CN105862414B - A kind of method for improving the rich and gaudy degree of pigment printing color and fastness - Google Patents

A kind of method for improving the rich and gaudy degree of pigment printing color and fastness Download PDF

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Publication number
CN105862414B
CN105862414B CN201610238844.9A CN201610238844A CN105862414B CN 105862414 B CN105862414 B CN 105862414B CN 201610238844 A CN201610238844 A CN 201610238844A CN 105862414 B CN105862414 B CN 105862414B
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fastness
pigment printing
work liquid
finishing
fabric
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CN201610238844.9A
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CN105862414A (en
Inventor
房宽峻
陈凯玲
张磊
李付杰
胡立华
刘立诗
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SHANDONG HUANGHE DELTA INSTITUTE OF TEXTILE SCIENCE AND TECHNOLOGY Co Ltd
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SHANDONG HUANGHE DELTA INSTITUTE OF TEXTILE SCIENCE AND TECHNOLOGY Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46Compounds containing quaternary nitrogen atoms
    • D06M13/467Compounds containing quaternary nitrogen atoms derived from polyamines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/04Processes in which the treating agent is applied in the form of a foam
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coloring (AREA)

Abstract

The present invention discloses a kind of method for improving the rich and gaudy degree of pigment printing color and fastness, and step is:Pretreatment work liquid is prepared first, and then the pretreatment work liquid of preparation is applied to by the arrangement of dip finishing, padding finishing, foam finishing or hydrojet on fabric, carries out pigment printing after drying;Wherein pretreatment work liquid includes following components by weight percentage:Cationic surfactant 1 10%, softening agent 0.1 5%, fastness elevator 0.5 10%, add deionized water to 100%.The apparent increase of the rich and gaudy degree of pigment printing fabric color obtained by present invention process, fastness significantly improves, soft.

Description

A kind of method for improving the rich and gaudy degree of pigment printing color and fastness
Technical field
The present invention relates to a kind of methods for improving the rich and gaudy degree of pigment printing color and fastness, belong to weaving pigment printing and locate in advance Manage technical field.
Background technology
Pigment printing is that will not have compatibility and the granules of pigments of reactivity to be adhered on fiber to fabric using adhesive With the printing technology of pattern needed for acquisition.Since pigment printing technique is to fiber non-selectivity, it is suitble to various fibers and its blended Fabric, the pattern contour of printing is clear, and pigment printing paste chromatography is complete, easy colorant match, while its process is simple, need not evaporate water It washes, meets the environmental requirement of energy-saving and emission-reduction, therefore pigment printing is using more and more extensive.But in pigment printing production mistake There are the contradictions between fastness, feel and tinctorial yield always in journey.It is soft in guarantee for middle dark paint Printing In the case of, the fastness index request for reaching client is the technical barrier that pigment printing worker's needs are broken through.At present, it is main Settling mode is to select soft imitative reactive printing adhesive soft to achieve the purpose that, but in such adhesive in itself Softening agent ingredient is blended, affects the dry fastness of PRINTED FABRIC, while relatively low glass transition temperature leads to adhesive Conjunctiva is too fast, and plug net problem is serious when causing stamp, affects product quality and production efficiency.Therefore, it is necessary to consider coating The fabric of stamp is pre-processed to solve the contradiction between fastness, feel and tinctorial yield.
At present, only a small amount of research to the pretreatment of pigment printing fabric.103741512 A of CN disclose a kind of lint system Resin cation, is first modified fabric by way of dip finishing by product pigment printing technique, then carries out pigment printing, Fastness elevator is finally added in tentering final finishing, obtains that fastness is good, pigment printing product of good hand touch.But the technique is soaked Stain pretreatment time is longer, and the promotion of fastness is the addition fastness elevator in tentering post-finishing liquid, increases the friendship of adhesive Connection degree improves fastness.More than patented technology carries out cation-modified promoted with fastness of fabric step by step, increases processing stream Journey.100500982 C of CN are disclosed a kind of improved using Gemini type cationic compound and improve ink-jet printed image performance Method, this method carry out fabric maceration extract dip finishing or padding finishing, then through drying using Gemini type cationic compound It is dry, ink-jet printed.Fabric is significantly improved through treated cation rear defence imbibition increase with obvious effects, the rich and gaudy degree of color in the patent, Feel also be improved significantly.But this patent is pre-processed for ink-jet printed fabric, fastness mainly passes through paint ink It is controlled, if the method is directly applied in the pretreatment of pigment printing fabric, adhesive film forming fastness is difficult to ensure that, works as visitor When family is to fastness and feel more demanding simultaneously, it is difficult to reach requirement.
Invention content
For the deficiency of above-mentioned technology, the invention discloses a kind of sides for improving the rich and gaudy degree of pigment printing color and fastness Method, the pretreatment work liquid in this method include the groups such as a kind of cationic compound of special construction, softening agent, fastness elevator Point, it acts synergistically between these components, improves the printing effect of pigment printing fabric.Wherein, using this special construction Cationic compound, which pre-processes fabric, can effectively prevent the pigment printing paste back of the body to blend imbibition, and then improves pigment printing and knit The color depth and pattern definition of object, while the cationic compound of the special construction has excellent frothing capacity, for bubble Foam single-face finishing is provided convenience, and saves energy consumption;Softening agent assigns the feel of soft fabric;The addition of fastness elevator improves Binding strength between cellulosic molecule and binder molecule reduces the dosage of adhesive in mill base, promotes feel indirectly, simultaneously The phenomenon that adhesive conjunctiva caused by adding in crosslinking agent in print paste is too fast is avoided to occur, and then effectively alleviate coating Stamp plug net problem, improves product quality and production efficiency.And formaldehyde etc. is not contained in the pretreatment work liquid of the present invention Harmful substance, ecological, environmental protective are pollution-free.
The technical proposal of the invention is realized in this way:Pretreatment work liquid is prepared first, then by the pretreatment of preparation Working solution by the arrangement of dip finishing, padding finishing, foam finishing or hydrojet be applied to by it is conventional singe, desizing, kiering, drift On fabric after the processing of white or mercerising, pigment printing is carried out after drying;Wherein pretreatment work liquid wraps by weight percentage Include following components:Cationic surfactant 1 ~ 10%, softening agent 0.1-5%, fastness elevator 0.5 ~ 10%, add deionized water extremely 100%。
The cationic surfactant is with below formula:
The softening agent is organic silicon, quaternary amine salt form.
The fastness elevator is epoxies, aziridines, polyurethanes, twain-aldehyde compound, silane coupling agent class.
What pretreatment work liquid of the present invention can be arranged by dip finishing, padding finishing, foam finishing or hydrojet Mode is arranged by routinely singing, on the fabric after the processing of desizing, kiering, bleaching or mercerising.For the technique of dip finishing For:10 ~ 50 DEG C of pretreatment work liquid temperature, pH value 7 ~ 9, bath raio 1:30,2 ~ 15min of dip time;For the work of padding finishing Skill is:10 ~ 50 DEG C of pretreatment work liquid temperature, pH value 7 ~ 9, pick-up 60 ~ 90%;It is for the technique of foam finishing:Pretreatment 10 ~ 50 DEG C of working solution temperature, pH value 7 ~ 9, liquid carrying rate 20 ~ 40%;For hydrojet arrange technique be:Pretreatment fluid temperature 10 ~ 50 DEG C, pH value 7 ~ 9, liquid carrying rate 10 ~ 30%.
Beneficial effects of the present invention
The present invention provides a kind of method for improving the rich and gaudy degree of pigment printing color and fastness, the coating obtained by this method The rich and gaudy degree of color and fastness of stamp are higher, soft, and cloth face color is uniform.
Specific embodiment
The present invention is described in further detail with reference to specific embodiment, but does not limit the use scope of the present invention.
A kind of technical solution implementation process for the method for improving the rich and gaudy degree of pigment printing color and fastness of the present invention is as follows:
(1)Pretreatment work liquid is prepared:
Pretreatment work liquid of the present invention, by weight percentage including following components:Cationic surfactant 1 ~ 10%, softening agent 0.1-5%, fastness elevator 0.5 ~ 10%, add deionized water to 100%.
The above-mentioned cationic surfactant of precise stirs evenly in deionized water, and under stirring condition by Softening agent, fastness elevator are added dropwise to, pretreatment work liquid is obtained after being sufficiently stirred.
(2)Pretreatment work liquid Collator Mode is:Dip finishing, padding finishing, foam finishing or hydrojet arrange.
A uses dip finishing
Through routine is singed, the fabric after the processing of desizing, kiering, bleaching or mercerising uses above-mentioned pretreatment work liquid dipping whole Reason, inorganic agent temperature are 10 ~ 50 DEG C, and pH value is 7 ~ 9, and fabric and pretreatment work bath of liquid ratio are 1:30, dip time for 2 ~ 15min。
B uses padding finishing
Fabric after routine is singed, desizing, kiering, bleaching or mercerising are processed is padded whole using above-mentioned pretreatment work liquid Reason, pretreatment fluid temperature are 10 ~ 50 DEG C, and pH value is 7 ~ 9, and pick-up is 60 ~ 90%.
C uses foam finishing
Through routine is singed, the fabric after the processing of desizing, kiering, bleaching or mercerising uses above-mentioned pretreatment work vacuole foam whole Reason, pretreatment work liquid temperature are 10 ~ 50 DEG C, and pH value is 7 ~ 9, and liquid carrying rate is 20 ~ 40%.
D is arranged using hydrojet
Through routine is singed, the fabric after the processing of desizing, kiering, bleaching or mercerising uses above-mentioned pretreatment work liquid hydrojet whole Reason, pretreatment work liquid temperature are 10 ~ 50 DEG C, and pH value is 7 ~ 9, and liquid carrying rate is 10 ~ 30%.
(3)Drying-stamp-bakes-tentering
The complete fabric of above-mentioned pretreatment is dried under the conditions of 60 ~ 120 DEG C, routinely pigment printing technique stamp, 160 DEG C Bake 2min.
In comparative example of the present invention and embodiment the color data of pigment printing fabric using 650 colour photometers of Datacolor into Row test, crock fastness according to《GB/T 3920-2008 textile color stabilities test colour fastness to rubbing》Test.Wherein compare Compared with the fabric that example is the pretreatment work liquid processing without the present invention.
Embodiment 1
A kind of method for improving the rich and gaudy degree of pigment printing color and fastness, includes the following steps:
Prepare pretreatment work liquid:Include following components by weight percentage:Trimethylene-bis-(Dimethyl Ammonium chloride)2%th, dimethyl silicone polymer 0.5%, fastness elevator UN-125F(Shanghai You En Chemical Co., Ltd.s)1 %, adds Deionized water is to 100%.Take 2% trimethylene-bis-(Dodecyl dimethyl ammonium chloride)In deionized water, stir evenly, 0.5% dimethyl silicone polymer and 1% fastness elevator UN-125F are added dropwise under stirring condition, coating is obtained after being sufficiently stirred Stamp pretreatment work liquid.
With above-mentioned pretreatment work liquid to using it is conventional singe, the fabric after the processing of desizing, kiering, bleaching or mercerising into Row pads pretreatment, and pretreatment work liquid temperature is 23 DEG C, pH value 7, pick-up 75%, and 100 DEG C of drying, then with red Color mill base carries out pigment printing, bakes 2min through 160 DEG C after hot-air seasoning.
Comparative example 1
It singes to use routine, the fabric after the processing of desizing, kiering, bleaching or mercerising is directly with same as Example 1 Red mill base carries out pigment printing, and 2min is baked through 160 DEG C after hot-air seasoning.
Color data, fastness index and the hand valuation of encrimson PRINTED FABRIC are shown in Table 1.
Embodiment 2
A kind of method for improving the rich and gaudy degree of pigment printing color and fastness, includes the following steps:
Prepare pretreatment work liquid:Include following components by weight percentage:Hexa-methylene-bis-(Dimethyl Ammonium chloride)5%th, amino-modified silicone oil 0.5%, fastness elevator UN-125F 2%, add deionized water to 100%.Take 5% six Asias Methyl-bis-(Dodecyl dimethyl ammonium chloride)It in deionized water, stirs evenly, 0.5% amino is added dropwise under stirring condition Modified silicon oil and 2% fastness elevator UN-125F, obtain pigment printing pretreatment work liquid after being sufficiently stirred.
With above-mentioned pretreatment work liquid to using it is conventional singe, the fabric after the processing of desizing, kiering, bleaching or mercerising into Row foam finishing pre-processes, and pretreatment work liquid temperature is 20 DEG C, pH value 7, liquid carrying rate 25%, and 100 DEG C of drying, then Pigment printing is carried out with black color paste, and 2min is baked through 160 DEG C after hot-air seasoning.
Comparative example 2
It singes to use routine, the fabric after the processing of desizing, kiering, bleaching or mercerising is directly with same as Example 2 Black color paste carries out pigment printing, bakes 2min through 160 DEG C after hot-air seasoning.
Color data, fastness index and the hand valuation of blacking PRINTED FABRIC are shown in Table 2.
Embodiment 3
A kind of method for improving the rich and gaudy degree of pigment printing color and fastness, includes the following steps:
Prepare pretreatment work liquid:Include following components by weight percentage:Hexa-methylene-bis-(Dimethyl Ammonium chloride)5%th, film solution 0.5%, fastness elevator UN-125F 2%, add deionized water to 100%.Take 5% six methylenes Base-bis-(Dodecyl dimethyl ammonium chloride)It in deionized water, stirs evenly, 0.5% film is slowly added under stirring condition Solution and 2% fastness elevator UN-125F, obtain pigment printing pretreatment work liquid after being sufficiently stirred.
With above-mentioned pretreatment work liquid to using it is conventional singe, the fabric after the processing of desizing, kiering, bleaching or mercerising into Row hydrojet arranges pretreatment, and pretreatment fluid temperature is 20 DEG C, pH value 8, liquid carrying rate 21%, and 100 DEG C of drying, then with red Color mill base carries out pigment printing, bakes 2min through 160 DEG C after hot-air seasoning.
Comparative example 3
It singes to use routine, the fabric after the processing of desizing, kiering, bleaching or mercerising is directly with same as Example 3 Red mill base carries out pigment printing, and 2min is baked through 160 DEG C after hot-air seasoning.
Color data, fastness index and the hand valuation of encrimson PRINTED FABRIC are shown in Table 3.
Illustrative description has been done to the present invention above, it should explanation, in the situation for the core for not departing from the present invention Under, any simple deformation, modification or other skilled in the art can not spend the equivalent replacement of creative work equal Fall into protection scope of the present invention.

Claims (1)

  1. A kind of 1. method for improving the rich and gaudy degree of pigment printing color and fastness, which is characterized in that include the following steps:It prepares first Then pretreatment work liquid is arranged the pretreatment work liquid of preparation by dip finishing, padding finishing, foam finishing or hydrojet It is applied to by routinely singing, on the fabric after the processing of desizing, kiering, bleaching or mercerising, carries out pigment printing after drying;Institute The pretreatment work liquid stated is by weight percentage:Cationic surfactant 1-10%, softening agent 0.1-5%, fastness carry Agent 0.5-10% is risen, adds deionized water to 100%;The cationic surfactant has below formula:
    Wherein:N is 2~10 integer;M is 6~18 integer;
    R is Cl or Br;
    Composition of the softening agent for one or both of organic silicon or quaternary amine salt form;The fastness elevator is One or more of composition in epoxies, aziridines, polyurethanes, twain-aldehyde compound, silane coupling agent class crosslinking agent.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107916518B (en) * 2017-12-11 2020-08-25 佛山市顺德金纺集团有限公司 Process method for improving wet rubbing fastness of tatted dark cloth
CN108193524A (en) * 2018-01-16 2018-06-22 深圳市墨库图文技术有限公司 A kind of Pretreatment of textile liquid and its treatment process and application

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CN1707017A (en) * 2005-05-18 2005-12-14 江南大学 Digital ink jet fabric-treating process
CN101117765A (en) * 2007-07-23 2008-02-06 江南大学 Gemini type positive ion collosol and method for improving fabric dyeing stability
CN101457486A (en) * 2007-10-26 2009-06-17 江南大学 Gemini quaternary ammonium salt style ultra-fining coating preparation and application process for fabric dyeing
CN102965912A (en) * 2012-11-20 2013-03-13 江南大学 Preparation method of alkaline reaction type silicon-titanium collosol applicable to thermal transfer printing of cotton fabric

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Publication number Priority date Publication date Assignee Title
CN1707017A (en) * 2005-05-18 2005-12-14 江南大学 Digital ink jet fabric-treating process
CN101117765A (en) * 2007-07-23 2008-02-06 江南大学 Gemini type positive ion collosol and method for improving fabric dyeing stability
CN101457486A (en) * 2007-10-26 2009-06-17 江南大学 Gemini quaternary ammonium salt style ultra-fining coating preparation and application process for fabric dyeing
CN102965912A (en) * 2012-11-20 2013-03-13 江南大学 Preparation method of alkaline reaction type silicon-titanium collosol applicable to thermal transfer printing of cotton fabric

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