CN107164114A - A kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO and preparation method thereof - Google Patents
A kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO and preparation method thereof Download PDFInfo
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- CN107164114A CN107164114A CN201710369251.0A CN201710369251A CN107164114A CN 107164114 A CN107164114 A CN 107164114A CN 201710369251 A CN201710369251 A CN 201710369251A CN 107164114 A CN107164114 A CN 107164114A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
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Abstract
The invention discloses a kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO and preparation method thereof, in parts by weight, including following components：APEO chain quaternary cationics：2 30 parts；AEO：5 20 parts；APG APG：5 15 parts；Anhydrous sorbitol laurate：5 20 parts；The sodium of iminodisuccinic acid four：5 17 parts；Sodium citrate：3 10 parts；Sodium tripolyphosphate：3 15 parts；Defoamer：13 parts；Water：Surplus.The present invention has splendid surface-active, and washing ability is excellent, enables in particular to protection well in vain, prevent loose colour is counter to be stained with fiber, improves fiber colour vividness；And preparation method is simple, reaction condition is gentle, and production cost is low.
Description
Technical field
The present invention relates to a kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO and preparation method thereof.Belong to textile printing and dyeing
Auxiliary agent research field.
Background technology
Soaping agent is indispensable pith in cotton fiber reactive dyeing or stamp.In order to remove on textile
Stain and yarn applied in degreaser, and after dyeing or stamp be except removal floating color, ensure by dyeing and weaving thing to reach one
Fixed dyefastness, is required for progress to soap processing.In addition, the requirement with people to textiles such as clothings is improved constantly, it is many
Component fibre blending, intertexture, compound fabric emerge in an endless stream, and the final technique to printing and dyeing it is also proposed higher requirement, not only
Ask the dyeing color and luster of multicomponent fibre consistent, bright-coloured and fastness will also get well.For the purpose of energy-saving and emission-reduction, during dyeing usually
It is multiple fiber, a variety of dyestuffs while being dyed, very easy generation staining phenomenon between so different fibers, it is therefore necessary to
Antifouling soaping agent is used to solve this problem.
At present, the soaping agent species occurred on the market is more, but efficiently, still, soil resistant, the performance such as environmental protection be always soap
The main R＆D direction of lotion.Chinese invention patent CN102093508A, CN102876476A etc. disclose a kind of horse Class C without
Bubble or low bubble soaping agent, this class soaping agent has removes loose colour ability well, excellent effect of soaping, and stability is strong and soap
Non-foam is produced during washing, but it does not possess excellent anti-staining ability.In addition, Publication No. CN102994259A with
And the Chinese invention patent such as CN103642600B, polyvinylpyrrolidone is added in formula, its dispersiveness and dissolubility are excellent
Good and many dyestuffs have extremely strong interaction, thus possess preferable anti-staining effect, but because its is expensive, because
And consider not being widely used yet from the angle of cost.
The content of the invention
Present invention aims at there is provided a kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO and preparation method thereof,
The quaternary cationics that the present invention is used is had an effect with the anionic dye eluted, and is uniformly disperseed
In liquid of soaping, substantially reduce or even prevent the anti-ability for being stained with fiber of loose colour, thus with protection well in vain, prevent from floating
The anti-effect be stained with fiber, improve fiber colour vividness of color.And the antifouling soaping agent of the present invention has coordinated iminodisuccinic acid
The surface active compositions such as four sodium, AEO, APG APG, with splendid surface-active, washing and scattered
The characteristics of ability is excellent.Other antifouling soaping agent preparation method of the invention is simple, and reaction condition is gentle, and production cost is low, operation letter
Just, available for industrial production.
The technical scheme that is used to solve its technical problem of the present invention is：
A kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO, in parts by weight, including following components：
APEO chain quaternary cationics：2-30 parts；
AEO：5-20 parts；
APG APG：5-15 parts；
Anhydrous sorbitol laurate：5-20 parts；
The sodium of iminodisuccinic acid four：5-17 parts；
Sodium citrate：3-10 parts；
Sodium tripolyphosphate：3-15 parts；
Defoamer：1-3 parts；
Water：Surplus.
A kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO, in parts by weight, preferably includes following components：
APEO chain quaternary cationics：15 parts；
AEO：12 parts；
APG APG：10 parts；
Anhydrous sorbitol laurate：12.5 parts；
The sodium of iminodisuccinic acid four：11 parts；
Sodium citrate：6.5 part；
Sodium tripolyphosphate：9 parts；
Defoamer：2 parts；
Water：Surplus.
Described APEO chain quaternary cationics, its structural formula is formula (I)：
R1 is one kind in alkyl carbon chain and its alkyl chain derivative in formula (I)；R2 structural formula is
Or it spreads out
One kind (1≤m, n≤20) in biology；
X, y scope are 8≤x, y≤80 in formula (I)；
In described APEO chain quaternary cationics formula (I), the structural formula of preferably R1 groups is
Formula (II)；It is preferred that the structural formula of R2 groups is formula (III).
-CH2(CH2CH2)8CH3(II)；
-CH2CH2OH (III)；
In formula (I), preferably x=y=30.
A kind of preparation method of the antifouling soaping agent of the quaternary ammonium salt of chain containing APEO, comprises the following steps：
(1) water temperature is risen to 40-60 DEG C first, then adds following components according to parts by weight：APEO chain season
Ammonium salt cationic surfactant：2-30 parts；AEO：5-20 parts；APG APG：5-15 parts；Dehydration mountain
Pears alcohol laurate：5-20 parts；Defoamer：1-3 parts；And continue to stir 10-30min in 60 DEG C of insulations.
(2) and then according to mass fraction the sodium of iminodisuccinic acid four is added：5-17 parts；Sodium citrate：3-10 parts；Trimerization
Sodium phosphate：3-15 parts；Continue to stir 20-40min.
(3) after after uniform mixing, 40-50 DEG C is cooled to, antifouling soaping agent finished product is obtained.
Reaction condition is preferably warming up to 50 DEG C first in the step (1), adds and is warming up to 60 DEG C after material and continues to stir
Mix 20min.
Reaction condition is preferably to add the follow-up continuous stirring 30min of material in the step (2).
Reaction condition is preferably and is cooled to 45 DEG C to obtain antifouling soaping agent in the step (3).
The beneficial effects of the invention are as follows：The present invention added in soaping agent a kind of quaternary ammonium salt of chain containing APEO it is positive from
Sub- surfactant, the surfactant is had an effect with the anionic dye eluted, and is uniformly dispersed in liquid of soaping
In, substantially reduce or even prevent the anti-ability for being stained with fiber of loose colour, thus with protection well in vain, prevent loose colour is counter to be stained with fibre
Dimension, improves the effect of fiber colour vividness.And the antifouling soaping agent of the present invention has coordinated the sodium of iminodisuccinic acid four, fat
The surface active compositions such as alcohol APEO, APG APG, with splendid surface-active, washing and dispersibility are excellent
Feature.The antifouling soaping agent preparation method of the present invention is simple in addition, and reaction condition is gentle, and production cost is low, easy to operate, can use
In industrial production.
Embodiment
Embodiment 1
A kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO of the present embodiment, in parts by weight, including with the following group
Point：APEO chain quaternary cationics：15 parts；AEO：12 parts；APG APG：
10 parts；Anhydrous sorbitol laurate：12.5 parts；The sodium of iminodisuccinic acid four：11 parts；Sodium citrate：6.5 part；Trimerization phosphorus
Sour sodium：9 parts；Defoamer：2 parts；Water：Surplus.
R1 is-CH in described APEO chain quaternary cationics molecular structural formula2(CH2CH2)8CH3, R2 is-CH2CH2OH, x=y=30.
A kind of preparation method of the antifouling soaping agent of the quaternary ammonium salt of chain containing APEO, comprises the following steps：
(1) water temperature is risen to 40 DEG C first, then by above-mentioned photograph mass fraction add APEO chain quaternary ammonium salt sun from
Sub- surfactant, AEO, APG APG, anhydrous sorbitol laurate, defoamer, and be warming up to
60 DEG C of insulations continue to stir 20min.
(2) sodium of iminodisuccinic acid four, sodium citrate, sodium tripolyphosphate and then according to above-mentioned mass fraction are added, after
Continuous stirring 30min.
(3) after after uniform mixing, 45 DEG C is cooled to, antifouling soaping agent finished product is obtained.
The present embodiment adds a kind of quaternary cationics of chain containing APEO, the table in soaping agent
Face activating agent is had an effect with the anionic dye eluted, and is uniformly dispersed in liquid of soaping, and is substantially reduced or even anti-
Stopped the anti-ability for being stained with fiber of loose colour, thus with protection well in vain, prevent that loose colour is counter and be stained with fiber, improve fiber colour fresh
The effect of gorgeous degree.And the antifouling soaping agent of the present embodiment has coordinated the sodium of iminodisuccinic acid four, AEO, alkane
The surface active compositions such as base glucosides APG, with splendid surface-active, the characteristics of washing and excellent dispersibility.This other implementation
The antifouling soaping agent preparation method of example is simple, and reaction condition is gentle, and production cost is low, easy to operate, available for industrial production.
Embodiment 2
A kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO of the present embodiment, in parts by weight, including with the following group
Point：APEO chain quaternary cationics：2 parts；AEO：15 parts；APG APG：5
Part；Anhydrous sorbitol laurate：5 parts；The sodium of iminodisuccinic acid four：5 parts；Sodium citrate：3 parts；Sodium tripolyphosphate：3 parts；
Defoamer：2 parts；Water：Surplus.
R1 is-CH in described APEO chain quaternary cationics molecular structural formula2(CH2CH2)3CH3, R2 isX=y=10.
A kind of preparation method of the antifouling soaping agent of the quaternary ammonium salt of chain containing APEO, comprises the following steps：
(1) water temperature is risen to 50 DEG C first, then by above-mentioned photograph mass fraction add APEO chain quaternary ammonium salt sun from
Sub- surfactant, AEO, APG APG, anhydrous sorbitol laurate, defoamer, and be warming up to
60 DEG C of insulations continue to stir 15min.
(2) sodium of iminodisuccinic acid four, sodium citrate, sodium tripolyphosphate and then according to above-mentioned mass fraction are added, after
Continuous stirring 40min.
(3) after after uniform mixing, 50 DEG C is cooled to, antifouling soaping agent finished product is obtained.
The present embodiment adds a kind of quaternary cationics of chain containing APEO, the table in soaping agent
Face activating agent is had an effect with the anionic dye eluted, and is uniformly dispersed in liquid of soaping, and is substantially reduced or even anti-
Stopped the anti-ability for being stained with fiber of loose colour, thus with protection well in vain, prevent that loose colour is counter and be stained with fiber, improve fiber colour fresh
The effect of gorgeous degree.And the antifouling soaping agent of the present embodiment has coordinated the sodium of iminodisuccinic acid four, AEO, alkane
The surface active compositions such as base glucosides APG, with splendid surface-active, the characteristics of washing and excellent dispersibility.This other implementation
The antifouling soaping agent preparation method of example is simple, and reaction condition is gentle, and production cost is low, easy to operate, available for industrial production.
Embodiment 3
A kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO of the present embodiment, in parts by weight, including with the following group
Point：APEO chain quaternary cationics：25 parts；AEO：20 parts；APG APG：
10 parts；Anhydrous sorbitol laurate：9 parts；The sodium of iminodisuccinic acid four：12 parts；Sodium citrate：8 parts；Sodium tripolyphosphate：5
Part；Defoamer：3 parts；Water：Surplus.
R1 is-CH in described APEO chain quaternary cationics molecular structural formula2(CH2CH2)5CH3, R2 isX=y=60.
A kind of preparation method of the antifouling soaping agent of the quaternary ammonium salt of chain containing APEO, comprises the following steps：
(1) water temperature is risen to 60 DEG C first, then by above-mentioned photograph mass fraction add APEO chain quaternary ammonium salt sun from
Sub- surfactant, AEO, APG APG, anhydrous sorbitol laurate, defoamer, and at 60 DEG C
Insulation continues to stir 30min.
(2) sodium of iminodisuccinic acid four, sodium citrate, sodium tripolyphosphate and then according to above-mentioned mass fraction are added, after
Continuous stirring 25min.
(3) after after uniform mixing, 40 DEG C is cooled to, antifouling soaping agent finished product is obtained.
The present embodiment adds a kind of quaternary cationics of chain containing APEO, the table in soaping agent
Face activating agent is had an effect with the anionic dye eluted, and is uniformly dispersed in liquid of soaping, and is substantially reduced or even anti-
Stopped the anti-ability for being stained with fiber of loose colour, thus with protection well in vain, prevent that loose colour is counter and be stained with fiber, improve fiber colour fresh
The effect of gorgeous degree.And the antifouling soaping agent of the present embodiment has coordinated the sodium of iminodisuccinic acid four, AEO, alkane
The surface active compositions such as base glucosides APG, with splendid surface-active, the characteristics of washing and excellent dispersibility.This other implementation
The antifouling soaping agent preparation method of example is simple, and reaction condition is gentle, and production cost is low, easy to operate, available for industrial production.
Embodiment 4
A kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO of the present embodiment, in parts by weight, including with the following group
Point：APEO chain quaternary cationics：30 parts；AEO：5 parts；APG APG：
15 parts；Anhydrous sorbitol laurate：20 parts；The sodium of iminodisuccinic acid four：17 parts；Sodium citrate：10 parts；Tripolyphosphate
Sodium：15 parts；Defoamer：1 part；Water：Surplus.
R1 is-CH in described APEO chain quaternary cationics molecular structural formula2(CH2CH2)7CH3, R2 isX=y=20.
A kind of preparation method of the antifouling soaping agent of the quaternary ammonium salt of chain containing APEO, comprises the following steps：
(1) water temperature is risen to 55 DEG C first, then by above-mentioned photograph mass fraction add APEO chain quaternary ammonium salt sun from
Sub- surfactant, AEO, APG APG, anhydrous sorbitol laurate, defoamer, and be warming up to
60 DEG C of insulations continue to stir 10min.
(2) sodium of iminodisuccinic acid four, sodium citrate, sodium tripolyphosphate and then according to above-mentioned mass fraction are added, after
Continuous stirring 20min.
(3) after after uniform mixing, 47 DEG C is cooled to, antifouling soaping agent finished product is obtained.
The present embodiment adds a kind of quaternary cationics of chain containing APEO, the table in soaping agent
Face activating agent is had an effect with the anionic dye eluted, and is uniformly dispersed in liquid of soaping, and is substantially reduced or even anti-
Stopped the anti-ability for being stained with fiber of loose colour, thus with protection well in vain, prevent that loose colour is counter and be stained with fiber, improve fiber colour fresh
The effect of gorgeous degree.And the antifouling soaping agent of the present embodiment has coordinated the sodium of iminodisuccinic acid four, AEO, alkane
The surface active compositions such as base glucosides APG, with splendid surface-active, the characteristics of washing and excellent dispersibility.This other implementation
The antifouling soaping agent preparation method of example is simple, and reaction condition is gentle, and production cost is low, easy to operate, available for industrial production.
Application Example
To verify that the antifouling soaping agent of the quaternary cationics of chain containing APEO of the present invention exists
Effect in technique of being soaped after fabric or stock-dye, in this application embodiment, with commercially available conventional soaping agent sample and this
The antifouling soaping agent of invention makees anti-staining and fastness to rubbing is contrasted.
Anti- Crockmeter Test
This experiment elder generation active black XD-70R is dyed to pure cotton fabric, and dyeing prescription and technique are：Pure cotton fabric：
100g, active black XD-70R：5% (owf.), soda ash：20g/L, glauber salt 50g/L, bath raio：1：10.Room temperature enters dye, and with 1.5
DEG C/min be warming up to 70 DEG C insulation 60min.After dyeing terminates, the dyed cotton fabric of homogenous quantities and the undyed pure cotton such as take respectively
Calico, and technique of soaping is carried out to it according to following condition：Soaping agent：1g/L, temperature of soaping：90 DEG C, bath raio：1：10 when soaping
Between：20min.Soap and determine the K/S values for the calico that is unstained after terminating with X-rite colori7 color measurement and color matches instrument, with K/S values
Size judges the seriousness of staining.K/S values are smaller, illustrate that the anti-staining effect of soaping agent is better, on the contrary then poorer.As a result such as table
Shown in 1, antifouling soaping agent and the anti-Crockmeter Test result of commercially available soaping agent that table 1 is embodiment 1-4.
By the antifouling soaping agent prepared by embodiments of the invention it can be seen from data result in table 1 and commercially available soaping agent
Compare, with obvious anti-staining ability.
Fastness to rubbing
With reference to GB/T 3920-1997《Textile color stability tests colour fastness to rubbing》, in the test of fabric abrasive color fastness
Tested on instrument Y571 (Yuan Mao mechanical ＆ electronic equipment corporation, Ltds of Shaoxin City).Test temperature is room temperature.As a result it is as shown in table 2.Table 2 is real
Apply the antifouling soaping agent and commercially available soaping agent rubbing fastness test result of a 1-4.
As can be seen from Table 2, the antifouling soaping agent that prepared by embodiments of the invention is compared with commercially available soaping agent, resistance to dry friction
Fastness is suitable with commercially available soaping agent 1 and 2, but wet rubbing fastness is better than commercially available soaping agent 1, and suitable with commercially available soaping agent 2.
In summary, antifouling soaping agent of the invention is applied to bafta or polyester cotton and other contain cotton blended fabric
Technique of soaping in, with certain advantage compared with conventional soaping agent, due to adding a kind of season of chain containing APEO
Ammonium salt cationic surfactant, the surfactant is had an effect with the anionic dye eluted, and is uniformly disperseed
In liquid of soaping, substantially reduce or even prevent the anti-ability for being stained with fiber of loose colour, thus with protection well in vain, prevent from floating
The anti-effect be stained with fiber, improve fiber colour vividness of color.And the antifouling soaping agent has coordinated the imino-diacetic amber of certain component
Four sodium of amber acid, AEO, the surface active composition such as APG APG, with splendid surface-active, washing and
The features such as dispersibility is excellent.
Table 1
Table 2
Claims (8)
1. a kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO, it is characterised in that：In parts by weight, including with the following group
Point：
APEO chain quaternary cationics：2-30 parts；
AEO：5-20 parts；
APG APG：5-15 parts；
Anhydrous sorbitol laurate：5-20 parts；
The sodium of iminodisuccinic acid four：5-17 parts；
Sodium citrate：3-10 parts；
Sodium tripolyphosphate：3-15 parts；
Defoamer：1-3 parts；
Water：Surplus.
2. a kind of antifouling soaping agent of quaternary ammonium salt of chain containing APEO according to claim 1, it is characterised in that：With weight
Measure part meter, including following components：
APEO chain quaternary cationics：15 parts；
AEO：12 parts；
APG APG：10 parts；
Anhydrous sorbitol laurate：12.5 parts；
The sodium of iminodisuccinic acid four：11 parts；
Sodium citrate：6.5 part；
Sodium tripolyphosphate：9 parts；
Defoamer：2 parts；
Water：Surplus.
3. a kind of antifouling soaping agent of quaternary ammonium salt of chain containing APEO according to claim 1, it is characterised in that：It is described
APEO chain quaternary cationics, its structural formula be formula (I)：
R1 is one kind in alkyl carbon chain and its alkyl chain derivative in formula (I)；R2 structural formula is
Or derivatives thereof
In one kind (1≤m, n≤20)；
X, y scope are 8≤x, y≤80 in formula (I).
4. a kind of antifouling soaping agent of quaternary ammonium salt of chain containing APEO according to profit requires 3, it is characterised in that：Described
In APEO chain quaternary cationics, formula (I), the structural formula of R1 groups is formula (II)；The knot of R2 groups
Structure formula is formula (III).
-CH2(CH2CH2)8CH3(II)；
-CH2CH2OH (III)；
In formula (I), x=y=30.
5. a kind of preparation method of the antifouling soaping agent of the quaternary ammonium salt of chain containing APEO according to claim 1, it is special
Levy and be：Comprise the following steps：
(1) water temperature is risen to 40-60 DEG C first, then adds following components according to parts by weight：APEO chain quaternary ammonium salt
Cationic surfactant：2-30 parts；AEO：5-20 parts；APG APG：5-15 parts；Anhydrous sorbitol
Laurate：5-20 parts；Defoamer：1-3 parts；And continue to stir 10-30min in 60 DEG C of insulations.
(2) and then according to mass fraction the sodium of iminodisuccinic acid four is added：5-17 parts；Sodium citrate：3-10 parts；Tripolyphosphate
Sodium：3-15 parts；Continue to stir 20-40min.
(3) after after uniform mixing, 40-50 DEG C is cooled to, antifouling soaping agent finished product is obtained.
6. a kind of preparation method of the antifouling soaping agent of quaternary ammonium salt of chain containing APEO according to claim 5, it is special
Levy and be：Reaction condition adds and 60 DEG C of continuation stirrings is warming up to after material to be warming up to 50 DEG C first in the step (1)
20min。
7. a kind of preparation method of the antifouling soaping agent of quaternary ammonium salt of chain containing APEO according to claim 5, it is special
Levy and be：Reaction condition is the follow-up continuous stirring 30min of addition material in the step (2).
8. a kind of preparation method of the antifouling soaping agent of quaternary ammonium salt of chain containing APEO according to claim 5, it is special
Levy and be：Reaction condition obtains antifouling soaping agent to be cooled to 45 DEG C in the step (3).
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| CN110655993A (en) * | 2018-06-29 | 2020-01-07 | 3M创新有限公司 | Detergent composition having long-term antibacterial properties |
| CN112323520A (en) * | 2020-11-16 | 2021-02-05 | 五邑大学 | Nylon, nylon/spandex acid dye printing anti-staining soaping agent and preparation method thereof |
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