CN105463878B - A kind of dyeing of denim yarn/ready-made clothes or Staining Method With Agnor Technique - Google Patents

A kind of dyeing of denim yarn/ready-made clothes or Staining Method With Agnor Technique Download PDF

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Publication number
CN105463878B
CN105463878B CN201510908181.2A CN201510908181A CN105463878B CN 105463878 B CN105463878 B CN 105463878B CN 201510908181 A CN201510908181 A CN 201510908181A CN 105463878 B CN105463878 B CN 105463878B
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dyeing
yarn
denim
staining
technique
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CN105463878A (en
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汪媛
何叶丽
陈小利
纪俊玲
晏苏
沙莹
杨坤
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Changzhou University
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Changzhou University
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48Derivatives of carbohydrates
    • D06P1/50Derivatives of cellulose
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/5214Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
    • D06P1/5242Polymers of unsaturated N-containing compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613Polyethers without nitrogen
    • D06P1/6138Polymerisation products of glycols, e.g. Carbowax, Pluronics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds

Abstract

The invention belongs to technical field of textile printing, more particularly to it is a kind of to denim yarn/garment dyeing or the method for resisdye.The technique need not carry out desizing, and yarn/fabrics are padded by coating vital staining liquid, drying, decatize, bake rear wash water processing.Technique involved in the present invention, which overcomes cowboy's pigment dyeing, needs repeatedly (continuous) pad dyeing, it is dark in ability the problem of, reactive dye is not contaminated in dyeing course again, the characteristics of remaining in that cowboy Bai Xin;The complete coating of chromatogram, reactive dyeing are introduced in denim yarn dyeing, is greatly enriched the kind of denim fabric, and it is simple for process.Yarn/fabrics after the method provided by the present invention dyes (or resisdye), cowboy's characteristic is kept, after repeatedly washing, the individual style for imitating old whiting occur.

Description

A kind of dyeing of denim yarn/ready-made clothes or Staining Method With Agnor Technique
Technical field
The invention belongs to technical field of textile printing, more particularly to it is a kind of to denim yarn/garment dyeing or the side of resisdye Method.
Background technology
Traditional denim fabric is that warp dyeing weft yarn is left white the single-face dyeing fabric being interwoven.Typically use bipseudoindoxyl dye First warp thread is dyed on sizing-dyeing machine, then again with true qualities weft yarns;Or using sulphur black dye warp thread again with White latitude is interwoven.The continuous development of industry printing technology is knitted with coloring, and the requirement to denim fabric stylistic style is also increasingly Diversification.The colored jean material country contaminates slurry Joint Production frequently with sulfur dye sheet.Also someone uses exhaust dyeing with pigment technique Produce the colored jean material of granite-wash, mill white and other effects.Reducing dye, reactive dye etc. were also all employed and denim in recent years Dyeing on.In numerous colouring methods, because its technique is simple, the advantages that additive dosage is few, is generally closed for pigment dyeing Note, compared with indigo, active, reduction, vulcanization dyeing, the techniques such as pigment dyeing eliminates oxidation/reduction, washes, soaps, water saving Energy-conservation, improves production efficiency, really realizes the process for cleanly preparing of energy-saving and emission-reduction.
Pigment dyeing is by non-water-soluble pigment, is attached to by auxiliary agents such as adhesive, crosslinking agents on fabric or yarn A kind of colouring method.Because coating is in itself with fabric or yarn without affinity, therefore in dye, phenomena such as dark difficult.Make When being dyed with coating to denim yarn, most technique is that yarn is refined to carry out cationization after (desizing) and change first Property processing, dry after carry out padding coating again, subsequently carry out drying sizing technique again.In order to ensure tinctorial yield, can carry out more Secondary coating pads process, or carries out set dyeing technique again after padding coating.Also have and carry out coating set for openpore denim garment The technique of color, process implementing carry out cation-modified processing again after still carrying out desizing to fabric before.Such as traditional painting Expect ready-made clothes chromatography flow:Openpore ready-made clothes → cation-modified processing (3~5%, 60 DEG C, 20min) → l roads cold water → pigment dyeing → 1 cold water → fastness to wet rubbing agent processing (90 DEG C, 20min) → 1 cold water → drying.
Reactive dye, it is and the dye of upper dye by fiber chemically reactive.Containing can be with this kind of dye molecule The group that fiber chemically reacts, dyestuff and fiber-reactive, form therebetween covalent bond during dyeing, but due to traditional Produce and lack high temperature baking device on the sizing-dyeing machine of denim fabric yarn, the fixation step of reactive dye common process without Method is realized, is easily rinsed during rear road wash water.This is the original that denim fabric yarn dyeing seldom uses reactive dye Cause.This recent someone is transformed equipment, drying cylinder is added in sizing-dyeing machine, is changed to staining bath → drying cylinder → dye Groove.But the technique brings that dyestuff penetration is fast, yarn dye thoroughly after lose yarn ring dye i.e. cowboy Bai Xin effect.Also someone uses First pass through and roll bottom liquid, for preventing dye on reactive dye (by making reactive dye generation and fiber under conditions of sodium trichloroacetate The material of reactionless ability), pure cotton bamboo-joint yarn is imitated cowboy's technique by the mode for the active dye liquor that rerolls.This method technics comparing is answered It is miscellaneous, and auxiliary agent usage amount is higher, it is difficult to adapt to big production.Also have using reactive dye in cowboy's later stage resisdye, usual work Skill is:Refine pre-treatment → dyeing (glauber salt 100g/L, soda ash 30g/L, 60 DEG C) → 2 cold water and wash → the cold water of fixation → 1 → pickling → 1 is soaped the cold wash of → 1 hot wash → 1 → softness → 1 cold water → drying.
The content of the invention
The present invention overcomes cowboy's pigment dyeing in the prior art or the dark difficulty of resisdye, it is necessary to enter in advance to fabric or yarn The cation-modified processing of row;And dye can contaminate denim fabric or yarn thoroughly on reactive dye, and cause to lose cowboy Bai Xin effects The deficiency of fruit, there is provided a kind of new dyeing (or resisdye) method of colored denim yarn/fabric.
In order to solve the above technical problems, the technical solution adopted in the present invention is:A kind of denim yarn/textile dyeing (or Resisdye) method, without carrying out desizing to yarn or fabric, its step is as follows:
(1) pigment printing paste is configured according to the percentage by weight of following each component, and the pH value of adjusting coating mill base is 6~7,
Coating 50%~60%
Cationic binder 20%~30%
Dispersant 10%~30%,
Wherein, coating is commercially available prod, can be inorganic pigment, such as carbon black, titanium dioxide, chrome yellow or is had Machine pigment, such as AZOpigments, phthalocyanine color,
Cationic binder is patented product (CN 101289601), without APEO, without formaldehyde, with pigment printing paste and phase It is good to close the compatibility of auxiliary agent, stable performance, such as cationic binder PDY (Hansi Chemical Article Co., Ltd., Changzhou),
The cationic binder used in the present invention is a kind of polyacrylate adhesive of cationic, there is provided crosslinking Group is combined with fiber, and the composition of cationic binder and the composition of slurry are similar, cowboy cover dyeing technique in without Slurry is washed away,
Dispersant is the one or more therein such as polyvinylpyrrolidone, polypropylene glycol, carboxymethyl cellulose,
During adjusting coating mill base pH value, the pH value regulator of use can be sodium hydroxide, potassium hydroxide, sodium carbonate, carbon One or more in sour hydrogen sodium, acetic acid, formic acid, citric acid;
(2) pigment printing paste prepared in step (1) is configured to dyeing liquor, dyeing liquor each group distribution ratio is as follows, and adjusts The pH value of dyeing liquor is 7~8,
Wherein, reactive dye are commercially available prod,
Adhesive is nonionic adhesive, can be conventional commercial nonionic adhesive,
Bleeding agent can be one or more compoundings in JFC, AEO-15, XL-40, alkyl acyl hydramine, DX;
(3) dyeing liquor of the denim yarn/fabric of non-desizing Jing Guo step (2) being padded, pick-up is 95~110%, Dried by 80~100 DEG C of drying cylinders, decatize (102~110 DEG C, 60~90s), then 3 are baked through 120~130 DEG C of baking oven~ 4min, last wash water processing, drying,
Wherein, involved yarn is sizing or white denim yarn;Denim fabric is the denim fabric after weaving, can be with It is to weave the denim fabric formed through indigo dyeing starching by yarn or formed by yarn through sulfur dyeing starching weaving Denim fabric yarn through the pigment dyeing starching denim fabric that forms of weaving or white denim fabric,
Drying cylinder drying time is 1~3min, and decatize relative humidity is 15~20%.
The beneficial effects of the present invention are:Technique provided by the present invention goes for sizing dyeing, denim fabric dye In color, denim fabric ready-made clothes resisdye.Present invention, avoiding the desizing before cowboy's pigment dyeing and cation-modified pre-treatment, activity The addition of dyestuff, which overcomes cowboy's pigment dyeing, needs repeatedly (continuous) pad dyeing, it is dark in ability the problem of, make reactive dye again It will not be contaminated in dyeing course, the characteristics of remaining in that cowboy Bai Xin.The complete painting of chromatogram is introduced in denim yarn dyeing Material, reactive dyeing, the kind of denim fabric is greatly enriched, and it is simple for process.Contaminated through the method provided by the present invention Yarn/fabrics after color (or resisdye), cowboy's characteristic is kept, after repeatedly washing, the individual style for imitating old whiting occur.
Embodiment
Embodiment 1
Black denim yarn is dyed using sizing
(1) pigment printing paste 1 is configured, its pigment printing paste composition and percentage are as follows:
Coating carbon black 50%
Cationic binder PDY (Hansi Chemical Article Co., Ltd., Changzhou) 30%
Polyvinylpyrrolidone 20%
After above composition uniformly mixes, with lemon acid for adjusting pH to 6.5.
(2) it is as follows that the pigment printing paste 1 for taking step (1) to obtain configures dyeing liquor:
After mixing, pH value is adjusted to 7~8 with sodium carbonate;
(3) by sizing first after hot water soaks, the dyeing liquor by step (2) is padded, pick-up 95%, through 80 The drying of DEG C drying cylinder, decatize (105 DEG C, 60s), then baked through baking oven, 120 DEG C of temperature, time 4min;
(4) washing (1 soap → 1 hot wash → 2 cold wash → drying).
The black denim yarn good color fastness dyed, color is uniform, and feel is excellent, and resistance to dry fastness is up to 4 grades, moisture-proof Crock fastness is up to 3.5 grades, and light fastness is up to 5 grades.The distinctive imitative old style of denim can be obtained after washing.
Comparative example 1
After sizing is first passed through into refining desizing in step (3), then carry out hot water wetting and subsequent operation, the technique such as to pad equal It is same as Example 1.
It is still undesirable to imitate old style after repeatedly washing for the black denim yarn dyed.
Embodiment 2
Imitative old black and blue color cowboy is dyed using indigo denim yarn set
(1) pigment printing paste 2 is configured, its pigment printing paste composition and percentage are as follows:
Coating carbon black 60%
Cationic binder PDY (Hansi Chemical Article Co., Ltd., Changzhou) 30%
CMC 10%
After above composition uniformly mixes, with lemon acid for adjusting pH to 6.
(2) it is as follows that the pigment printing paste 2 for taking step (1) to obtain configures dyeing liquor:
After mixing, pH value is adjusted to 7.5 with sodium acid carbonate;
(3) by indigo yarn first after hot water soaks, the dyeing liquor by step (2) is padded, and pick-up is 100%, dried through 90 DEG C of drying cylinders, decatize (110 DEG C, 60s), then baked through baking oven, 125 DEG C of temperature, time 4min;
(4) washing (1 soap the hot wash of the cold wash of → 1 hot wash → 1 → 1 → 1 cold wash → drying).
The black and blue color denim yarn good color fastness dyed, color is uniform, and feel is excellent, has denim is distinctive to imitate old wind Lattice.Resistance to dry fastness is up to 4, and wet rubbing fastness is up to 3.5 grades, and light fastness is up to 5 grades.
Comparative example 2
After indigo yarn is first passed through into refining desizing in step (3), then carry out hot water wetting and the subsequent operation such as pad, work Skill is same as Example 2.
It is still undesirable to imitate old style after repeatedly washing for the black and blue color denim yarn dyed.
Embodiment 3
Using white cowboy's woven fabric (white ox) (320g/m2) stained yellow coloured silk ox
(1) pigment printing paste 3 is configured, its pigment printing paste composition and percentage are as follows:
Coating chrome yellow 60%
Cationic binder PDY (Hansi Chemical Article Co., Ltd., Changzhou) 25%
Polypropylene glycol 15%
After above composition uniformly mixes, with vinegar acid for adjusting pH to 7.
(2) pigment printing paste 3 obtained in step (1) is taken to configure dyeing liquor as follows:
After mixing, pH value is adjusted to 8 with sodium acid carbonate;
(3) by white ox first after hot water soaks, the dyeing liquor by step (2) is padded, pick-up 105%, warp 100 DEG C of drying cylinder drying, decatize (102 DEG C, 90s), then baked through baking oven, 120 DEG C of temperature, time 4min;
(4) washing (1 soap → 1 hot wash → 1 cold wash → drying).
The yellow denim fabric good color fastness dyed, color is uniform, and feel is excellent, has denim is distinctive to imitate old wind Lattice.Resistance to dry fastness is up to 4, and wet rubbing fastness is up to 3.5 grades, and light fastness is up to 5 grades.
Embodiment 4
Imitative old bronze color ox is dyed using indigo denim fabric
(1) pigment printing paste 4 is configured, its pigment printing paste composition and percentage are as follows:
After above composition uniformly mixes, with first acid for adjusting pH to 6.
(2) pigment printing paste 4 obtained in step (1) is taken to configure dyeing liquor as follows:
After mixing, pH value is adjusted to 8 with sodium carbonate;
(3) by indigo denim fabric first after hot water soaks, the dyeing liquor by step (2) is padded, and pick-up is 98%, dried through 95 DEG C of drying cylinders, decatize (105 DEG C, 80s), then baked through baking oven, 120 DEG C of temperature, time 4min;
(4) washing (1 soap the hot wash of the cold wash of → 1 hot wash → 1 → 1 → 2 cold wash → drying).
The imitative old bronze color ox fabric color fastness dyed is good, and color is characteristic, and feel is excellent, has denim distinctive Imitative old style.Resistance to dry fastness is up to 4, and wet rubbing fastness is up to 3.5 grades, and light fastness is up to 5 grades.

Claims (6)

1. a kind of denim yarn/textile dyeing or Staining Method With Agnor Technique, it is characterised in that:Without carrying out desizing work to yarn or fabric Skill, comprise the following steps that,
(1)Percentage by weight according to following each component configures pigment printing paste, and the pH value of adjusting coating mill base is 6~7,
Coating 50%~60%
Cationic binder 20%~30%
Dispersant 10%~30%,
Described dispersant is one or more of compoundings in polyvinylpyrrolidone, polypropylene glycol, carboxymethyl cellulose;
(2)By step(1)The pigment printing paste of middle preparation is configured to dyeing liquor, and dyeing liquor each group distribution ratio is as follows, and adjusts dyeing The pH value of liquid is 7~8,
10 ~ 50g/L of pigment printing paste
4 ~ 8g/L of adhesive
6 ~ 10g/L of bleeding agent
4 ~ 6g/L of reactive dye
Remaining is water,
Described bleeding agent is one or more compoundings in JFC, AEO-15, XL-40, alkyl acyl hydramine, DX;
(3)Denim yarn/fabric of non-desizing is passed through into step(2)Dyeing liquor pad, dried by drying cylinder, decatize, then pass through Baking oven bakes, last wash water processing, drying.
2. denim yarn/textile dyeing as claimed in claim 1 or Staining Method With Agnor Technique, it is characterised in that:Step(1)Described in Cationic binder is the cationic binder PDY of Hansi Chemical Article Co., Ltd., Changzhou.
3. denim yarn/textile dyeing as claimed in claim 1 or Staining Method With Agnor Technique, it is characterised in that:Step(3)In, pad Pick-up is 95% ~ 110%.
4. denim yarn/textile dyeing as claimed in claim 1 or Staining Method With Agnor Technique, it is characterised in that:Step(3)In, drying cylinder Temperature is 80 ~ 100 DEG C, and drying cylinder drying time is 1 ~ 3min.
5. denim yarn/textile dyeing as claimed in claim 1 or Staining Method With Agnor Technique, it is characterised in that:Step(3)In, decatize Temperature is 102 ~ 110 DEG C, and decatize relative humidity is 15 ~ 20%, and steaming time is 1 ~ 1.5min.
6. denim yarn/textile dyeing as claimed in claim 1 or Staining Method With Agnor Technique, it is characterised in that:Step(3)In, wash water Handle as → hot wash → cold wash of soaping.
CN201510908181.2A 2015-12-10 2015-12-10 A kind of dyeing of denim yarn/ready-made clothes or Staining Method With Agnor Technique Active CN105463878B (en)

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105951417A (en) * 2016-05-07 2016-09-21 鲁泰纺织股份有限公司 Dyeing method of bleached cellulose fiber clothes
CN106120381B (en) * 2016-07-27 2018-08-14 常州大学 It is a kind of to prepare the technique for imitating old style fabric based on bipseudoindoxyl dye pad dyeing
CN106480749B (en) * 2016-10-10 2019-03-05 福建协盛协丰印染实业有限公司 A kind of dyeing improving pure cotton fabric dusty blue sweat light fastness

Citations (4)

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Publication number Priority date Publication date Assignee Title
GB1058966A (en) * 1964-10-23 1967-02-15 Basf Ag Binders for pigment dyeings and prints on fibrous material
CN102605649A (en) * 2012-03-15 2012-07-25 常州大学 Pigment dyeing method of denim yarn
CN104372686A (en) * 2014-08-06 2015-02-25 福建省华奇环保印花有限公司 Four color separation printing dye-based ink formula, preparation and application method thereof
CN104695242A (en) * 2015-03-16 2015-06-10 杭州聚米纺织服饰有限公司 Dyeing process of colored washed denim-imitating clothing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1058966A (en) * 1964-10-23 1967-02-15 Basf Ag Binders for pigment dyeings and prints on fibrous material
CN102605649A (en) * 2012-03-15 2012-07-25 常州大学 Pigment dyeing method of denim yarn
CN104372686A (en) * 2014-08-06 2015-02-25 福建省华奇环保印花有限公司 Four color separation printing dye-based ink formula, preparation and application method thereof
CN104695242A (en) * 2015-03-16 2015-06-10 杭州聚米纺织服饰有限公司 Dyeing process of colored washed denim-imitating clothing

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