1～2%, 3～4% synthetic thickening agents slurry 60～70%, strengthening agent 0～5%, softener 0～5%; Ammoniacal liquor or triethanolamine 1～2% add water to 100%.
2. textile printing method with little amount of water of cotton fabric by utilizing reactive dye according to claim 1 is characterized in that: the described cotton grafting agent that uses is: molecule one end contains reactive group, can react with cotton fiber to combine; The other end contains cation group, helps anionic REACTIVE DYES and cotton fiber and draws close with covalent bonds.
3. textile printing method with little amount of water of cotton fabric by utilizing reactive dye according to claim 1 is characterized in that: described synthetic thickening agent is polyacrylic acid or polyacrylate macromolecular compound.
4. textile printing method with little amount of water of cotton fabric by utilizing reactive dye according to claim 1 is characterized in that: described strengthening agent to reduce loose colour, improves the COLOR FASTNESS of PRINTED FABRIC in the application of dye printing mill base.
5. textile printing method with little amount of water of cotton fabric by utilizing reactive dye according to claim 1 is characterized in that: described softener is amido silicon oil or amodimethicone macromolecular compound.
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| CN2011103670266A Division CN102493221A (en) | 2009-11-23 | 2009-11-23 | Cotton fabric reactive dye printing method with small water volume |
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| CN102392343B (en) * | 2011-06-24 | 2013-07-31 | 南通大学 | Pretreatment and bath-treatment method for modifying cotton fabrics |
| CN103015229A (en) * | 2012-12-17 | 2013-04-03 | 绍兴鼎记印染有限公司 | Anti-flushing slurry for digital printing and using method thereof |
| CN103911880A (en) * | 2013-12-25 | 2014-07-09 | 苏州芳然纺织有限公司 | Thickening agent for textile, and preparation method thereof |
| CN105297416A (en) * | 2014-11-29 | 2016-02-03 | 耿云花 | Preparation method of cotton fabric with formaldehyde removing function |
| CN104480660B (en) * | 2014-12-30 | 2017-01-18 | 区有辉 | Manufacturing process for continuously dyeing and sizing yarn coating |
| CN105507031B (en) * | 2015-12-31 | 2017-09-01 | 浙江劲光纺织科技有限公司 | It is a kind of for slurry of digit printing and its preparation method and application |
| CN105821683A (en) * | 2016-05-14 | 2016-08-03 | 山东黄河三角洲纺织科技研究院有限公司 | Method for preventing printing-free areas of positive-ion-modified cotton fabric from staining |
| CN109440286A (en) * | 2018-12-14 | 2019-03-08 | 山东新丝路工贸股份有限公司 | A kind of preparation process of Non-water washing recycled polyester woollen blanket |
| CN111593585A (en) * | 2020-05-27 | 2020-08-28 | 山东黄河三角洲纺织科技研究院有限公司 | Method for printing-proof reactive dye on cation modified cotton fabric |
| CN111809415A (en) * | 2020-07-07 | 2020-10-23 | 山东黄河三角洲纺织科技研究院有限公司 | Digital printing process of cellulose fiber fabric |
| CN112301761A (en) * | 2020-11-06 | 2021-02-02 | 安徽聚合辐化化工有限公司 | Printing method free of washing or less washing |
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