CN102926237A - Wetting liquid for fabric pattern transfer - Google Patents
Wetting liquid for fabric pattern transfer Download PDFInfo
- Publication number
- CN102926237A CN102926237A CN2012104639462A CN201210463946A CN102926237A CN 102926237 A CN102926237 A CN 102926237A CN 2012104639462 A CN2012104639462 A CN 2012104639462A CN 201210463946 A CN201210463946 A CN 201210463946A CN 102926237 A CN102926237 A CN 102926237A
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- CN
- China
- Prior art keywords
- fabric
- acid
- fountain solution
- water
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 129
- 239000007788 liquid Substances 0.000 title claims abstract description 11
- 238000009736 wetting Methods 0.000 title abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 61
- 239000003960 organic solvent Substances 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 27
- 239000002253 acid Substances 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- 239000000835 fiber Substances 0.000 claims abstract description 19
- 229920000742 Cotton Polymers 0.000 claims abstract description 14
- 238000010023 transfer printing Methods 0.000 claims description 39
- 239000000975 dye Substances 0.000 claims description 34
- 210000002268 wool Anatomy 0.000 claims description 33
- 239000000463 material Substances 0.000 claims description 31
- 239000012296 anti-solvent Substances 0.000 claims description 24
- 235000011837 pasties Nutrition 0.000 claims description 24
- 239000000985 reactive dye Substances 0.000 claims description 23
- 239000006096 absorbing agent Substances 0.000 claims description 16
- 150000003839 salts Chemical class 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 12
- 229920003043 Cellulose fiber Polymers 0.000 claims description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 10
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 9
- 239000004677 Nylon Substances 0.000 claims description 9
- 229920001778 nylon Polymers 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 8
- 239000002585 base Substances 0.000 claims description 8
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N dimethyl sulfoxide Natural products CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000003292 glue Substances 0.000 claims description 8
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims description 7
- 229920002472 Starch Polymers 0.000 claims description 7
- 239000000980 acid dye Substances 0.000 claims description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 7
- 239000000982 direct dye Substances 0.000 claims description 7
- 235000019698 starch Nutrition 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- 239000004202 carbamide Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000008107 starch Substances 0.000 claims description 6
- 229920002972 Acrylic fiber Polymers 0.000 claims description 5
- 150000001768 cations Chemical class 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 108090000623 proteins and genes Proteins 0.000 claims description 5
- 102000004169 proteins and genes Human genes 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 150000001447 alkali salts Chemical class 0.000 claims description 4
- 239000001110 calcium chloride Substances 0.000 claims description 4
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 4
- 150000001720 carbohydrates Chemical class 0.000 claims description 4
- 235000014633 carbohydrates Nutrition 0.000 claims description 4
- 239000004359 castor oil Substances 0.000 claims description 4
- 150000004676 glycans Chemical class 0.000 claims description 4
- 150000007529 inorganic bases Chemical class 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 150000007522 mineralic acids Chemical class 0.000 claims description 4
- 150000007524 organic acids Chemical class 0.000 claims description 4
- 150000007530 organic bases Chemical class 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 229920001282 polysaccharide Polymers 0.000 claims description 4
- 239000005017 polysaccharide Substances 0.000 claims description 4
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 4
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical group [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical group N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 3
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 3
- 229920003086 cellulose ether Polymers 0.000 claims description 3
- 235000015165 citric acid Nutrition 0.000 claims description 3
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 3
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 3
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical group [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical compound Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 claims description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical class CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 2
- SAQSTQBVENFSKT-UHFFFAOYSA-M TCA-sodium Chemical compound [Na+].[O-]C(=O)C(Cl)(Cl)Cl SAQSTQBVENFSKT-UHFFFAOYSA-M 0.000 claims description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- LPQOADBMXVRBNX-UHFFFAOYSA-N ac1ldcw0 Chemical group Cl.C1CN(C)CCN1C1=C(F)C=C2C(=O)C(C(O)=O)=CN3CCSC1=C32 LPQOADBMXVRBNX-UHFFFAOYSA-N 0.000 claims description 2
- 235000011054 acetic acid Nutrition 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 150000002016 disaccharides Chemical class 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 125000003916 ethylene diamine group Chemical group 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 229940072033 potash Drugs 0.000 claims description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 2
- 235000015320 potassium carbonate Nutrition 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 claims description 2
- 230000002209 hydrophobic effect Effects 0.000 abstract description 10
- 238000009941 weaving Methods 0.000 abstract description 5
- 239000002562 thickening agent Substances 0.000 abstract description 3
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 238000011109 contamination Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 16
- 235000002639 sodium chloride Nutrition 0.000 description 12
- 230000008595 infiltration Effects 0.000 description 10
- 238000001764 infiltration Methods 0.000 description 10
- 238000007639 printing Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- 229920000297 Rayon Polymers 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 239000004519 grease Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000012752 auxiliary agent Substances 0.000 description 6
- 239000012528 membrane Substances 0.000 description 5
- 239000002964 rayon Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical class CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 230000001788 irregular Effects 0.000 description 3
- 238000009940 knitting Methods 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229960001760 dimethyl sulfoxide Drugs 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 210000004209 hair Anatomy 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000010022 rotary screen printing Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- 241000223678 Aureobasidium pullulans Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 238000007774 anilox coating Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 238000010020 roller printing Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000009955 starching Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 150000007984 tetrahydrofuranes Chemical class 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Coloring (AREA)
Abstract
The invention discloses a wetting liquid for fabric pattern transfer. The wetting liquid comprises the following components by weight of 20-80% of water, 10-70% of organic solvent, 3-15% of water absorbent, 0.5-5% of base-releasing agent or acid-releasing agent and 0-20% of solvent-resistant thickener. By wetting the fabric with the wetting liquid, the problem that fabrics of a hydrophobic fabric in the wetting pattern transfer is difficult to wet uniformly is solved relatively thoroughly. The influence of the natural fiber such as cotton comprising the unremovable fat to the fabric wetting when performing the wetting pattern transfer is solved relatively thoroughly. The influence of the oil contamination on the fabric of the hydrophobic fabric in the wetting pattern transfer is removed relatively thoroughly in the process of fabric weaving.
Description
Technical field
The invention belongs to the textile printing and dyeing field, the fountain solution when particularly a kind of patterns of fabric shifts.
Background technology
It is that wet method shifts that the colored type of natural fabric and polyamide fibre and acrylic fabric shifts the best approach.Most essential steps was the even dewing of fabric when wet method shifted.And in the dewing operation of existing wet transfer printing, the producer only pays close attention to dewing equipment, improves and control the purpose that reaches even dewing by the difference of equipment.A kind of method of soaking of side transfer printed fabric is disclosed such as patent CN2844175.Patent CN101643984 discloses the soaking device that uses in a kind of fabric wet transfer printing process.Patent CN201350725 discloses a kind of quantitative wetting apparatus of transfer printing machine.
These patents all are the even dewing that solves fabric from the equipment angle.Yet in existing fabric, nylon fabric, acrylic fabric is the hydrophobic fiber fabric, and often speckles with the greasy dirt that is difficult to thorough removal in weaving process.Viscose fabric is artificial fibre, often is mixed with hydrophobic impurity when fiber is made, and often speckles with the greasy dirt that is difficult to remove in weaving process.All-cotton fabric itself contains more hydrophobic impurity and grease, and these impurity and grease are removed difficulty when pre-treatment very big, and it is inconsistent to remove easily the bad fabric capillary effect that causes, water capacity difference when causing wet transfer printing.
The fountain solution of existing wet transfer printing wet fabric, its main component is water, be added with a little different auxiliary agents according to the difference of fabric and the difference of dyestuff in its water, the surface tension of this fountain solution is large, be difficult to some hydrophobic fiber fabrics contain the fabric of grease or weaving process in to speckle with the fabric Quick uniform of greasy dirt wetting.
So, only improve and control by the difference of the equipment of soaking, want to reach the even dewing effect of the best, be that suitable difficulty is arranged.
Summary of the invention
Technical problem to be solved by this invention provides a kind of low surface tension and the fountain solution can shift the patterns of fabric of weaving greasy dirt or natural oil and have certain solvability and good wetting property on the fabric time.
For solving the problems of the technologies described above, thinking of the present invention is: water is mixed with organic solvent, become the mixed liquor of water and organic solvent, add conventional auxiliary agent according to the difference of fabric or the difference of dyeing and printing process or the difference of dyestuff again, the fountain solution when forming patterns of fabric and shifting.
Concrete technical scheme is:
The fountain solution that a kind of patterns of fabric shifts, it comprises the component of following percentage by weight: water 20～80%, organic solvent 10～70%, water absorbing agent 0～15%, releasing alkaline agent or acid-releasing agent is 0.5～5%, anti-solvent pasty materials 0～20%.
Wherein, described organic solvent is strong polarity, and can be any than the organic solvent that dissolves each other with water, is alcohols, ethers, cellosolve series, amide-type, acetonitrile, ketone, dimethyl sulfoxide (DMSO) or sulfonated castor oil.
Wherein, described water absorbing agent is the material of energy deliquescence suction in the air, and it comprises urea, glycerine, calcium chloride or magnesium chloride etc.
Wherein, the described alkaline agent of releasing is for ionizing the material that generates hydroxide ion in solution, it comprises inorganic base, organic base, basic salt or strong base-weak acid salt, wherein, described inorganic base is NaOH, calcium hydroxide or potassium hydroxide, described organic base is ethylenediamine or triethanolamine, and described basic salt is alkali formula calcium chloride, and described strong acid weak base salt is sodium bicarbonate, saleratus, potash, sodium trichloroacetate, tertiary sodium phosphate or soda ash; Described acid-releasing agent is can ionize to produce hydrionic material in solution, it comprises organic acid, inorganic acid, acid salt or strong acid weak base salt, wherein, described organic acid is formic acid, acetic acid, oxalic acid, citric acid, malic acid or trichloroacetic acid, described inorganic acid is hydrochloric acid, sulfuric acid, phosphoric acid or nitric acid, described acid salt is niter cake or sodium dihydrogen phosphate, and described strong acid weak base salt is ammonium sulfate.
Wherein, described anti-solvent pasty materials refers to be dissolved in the mixed liquor of water and organic solvent, and can form polymer substance or the carbohydrate of thick liquid, wherein, described polymer substance is cellulose ether, starch ether, seed glue etherate or glucidtemns, and described carbohydrate is monose or disaccharide or polysaccharide.
Wherein, when adopting padding machine dipping dewing and spray gun spraying dewing, in fountain solution, can not need to add anti-solvent pasty materials; When adopting wire mark dewing and intaglio plate anilox roll dewing, dewing liquid need to add certain anti-solvent pasty materials, so that dewing liquid keeps certain viscosity.These all are technological means well known to those skilled in the art, and those skilled in the art can according to different dewing modes, select to add or do not add anti-solvent pasty materials.
When fabric is cellulose fibre, real silk or wool, when dyestuff was direct dyes, fountain solution was comprised of the component of following percentage by weight: water 20～80%, organic solvent 10～70%, water absorbing agent 5～15%, anti-solvent pasty materials 0.5～20%;
When fabric is cellulose fibre or real silk, when dyestuff was REACTIVE DYES, fountain solution was comprised of the component of following percentage by weight: water 20～80%, and organic solvent 10～70%, water absorbing agent 5～15%, releasing alkaline agent is 1～5%, anti-solvent pasty materials 0.5～20%;
When fabric is real silk, nylon or wool, when dyestuff was ACID DYES or REACTIVE DYES, fountain solution was comprised of the component of following percentage by weight: water 20～80%, and organic solvent 10～70%, water absorbing agent 5～15%, acid-releasing agent are 1～5%, anti-solvent pasty materials 0.5～20%;
When fabric is acrylic fibers, when dyestuff was cation dyes, fountain solution was comprised of the component of following percentage by weight: water 20～80%, and organic solvent 10～70%, water absorbing agent 3～7%, acid-releasing agent are 1～5%, anti-solvent pasty materials 0.5～20%.
When fabric is all-cotton fabric, dyestuff is REACTIVE DYES, and when color fixing process was the cold dome fixation, fountain solution was comprised of the component of following percentage by weight: water 20～80%, and organic solvent 10～70%, releasing alkaline agent is 1～5%, anti-solvent pasty materials 0～20%;
When fabric is wool or real silk, dyestuff is REACTIVE DYES or ACID DYES, and when color fixing process was the cold dome fixation, fountain solution was comprised of the component of following percentage by weight: water 20～80%, organic solvent 10～70%, acid-releasing agent are 1～5%, anti-solvent pasty materials 0.5～20%.
When fabric is that cellulose fibre (such as cotton, viscose glue, day silk etc.) interweaves with protein fibre (such as real silk, wool, fibre and soya, milk fibre) or during blending, the fountain solution prescription is with reference to the fountain solution prescription of cellulose base fiber fabric.
Namely when fabric be cellulose fibre and protein fibre interweaves or during blending, when dyestuff was direct dyes, fountain solution was comprised of the component of following percentage by weight: water 20～80%, organic solvent 10～70%, water absorbing agent 5～15%, anti-solvent pasty materials 0.5～20%;
When fabric is cellulose fibre and protein fibre interweaves or during blending, when dyestuff was REACTIVE DYES, fountain solution was comprised of the component of following percentage by weight: water 20～80%, organic solvent 10～70%, water absorbing agent 5～15%, releasing alkaline agent is 1～5%, anti-solvent pasty materials 0.5～20%.
In addition, be cellulose fibre at kinds of fibers, when dyestuff is direct dyes, in order to increase the affinity between dyestuff and the fiber, increase the dye-uptake of dyestuff, in fountain solution, can add the neutral inorganic of 1～5wt%; Be cellulose fibre, cocoon fiber at kinds of fibers, when dyestuff is REACTIVE DYES, in order to increase the affinity between dyestuff and the fiber, increase the dye-uptake of dyestuff, in fountain solution, can add the neutral inorganic of 1～5wt%.These all are technology well known to those skilled in the art, and those skilled in the art can according to infiltration and the color depth situation of different dyestuffs on fabric, select to add or do not add neutral inorganic.
Wherein, neutral inorganic refers to the salt that the neutralization reaction of strong acid and strong base generates, and generally commonly used is sodium chloride, sodium sulphate, potassium chloride, potassium sulfate etc.
Beneficial effect: compare with the fountain solution of routine in the fountain solution when patterns of fabric of the present invention shifts, because contain low surface tension, to greasy dirt, organic solvent that the grease solvability is powerful, so, it has following beneficial effect: on the one hand, it is compared with conventional fountain solution, and very low surface tension is arranged, and easily hydrophobic substance is infiltrated.On the other hand, the organic solvent of strong polarity has the extremely strong solvability to greasy dirt or grease, and fountain solution of the present invention can dissolve greasy dirt or grease, eliminates greasy dirt or grease to wetting impact.Also have, fountain solution of the present invention is larger to the solubility of dyestuff, and dissolution velocity is faster, and the rate of transform is higher.
Wetting to fabric by fountain solution of the present invention, fabric was difficult to evenly wetting problem during the wet method flower type that has solved more thoroughly the hydrophobic fiber fabric shifted.Natural fabric such as cotton have been solved more thoroughly, the wetting impact of fabric when containing the grease that is difficult to remove on the wool fabric wet method flower type being shifted.Solved more thoroughly the wetting impact of fabric when being infected with greasy dirt on the transfer of wet method flower type in the face weave process.
The specific embodiment
According to following embodiment, the present invention may be better understood.Yet, those skilled in the art will readily understand that the described content of embodiment only is used for explanation the present invention, and should also can not limit the present invention described in detail in claims.
Embodiment 1:
Fetch water 100 kilograms, add 30 kilograms of ethanol, stir; Add 10 kilograms of urea, 2.5 kilograms of citric acids stir, and until completely dissolved, add 8 kilograms of seed glue etherate PS-14, stir, and treat that PS-14 dissolves fully, form slurry, and are stand-by again.
Get 50 meters and be subjected to oil pollution, the nylon elastic knitted cloth that is difficult to complete wipe oil is some, to coat nylon elastic knitted cloth surface with spreading mass with single chromatography rotary screen printing machine, again the printing surface of ACID DYES transfer film and the pasting face of nylon elastic knitted cloth are fitted, pressurization, the ACID DYES on the transfer film has just been transferred on the nylon elastic fabric uniformly.Through decatize, washing, the rear arrangements such as typing, transfer printing nylon elastic knit fabric.
By range estimation, can find out obviously that color is deeply dense, Dry Sack is even, and infiltration is good, and greasy dirt place Dry Sack is impact not.The comparative example 1:
More than in the prescription, 30 kg of water are replaced 30 kilograms of ethanol, all the other compositions and ratio are in full accord.
It is some to get same fabric, with same acid transfer membrane and same method transfer printing, obtains nylon elastic knitted cloth transfer printing fabric.
By range estimation, can find out obviously that color is relatively light, Dry Sack is deep mixed, and the fabric core that shows money or valuables one carries unintentionally in greasy dirt place is arranged, and the infiltration of flower type is bad.
Embodiment 2:
Fetch water 75 kilograms, add 17 kilograms of sulfonated castor oils, stir, add 2 kilograms in caustic soda again, 5 kilograms of salt stir, and are so that caustic soda and salt dissolves fully, stand-by.
It is some to get the irregular woven cotton fabric of kiering, insert in the common evenness calender charging spout with above solution, regulate evenness calender pressure, allow cotton pass the evenness calender quick humidification, again the printing surface of REACTIVE DYES transfer paper and wetting cotton are fitted, through cold-transfer printing machine, the REACTIVE DYES on the REACTIVE DYES transfer paper has just been transferred on the cotton.Use the cold dome color fixing process, be about to this cotton PE plastic film wrapped, prevent moisture evaporation, leave standstill 10 hours after, washing, oven dry is finalized the design, the transfer printing cotton.
By range estimation, can find out obviously that color is deeply dense, Dry Sack is even, and infiltration is good, and kiering is irregular on not impact of Dry Sack.
The comparative example 2:
More than in the prescription, 10 kg of water are replaced 10 kilograms of sulfonated castor oils, all the other compositions and ratio are in full accord.
It is some to get same fabric, with same REACTIVE DYES transfer paper and same method transfer printing, obtains cotton transfer printing fabric.
By range estimation, can find out obviously that color is relatively light, Dry Sack is deep mixed, and the white core of obvious look shallow is arranged at the irregular place of destarch.
Embodiment 3:
Fetch water 30 kilograms, add 70 kilograms of ethyl cellosolves, stir, add again 1.5 kilograms of ammonium sulfate, 3 kilograms of glycerine, 7 kilograms of urea, 1.2 kilograms of hydroxypropyl methylcelluloses (belonging to cellulose ether) stir, treat that auxiliary agent and anti-solvent pasty materials dissolve fully, form slurry, stand-by.
It is some to get wool knitted fabric, insert in order to spreading mass in the charging spout of intaglio plate coating roller, start the intaglio plate coating roller, allow the surface that is coated on wool knitted fabric with spreading mass, again the printing surface of reactive dye for wool transfer film and the coated face of wool fabric are fitted, enter the cold-transfer printing machine transfer printing, after reactive dye for wool is transferred on the wool knitted fabric, oven dry, decatize, the washing, the typing, the transfer printing wool knitted fabric.
By range estimation, can find out obviously that color is deeply dense, Dry Sack is even, and infiltration is good.
The comparative example 3:
More than in the prescription, 70 kg of water are replaced 70 kilograms of ethyl cellosolves, all the other compositions are consistent with ratio.
It is some to get same wool knitting fabrics, with same reactive dye for wool transfer membrane and same method transfer printing, when intaglio plate coating roller rolling pulp material, can find, because wool fabric is hydrophobic fabric, slurry can not infiltrate wool fabric, and wool fabric can not be wetting by the intaglio plate coating roller, and transfer printing can not be finished.
Embodiment 4:
Fetch water 50 kilograms, 50 kilograms of dimethyl formamides stir, and add 4 kilograms in sodium bicarbonate, 15 kilograms in urea, 3.5 kilograms of glauber salt stir, and add at last 2.5 kilograms of sodium carboxymethyl starches (belonging to starch ether), stir, treat that sodium carboxymethyl starch dissolves fully, form pulpous state, stand-by.
Get and be woven oil pollution, the rayon satin that pre-treatment is difficult to remove is some, to place with spreading mass the charging spout of evenness calender, regulate evenness calender pressure, allow the rayon satin pass the evenness calender quick humidification, the printing surface of REACTIVE DYES transfer paper is fitted with wetting rayon satin, through cold-transfer printing machine, the REACTIVE DYES on the REACTIVE DYES transfer paper has just been transferred on the cotton again.The oven dry, decatize, the washing, the typing, transfer printing rayon satin.
By range estimation, can find out obviously that color is deeply dense, Dry Sack is even, and infiltration is good, and greasy dirt place Dry Sack is impact not.The comparative example 4:
Dimethyl formamide in the above prescription is substituted with 50 kg of water, and all the other compositions are consistent with ratio.
It is some to get same fabric, with same REACTIVE DYES transfer paper and same method transfer printing, obtains rayon satin's transfer printing fabric.
By range estimation, can find out obviously that color is relatively light, Dry Sack is deep mixed, at greasy dirt and the white core of obvious look shallow is arranged everywhere.
Embodiment 5:
Fetch water 60 kilograms, 40 kilograms in acetone mixes, and stirs, and adds 1 kilogram of sodium chloride, 7 kilograms of glycerine, and 20 kilograms of sucrose, stirring treats that sucrose and sodium chloride is dissolved into pulpous state fully, and is stand-by.
Get that to move back glue silk knitting fabric not to the utmost some, insert in order to spreading mass in the charging spout of intaglio plate coating roller, start the intaglio plate coating roller, allow surface with spreading mass coating silk knitting fabric, again with the coated face applying of printing surface with the real silk knitted cloth fabric of direct dyes transfer film, enter the cold-transfer printing machine transfer printing, oven dry, decatize, washing, typing becomes the transfer printing real silk knitted fabrics.
By range estimation, can find out obviously that color is deeply dense, Dry Sack is even, and infiltration is good, moves back glue not to the utmost on not impact of Dry Sack.
The comparative example 5:
Acetone in the above prescription is substituted with 40 kg of water, and all the other compositions are consistent with ratio.
It is some to get same fabric, with same direct dyes transfer membrane and same method transfer printing, obtains real silk knitted transfer printing fabric.
By range estimation, can find out obviously that color is relatively light, Dry Sack is deep mixed, moves back glue and locates not to the utmost obviously to paint shallow and white core.
Embodiment 6:
Fetch water 80 kilograms, 30 kilograms of methyl-sulfoxides mix, and stir, and add 3 kilograms of sodium dihydrogen phosphates, and 6 kilograms of glycerine are got 8 kilograms of yellow starch gums (belonging to glucidtemns), stir, and treat that auxiliary agent and yellow starch gum dissolve fully, and the slurry that poling is thin is stand-by.
It is some to get the acrylic fibers knitted cloth, will add in the spray gun with spreading mass, regulates spray gun air pressure, slurry evenly is sprayed on the fabric surface, gets the spray-coating surface of cation dyes transfer film and fabric and fit, put into cold-transfer printing machine, pressurization, cation dyes just have been dissolved on the acrylic fabric.The oven dry, decatize, the washing, the typing, the transfer printing acrylic fabric.
By range estimation, can find out obviously that color is deeply dense, Dry Sack is even, and infiltration is good.
The comparative example 6:
Methyl-sulfoxide in the above prescription is substituted with 30 kg of water, and all the other compositions are consistent with ratio.
It is some to get same acrylic fibers knitted cloth, with same cation dyes transfer membrane and same method transfer printing, because the acrylic fibers knitted cloth is hydrophobic fabric, can not permeate in fabric inside with spreading mass, and at the fabric surface sediment, trickling can not be carried out transfer printing.
Embodiment 7:
Get 65 kg of water, add 35 kilograms of oxolanes, add again 0.6 kilogram of niter cake, add 2 kilograms of Aureobasidium pullulans polysaccharide, stir, treat that auxiliary agent and thickener be dissolved into thick liquid fully, stand-by.
On rotary screen printing machine, load onto 120 order garden nets, above thick liquid is coated on the wool fabric surface, printing surface and the wool fabric coated face of ACID DYES transfer film are fitted, put into the wet transfer printing machine and shift, after transfer finishes, use the cold dome fixation, both finished the wool fabric that dyestuff shifts with plastic film wrapped, prevent moisture evaporation, after 24 hours, tear wrap film off, washing, oven dry.
By range estimation, can find that color is full, infiltration is good, and the Dry Sack of the left, center, right of fabric is even, and the core phenomenon does not show money or valuables one carries unintentionally.
The comparative example 7:
Change the oxolane in the above prescription into 35 kg of water, all the other compositions and constant rate.Behind above identical printing transferring method and color-fixing method, transfer printing wool fabric finished product is dried in washing.
By range estimation, can see obviously that dyestuff is residual many on the transfer membrane, wool stamp finished product of light color, fabric has very serious left, center, right aberration, and the serious core phenomenon that shows money or valuables one carries unintentionally is arranged.
Embodiment 8:
Fetch water 50 kilograms, 45 kilograms of acetonitriles add 3 kilograms of tertiary sodium phosphates, 10 kilograms in urea, and 3 kilograms of pulullan polysaccharides stir, and treat that auxiliary agent and thickener be dissolved into thick liquid fully, and are stand-by.
Get wool content 50%, the blending cut velvet hair wool fabric of viscose glue content 50%, use 50 order intaglio plate applicator rolls to be uniformly coated on cut velvet hair wool fabric surface with spreading mass with the intaglio plate starching machine, printing surface and the coated face of REACTIVE DYES transfer paper are fitted, enter wet transfer printing machine transfer printing, tear transfer paper after the transfer printing off, oven dry, decatize, washing, again the oven dry, transfer printing cut velvet hair wool fabric.
By range estimation, can find out that dyestuff penetration is dark, can be penetrated into the reverse side of mao wool fabric, Dry Sack is rich and gaudy, and the suitable of the stamp place fine hair of cut velvet hair wool fabric can not cause colored type show-through.
The comparative example 8:
Acetonitrile in the above prescription is replaced all the other compositions and constant rate with 45 kg of water.Use the same method transfer printing of same fabric, obtain wool blended vertical fluff woolen cloth transfer printing fabric.
By range estimation, can find out that the infiltration of dyestuff is shallow, only float over cut velvet hair wool fabric surface, the suitable of cut velvet fabric stamp place fine hair can cause serious grinning effect.
Claims (9)
1. the fountain solution that shifts of a patterns of fabric is characterized in that it comprises the component of following percentage by weight: water 20～80%, and organic solvent 10～70%, water absorbing agent 0～15%, releasing alkaline agent or acid-releasing agent is 0.5～5%, anti-solvent pasty materials 0～20%.
2. the fountain solution that shifts of patterns of fabric according to claim 1, it is characterized in that, described organic solvent is strong polarity, and can be any than the organic solvent that dissolves each other with water, be alcohols, ethers, cellosolve series, amide-type, oxolane, acetonitrile, ketone, dimethyl sulfoxide (DMSO) or sulfonated castor oil.
3. the fountain solution of patterns of fabric transfer according to claim 1 is characterized in that, described water absorbing agent is the material of energy deliquescence suction in the air, and it comprises urea, glycerine, calcium chloride or magnesium chloride.
4. the fountain solution that shifts of patterns of fabric according to claim 1, it is characterized in that, the described alkaline agent of releasing is for ionizing the material that generates hydroxide ion in solution, it comprises inorganic base, organic base, basic salt or strong base-weak acid salt, wherein, described inorganic base is NaOH, calcium hydroxide or potassium hydroxide, described organic base is ethylenediamine or triethanolamine, described basic salt is alkali formula calcium chloride, and described strong acid weak base salt is sodium bicarbonate, saleratus, potash, sodium trichloroacetate, tertiary sodium phosphate or soda ash; Described acid-releasing agent is can ionize to produce hydrionic material in solution, it comprises organic acid, inorganic acid, acid salt or strong acid weak base salt, wherein, described organic acid is formic acid, acetic acid, oxalic acid, citric acid, malic acid or trichloroacetic acid, described inorganic acid is hydrochloric acid, sulfuric acid, phosphoric acid or nitric acid, described acid salt is niter cake or sodium dihydrogen phosphate, and described strong acid weak base salt is ammonium sulfate.
5. the fountain solution that shifts of patterns of fabric according to claim 1, it is characterized in that, described anti-solvent pasty materials refers to be dissolved in the mixed liquor of water and organic solvent, and can form polymer substance or the carbohydrate of thick liquid, wherein, described polymer substance is cellulose ether, starch ether, seed glue etherate or glucidtemns, and described carbohydrate is monose or disaccharide or polysaccharide.
6. the fountain solution of patterns of fabric transfer according to claim 1 is characterized in that,
When fabric is cellulose fibre, real silk or wool, when dyestuff was direct dyes, fountain solution was comprised of the component of following percentage by weight: water 20～80%, organic solvent 10～70%, water absorbing agent 5～15%, anti-solvent pasty materials 0.5～20%;
When fabric is cellulose fibre or real silk, when dyestuff was REACTIVE DYES, fountain solution was comprised of the component of following percentage by weight: water 20～80%, and organic solvent 10～70%, water absorbing agent 5～15%, releasing alkaline agent is 1～5%, anti-solvent pasty materials 0.5～20%;
When fabric is real silk, nylon or wool, when dyestuff was ACID DYES or REACTIVE DYES, fountain solution was comprised of the component of following percentage by weight: water 20～80%, organic solvent 10～70%, water absorbing agent 5～15%, acid-releasing agent are 0.5～5%, anti-solvent pasty materials 0.5～20%;
When fabric is acrylic fibers, when dyestuff was cation dyes, fountain solution was comprised of the component of following percentage by weight: water 20～80%, and organic solvent 10～70%, water absorbing agent 3～7%, acid-releasing agent are 1～5%, anti-solvent pasty materials 0.5～20%.
7. the fountain solution of patterns of fabric transfer according to claim 1 is characterized in that,
When fabric is all-cotton fabric, dyestuff is REACTIVE DYES, and when color fixing process was the cold dome fixation, fountain solution was comprised of the component of following percentage by weight: water 20～80%, and organic solvent 10～70%, releasing alkaline agent is 1～5%, anti-solvent pasty materials 0～20%;
When fabric is wool or real silk, dyestuff is REACTIVE DYES or ACID DYES, and when color fixing process was the cold dome fixation, fountain solution was comprised of the component of following percentage by weight: water 20～80%, organic solvent 10～70%, acid-releasing agent are 1～5%, anti-solvent pasty materials 0.5～20%.
8. the fountain solution of patterns of fabric transfer according to claim 1 is characterized in that,
When fabric is cellulose fibre and protein fibre interweaves or during blending, when dyestuff was direct dyes, fountain solution was comprised of the component of following percentage by weight: water 20～80%, organic solvent 10～70%, water absorbing agent 5～15%, anti-solvent pasty materials 0.5～20%;
When fabric is cellulose fibre and protein fibre interweaves or during blending, when dyestuff was REACTIVE DYES, fountain solution was comprised of the component of following percentage by weight: water 20～80%, organic solvent 10～70%, water absorbing agent 5～15%, releasing alkaline agent is 1～5%, anti-solvent pasty materials 0.5～20%.
9. the application of fountain solution in wet transfer printing of patterns of fabric transfer claimed in claim 1.
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| CN106012594A (en) * | 2016-06-24 | 2016-10-12 | 常州旭荣针织印染有限公司 | Wet transfer printing method for milk protein fiber/cotton fiber mixed fabric |
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| CN103276611A (en) * | 2013-06-09 | 2013-09-04 | 东华大学 | Dyeing method adopting activated dye with high fixation rate |
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| CN106012594A (en) * | 2016-06-24 | 2016-10-12 | 常州旭荣针织印染有限公司 | Wet transfer printing method for milk protein fiber/cotton fiber mixed fabric |
| WO2018018800A1 (en) * | 2016-07-26 | 2018-02-01 | 黄庄芳容 | Method for wet transfer printing of polyester fiber/cotton fiber union fabric |
| CN107034700A (en) * | 2016-11-03 | 2017-08-11 | 江苏海云花新材料有限公司 | A kind of dyeing nylon acid-releasing agent and preparation method thereof |
| CN108239887A (en) * | 2016-12-27 | 2018-07-03 | 长胜纺织科技发展(上海)有限公司 | One kind gives liquid pre-treating method to version |
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| CN107083698B (en) * | 2017-04-07 | 2021-05-25 | 常州旭荣针织印染有限公司 | Padding liquid for wet transfer printing of chinlon fabric and its compounding process |
| CN111118717A (en) * | 2019-12-31 | 2020-05-08 | 江苏东源纺织科技实业有限公司 | Production process of natural antibacterial skin-friendly environment-friendly knitted fabric |
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Effective date of registration: 20151113 Address after: 213000 room 196, building 904, city Taoyuan, bell tower area, Changzhou, Jiangsu Patentee after: Liu Jing Address before: 703, room 2, building A, building No. 801, Changzhou research and education port, Changzhou science and Education City, No. 213000 middle Wu Road, Wujin District, Jiangsu, China Patentee before: Changzhou fine Textile Technology Co., Ltd. |
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Effective date of registration: 20191126 Address after: 215222 floor 108, building B, nanshang District, textile market, Baiyang village, Tanqiu West, Shengze Town, Wujiang District, Suzhou City, Jiangsu Province Patentee after: Suzhou meiyoujie Fashion Fabric Co., Ltd Address before: 213000 room 196, building 904, city Taoyuan, bell tower area, Changzhou, Jiangsu Patentee before: Liu Jing |