CN112411213A - Processing method of polyester fabric penetration printing - Google Patents

Processing method of polyester fabric penetration printing Download PDF

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Publication number
CN112411213A
CN112411213A CN202011441957.1A CN202011441957A CN112411213A CN 112411213 A CN112411213 A CN 112411213A CN 202011441957 A CN202011441957 A CN 202011441957A CN 112411213 A CN112411213 A CN 112411213A
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Prior art keywords
polyester fabric
printing
dosage
grafting
methyl methacrylate
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CN202011441957.1A
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Chinese (zh)
Inventor
王灏洁
章金芳
陈万明
张永高
徐华君
张忠
王力
史元庆
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Zhejiang Hanyu Technology Co ltd
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Zhejiang Hanyu Technology Co ltd
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Priority to CN202011441957.1A priority Critical patent/CN112411213A/en
Publication of CN112411213A publication Critical patent/CN112411213A/en
Withdrawn legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34Material containing ester groups
    • D06P3/52Polyesters
    • D06P3/54Polyesters using dispersed dyestuffs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/08Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin
    • D06M14/12Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M14/14Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48Derivatives of carbohydrates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/6426Heterocyclic compounds

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a processing method of polyester fabric permeation printing, which comprises the steps of carrying out grafting pretreatment and water washing on desized polyester fabric; the grafting process comprises the following steps: carrying out grafting reaction on the polyester fabric by adopting a mixture of methacrylic acid and methyl methacrylate, and adopting alkyl glycoside, citric acid, ammonium persulfate or potassium persulfate as an auxiliary agent for auxiliary grafting; the polyester fabric is subjected to grafting pretreatment, so that the hydrophilicity of the fabric is improved, and a precondition is provided for permeation printing; in addition, the printing adopts the N-octyl pyrrolidone to plasticize the polyester fiber, so that the fiber pores are enlarged, and the high-temperature migration of the dye is facilitated. The invention can solve the technical problems of consistent color and luster of the front and back sides and high definition of fabric printing.

Description

Processing method of polyester fabric penetration printing
Technical Field
The invention belongs to the technical field of spinning, and particularly relates to a processing method for polyester fabric permeation printing.
Background
Printing refers to the use of dyes or paints to form patterns and characters on the surface of fabrics. The pattern printed on the fabric is mainly colored on the front side and has no special requirement on the back side. However, as the requirements of people on fashionable, personalized and aesthetic textiles increase, the demand on high-permeability printed fabrics increases, especially double-sided printed fabrics. At present, with the development of electronic technology, some manufacturers realize double-sided printing by adopting high-precision digital printing twice, but the printing mode has high requirements on equipment, long production period and high production risk. The traditional screen printing process realizes a high-penetration printing process on certain thin natural fiber fabrics and long-pile long-wool fabrics, for example, Wang Hui Jun proposes double-side printing of thin fabrics such as real silk and cellulose fibers in a high-penetration printing technology, and the invention patents CN109572160B and CN104553419B propose a processing method for penetration printing of thick flannelette. However, thin chemical fiber fabrics such as terylene have poor hydrophobicity, and the thin chemical fiber fabrics cannot be subjected to permeation printing due to insufficient hygroscopicity and permeability during printing, so that the permeation printing of the thin terylene fabrics is a difficult problem in the industry.
Disclosure of Invention
In order to solve the technical problems, the invention aims to provide a processing method for polyester fabric penetration printing, which solves the technical problems of consistent color and luster of the front and back sides and high definition of fabric printing.
The processing method of the polyester fabric penetration printing comprises the following steps:
a. carrying out grafting pretreatment and water washing on the desized polyester fabric; the grafting process comprises the following steps: carrying out grafting reaction on the polyester fabric by adopting a mixture of methacrylic acid and methyl methacrylate, and adopting alkyl glycoside, citric acid, ammonium persulfate or potassium persulfate as an auxiliary agent for auxiliary grafting;
the mass ratio of methacrylic acid to methyl methacrylate is 2: 3-3: 2, the total amount is 40-60% of the weight of the polyester fabric;
the dosage of the alkyl glycoside is 5-10g/L, the dosage of the citric acid is 2-4g/L, the dosage of the formic acid is 1-2g/L, the dosage of the ammonium persulfate or the potassium persulfate is 5-8% of the total dosage of the methacrylic acid and the methyl methacrylate, the auxiliary agents are uniformly mixed, and the bath ratio is 1: 15-1: 20;
adding polyester fabric, heating to 80-85 ℃ at the speed of 1 ℃/min, and reacting for 50-70min to perform grafting reaction; after the grafting reaction is finished, mixing 2-4g/L of sodium carbonate and 1-2g/L of sodium hydrosulfite to form water washing liquid, wherein the bath ratio is 1: 15-1: washing with water at 80-85 deg.C for 10-15min, and washing with water at normal temperature for 10-15 min;
b. tentering and drying the dacron finished in the step (a) at 165-175 ℃ for 1 min;
c. printing the polyester fabric finished in the step (b); the printing paste is prepared as follows: the dye is prepared from 1-6% of liquid nano disperse dye, 0.5-1% of thickening agent, 1-2% of sodium alginate and 5-20% of N-octyl pyrrolidone, and the above materials are mixed, added with water, beaten, printed by rotary screen or flat screen printing, and dried at 175-180 ℃ for 3-5min to obtain the final product.
The gram weight of the polyester fabric is 90-140g/m2
The invention has the beneficial effects that: the polyester fabric is subjected to grafting pretreatment, so that the hydrophilicity of the fabric is improved, and a precondition is provided for permeation printing; in addition, the printing adopts the N-octyl pyrrolidone to plasticize the polyester fiber, so that the fiber pores are enlarged, and the high-temperature migration of the dye is facilitated; on the other hand, the adoption of the liquid nano disperse dye has the technical advantage of no need of washing after printing. Therefore, through the unique grafting pretreatment and water washing processes, and the drying and preparation of the unique sizing agent, the fabric obtained by the method has consistent color on the front side and the back side and high printing definition. The process has the advantages of convenient operation, high feasibility and simple and easily obtained raw materials.
Detailed Description
Example 1
The processing method of the polyester fabric penetration printing comprises the following steps:
a. carrying out grafting pretreatment and water washing on the desized polyester fabric; the grafting process comprises the following steps: carrying out grafting reaction on the polyester fabric by adopting a mixture of methacrylic acid and methyl methacrylate, and adopting alkyl glycoside, citric acid, ammonium persulfate or potassium persulfate as an auxiliary agent for auxiliary grafting;
the mass ratio of the methacrylic acid to the methyl methacrylate is 2:3, and the total using amount is 40 percent of the weight of the polyester fabric; the dosage of the alkyl glycoside is 5g/L, the dosage of the citric acid is 2g/L, the dosage of the formic acid is 1g/L, the dosage of the ammonium persulfate is 5 percent of the total dosage of the methacrylic acid and the methyl methacrylate, the auxiliary agents are uniformly mixed, and the bath ratio is 1: 15; the gram weight of the polyester fabric is 90g/m2
Adding a polyester fabric, and then heating to 80 ℃ at the speed of 1 ℃/min to react for 50min to perform grafting reaction; after the grafting reaction is finished, mixing 2g/L of soda ash and 1g/L of sodium hydrosulfite to form water washing liquid, wherein the bath ratio is 1: washing with water at 80 deg.C for 10min, and washing with water at normal temperature for 10 min.
b. And (b) tentering and drying the polyester fabric finished in the step (a) at 165 ℃ for 1 min.
c. Printing the polyester fabric finished in the step (b); the printing paste is prepared as follows: the preparation method comprises the following steps of mixing 1% of liquid nano disperse dye, 0.5% of thickening agent, 1% of sodium alginate and 5% of N-octyl pyrrolidone, pulping the mixture by adding water, printing by adopting a rotary screen or a flat screen, and drying at 175 ℃ for 3min to obtain the finished product.
Example 2
The processing method of the polyester fabric penetration printing comprises the following steps:
a. carrying out grafting pretreatment and water washing on the desized polyester fabric; the grafting process comprises the following steps: carrying out grafting reaction on the polyester fabric by adopting a mixture of methacrylic acid and methyl methacrylate, and using alkyl glycoside, citric acid and potassium persulfate as auxiliary agents for auxiliary grafting;
the mass ratio of the methacrylic acid to the methyl methacrylate is 3:2, and the total using amount is 60 percent of the weight of the polyester fabric; the dosage of the alkyl glycoside is 10g/L, the dosage of the citric acid is 4g/L, the dosage of the formic acid is 2g/L, the dosage of the potassium persulfate is 8 percent of the total dosage of the methacrylic acid and the methyl methacrylate, the auxiliary agents are uniformly mixed, and the bath ratio is 1: 20; the gram weight of the polyester fabric is 140g/m2
Adding a polyester fabric, and then heating to 85 ℃ at the speed of 1 ℃/min to react for 70min to perform grafting reaction; after the grafting reaction is finished, mixing 4g/L of soda ash and 2g/L of sodium hydrosulfite to form water washing liquid, wherein the bath ratio is 1: washing with water at 20, 85 deg.C for 15min, and washing with water at normal temperature for 15 min;
b. tentering and drying the polyester fabric finished in the step (a) at 175 ℃ for 1 min;
c. printing the polyester fabric finished in the step (b); the printing paste is prepared as follows: the preparation method comprises the following steps of mixing liquid nano disperse dye with the dosage of 6%, thickening agent with the dosage of 1%, sodium alginate with the dosage of 2% and N-octyl pyrrolidone with the dosage of 20% of the dye, adding water into the mixture, pulping, printing by adopting a rotary screen or a flat screen, and drying for 5min at 180 ℃ to obtain the finished product.
Example 3
The processing method of the polyester fabric penetration printing comprises the following steps:
a. carrying out grafting pretreatment and water washing on the desized polyester fabric; the grafting process comprises the following steps: carrying out grafting reaction on the polyester fabric by adopting a mixture of methacrylic acid and methyl methacrylate, and using alkyl glycoside, citric acid and ammonium persulfate as auxiliary agents for auxiliary grafting;
the mass ratio of the methacrylic acid to the methyl methacrylate is 2.2:1, and the total using amount is 45 percent of the weight of the polyester fabric; the dosage of the alkyl glycoside is 6g/L, the dosage of the citric acid is 3g/L, the dosage of the formic acid is 2g/L, and the dosage of the ammonium persulfate is the total dosage of the methacrylic acid and the methyl methacrylate6% of the above auxiliary agents are uniformly mixed, and the bath ratio is 1: 16; the gram weight of the polyester fabric is 120g/m2
Adding a polyester fabric, and then heating to 82 ℃ at the speed of 1 ℃/min to react for 55min to carry out grafting reaction; after the grafting reaction is finished, mixing 3g/L of soda ash and 1g/L of sodium hydrosulfite to form water washing liquid, wherein the bath ratio is 1: washing with water at 16, 82 deg.C for 12min, and washing with water at normal temperature for 12 min;
b. tentering and drying the polyester fabric finished in the step (a) at 168 ℃ for 1 min;
c. printing the polyester fabric finished in the step (b); the printing paste is prepared as follows: the dosage of the liquid is 3 percent
Example 4
The processing method of the polyester fabric penetration printing comprises the following steps:
a. carrying out grafting pretreatment and water washing on the desized polyester fabric; the grafting process comprises the following steps: carrying out grafting reaction on the polyester fabric by adopting a mixture of methacrylic acid and methyl methacrylate, and using alkyl glycoside, citric acid and potassium persulfate as auxiliary agents for auxiliary grafting;
the mass ratio of the methacrylic acid to the methyl methacrylate is 2.4:3, and the total using amount is 55 percent of the weight of the polyester fabric; the dosage of the alkyl glycoside is 7g/L, the dosage of the citric acid is 2.5g/L, the dosage of the formic acid is 1.6g/L, the dosage of the potassium persulfate is 7 percent of the total dosage of the methacrylic acid and the methyl methacrylate, the auxiliary agents are uniformly mixed, and the bath ratio is 1: 18; the gram weight of the polyester fabric is 110g/m2
Adding a polyester fabric, and then heating to 82 ℃ at the speed of 1 ℃/min to react for 62min to carry out grafting reaction; after the grafting reaction is finished, mixing 3.5g/L of soda and 1.8g/L of sodium hydrosulfite to form water washing liquid, wherein the bath ratio is 1: washing with water at 18, 81 deg.C for 11min, and washing with water at normal temperature for 14 min;
b. tentering and drying the polyester fabric finished in the step (a) at 172 ℃ for 1 min;
c. printing the polyester fabric finished in the step (b); the printing paste is prepared as follows: the preparation method comprises the following steps of mixing 2% of liquid nano disperse dye, 0.9% of thickening agent, 1.6% of sodium alginate and 12% of N-octyl pyrrolidone, pulping, printing by a rotary screen or a flat screen, and drying at 176 ℃ for 3.5min to obtain the finished product.
Example 5
The processing method of the polyester fabric penetration printing comprises the following steps:
a. carrying out grafting pretreatment and water washing on the desized polyester fabric; the grafting process comprises the following steps: carrying out grafting reaction on the polyester fabric by adopting a mixture of methacrylic acid and methyl methacrylate, and adopting alkyl glycoside, citric acid, ammonium persulfate or potassium persulfate as an auxiliary agent for auxiliary grafting;
the mass ratio of the methacrylic acid to the methyl methacrylate is 2.4:2, and the total using amount is 54 percent of the weight of the polyester fabric; the dosage of the alkyl glycoside is 7g/L, the dosage of the citric acid is 3g/L, the dosage of the formic acid is 1.2g/L, the dosage of the ammonium persulfate or the potassium persulfate is 7 percent of the total dosage of the methacrylic acid and the methyl methacrylate, the auxiliary agents are uniformly mixed, and the bath ratio is 1: 19; the gram weight of the polyester fabric is 105g/m2
Adding a polyester fabric, and then heating to 83 ℃ at the speed of 1 ℃/min to react for 53min to carry out grafting reaction; after the grafting reaction is finished, mixing 3g/L of soda ash and 1.5g/L of sodium hydrosulfite to form water washing liquid, wherein the bath ratio is 1: washing with water at 18, 82 deg.C for 13min, and washing with water at normal temperature for 14 min;
b. tentering and drying the polyester fabric finished in the step (a) at 167 ℃ for 1 min;
c. printing the polyester fabric finished in the step (b); the printing paste is prepared as follows: the preparation method comprises the following steps of mixing 4% of liquid nano disperse dye, 0.6% of thickening agent, 1.7% of sodium alginate and 12% of N-octyl pyrrolidone, pulping, printing by a rotary screen or a flat screen, and drying at 177 ℃ for 4min to obtain the finished product.
In the above examples, the liquid nano disperse dye and the thickener are commercially available from Zhejiang Kong organosilicon Co.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (2)

1. The processing method of the polyester fabric penetration printing comprises the following steps: the method is characterized in that:
a. carrying out grafting pretreatment and water washing on the desized polyester fabric; the grafting process comprises the following steps: carrying out grafting reaction on the polyester fabric by adopting a mixture of methacrylic acid and methyl methacrylate, and adopting alkyl glycoside, citric acid, ammonium persulfate or potassium persulfate as an auxiliary agent for auxiliary grafting;
the mass ratio of methacrylic acid to methyl methacrylate is 2: 3-3: 2, the total amount is 40-60% of the weight of the polyester fabric; the dosage of the alkyl glycoside is 5-10g/L, the dosage of the citric acid is 2-4g/L, the dosage of the formic acid is 1-2g/L, the dosage of the ammonium persulfate or the potassium persulfate is 5-8% of the total dosage of the methacrylic acid and the methyl methacrylate, the auxiliary agents are uniformly mixed, and the bath ratio is 1: 15-1: 20;
adding polyester fabric, heating to 80-85 ℃ at the speed of 1 ℃/min, and reacting for 50-70min to perform grafting reaction; after the grafting reaction is finished, mixing 2-4g/L of sodium carbonate and 1-2g/L of sodium hydrosulfite to form a water washing solution, wherein the bath ratio is 1: 15-1: washing with water at 80-85 deg.C for 10-15min, and washing with water at normal temperature for 10-15 min;
b. tentering and drying the dacron finished in the step (a) at 165-175 ℃ for 1 min;
c. printing the polyester fabric finished in the step (b); the printing paste is prepared as follows: the dye is prepared from 1-6% of liquid nano disperse dye, 0.5-1% of thickening agent, 1-2% of sodium alginate and 5-20% of N-octyl pyrrolidone by mixing, adding water, pulping, printing with a rotary screen or a flat screen, and drying at 175-180 deg.C for 3-5 min.
2. Processing method for polyester fabric penetration printing according to claim 1The method is characterized in that: the gram weight of the polyester fabric is 90-140g/m2
CN202011441957.1A 2020-12-08 2020-12-08 Processing method of polyester fabric penetration printing Withdrawn CN112411213A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115075005A (en) * 2022-06-08 2022-09-20 武汉纺织大学 Unidirectional moisture-conducting polyester fabric prepared based on printing process and preparation method thereof

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WO2018018800A1 (en) * 2016-07-26 2018-02-01 黄庄芳容 Method for wet transfer printing of polyester fiber/cotton fiber union fabric
CN109183466A (en) * 2018-06-21 2019-01-11 绍兴宏强印染有限公司 A kind of printing technology of resistance polyester fiber knitting fabric

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CN102080336A (en) * 2010-12-07 2011-06-01 江南大学 Preparation and process of darkening printing paste for superfine polyester disperse dye
WO2018010356A1 (en) * 2016-07-11 2018-01-18 黄庄芳容 Dyeing method for cationic dyeable polyester/polyester/nylon/spandex fabrics
WO2018018800A1 (en) * 2016-07-26 2018-02-01 黄庄芳容 Method for wet transfer printing of polyester fiber/cotton fiber union fabric
CN107227630A (en) * 2017-05-11 2017-10-03 江苏银桥纺织科技有限公司 A kind of printing technology of dacron
CN109183466A (en) * 2018-06-21 2019-01-11 绍兴宏强印染有限公司 A kind of printing technology of resistance polyester fiber knitting fabric

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115075005A (en) * 2022-06-08 2022-09-20 武汉纺织大学 Unidirectional moisture-conducting polyester fabric prepared based on printing process and preparation method thereof

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