CN106758165A - A kind of preprocess method for improving dacron direct injection jet printing clearness - Google Patents
A kind of preprocess method for improving dacron direct injection jet printing clearness Download PDFInfo
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- CN106758165A CN106758165A CN201611166114.9A CN201611166114A CN106758165A CN 106758165 A CN106758165 A CN 106758165A CN 201611166114 A CN201611166114 A CN 201611166114A CN 106758165 A CN106758165 A CN 106758165A
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- dacron
- porous nano
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- ink
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- 239000005020 polyethylene terephthalate Substances 0.000 title claims abstract description 55
- 229920004934 Dacron® Polymers 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims abstract description 26
- 238000002347 injection Methods 0.000 title claims abstract description 16
- 239000007924 injection Substances 0.000 title claims abstract description 16
- 238000007639 printing Methods 0.000 title abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 239000002562 thickening agent Substances 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- 239000006185 dispersion Substances 0.000 claims description 14
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 10
- 239000000080 wetting agent Substances 0.000 claims description 10
- -1 acryloyl-oxy Chemical group 0.000 claims description 9
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 8
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 8
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 8
- 229940113124 polysorbate 60 Drugs 0.000 claims description 8
- 239000002216 antistatic agent Substances 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 5
- 150000001768 cations Chemical class 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229920002642 Polysorbate 65 Polymers 0.000 claims description 4
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 4
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 claims description 4
- 235000010988 polyoxyethylene sorbitan tristearate Nutrition 0.000 claims description 4
- 239000001816 polyoxyethylene sorbitan tristearate Substances 0.000 claims description 4
- 229940099511 polysorbate 65 Drugs 0.000 claims description 4
- 239000004576 sand Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 235000011067 sorbitan monolaureate Nutrition 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 4
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 claims description 4
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 claims description 3
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 claims description 3
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003093 cationic surfactant Substances 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 150000003242 quaternary ammonium salts Chemical group 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- YXYZMHGSOKYZAF-UHFFFAOYSA-M [Cl-].C(C(=C)C)(=O)OCC[N+](C(C)(C)C)(C)C Chemical compound [Cl-].C(C(=C)C)(=O)OCC[N+](C(C)(C)C)(C)C YXYZMHGSOKYZAF-UHFFFAOYSA-M 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- PLRSNUWXOYYMKP-UHFFFAOYSA-M chloromethyl-(3-hydroxypropyl)-dimethylazanium;chloride Chemical compound [Cl-].ClC[N+](C)(C)CCCO PLRSNUWXOYYMKP-UHFFFAOYSA-M 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- ILWRPSCZWQJDMK-UHFFFAOYSA-N triethylazanium;chloride Chemical compound Cl.CCN(CC)CC ILWRPSCZWQJDMK-UHFFFAOYSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 3
- 125000002091 cationic group Chemical group 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 8
- 230000008569 process Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000007641 inkjet printing Methods 0.000 abstract description 2
- 239000007783 nanoporous material Substances 0.000 abstract description 2
- 239000004753 textile Substances 0.000 abstract description 2
- 239000004744 fabric Substances 0.000 description 32
- 239000012530 fluid Substances 0.000 description 16
- 239000002202 Polyethylene glycol Substances 0.000 description 8
- 230000008859 change Effects 0.000 description 8
- 238000012360 testing method Methods 0.000 description 7
- 238000005213 imbibition Methods 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 238000002156 mixing Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 description 3
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- 239000001116 FEMA 4028 Substances 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 description 1
- 235000011175 beta-cyclodextrine Nutrition 0.000 description 1
- 229960004853 betadex Drugs 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 238000004144 decalcomania Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000005543 nano-size silicon particle Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 229920006316 polyvinylpyrrolidine Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000010865 video microscopy Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of preprocess method for improving dacron direct injection jet printing clearness, belong to the digital ink-jet printed field of textile.The present invention for dacron direct injection it is ink-jet printed present in the unsharp problem of impressing pattern is produced due to electrostatic, propose the method that direct injection dacron jet printing clearness is lifted using nano-porous materials, compared with foregoing raising ink jet printing performance, definition, color depth and vividness effect to lifting pattern is obvious, the method process is simple, it is workable, to environment-friendly, meet the requirement of modern industry environmental protection, be suitable for the mass working process of dacron.
Description
Technical field
The present invention relates to a kind of preprocess method for improving dacron direct injection jet printing clearness, belong to textile
Digital ink-jet printed field.
Background technology
Dacron direct injection is ink-jet printed to enjoy people to pay close attention to because it eliminates transfer medium, yet with dispersion ink
The viscosity of water is low, and the surface of dacron lacks hydrophilic radical, after causing ink droplet to be ejected into dacron, can be with fibre
Dimension through broadwise to around spreading, there is imbibition, cause pattern edge to obscure, fineness declines.In order to improve direct injection spray
The definition of floral pattern is inked, it is necessary to suitably be pre-processed to dacron before stamp.
The research for improving its jet printing clearness to fabric pretreatment both at home and abroad is more, is concentrated mainly on three aspects：
(1) high molecular polymer is padded in fabric face, by the imbibition performance of polymer plugging capillarity reduction dacron,
Such as CN101736606A is disclosed and is lifted coherent of the fabric to ink for pretreating agent with β-cyclodextrin, improves ink-jet print
Colored definition；Building Yongping et al. have studied the relation of thickener structure and dacron jet printing clearness；Yang Jing orchids et al.
Have studied carboxymethylcellulose calcium (CMC), sodium alginate, four kinds of polymer substances of polyethylene glycol (PEG) and polyethylene glycol oxide (PEO)
Influence to the ink-jet printed effect of dacron, it is found that these four polymer substances can to some extent improve dacron
Imbibition performance, improves the definition of PRINTED FABRIC pattern, and polyethylene glycol and polyethylene glycol oxide can improve ink in dacron
On degree of fixation, and the influence of carboxymethylcellulose calcium and sodium alginate to its degree of fixation is little.But due to making in processing procedure
With more thickener, macromolecular compound etc., the feel of PRINTED FABRIC has been had a strong impact on.(2) using cation reagent to washing
Synthetic fibre fabric carries out cationization treatment, and set of the fabric to ink droplet is realized by the attraction of positive and negative charge, so as to reduce ink-jet print
Colored infiltration and imbibition phenomenon, such as patent CN102071574A disclose by the use of n-trimethyl chitosan chloride as pretreating agent to change
The ink-jet printed definition and color depth of kind fabric, and endowing terylene fabric antibacterial functions, but this method is general only
The stamp of type of dye ink can be used for；(3) hydrophilic modification is carried out to dacron, embracing for lifting dacron is aqueous, such as adopts
Such method, but this method pair are belonged to plasma technique, high-energy ray irradiation skill upgrading jet printing clearness
Equipment and operation requirement are higher, and cost is also higher, is not suitable for the mass working process of dacron.
The content of the invention
The purpose of the present invention：A kind of preprocess method for improving dacron direct injection jet printing clearness is provided, is carried
Rise dacron embraces aqueous and antistatic effect, reduces because ink bleed, imbibition and electrostatic attraction effect cause decalcomania
Definition disadvantage not high, the ink-jet printed definition of lifting direct injection dacron, propulsion dacron direct injection ink-jet print
The development and application of flower technology, reduce because of transfer paper production and the environmental pollution caused by.
Therefore, present invention firstly provides a kind of dacron pretreating agent, being by porous nano oxide dispersion, resisting
Electrostatic agent, thickener, wetting agent and water are mixed by a certain percentage, are uniformly mixing to obtain dacron pretreating agent.
In one embodiment of the invention, the composition of dacron pretreating agent is porous nano oxide dispersion
10-50%, antistatic additive 1-4%, thickener 1-5%, wetting agent 1-5%, remaining adds water and fills 100%.
In one embodiment of the invention, the composition of dacron pretreating agent is porous nano oxide dispersion
30-40%, antistatic additive 2%, thickener 2-3%, wetting agent 2-3%, remaining adds water and fills 100%.
The porous nano oxide dispersion preparation method, it will be 10- to the mass fraction of porous nano oxide to be
30% cation dispersing agent, the mass fraction to porous nano oxide is the wetting agent of 1-5%, is dissolved into deionized water
In, it is the porous nano oxide of 20-30% to add to the mass fraction of porous nano oxide dispersion, is used after stirring
Sand mill grinding distribution, prepares average grain diameter<The porous nano oxide dispersion of 200nm；Cation dispersing agent described here
It is epoxypropyltrimethylchloride chloride, Epoxypropyl triethyl ammonium chloride, the chloro- hydroxypropyl-trimethyl ammonium chlorides of 3-, acryloyl-oxy
Ethyl-trimethyl salmiac, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, 2- ethoxys-bis- trimethyl ammonium chlorides or dihydroxy second
One or two in base trimethyl ammonium chloride；The wetting agent is non-ionic dispersing agent, including polysorbate60, polysorbate65, is told
Temperature 80, triton x-100, Qula logical X-10, Span 20, Span 40, Span 60, Span 80, peregal os-15, peregal A-
20th, one or more mixtures in peregal AEO-10, PEO, PVP；It is described porous
Nano-oxide is porous nano silica, porous nano titanium oxide or porous nano aluminum oxide.
In one embodiment of the invention, the quality of porous nano oxide is divided in porous nano oxide dispersion
Number is 20%.
The antistatic additive is quaternary ammonium salt cationic surfactant, such as antistatic agent TM, antistatic additive SN, polyethers
Type quaternary ammonium salt；Or amine oxide type cationic surfactant；Or imidazoline quaternary ammonium salt derivative, including antistatic softening agent
AS；Or aliphatic acid amine-based antistatic agent amine-based antistatic agent, including N, N- dimethyl-beta-hydroxyethyl stearamide-γ-propyl group
Quaternary ammonium nitrate.
The wetting agent includes polysorbate60, polysorbate65, Tween 80, triton x-100, Qula logical X-10, Span 20, Span
40th, Span 60, Span 80, peregal os-15, peregal A-20, peregal AEO-10, PEO, polyvinylpyrrolidine
One or more mixtures in alkanone.
The thickener is non-ionic thickening agent, including alkyl phenol polyether thickener, urethane thickener, polyvinyl alcohol, poly-
Oxygen vinyl thickener.
The present invention is also provided after being pre-processed to dacron using the dacron pretreating agent and carries out direct injection
Ink-jet printed method, is that pretreating agent is applied into dacron surface using pad method, and drying can be obtained for straight
The dacron of the ink-jet printed pretreatment of spray formula.
In one embodiment of the invention, pick-up rate is controlled between 60-100% when padding, then at 60 DEG C
Preliminary drying, finally bakes under the conditions of 100-150 DEG C.
The present invention for dacron direct injection it is ink-jet printed present in produce impressing pattern unintelligible due to electrostatic
Problem, it is proposed that using nano-porous materials lifted direct injection dacron jet printing clearness method, with above institute
The raising ink jet printing performance stated is compared, and definition, color depth and the vividness effect to lifting pattern are obvious, the method technique
Simply, it is workable, to environment-friendly, meet the requirement of modern industry environmental protection, be suitable for the mass processing of dacron
Treatment.
Specific embodiment
Method of testing, makes a concrete analysis of as follows：
(1) test of definition
The width that printing lines are set on patterning machines is 1mm, and using metallographic videomicroscopy, selection low power is amplified
Mirror, the lines after shooting printing at 50 times.The line width at the maximum imbibition of lines after printing is measured with ToupView softwares again.
(2) K/S values test
By the fabric CI7800 computer colour matching instrument devices with stamp, in the system of CIE Lab, D65 light sources, 10 ° regard
Under conditions of angle, the K/S values and C* of test fabric.Each sample is surveyed 3 times and takes its average value.
(3) antistatic test
By the woven dacron after before processing, measurement sample electrostatic on YG (B) 342D type fabric induction type static charge testers is placed on
Pressure and half-life period.Test condition is：37 DEG C of bad border temperature, relative humidity 58%.
(4) finished tensile strength test
Woven dacron after before processing is placed on test fabric on YG (B) 026D -250 model imported electronic fabric strength tester by this experiment
Ultimate strength.
Embodiment 1
The present embodiment selects 230g/m2Terylene tWarp Knitted Fabrics, the technique of use is as follows：
(1) porous nano silica dispersion is prepared：Epoxypropyltrimethylchloride chloride 12g is taken, polysorbate60 is 0.4g, is gone
Ionized water 147.6g, after being sufficiently stirred under agitator, adds 40g porous nano silica, continues to stir 30min, then puts
2h is ground in laboratory circulation sand mill, average grain diameter is obtained<200nm, porous nano silica content be 20% it is porous
Nano silicon oxide dispersion；
(2) pretreatment fluid is prepared：By porous nano silica dispersion 60g, antistatic agent TM is 4g, urethane thickener
4g, polysorbate60 is 6g, deionized water 126g, is sufficiently stirred under agitator, rotating speed 800-1000r/min, and mixing time is
30min, obtains fabric pretreatment fluid.
(3) pretreatment fluid is padded：Dacron is padded into pretreatment fluid, when padding pick-up rate control 60-100% it
Between；
(4) preliminary drying, bake：Fabric after the padding preliminary drying under the conditions of 60 DEG C, then bakes under the conditions of 150 DEG C；
(5) it is ink-jet printed：Under conditions of 720 × 540dpi, 3Pass, ink-jet is carried out using aqueous dispersion dye ink
Stamp；
(6) distil fixation：Distil fixation 1min at 180 DEG C.
Performance change before and after the fabric treating of table 1
As it can be seen from table 1 the definition and color depth of fabric substantially change after being pre-processed through the present embodiment pretreatment fluid
Kind, its red, yellow, blue C* substantially increase, and color saturation is improved, and the C* values of black reduce, and illustrate surface color more
It is pure.The antistatic effect of fabric is lifted after being pre-processed through the present embodiment pretreatment fluid, and ultimate strength change is little.
Embodiment 2
The present embodiment selects 230g/m2Terylene tWarp Knitted Fabrics, the technique of use is as follows：
(1) porous nano titanium oxide dispersion is prepared：Epoxypropyltrimethylchloride chloride 10g is taken, polysorbate60 is 0.8g, is gone
Ionized water 149.2g, after being sufficiently stirred under agitator, adds 40g porous nano titanium oxides, continues to stir 30min, then puts
2h is ground in laboratory circulation sand mill, average grain diameter is obtained<200nm, porous nano titanium oxide content be 20% it is porous
Nano-titanium oxide dispersion；
(2) pretreatment fluid is prepared：By porous nano titanium oxide dispersion 80g, antistatic agent TM is 4g, urethane thickener
6g, polysorbate60 is 6g, deionized water 104g, is sufficiently stirred under agitator, rotating speed 800-1000r/min, and mixing time is
30min, obtains fabric pretreatment fluid；
(3) pretreatment fluid is padded：Dacron is padded into pretreatment fluid, when padding pick-up rate control 60-100% it
Between；
(4) preliminary drying, bake：Fabric after the padding preliminary drying under the conditions of 60 DEG C, then bakes under the conditions of 150 DEG C；
(5) it is ink-jet printed：Under conditions of 720 × 540dpi, 3Pass, ink-jet is carried out using aqueous dispersion dye ink
Stamp；
(6) distil fixation：Distil fixation 1min under the conditions of 180 DEG C.
Performance change before and after the fabric treating of table 2
From table 2 it can be seen that the definition and color depth of fabric substantially change after being pre-processed through the present embodiment pretreatment fluid
Kind, its red, yellow, blue C* substantially increase, and color saturation is improved, and the C* values of black reduce, and illustrate surface color more
It is pure.The antistatic effect of fabric is lifted after being pre-processed through the present embodiment pretreatment fluid, and ultimate strength change is little.
Embodiment 3
The present embodiment selects 230g/m2Terylene tWarp Knitted Fabrics, the technique of use is as follows：
(2) pretreatment fluid is prepared：It is 4g by antistatic agent TM, urethane thickener 4g, polysorbate60 is 6g, deionized water
186g, is sufficiently stirred under agitator, and rotating speed 800-1000r/min, mixing time is 30min, obtains fabric pretreatment fluid.
(3) pretreatment fluid is padded：Dacron is padded into pretreatment fluid, when padding pick-up rate control 60-100% it
Between；
(4) preliminary drying, bake：Fabric after the padding preliminary drying under the conditions of 60 DEG C, then bakes under the conditions of 150 DEG C；
(5) it is ink-jet printed：Under conditions of 720 × 540dpi, 3Pass, ink-jet is carried out using aqueous dispersion dye ink
Stamp；
(6) distil fixation：Distil fixation 1min at 180 DEG C.
Performance change before and after the fabric treating of table 3
From table 3 it can be seen that when being not added with porous nano silica dispersion compared with Example 1, in pretreating agent, place
The definition and color depth of fabric, the antistatic effect of color saturation and fabric are not significantly improved after reason.
Although the present invention is disclosed as above with preferred embodiment, it is not limited to the present invention, any to be familiar with this skill
The people of art, without departing from the spirit and scope of the present invention, can do various changes with modification, therefore protection model of the invention
Enclose being defined of being defined by claims.
Claims (10)
1. a kind of dacron pretreating agent, it is characterised in that as mass fraction, consisting of porous nano oxide disperses
Body 10-50%, antistatic additive 1-4%, thickener 1-5%, wetting agent 1-5%, remaining adds water and fills 100%.
2. a kind of dacron pretreating agent according to claim 1, it is characterised in that the porous nano oxide point
It will be the cation dispersing agent of 10-30% to the mass fraction of porous nano oxide that prose style free from parallelism preparation method is, to porous nano
The mass fraction of oxide is the wetting agent of 1-5%, is dissolved into deionized water, is added to porous nano oxide dispersion
Mass fraction is the porous nano oxide of 20-30%, and sand mill grinding distribution is used after stirring, and prepares average grain diameter<
The porous nano oxide dispersion of 200nm.
3. a kind of dacron pretreating agent according to claim 2, it is characterised in that the cation dispersing agent includes
The chloro- hydroxypropyl-trimethyl ammonium chloride of epoxypropyltrimethylchloride chloride, Epoxypropyl triethyl ammonium chloride, 3-, acryloyl-oxy second
Base trimethyl ammonium chloride, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, 2- ethoxys-bis- trimethyl ammonium chlorides or dihydroxy ethyl
One or two in trimethyl ammonium chloride.
4. a kind of dacron pretreating agent according to Claims 2 or 3, it is characterised in that the wetting agent includes telling
Temperature 60, polysorbate65, Tween 80, triton x-100, Qula logical X-10, Span 20, Span 40, Span 60, Span 80, peregal
One or more in OS-15, peregal A-20, peregal AEO-10, PEO, PVP are mixed
Compound.
5. a kind of dacron pretreating agent according to Claims 2 or 3, it is characterised in that the porous nano oxidation
Thing is porous nano silica, porous nano titanium oxide or porous nano aluminum oxide.
6. a kind of dacron pretreating agent according to claim 1, it is characterised in that the antistatic additive is quaternary ammonium salt
Type cationic surface active agent, amine oxide type cationic surfactant, imidazoline quaternary ammonium salt derivative, aliphatic acid amine resist
Electrostatic agent amine-based antistatic agent.
7. a kind of dacron pretreating agent according to claim 1 or 6, it is characterised in that the wetting agent right and wrong from
Subtype dispersant, including polysorbate60, polysorbate65, Tween 80, triton x-100, Qula logical X-10, Span 20, Span 40, Span
60th, in Span 80, peregal os-15, peregal A-20, peregal AEO-10, PEO, PVP
One or more mixtures.
8. a kind of dacron pretreating agent according to claim 1 or 6, it is characterised in that the thickener right and wrong from
Sub- thickener, including alkyl phenol polyether thickener, urethane thickener, polyvinyl alcohol, polyoxyethylene thickener.
9. that pretreatment is carried out to dacron is laggard for a kind of any described dacron pretreating agent of application claim 1~8
The ink-jet printed method of row direct injection, it is characterised in that be that pretreating agent is applied to by dacron surface using pad method,
Drying can obtain the dacron for the ink-jet printed pretreatment of direct injection.
10. method according to claim 9, it is characterised in that when padding pick-up rate control between 60-100%, then
The preliminary drying at 60 DEG C, then baked under the conditions of 100-150 DEG C；Under conditions of 720 × 540dpi, 3Pass, using aqueous dispersion
Dye ink carries out ink-jet printed.
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| CN201611166114.9A CN106758165A (en) | 2016-12-16 | 2016-12-16 | A kind of preprocess method for improving dacron direct injection jet printing clearness |
| US15/801,696 US10378147B2 (en) | 2016-12-16 | 2017-11-02 | Pretreating agent to improve the effect of ink-jet printing on polyester fabric and its application |
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| CN201611166114.9A CN106758165A (en) | 2016-12-16 | 2016-12-16 | A kind of preprocess method for improving dacron direct injection jet printing clearness |
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| CN107100020A (en) * | 2017-06-13 | 2017-08-29 | 莱美科技股份有限公司 | A kind of pretreating agent and preprocess method for improving dacron jet printing clearness |
| CN107503197A (en) * | 2017-09-04 | 2017-12-22 | 珠海华彩打印耗材有限公司 | A kind of chalk pretreatment fluid and preparation method thereof, direct-injection digital printing process |
| CN108193485A (en) * | 2017-12-31 | 2018-06-22 | 金华洁灵家居用品有限公司 | A kind of preprocess method for improving dacron jet printing clearness |
| CN108301242A (en) * | 2017-12-31 | 2018-07-20 | 金华洁灵家居用品有限公司 | It is a kind of improve dacron jet printing clearness pretreating agent and its application |
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| CN109797578A (en) * | 2019-01-23 | 2019-05-24 | 深圳市全印图文技术有限公司 | Stamp printing technology |
| CN109914130A (en) * | 2019-03-06 | 2019-06-21 | 常州纺织服装职业技术学院 | A kind of terylene digital ink-jet printed antistatic preprocessing solution and application |
| CN110230212A (en) * | 2019-05-21 | 2019-09-13 | 武汉纺织大学 | A kind of Polyester Textiles colouring method |
| CN111501382A (en) * | 2020-04-20 | 2020-08-07 | 天津工业大学 | Non-urea ink-jet printing pretreatment liquid suitable for wool fabric and pretreatment method |
| CN114481649A (en) * | 2022-04-02 | 2022-05-13 | 宏华印染(苏州)有限公司 | High-permeability anhydrous digital printing and dyeing method |
| CN115094650A (en) * | 2022-08-03 | 2022-09-23 | 浙江迎丰科技股份有限公司 | Digital printing short-process technology suitable for polyester cotton |
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| CN107503197A (en) * | 2017-09-04 | 2017-12-22 | 珠海华彩打印耗材有限公司 | A kind of chalk pretreatment fluid and preparation method thereof, direct-injection digital printing process |
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| CN108193485A (en) * | 2017-12-31 | 2018-06-22 | 金华洁灵家居用品有限公司 | A kind of preprocess method for improving dacron jet printing clearness |
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| CN109914130B (en) * | 2019-03-06 | 2021-11-02 | 常州纺织服装职业技术学院 | Antistatic pretreatment solution for digital ink-jet printing of terylene and application thereof |
| CN110230212A (en) * | 2019-05-21 | 2019-09-13 | 武汉纺织大学 | A kind of Polyester Textiles colouring method |
| CN110230212B (en) * | 2019-05-21 | 2021-09-17 | 武汉纺织大学 | Polyester textile dyeing method |
| CN111501382A (en) * | 2020-04-20 | 2020-08-07 | 天津工业大学 | Non-urea ink-jet printing pretreatment liquid suitable for wool fabric and pretreatment method |
| CN114481649A (en) * | 2022-04-02 | 2022-05-13 | 宏华印染(苏州)有限公司 | High-permeability anhydrous digital printing and dyeing method |
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