CN112323520A - Nylon, nylon/spandex acid dye printing anti-staining soaping agent and preparation method thereof - Google Patents
Nylon, nylon/spandex acid dye printing anti-staining soaping agent and preparation method thereof Download PDFInfo
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- CN112323520A CN112323520A CN202011275842.XA CN202011275842A CN112323520A CN 112323520 A CN112323520 A CN 112323520A CN 202011275842 A CN202011275842 A CN 202011275842A CN 112323520 A CN112323520 A CN 112323520A
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- nylon
- soaping agent
- acid dye
- spandex
- staining
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- 239000004677 Nylon Substances 0.000 title claims abstract description 42
- 229920001778 nylon Polymers 0.000 title claims abstract description 42
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 40
- 239000000980 acid dye Substances 0.000 title claims abstract description 33
- 229920002334 Spandex Polymers 0.000 title claims abstract description 22
- 239000004759 spandex Substances 0.000 title claims abstract description 22
- 238000010186 staining Methods 0.000 title claims description 31
- 238000002360 preparation method Methods 0.000 title abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 18
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 13
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 150000001412 amines Chemical class 0.000 claims abstract description 7
- 238000010790 dilution Methods 0.000 claims abstract description 6
- 239000012895 dilution Substances 0.000 claims abstract description 6
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 6
- 239000002904 solvent Substances 0.000 claims abstract description 6
- 239000003760 tallow Substances 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 16
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 14
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 29
- 230000000694 effects Effects 0.000 abstract description 20
- 239000002775 capsule Substances 0.000 abstract description 3
- 229920001938 Vegetable gum Polymers 0.000 abstract description 2
- 239000000693 micelle Substances 0.000 abstract description 2
- 239000000975 dye Substances 0.000 description 12
- 230000002378 acidificating effect Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 235000017550 sodium carbonate Nutrition 0.000 description 5
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- -1 polyoxyethylene Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- WXLFIFHRGFOVCD-UHFFFAOYSA-L azophloxine Chemical compound [Na+].[Na+].OC1=C2C(NC(=O)C)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 WXLFIFHRGFOVCD-UHFFFAOYSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/39—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
- D06P3/241—Polyamides; Polyurethanes using acid dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Abstract
The invention provides a nylon, nylon/spandex acid dye printing anti-sticking soaping agent and a preparation method thereof, wherein 45-55% tallow amine polyoxyethylene ether is injected into a reaction vessel, 3.6-6.0% dimethyl sulfate is input through a closed system, and the sealed reaction is carried out for 4 hours at 85-90 ℃; adding 10-20% of diethylene glycol solvent for dilution, adding 46% of 2.5-4.0% of sodium hydroxide for neutralization, adjusting the pH value to 6.0-7.0, and finally adding 10-20% of softened water until the sum of the formula components is 100%. The soaping agent has longer molecular chain and positive charge to form micelle, and can tightly bind and wrap the acid dye remained in water in the capsule, so that the acid dye remained in water can not be adhered to the white bottom of a soaped fabric, and the soaping agent has good anti-adhesion effect and good removal effect on printing paste of natural vegetable gum on a cloth cover. Has good anti-sticking soaping effect.
Description
Technical Field
The invention relates to the technical field of textile auxiliary agents, in particular to a nylon and nylon/spandex acid dye printing anti-staining soaping agent and a preparation method thereof.
Background
The nylon and nylon/spandex fabrics are printed by using an acid dye or an acid mordant-containing dye, after printing and steaming for color development, soaping is needed to remove printing paste, dye remained in the printing paste and some auxiliaries which are not dyed, in the soaping process, the dye which is not dyed on the fabrics in the printing paste falls into water and is re-stained on the printed fabrics, so that the printed fabrics are grey and dark in color, stained with white background, and fuzzy in pattern and lines, and many garment factories reject the printed fabrics, thereby bringing huge economic loss to the printing factories. The stain resistance of dye with poor fastness or dye with low dyeing rate is very poor, particularly when the dye is soaped in warm water at 40-50 ℃, the dye is seriously rewetted,
in order to solve the technical problem, a plurality of acidic printing anti-staining soaping agents appear on the market, which mainly act on the soaping process of nylon and nylon/spandex printed fabrics, are added to prevent residual dyes eluted from printing pastes from being dyed on the surfaces of the fabrics again, most of the acidic soaping agents are compounds of fatty amine polyoxyethylene ether and a plurality of surfactants, although the acidic soaping agents have a certain anti-staining effect, the anti-staining capability is insufficient, the reason is that the compound soaping agents have insufficient adsorption and cohesion force on the residual dyes in water, a small amount of acidic dyes or acidic dyes with poor washing fastness are stained on white bottoms of the soaped fabrics, and the printed fabrics with the white bottoms are often complained by customers, or returned goods or shifted down.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides the nylon and nylon/spandex acid dye printing anti-staining soaping agent and the preparation method thereof.
The technical scheme of the invention is as follows: the acid dye printing anti-staining soaping agent for nylon, nylon/spandex comprises the following components in percentage by mass:
further, the soaping agent comprises the following components in percentage by mass:
further, the soaping agent comprises the following components in percentage by mass:
the invention also provides a preparation method of the nylon and nylon/spandex acid dye printing anti-staining soaping agent, which comprises the following steps of:
s1), injecting 45-55% tallow amine polyoxyethylene ether (containing 30 polyoxyethylene ether) into a 1000ml three-mouth round bottom reaction bottle, inputting 3.6-6.0% dimethyl sulfate through a closed system, and carrying out sealed reaction for 4 hours at 85-90 ℃;
s2), adding 10-20% of diethylene glycol solvent for dilution, adding 46% of sodium hydroxide with the concentration of 2.5-4.0% for neutralization, adjusting the pH to 6.0-7.0, and finally adding 10-20% of softened water until the sum of the formula components is 100% to obtain the soaping agent.
The invention also provides a use method of the nylon and nylon/spandex acid dye printing anti-staining soaping agent, which specifically comprises the following steps:
adding 1.0-2.0g/L of acid dye printing soaping agent into cold water, running 1g/L of sodium carbonate for 6-12 minutes, discharging water, and fixing color in the next procedure.
The invention also provides a use method of the other nylon and nylon/spandex acid dye printing anti-staining soaping agent, which specifically comprises the following steps:
1.0-2.0g/L of the acid dye printing soaping agent is added into cold water, 1g/L of sodium carbonate is heated to 40-50 ℃ to run for 25 minutes for water discharging, and the color fixation is carried out in the next procedure.
The invention has the beneficial effects that:
1. the soaping agent provided by the invention has a polyoxyethylene long chain, has a certain dispersion performance, and has a good removing effect on printing paste remained on soaped fabrics, so that the soaped printed fabrics have good hand feeling;
2. the method is mainly used for the soaping process after the acid dye printing of the nylon, nylon/spandex fabrics, prevents the acid dye in the dropped soap washing liquor from being stained on the soaped printed fabrics, and prevents the white bottom of the printed fabrics from staining or other colored places from cross-staining;
3. by using the printing soaping agent, the printed fabric after washing has pure white bottom, does not have the feeling of darkness, has clear fine lines and no blurring, and has bright-colored cloth cover and more bright color;
4. the soaping agent has longer molecular chains and positive charges to form micelles, and can tightly bind and wrap the acid dye remained in water in the capsules, so that the acid dye remained in water cannot be back-stained on white bottom of soaped fabric, and a good anti-staining soaping effect is achieved;
5. the soaping agent molecular structure contains positive charges and a polyoxyethylene long chain, the polyoxyethylene long chain with the positive charges can be formed, the good binding force and cohesive force for eluting acid dyes remained in the soaping solution are achieved, the acid dyes are prevented from being stained on printed fabrics in soaping, the positive charges are like a rivet and an anion anchoring the acid dyes, the acid dyes are tightly bound on the acid printing anti-staining soaping agent molecular chains or in capsules, and therefore the anti-staining effect is far better than that of existing products in the market;
6. the molecular structure of the acidic printing anti-staining soaping agent has multiple functions, has positive charges and long-chain polyoxyethylene ether, has good anti-staining effect on acidic dyes remained in the soaping solution, and has good removing effect on printing paste of natural vegetable gum on cloth surfaces; the white background whiteness, the brightness and the definition of the soaped printed fabric are far better than those of similar products in the market.
Drawings
FIG. 1 is a flow chart illustrating the synthesis of the anti-staining soaping agent of the present embodiment.
Detailed Description
The following further describes embodiments of the present invention with reference to the accompanying drawings:
example 1
As shown in fig. 1, the embodiment provides a preparation method of an acid dye printing anti-staining soaping agent of nylon, nylon/spandex, comprising the following steps:
s1), raw materials
S2) preparation process:
650g of tallow amine polyoxyethylene ether (containing 30 polyoxyethylene ether) is injected into a 1000ml three-mouth round bottom reaction bottle, 40g of dimethyl sulfate is input through a closed system, sealed reaction is carried out for 4 hours at 85-90 ℃, 100g of diethylene glycol solvent is added for dilution, 50g of sodium hydroxide with the concentration of 46 percent is added for neutralization, the pH value is adjusted to 6.0-7.0, and 389g of softened water is finally added.
Example 2
As shown in fig. 1, the embodiment provides a preparation method of an acid dye printing anti-staining soaping agent of nylon, nylon/spandex, comprising the following steps:
s1), raw materials
S2), 500g of tallow amine polyoxyethylene ether (containing 30 polyoxyethylene ether) is injected into a 1000ml three-mouth round bottom reaction bottle, 48g of dimethyl sulfate is input through a closed system, sealed reaction is carried out for 4 hours at 85-90 ℃, 150g of diethylene glycol solvent is added for dilution, 33g of 46% sodium hydroxide is added for neutralization, the pH is adjusted to 6.0-7.0, and finally 269g of softened water is added.
Example 3
As shown in fig. 1, the embodiment provides a preparation method of an acid dye printing anti-staining soaping agent of nylon, nylon/spandex, comprising the following steps:
s1), raw materials
S2), 500g of tallow amine polyoxyethylene ether (containing 30 polyoxyethylene ether) is injected into a 1000ml three-mouth round bottom reaction bottle, 60g of dimethyl sulfate is input through a closed system, sealed reaction is carried out for 4 hours at 85-90 ℃, 200g of diethylene glycol solvent is added for dilution, 46% of sodium hydroxide 40 is added for neutralization, the pH value is adjusted to 6.0-7.0, and finally 200g of softened water is added.
Example 4
Application testing
Soaping the printed fabric: acid bright lanilon printed fabric, acid bright lanilon/spandex printed fabric
And (3) effect testing:
after the soaping is finished, the overall appearance effect, the definition and the color vividness of the soaped fabric are visually observed; the anti-staining effect is applied to the international standard ISO105/A02-1993 textile color fastness test-grey sample card for evaluating color change, is used for evaluating color change and staining in a color fastness test and is divided into 1-5 grades, the semi-grade is increased gradually, the 5-grade anti-staining effect is the best, and the 1-grade is the worst; the hand of the cleaned fabric was used primarily to test the de-pasting effect of the examples.
The following process is generally recommended to achieve good white soil release and to ensure paste removal.
1. Adding 1.0-2.0g/L of example 1 or example 2 or example 3 into cold water, and running for 6 minutes at 1g/L of soda ash;
2. adding 1.0-2.0g/L of example 1 or example 2 or example 3 into cold water, and running for 12 minutes at 1g/L of soda ash;
3. 1.0-2.0g/L of example 1 or example 2 or example 3 is added, and 1g/L of soda ash is heated to 40-50 ℃ for 25 minutes.
The test results are shown in table 1, and the examples were tested for anti-pick-up and anti-soaping effects.
As can be seen from the test in Table 1, the soaping process without adding the examples has poor anti-sticking effect on the white background, the minimum level is only 1-2, and the soaped fabric has poor hand feeling due to severe staining, blurred patterns and lines.
The addition of the additive in the embodiment 1, the addition of the additive in the embodiment 2 or the addition of the additive in the embodiment 3 has a good soaping effect, the effect of the additive in the embodiment 3 is optimal, the effect of preventing acid bright red from being stained is best under the action of 2g/L, the level of the additive can reach 5, the effect of acid brilliant blue can reach about 4-5, the patterns and lines of the washed printed fabric are very clear, and the hand feeling is very good.
The foregoing embodiments and description have been presented only to illustrate the principles and preferred embodiments of the invention, and various changes and modifications may be made therein without departing from the spirit and scope of the invention as hereinafter claimed.
Claims (6)
1. The nylon, nylon/spandex acid dye printing anti-staining soaping agent is characterized by comprising the following components in percentage by mass:
2. the acid dye printing anti-staining soaping agent for nylon, nylon/spandex according to claim 1, wherein the soaping agent comprises the following components in percentage by mass:
3. the acid dye printing anti-staining soaping agent for nylon, nylon/spandex according to claim 1, wherein the soaping agent comprises the following components in percentage by mass:
4. a method for preparing the nylon, nylon/spandex acid dye printing anti-staining soaping agent as defined in any one of claims 1-3, which is characterized by comprising the following steps, wherein the component percentages in the following steps are in percentage by mass:
s1), injecting 45-55% tallow amine polyoxyethylene ether (containing 30 polyoxyethylene ether) into a 1000ml three-mouth round bottom reaction bottle, inputting 3.6-6.0% dimethyl sulfate through a closed system, and carrying out sealed reaction for 4 hours at 85-90 ℃;
s2), then adding 10-20% of diethylene glycol solvent for dilution, adding 46% of sodium hydroxide with the concentration of 2.5-4.0% for neutralization, adjusting the pH to 6.0-7.0, and finally adding 10-20% of softened water until the sum of the formula components is 100%.
5. A method for printing an anti-pick soaping agent by using the nylon, the nylon/spandex acid dye as defined in any one of claims 1-4, wherein: adding 1.0-2.0g/L of acid dye printing soaping agent into cold water, running 1g/L of sodium carbonate for 6-12 minutes, discharging water, and fixing color in the next procedure.
6. The use method of the nylon, nylon/spandex acid dye printing anti-staining soaping agent as claimed in claim 5, wherein the method comprises:
adding 1.0-2.0g/L of acid dye printing soaping agent into cold water, heating 1g/L of sodium carbonate to 40-50 ℃, running for 25 minutes, discharging water, and fixing color in the next procedure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011275842.XA CN112323520A (en) | 2020-11-16 | 2020-11-16 | Nylon, nylon/spandex acid dye printing anti-staining soaping agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011275842.XA CN112323520A (en) | 2020-11-16 | 2020-11-16 | Nylon, nylon/spandex acid dye printing anti-staining soaping agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112323520A true CN112323520A (en) | 2021-02-05 |
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|---|---|---|---|
| CN202011275842.XA Pending CN112323520A (en) | 2020-11-16 | 2020-11-16 | Nylon, nylon/spandex acid dye printing anti-staining soaping agent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115772812A (en) * | 2022-11-28 | 2023-03-10 | 东莞市伊时针织印花有限公司 | Environment-friendly mixed acid dye for mixed wool and production method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419958A (en) * | 2015-12-14 | 2016-03-23 | 厦门大邦瑞达印染材料有限公司 | Anti-staining soaping agent for acid dyes as well as preparation method and application of soaping agent |
| CN105625061A (en) * | 2016-01-12 | 2016-06-01 | 浙江雀屏纺织化工股份有限公司 | Anionic dye anti-staining saponifying agent and production method thereof |
| CN105755866A (en) * | 2016-02-29 | 2016-07-13 | 苏州纺友新材料有限公司 | Fabric leveling agent for acid dye |
| CN106833940A (en) * | 2017-02-10 | 2017-06-13 | 苏州市统业化工有限公司 | Anti- staining laundry detergents, anti-staining liquid detergent and anti-staining laundry cloth |
| CN107164114A (en) * | 2017-05-23 | 2017-09-15 | 浙江丝科院轻纺材料有限公司 | A kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO and preparation method thereof |
-
2020
- 2020-11-16 CN CN202011275842.XA patent/CN112323520A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419958A (en) * | 2015-12-14 | 2016-03-23 | 厦门大邦瑞达印染材料有限公司 | Anti-staining soaping agent for acid dyes as well as preparation method and application of soaping agent |
| CN105625061A (en) * | 2016-01-12 | 2016-06-01 | 浙江雀屏纺织化工股份有限公司 | Anionic dye anti-staining saponifying agent and production method thereof |
| CN105755866A (en) * | 2016-02-29 | 2016-07-13 | 苏州纺友新材料有限公司 | Fabric leveling agent for acid dye |
| CN106833940A (en) * | 2017-02-10 | 2017-06-13 | 苏州市统业化工有限公司 | Anti- staining laundry detergents, anti-staining liquid detergent and anti-staining laundry cloth |
| CN107164114A (en) * | 2017-05-23 | 2017-09-15 | 浙江丝科院轻纺材料有限公司 | A kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115772812A (en) * | 2022-11-28 | 2023-03-10 | 东莞市伊时针织印花有限公司 | Environment-friendly mixed acid dye for mixed wool and production method thereof |
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