CN105463878B - A kind of dyeing of denim yarn/ready-made clothes or Staining Method With Agnor Technique - Google Patents
A kind of dyeing of denim yarn/ready-made clothes or Staining Method With Agnor Technique Download PDFInfo
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- CN105463878B CN105463878B CN201510908181.2A CN201510908181A CN105463878B CN 105463878 B CN105463878 B CN 105463878B CN 201510908181 A CN201510908181 A CN 201510908181A CN 105463878 B CN105463878 B CN 105463878B
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- staining method
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- 238000004043 dyeing Methods 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims abstract description 38
- 238000007447 staining method Methods 0.000 title claims description 8
- 239000004744 fabric Substances 0.000 claims abstract description 32
- 239000000049 pigment Substances 0.000 claims abstract description 30
- 238000001035 drying Methods 0.000 claims abstract description 25
- 238000007639 printing Methods 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000011248 coating agent Substances 0.000 claims abstract description 17
- 238000000576 coating method Methods 0.000 claims abstract description 17
- 239000000985 reactive dye Substances 0.000 claims abstract description 12
- 238000009990 desizing Methods 0.000 claims abstract description 10
- 239000004753 textile Substances 0.000 claims abstract description 9
- 239000007788 liquid Substances 0.000 claims abstract description 3
- 125000002091 cationic group Chemical group 0.000 claims description 12
- 239000011230 binding agent Substances 0.000 claims description 11
- 239000000853 adhesive Substances 0.000 claims description 6
- 230000001070 adhesive effect Effects 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 230000000740 bleeding effect Effects 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 238000013329 compounding Methods 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- -1 alkyl acyl hydramine Chemical compound 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims 1
- 238000010025 steaming Methods 0.000 claims 1
- 239000000975 dye Substances 0.000 abstract description 18
- 238000005406 washing Methods 0.000 abstract description 9
- 238000009970 yarn dyeing Methods 0.000 abstract description 5
- 241000276489 Merlangius merlangus Species 0.000 abstract description 2
- 238000009972 garment dyeing Methods 0.000 abstract description 2
- 238000009980 pad dyeing Methods 0.000 abstract description 2
- 238000004045 reactive dyeing Methods 0.000 abstract description 2
- 238000010186 staining Methods 0.000 abstract description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 7
- 229940097275 indigo Drugs 0.000 description 7
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 7
- 238000004513 sizing Methods 0.000 description 6
- 239000000344 soap Substances 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 238000009955 starching Methods 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- 229910000906 Bronze Inorganic materials 0.000 description 2
- 244000248349 Citrus limon Species 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 239000010974 bronze Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- PGYZAKRTYUHXRA-UHFFFAOYSA-N 2,10-dinitro-12h-[1,4]benzothiazino[3,2-b]phenothiazin-3-one Chemical compound S1C2=CC(=O)C([N+]([O-])=O)=CC2=NC2=C1C=C1SC3=CC=C([N+](=O)[O-])C=C3NC1=C2 PGYZAKRTYUHXRA-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- SAQSTQBVENFSKT-UHFFFAOYSA-M TCA-sodium Chemical compound [Na+].[O-]C(=O)C(Cl)(Cl)Cl SAQSTQBVENFSKT-UHFFFAOYSA-M 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000010016 exhaust dyeing Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000000988 sulfur dye Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
- D06P1/50—Derivatives of cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5242—Polymers of unsaturated N-containing compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6138—Polymerisation products of glycols, e.g. Carbowax, Pluronics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention belongs to technical field of textile printing, more particularly to it is a kind of to denim yarn/garment dyeing or the method for resisdye.The technique need not carry out desizing, and yarn/fabrics are padded by coating vital staining liquid, drying, decatize, bake rear wash water processing.Technique involved in the present invention, which overcomes cowboy's pigment dyeing, needs repeatedly (continuous) pad dyeing, it is dark in ability the problem of, reactive dye is not contaminated in dyeing course again, the characteristics of remaining in that cowboy Bai Xin；The complete coating of chromatogram, reactive dyeing are introduced in denim yarn dyeing, is greatly enriched the kind of denim fabric, and it is simple for process.Yarn/fabrics after the method provided by the present invention dyes (or resisdye), cowboy's characteristic is kept, after repeatedly washing, the individual style for imitating old whiting occur.
Description
Technical field
The invention belongs to technical field of textile printing, more particularly to it is a kind of to denim yarn/garment dyeing or the side of resisdye
Method.
Background technology
Traditional denim fabric is that warp dyeing weft yarn is left white the single-face dyeing fabric being interwoven.Typically use bipseudoindoxyl dye
First warp thread is dyed on sizing-dyeing machine, then again with true qualities weft yarns；Or using sulphur black dye warp thread again with
White latitude is interwoven.The continuous development of industry printing technology is knitted with coloring, and the requirement to denim fabric stylistic style is also increasingly
Diversification.The colored jean material country contaminates slurry Joint Production frequently with sulfur dye sheet.Also someone uses exhaust dyeing with pigment technique
Produce the colored jean material of granite-wash, mill white and other effects.Reducing dye, reactive dye etc. were also all employed and denim in recent years
Dyeing on.In numerous colouring methods, because its technique is simple, the advantages that additive dosage is few, is generally closed for pigment dyeing
Note, compared with indigo, active, reduction, vulcanization dyeing, the techniques such as pigment dyeing eliminates oxidation/reduction, washes, soaps, water saving
Energy-conservation, improves production efficiency, really realizes the process for cleanly preparing of energy-saving and emission-reduction.
Pigment dyeing is by non-water-soluble pigment, is attached to by auxiliary agents such as adhesive, crosslinking agents on fabric or yarn
A kind of colouring method.Because coating is in itself with fabric or yarn without affinity, therefore in dye, phenomena such as dark difficult.Make
When being dyed with coating to denim yarn, most technique is that yarn is refined to carry out cationization after (desizing) and change first
Property processing, dry after carry out padding coating again, subsequently carry out drying sizing technique again.In order to ensure tinctorial yield, can carry out more
Secondary coating pads process, or carries out set dyeing technique again after padding coating.Also have and carry out coating set for openpore denim garment
The technique of color, process implementing carry out cation-modified processing again after still carrying out desizing to fabric before.Such as traditional painting
Expect ready-made clothes chromatography flow：Openpore ready-made clothes → cation-modified processing (3~5%, 60 DEG C, 20min) → l roads cold water → pigment dyeing
→ 1 cold water → fastness to wet rubbing agent processing (90 DEG C, 20min) → 1 cold water → drying.
Reactive dye, it is and the dye of upper dye by fiber chemically reactive.Containing can be with this kind of dye molecule
The group that fiber chemically reacts, dyestuff and fiber-reactive, form therebetween covalent bond during dyeing, but due to traditional
Produce and lack high temperature baking device on the sizing-dyeing machine of denim fabric yarn, the fixation step of reactive dye common process without
Method is realized, is easily rinsed during rear road wash water.This is the original that denim fabric yarn dyeing seldom uses reactive dye
Cause.This recent someone is transformed equipment, drying cylinder is added in sizing-dyeing machine, is changed to staining bath → drying cylinder → dye
Groove.But the technique brings that dyestuff penetration is fast, yarn dye thoroughly after lose yarn ring dye i.e. cowboy Bai Xin effect.Also someone uses
First pass through and roll bottom liquid, for preventing dye on reactive dye (by making reactive dye generation and fiber under conditions of sodium trichloroacetate
The material of reactionless ability), pure cotton bamboo-joint yarn is imitated cowboy's technique by the mode for the active dye liquor that rerolls.This method technics comparing is answered
It is miscellaneous, and auxiliary agent usage amount is higher, it is difficult to adapt to big production.Also have using reactive dye in cowboy's later stage resisdye, usual work
Skill is：Refine pre-treatment → dyeing (glauber salt 100g/L, soda ash 30g/L, 60 DEG C) → 2 cold water and wash → the cold water of fixation → 1
→ pickling → 1 is soaped the cold wash of → 1 hot wash → 1 → softness → 1 cold water → drying.
The content of the invention
The present invention overcomes cowboy's pigment dyeing in the prior art or the dark difficulty of resisdye, it is necessary to enter in advance to fabric or yarn
The cation-modified processing of row；And dye can contaminate denim fabric or yarn thoroughly on reactive dye, and cause to lose cowboy Bai Xin effects
The deficiency of fruit, there is provided a kind of new dyeing (or resisdye) method of colored denim yarn/fabric.
In order to solve the above technical problems, the technical solution adopted in the present invention is：A kind of denim yarn/textile dyeing (or
Resisdye) method, without carrying out desizing to yarn or fabric, its step is as follows：
(1) pigment printing paste is configured according to the percentage by weight of following each component, and the pH value of adjusting coating mill base is 6~7,
Coating 50%~60%
Cationic binder 20%~30%
Dispersant 10%~30%,
Wherein, coating is commercially available prod, can be inorganic pigment, such as carbon black, titanium dioxide, chrome yellow or is had
Machine pigment, such as AZOpigments, phthalocyanine color,
Cationic binder is patented product (CN 101289601), without APEO, without formaldehyde, with pigment printing paste and phase
It is good to close the compatibility of auxiliary agent, stable performance, such as cationic binder PDY (Hansi Chemical Article Co., Ltd., Changzhou),
The cationic binder used in the present invention is a kind of polyacrylate adhesive of cationic, there is provided crosslinking
Group is combined with fiber, and the composition of cationic binder and the composition of slurry are similar, cowboy cover dyeing technique in without
Slurry is washed away,
Dispersant is the one or more therein such as polyvinylpyrrolidone, polypropylene glycol, carboxymethyl cellulose,
During adjusting coating mill base pH value, the pH value regulator of use can be sodium hydroxide, potassium hydroxide, sodium carbonate, carbon
One or more in sour hydrogen sodium, acetic acid, formic acid, citric acid；
(2) pigment printing paste prepared in step (1) is configured to dyeing liquor, dyeing liquor each group distribution ratio is as follows, and adjusts
The pH value of dyeing liquor is 7~8,
Wherein, reactive dye are commercially available prod,
Adhesive is nonionic adhesive, can be conventional commercial nonionic adhesive,
Bleeding agent can be one or more compoundings in JFC, AEO-15, XL-40, alkyl acyl hydramine, DX；
(3) dyeing liquor of the denim yarn/fabric of non-desizing Jing Guo step (2) being padded, pick-up is 95~110%,
Dried by 80~100 DEG C of drying cylinders, decatize (102~110 DEG C, 60~90s), then 3 are baked through 120~130 DEG C of baking oven~
4min, last wash water processing, drying,
Wherein, involved yarn is sizing or white denim yarn；Denim fabric is the denim fabric after weaving, can be with
It is to weave the denim fabric formed through indigo dyeing starching by yarn or formed by yarn through sulfur dyeing starching weaving
Denim fabric yarn through the pigment dyeing starching denim fabric that forms of weaving or white denim fabric,
Drying cylinder drying time is 1~3min, and decatize relative humidity is 15~20%.
The beneficial effects of the present invention are：Technique provided by the present invention goes for sizing dyeing, denim fabric dye
In color, denim fabric ready-made clothes resisdye.Present invention, avoiding the desizing before cowboy's pigment dyeing and cation-modified pre-treatment, activity
The addition of dyestuff, which overcomes cowboy's pigment dyeing, needs repeatedly (continuous) pad dyeing, it is dark in ability the problem of, make reactive dye again
It will not be contaminated in dyeing course, the characteristics of remaining in that cowboy Bai Xin.The complete painting of chromatogram is introduced in denim yarn dyeing
Material, reactive dyeing, the kind of denim fabric is greatly enriched, and it is simple for process.Contaminated through the method provided by the present invention
Yarn/fabrics after color (or resisdye), cowboy's characteristic is kept, after repeatedly washing, the individual style for imitating old whiting occur.
Embodiment
Embodiment 1
Black denim yarn is dyed using sizing
(1) pigment printing paste 1 is configured, its pigment printing paste composition and percentage are as follows：
Coating carbon black 50%
Cationic binder PDY (Hansi Chemical Article Co., Ltd., Changzhou) 30%
Polyvinylpyrrolidone 20%
After above composition uniformly mixes, with lemon acid for adjusting pH to 6.5.
(2) it is as follows that the pigment printing paste 1 for taking step (1) to obtain configures dyeing liquor：
After mixing, pH value is adjusted to 7~8 with sodium carbonate；
(3) by sizing first after hot water soaks, the dyeing liquor by step (2) is padded, pick-up 95%, through 80
The drying of DEG C drying cylinder, decatize (105 DEG C, 60s), then baked through baking oven, 120 DEG C of temperature, time 4min；
(4) washing (1 soap → 1 hot wash → 2 cold wash → drying).
The black denim yarn good color fastness dyed, color is uniform, and feel is excellent, and resistance to dry fastness is up to 4 grades, moisture-proof
Crock fastness is up to 3.5 grades, and light fastness is up to 5 grades.The distinctive imitative old style of denim can be obtained after washing.
Comparative example 1
After sizing is first passed through into refining desizing in step (3), then carry out hot water wetting and subsequent operation, the technique such as to pad equal
It is same as Example 1.
It is still undesirable to imitate old style after repeatedly washing for the black denim yarn dyed.
Embodiment 2
Imitative old black and blue color cowboy is dyed using indigo denim yarn set
(1) pigment printing paste 2 is configured, its pigment printing paste composition and percentage are as follows：
Coating carbon black 60%
Cationic binder PDY (Hansi Chemical Article Co., Ltd., Changzhou) 30%
CMC 10%
After above composition uniformly mixes, with lemon acid for adjusting pH to 6.
(2) it is as follows that the pigment printing paste 2 for taking step (1) to obtain configures dyeing liquor：
After mixing, pH value is adjusted to 7.5 with sodium acid carbonate；
(3) by indigo yarn first after hot water soaks, the dyeing liquor by step (2) is padded, and pick-up is
100%, dried through 90 DEG C of drying cylinders, decatize (110 DEG C, 60s), then baked through baking oven, 125 DEG C of temperature, time 4min；
(4) washing (1 soap the hot wash of the cold wash of → 1 hot wash → 1 → 1 → 1 cold wash → drying).
The black and blue color denim yarn good color fastness dyed, color is uniform, and feel is excellent, has denim is distinctive to imitate old wind
Lattice.Resistance to dry fastness is up to 4, and wet rubbing fastness is up to 3.5 grades, and light fastness is up to 5 grades.
Comparative example 2
After indigo yarn is first passed through into refining desizing in step (3), then carry out hot water wetting and the subsequent operation such as pad, work
Skill is same as Example 2.
It is still undesirable to imitate old style after repeatedly washing for the black and blue color denim yarn dyed.
Embodiment 3
Using white cowboy's woven fabric (white ox) (320g/m2) stained yellow coloured silk ox
(1) pigment printing paste 3 is configured, its pigment printing paste composition and percentage are as follows：
Coating chrome yellow 60%
Cationic binder PDY (Hansi Chemical Article Co., Ltd., Changzhou) 25%
Polypropylene glycol 15%
After above composition uniformly mixes, with vinegar acid for adjusting pH to 7.
(2) pigment printing paste 3 obtained in step (1) is taken to configure dyeing liquor as follows：
After mixing, pH value is adjusted to 8 with sodium acid carbonate；
(3) by white ox first after hot water soaks, the dyeing liquor by step (2) is padded, pick-up 105%, warp
100 DEG C of drying cylinder drying, decatize (102 DEG C, 90s), then baked through baking oven, 120 DEG C of temperature, time 4min；
(4) washing (1 soap → 1 hot wash → 1 cold wash → drying).
The yellow denim fabric good color fastness dyed, color is uniform, and feel is excellent, has denim is distinctive to imitate old wind
Lattice.Resistance to dry fastness is up to 4, and wet rubbing fastness is up to 3.5 grades, and light fastness is up to 5 grades.
Embodiment 4
Imitative old bronze color ox is dyed using indigo denim fabric
(1) pigment printing paste 4 is configured, its pigment printing paste composition and percentage are as follows：
After above composition uniformly mixes, with first acid for adjusting pH to 6.
(2) pigment printing paste 4 obtained in step (1) is taken to configure dyeing liquor as follows：
After mixing, pH value is adjusted to 8 with sodium carbonate；
(3) by indigo denim fabric first after hot water soaks, the dyeing liquor by step (2) is padded, and pick-up is
98%, dried through 95 DEG C of drying cylinders, decatize (105 DEG C, 80s), then baked through baking oven, 120 DEG C of temperature, time 4min；
(4) washing (1 soap the hot wash of the cold wash of → 1 hot wash → 1 → 1 → 2 cold wash → drying).
The imitative old bronze color ox fabric color fastness dyed is good, and color is characteristic, and feel is excellent, has denim distinctive
Imitative old style.Resistance to dry fastness is up to 4, and wet rubbing fastness is up to 3.5 grades, and light fastness is up to 5 grades.
Claims (6)
1. a kind of denim yarn/textile dyeing or Staining Method With Agnor Technique, it is characterised in that：Without carrying out desizing work to yarn or fabric
Skill, comprise the following steps that,
（1）Percentage by weight according to following each component configures pigment printing paste, and the pH value of adjusting coating mill base is 6~7,
Coating 50%~60%
Cationic binder 20%~30%
Dispersant 10%~30%,
Described dispersant is one or more of compoundings in polyvinylpyrrolidone, polypropylene glycol, carboxymethyl cellulose；
（2）By step（1）The pigment printing paste of middle preparation is configured to dyeing liquor, and dyeing liquor each group distribution ratio is as follows, and adjusts dyeing
The pH value of liquid is 7~8,
10 ~ 50g/L of pigment printing paste
4 ~ 8g/L of adhesive
6 ~ 10g/L of bleeding agent
4 ~ 6g/L of reactive dye
Remaining is water,
Described bleeding agent is one or more compoundings in JFC, AEO-15, XL-40, alkyl acyl hydramine, DX；
（3）Denim yarn/fabric of non-desizing is passed through into step（2）Dyeing liquor pad, dried by drying cylinder, decatize, then pass through
Baking oven bakes, last wash water processing, drying.
2. denim yarn/textile dyeing as claimed in claim 1 or Staining Method With Agnor Technique, it is characterised in that：Step（1）Described in
Cationic binder is the cationic binder PDY of Hansi Chemical Article Co., Ltd., Changzhou.
3. denim yarn/textile dyeing as claimed in claim 1 or Staining Method With Agnor Technique, it is characterised in that：Step（3）In, pad
Pick-up is 95% ~ 110%.
4. denim yarn/textile dyeing as claimed in claim 1 or Staining Method With Agnor Technique, it is characterised in that：Step（3）In, drying cylinder
Temperature is 80 ~ 100 DEG C, and drying cylinder drying time is 1 ~ 3min.
5. denim yarn/textile dyeing as claimed in claim 1 or Staining Method With Agnor Technique, it is characterised in that：Step（3）In, decatize
Temperature is 102 ~ 110 DEG C, and decatize relative humidity is 15 ~ 20%, and steaming time is 1 ~ 1.5min.
6. denim yarn/textile dyeing as claimed in claim 1 or Staining Method With Agnor Technique, it is characterised in that：Step（3）In, wash water
Handle as → hot wash → cold wash of soaping.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105951417A (en) * | 2016-05-07 | 2016-09-21 | 鲁泰纺织股份有限公司 | Dyeing method of bleached cellulose fiber clothes |
| CN106120381B (en) * | 2016-07-27 | 2018-08-14 | 常州大学 | It is a kind of to prepare the technique for imitating old style fabric based on bipseudoindoxyl dye pad dyeing |
| CN106480749B (en) * | 2016-10-10 | 2019-03-05 | 福建协盛协丰印染实业有限公司 | A kind of dyeing improving pure cotton fabric dusty blue sweat light fastness |
| CN110983822B (en) * | 2019-12-30 | 2022-06-07 | 张家港三得利染整科技有限公司 | Coating composition for yarn pigment dyeing |
| CN111074657A (en) * | 2019-12-30 | 2020-04-28 | 张家港三得利染整科技有限公司 | Dyeing method of colored denim yarn |
| CN111254723A (en) * | 2020-02-27 | 2020-06-09 | 深圳全棉时代科技有限公司 | Manufacturing method of fabric with double-color effect |
| CN113026386B (en) * | 2021-04-01 | 2021-11-16 | 浙江日升服装有限公司 | Garment fabric dyeing and finishing process |
| CN115613374B (en) * | 2022-09-09 | 2024-06-14 | 广东溢达纺织有限公司 | Fabric with color change effect, washing method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1058966A (en) * | 1964-10-23 | 1967-02-15 | Basf Ag | Binders for pigment dyeings and prints on fibrous material |
| CN102605649A (en) * | 2012-03-15 | 2012-07-25 | 常州大学 | Pigment dyeing method of denim yarn |
| CN104372686A (en) * | 2014-08-06 | 2015-02-25 | 福建省华奇环保印花有限公司 | Four color separation printing dye-based ink formula, preparation and application method thereof |
| CN104695242A (en) * | 2015-03-16 | 2015-06-10 | 杭州聚米纺织服饰有限公司 | Dyeing process of colored washed denim-imitating clothing |
-
2015
- 2015-12-10 CN CN201510908181.2A patent/CN105463878B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1058966A (en) * | 1964-10-23 | 1967-02-15 | Basf Ag | Binders for pigment dyeings and prints on fibrous material |
| CN102605649A (en) * | 2012-03-15 | 2012-07-25 | 常州大学 | Pigment dyeing method of denim yarn |
| CN104372686A (en) * | 2014-08-06 | 2015-02-25 | 福建省华奇环保印花有限公司 | Four color separation printing dye-based ink formula, preparation and application method thereof |
| CN104695242A (en) * | 2015-03-16 | 2015-06-10 | 杭州聚米纺织服饰有限公司 | Dyeing process of colored washed denim-imitating clothing |
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