CN107709479A - Water soluble dyestuffs system is printed black liquid and printing process and the method for printing and dyeing of black liquid is printed using the water soluble dyestuffs system - Google Patents
Water soluble dyestuffs system is printed black liquid and printing process and the method for printing and dyeing of black liquid is printed using the water soluble dyestuffs system Download PDFInfo
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- CN107709479A CN107709479A CN201680034031.6A CN201680034031A CN107709479A CN 107709479 A CN107709479 A CN 107709479A CN 201680034031 A CN201680034031 A CN 201680034031A CN 107709479 A CN107709479 A CN 107709479A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/02—Letterpress printing, e.g. book printing
- B41M1/04—Flexographic printing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/10—Intaglio printing ; Gravure printing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06Q—DECORATING TEXTILES
- D06Q1/00—Decorating textiles
- D06Q1/12—Decorating textiles by transferring a chemical agent or a metallic or non-metallic material in particulate or other form, from a solid temporary carrier to the textile
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Printing Methods (AREA)
- Paper (AREA)
Abstract
The present invention can be used for the water soluble dyestuffs black liquid of intaglio plate or flexographic printing to use, it is problem to provide based on the production efficiency in a manner of the high speed printing by paper or film for medium and the method for printing and dyeing of the fibrous material of excellent quality, a kind of manufacture method of print and dye paper or film of printing and dyeing is provided, by above-mentioned printing and dyeing paper or printing and dyeing film be sealed at fibrous material carry out transfer colour developing the method for printing and dyeing, and the fibrous material printed and dyed by this method, it is described printing and dyeing paper or print and dye film manufacture method have will contain dyestuff, viscosity modifier, auxiliary agent, water Combination organic solvent and water, and (25 DEG C) of its viscosity prints black liquid intaglio printing or flexographic printing in the process of printing and dyeing paper or printing and dyeing film for the water soluble dyestuffs system in specific scope.
Description
Technical field
The present invention relates to suitable intaglio printing or the water soluble dyestuffs system black liquid of flexographic printing.The invention further relates to using above-mentioned
The printing and dyeing paper of water soluble dyestuffs system black liquid, the manufacture method of printing and dyeing film, the printing and dyeing paper manufactured by above-mentioned manufacture method or printing and dyeing film,
Use the method for printing and dyeing and the fibrous material that is manufactured by the above-mentioned method of printing and dyeing of above-mentioned printing and dyeing paper or film of printing and dyeing.
Background technology
The 0002nd section such as patent document 1 (Japanese Unexamined Patent Publication 2001-30611 publications) is recorded, in conventional intaglio printing
Typically use organic solvent type (oiliness) black liquid.The black liquid is organic solvent type, therefore is noted the work situation of printery
Safety and sanitation problem and the environmental problems such as problem, the problem of upper of taking precautions against natural calamities, global environmental problems.Recently, oiliness black liquid is being wiped
The problem of cholangiocarcinoma occurs in operation.
In addition, in the case of present intaglio printing, time loss, toning untill existing up to printing are damaged
Lose, caused by the increase of residual ink amount the problem of influence to cost, be also required to improve from the position for saving resource.It is special
Be not nearest market trends for multi items, it is small quantities of quantify, short delivery receives the phase, therefore Cost Problems become more and more harsh, and
Environmental problem, food hygiene problem attract attention as larger social concern.But if using organic solvent type black liquid, deposit
Be difficult to tackle these social demands the problem of.
In face of it is above-mentioned the problem of solution, the exploitation of aqueous ink is carried out instead of organic solvent type black liquid, special
Sharp document 2 (Japanese Unexamined Patent Publication 11-172168 publications), patent document 3 (No. 4151801 publications of Japanese Patent No.), patent text
Offer disclosed in 4 (Japanese Unexamined Patent Publication 2009-256659 publications), patent document 5 (Japanese Unexamined Patent Application Publication 2005-518459 publications) etc..
But these are the aqueous inks with the film beyond fibrous material, wrapping paper, paper shell etc. for the pigment system of object.Pigment system ink
Required adhesive of the fixation of pigment etc. can be coordinated in liquid, the water soluble dyestuffs system printer's ink used in the printing with fibrous material etc.
The physical property of liquid requirement is also different, it is impossible to which above-mentioned pigment system black liquid is used for the print of fibrous material etc. by the method for the present invention
Dye.
As the method that pattern firmly, is subtly depicted in fibrous material with dyestuff, it is known to use high viscosity color paste
(Japanese：Color is pasted) screen printing, roll marks dye, rotary screen printing and dyeing and transfer methods of printing and dyeing etc. using these printing skill and technique,
So as to industrially implement.But these Plate making printing modes, it is noted following problems；Exist in chromatic number and restrict；Have
Shortcoming prints the big situation of the repeatability of processing, the risk of tractability；Make a plate costly and get a profit and deteriorate；Produce substantial amounts of row
Water l oad and environmental pollution etc. be present.
As the new method of printing and dyeing for solving these problem points, image procossing is carried out with computer, uses water-based dyestuff black liquid
A large amount of concerns have been attracted without Plate making printing (direct method) with ink-jetting style printing.Water soluble dyestuffs system prints black liquid as the ink-jet
The black liquid of printer is known, and is widely used.
But black liquid is printed on the water soluble dyestuffs system as ink-jet printer black liquid, it is as intaglio printing or soft
Version printing black liquid can not use for unsuitable physical property.In ink-jet printer and intaglio printing or flexographic printing, black liquid
Adding method is different, and the physical property of black liquid requirement is also differed widely, thus ink-jet printer black liquid and intaglio printing or soft version
The black liquid of printing does not have interchangeability.
It can be seen that being not aware that the water soluble dyestuffs system of suitable intaglio printing or flexographic printing printed black liquid in the past, its it is expected
Exploitation.
In addition, on as with dyestuff by pattern plotter in the transfer of the known dry type of the method for fibrous material or wet type
The method of printing and dyeing, in the past, various problems are indicated for production efficiency and quality, it is expected the fiber of Development and Production efficiency and excellent quality
The method of printing and dyeing of material.
Prior art literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 2001-30611 publications
Patent document 2：Japanese Unexamined Patent Publication 11-172168 publications
Patent document 3：No. 4151801 publications of Japanese Patent No.
Patent document 4：Japanese Unexamined Patent Publication 2009-256659 publications
Patent document 5：Japanese Unexamined Patent Application Publication 2005-518459 publications
The content of the invention
Problems to be solved by the invention
The present invention prints black liquid as problem using the water soluble dyestuffs system for providing suitable intaglio printing or flexographic printing.
The present invention problem also reside in, there is provided it is a kind of print and dye paper or print and dye film manufacture method and pass through above-mentioned manufacture
Method and manufacture (printing) printing and dyeing paper or printing and dyeing film, it is described printing and dyeing paper or print and dye film manufacture method with use above-mentioned water-based dye
Material system printing black liquid, to printing and dyeing with paper, printing and dyeing carry out intaglio printing with film or flexographic printing is characterized, solve use it is organic molten
Various problems during formulation black liquid.
The problem of the present invention also resides in, there is provided：Characterized by using above-mentioned printing and dyeing paper or printing and dyeing film, production efficiency and quality
It is excellent and without the method for printing and dyeing of environmental problem etc.；And the fibrous material printed and dyed by the above-mentioned method of printing and dyeing.
It should be noted that here, printing and dyeing refer respectively to impart the paper (coating of black liquid receiving layer with paper, printing and dyeing with film
With body paper), impart the film film of application (apply) of black liquid receiving layer.In addition, printing and dyeing paper, printing and dyeing film refer respectively to receive in black liquid
The printing and dyeing film of black liquid has been printed in the printing and dyeing that layer has printed black liquid with paper, in black liquid receiving layer.
The means used to solve the problem
The present inventor in order to develop can be used in intaglio printing or flexographic printing and without using organic solvent (be not oil
Property) water soluble dyestuffs system prints black liquid and has made intensive studies, as a result find,
Using containing dyestuff and while water, also containing viscosity modifier, auxiliary agent, water Combination organic solvent, and it is viscous
Degree is in the water soluble dyestuffs for being far above and being printed as the water soluble dyestuffs system of ink-jet printer black liquid in the range of the situation of black liquid
System's printing black liquid, thus, it is possible to fibrous material is carried out production efficiency and excellent quality, without environmental problem etc., with paper or film
For the printing and dyeing based on intaglio printing, flexographic printing mode of medium, and then complete the invention (water comprising composition as shown below
Property dyestuff system print black liquid preparation method and using its fibrous material the method for printing and dyeing).
That is, the present invention prints black liquid (technical scheme 1) for a kind of water soluble dyestuffs system, it is characterised in that
Containing dyestuff, viscosity modifier, auxiliary agent, water Combination organic solvent and water, (25 DEG C) of its viscosity be 30mPas with
Upper and 800mPas.More preferably 50~500mPas.
As above-mentioned dyestuff, can enumerate selected from for example water miscible reactive dye, acid dyes, metallic complex salt type dye,
One kind or two or more dyestuff (technical scheme 2) in the aqueous dispersions of direct dyes, the dye of positive ion and disperse dyes.
As above-mentioned viscosity modifier, can enumerate：Comprising selected from such as water-soluble poval and its derivative, water solubility
Polyacrylate and its derivative, soluble polyurethane and its derivative, water-soluble polyethylene oxide and its derivative, water solubility
Polyamide and its derivative, the water miscible copolymer (water-soluble poly styrene acrylic) of styrene and acrylic acid and its derivative
It is thing, water-soluble polyester and its derivative, polyethylene glycol, glycerine, polyvinylpyrrolidone, natural adhesive paste, cellulose derivative, more
One kind or two or more material (technical scheme 3) in carbohydrate, seaweeds, animality thickener.
As above-mentioned auxiliary agent, can enumerate：Comprising selected from such as dyestuff lytic agent, dispersant, surfactant, NMF,
In pH adjusting agent, dense stain, preservative, mould inhibitor, degasser, defoamer, redox preventing agent and metal ion end-capping reagent
One kind or two or more material (technical scheme 4).
As above-mentioned water Combination organic solvent, can enumerate：Contain the single methanol class selected from such as carbon number 1~5, carbon number 2~5
Aklylene glycol, the ether of aklylene glycol of carbon number 2~5, carbon number 2~5 aklylene glycol ester, single oxygen of carbon number 2~5
Aklylene glycol, the polyether polyols of carbon number 5~10, glycerine, thiodiglycol, monoalkanolamine, dialkanol amine and three alkanols
One kind or two or more material (technical scheme 5) in amine.
It is preferred that the content of above-mentioned water Combination organic solvent is the total of above-mentioned water Combination organic solvent and above-mentioned water
More than the 10 mass % and below 60 mass % (technical scheme 6) of content.
The present invention also provides the manufacture method (technical scheme 7) of a kind of printing and dyeing paper or film of printing and dyeing and by the printing and dyeing paper
Or printing and dyeing film manufacture method and the printing and dyeing paper that makes or printing and dyeing film (technical scheme 7,8), the manufacture method are characterised by,
With printed by above-mentioned water soluble dyestuffs system into black liquid intaglio printing or flexographic printing in the process of printing and dyeing paper or printing and dyeing film.
The present inventor alsos for exploitation and prints black liquid using above-mentioned water soluble dyestuffs system, printed with applying intaglio printing or soft version
The paper or film (printing and dyeing paper or film of printing and dyeing) of brush are the method for printing and dyeing of the fibrous material of medium, i.e. production efficiency and excellent quality and ring
The repressed method of printing and dyeing of border problem, and the result furtherd investigate is found,
Black liquid is printed using above-mentioned water soluble dyestuffs system, intaglio printing or flexographic printing are carried out with film with paper or printing and dyeing to printing and dyeing
And printing and dyeing paper or printing and dyeing film are made, by using the printing and dyeing paper or printing and dyeing film, production efficiency can be carried out and the quality of product is excellent
Different and small environmental problem printing and dyeing, and then complete the invention (method of printing and dyeing) for including composition as shown below.
That is, a kind of method of printing and dyeing (technical scheme 9), it is characterised in that including：
Printed by above-mentioned water soluble dyestuffs system into black liquid intaglio printing or flexographic printing to make in printing and dyeing paper or printing and dyeing film
The process for making printing and dyeing paper or film of printing and dyeing；With
Above-mentioned printing and dyeing paper or printing and dyeing film are sealed at fibrous material, carry out the process for transferring colour developing.
As above-mentioned printing and dyeing paper or printing and dyeing film, can preferably enumerate premium-quality paper, mean quality paper, recycled writing paper,
The print of black liquid receiving layer is formd on brown paper, glassine paper, coating paper, polyester film, polypropylene screen, polyethylene film or PA membrane
Film (technical scheme 10) is used in dye paper or printing and dyeing.
The present invention also provides the fibrous material (technical scheme 11) manufactured by the above-mentioned method of printing and dyeing.
Invention effect
Black liquid is printed by using the water soluble dyestuffs system of the present invention, paper, film (print and dye with paper, print and dye with film) can be carried out
Production efficiency, the intaglio printing of excellent quality, flexographic printing.Pass through the present invention, there is provided instead of conventional organic solvent type intaglio plate
Printing black liquid or flexographic printing black liquid, be adapted to the water soluble dyestuffs system of intaglio printing or flexographic printing to print black liquid.Using conventional
The intaglio printing black liquid of organic solvent type, in the case of flexographic printing black liquid, be noted safety and sanitation problem and environment asked
Topic, the water soluble dyestuffs system print black liquid without using water-insoluble organic solvents (not being oiliness), thus do not occur in the past like that
Safety and sanitation problem, environmental problem.
In addition, by the method for printing and dyeing of the present invention, i.e., black liquid is printed by using the water soluble dyestuffs system of the present invention and make printing and dyeing
Paper, printing and dyeing film, using the printing and dyeing paper, printing and dyeing film dyeing fiber materials, so as to turn into the environment of problem in the conventional method of printing and dyeing
Problem, production efficiency problem etc. are improved.That is, the present invention solves the environmental problem, quality that problem is big in the conventional method of printing and dyeing
Problem, the equipment investment problem of great number, production efficiency problem etc., there is provided excellent economy and it is ecological on the basis of, energy
Enough repeatabilities provide the method for printing and dyeing using Whole fiber material as object of the product of excellent quality well.
Meaning of the present invention in particular, in that, develop the aqueous intaglio printing black liquid containing dyestuff or aqueous flexible plate printing use
Black liquid, as a result, applying flexibly existing printing machine, the production system of printing and the printing and dyeing of excellent in efficiency, development environment can be constructed
Adaptability while economy and quality the effect also excellent method of printing and dyeing, pass through the present invention, there is provided to the Gao Pin of printed fibre product
Matter, the big contributive new method of printing and dyeing of a large amount of productions.
Embodiment
Hereinafter, the mode for implementing the present invention is further illustrated, but the present invention is not limited by following concrete mode.
1. water soluble dyestuffs system prints black liquid
The water soluble dyestuffs system of the present invention prints black liquid with dyestuff, viscosity modifier, auxiliary agent, water Combination organic solvent and water
For neccessary composition.Invention is not being damaged including situation about being only made up of above-mentioned neccessary composition and together with above-mentioned neccessary composition
Purport in the range of containing other compositions in the case of either case.
(1) dyestuff
The water soluble dyestuffs system of the present invention prints black liquid and is characterised by, as and pigment uses dyestuff.As used
Dyestuff, such as reactive dye, acid dyes, metallic complex salt type dye, direct dyes, the dye of positive ion and scattered dye can be enumerated
The aqueous dispersions of material, preferably use one kind or two or more in these.The content root of dyestuff (pigment substance) in black liquid
Change, be not particularly limited according to the deep or light of desired color pattern, the mass % of but preferably generally 1 mass %~20.
(2) viscosity modifier
Water soluble dyestuffs system as the present invention prints the viscosity modifier used in black liquid, can enumerate water-soluble poval
And its derivative, water-soluble polyacrylate and its derivative, soluble polyurethane and its derivative, water-soluble polyethylene oxide
And its water miscible copolymer (the water-soluble polyphenyl second of derivative, water soluble polyamide and its derivative, styrene and acrylic acid
Allyl olefin(e) acid) and its derivative, water-soluble polyester and its derivative, polyethylene glycol, glycerine, polyvinylpyrrolidone, natural gum
Paste, cellulose derivative, polysaccharide, seaweeds, animality thickener etc., one kind or two or more in these are engaged to this
Printed in black liquid by the water soluble dyestuffs system of invention.
Here, water-soluble poval and its derivative are meant, including the homopolymer of water miscible polyvinyl alcohol, with
And make other monomers and material of the polyvinyl alcohol after keeping being copolymerized in water miscible scope, the part importing in polyvinyl alcohol
The modified body of the polyvinyl alcohol such as the material of carboxyl, carbonyl, alkyl etc..Specifically, the modified body as polyvinyl alcohol, for example,
It can enumerate：It is total to the binary of starch or acrylic acid etc. and polyvinyl alcohol graft copolymerized material, polyvinyl alcohol and acrylic acid, acrylate
Polymers.On water-soluble polyacrylate and its derivative, soluble polyurethane and its derivative, water-soluble polyethylene oxide and
Its derivative, water soluble polyamide and its derivative, water-soluble poly styrene acrylic and its derivative, water-soluble polyester and its
Derivative, and the same meaning.
Cellulose derivative refers to, the modified body of cellulose and be water miscible material.For example, carboxymethyl cellulose can be enumerated
Plain (CMC), methylcellulose, hydroxy alkyl cellulose etc..
As the commercially available product that viscosity modifier is can act as in the present invention, can enumerate：(this loose grease is public for Marpolose classes
Department's system：Water-soluble cellulose ether), CMC classes (Daicel FineChem company systems), (Japanese Cao reaches company system to HPC classes：Hydroxypropyl
Cellulose), POVAL classes (Japan Vam＆Povel Co., Ltd systems：Modified polyvinylalcohol), GOHSENOL classes (Japanese synthesisization
Learn company system：Polyvinyl alcohol), METOLOSE classes (chemical company of SHIN-ETSU HANTOTAI system：Water-soluble cellulose ether) etc. be used as concrete example.
The use level of viscosity modifier is that the viscosity (25 DEG C) that printed to by water soluble dyestuffs system black liquid is adjusted to 30~800mPas
Scope amount.
In foregoing illustrative viscosity modifier, cellulose derivative and polyvinyl alcohol derivative are keeping the stability of viscosity
On bring especially good result, thus preferably.
(3) auxiliary agent
Water soluble dyestuffs system as the present invention prints the auxiliary agent used in black liquid, for example, can enumerate dyestuff lytic agent, disperse
Agent, surfactant, NMF, pH adjusting agent, dense stain, preservative, mould inhibitor, degasser, defoamer, redox prevent
Agent and metal ion end-capping reagent, it is one kind or two or more in these by coordinating, good water soluble dyestuffs system can be obtained
Print black liquid.
As dyestuff lytic agent, for example, can enumerate：Thiodiglycol, epsilon-caprolactams, butyl carbitol, 2-Pyrrolidone,
1-METHYLPYRROLIDONE etc..As surfactant, can enumerate：Nonionic surfactant, for example, Olfine PD-002W,
E1004, E1010, E1020, PD-003, PD-201, Surfynol 420,440,465,485, Silface (Xin chemical companies
System) etc. surface tension modifier, defoamer, dispersant.It can be enumerated using urea as hydrotropic agent of representative etc. as NMF.
As redox preventing agent, for example, the such reduction preventing agent of nitrobenzene sodium sulfonate can be enumerated.Blocked as metal ion
Agent, for example, EDTA can be enumerated.
These auxiliary agents coordinate 0.5~30 mass % in the water soluble dyestuffs system of the present invention prints black liquid.The auxiliary agent of cooperation
Physical property of the species according to needed for the species of dyestuff, the physical property and black liquid of i.e. each dyestuff and change.For example, do not filled in dissolubility
In the case of the dyestuff divided, using dyestuff lytic agent, but dye can be omitted in the case of the good dyestuff of dissolubility, disperse dyes
Expect the use of lytic agent.
(4) water Combination organic solvent
The water soluble dyestuffs system of the present invention prints the water Combination organic solvent used in black liquid and referred to, can be with water with appropriate
The mixed uniformly organic solvent of concentration range.As water Combination organic solvent, single methanol class, the carbon number of carbon number 1~5 can be enumerated
2~5 aklylene glycol, the ether of the aklylene glycol of carbon number 2~5, the ester of aklylene glycol of carbon number 2~5, carbon number 2~5
Single oxyalkylene glycol, the polyether polyols of carbon number 5~10, glycerine, thiodiglycol, monoalkanolamine, dialkanol amine and three
Alkanolamine etc., printed in black liquid by the one kind or two or more water soluble dyestuffs system for being comprised in the present invention in these.
As the single methanol class of carbon number 1~5, for example, methanol, ethanol, isopropanol, butanol, amylalcohol can be enumerated.As carbon number 2
~5 aklylene glycol, for example, ethylene glycol, propane diols, butanediol etc. can be enumerated.Single oxyalkylene two as carbon number 2~5
Alcohol, for example, diethylene glycol class can be enumerated.As the polyether polyols of carbon number 5~10, for example, polyethylene glycol can be enumerated.
In above-mentioned illustration, the single methanol class of carbon number 1~5 is keeping the physical property of black liquid, printed in adaptability particularly preferably.
The content of water Combination organic solvent is preferably 10 matter of total content of water Combination organic solvent and water
Measure more than % and below 60 mass %.By the way that the content of water Combination organic solvent is set in the range of this, so as to obtain
It is adapted to the water-based printing black liquid of purpose.Especially by the alcohols using carbon number 1~5, and containing water Combination organic solvent
Amount is set in above-mentioned scope, so as to obtain preferable effect.
(5) water soluble dyestuffs system prints the viscosity of black liquid
The water soluble dyestuffs system of the present invention print black liquid and is characterised by, (25 DEG C) of its viscosity for more than 30mPas and
Below 800mPas.By using the black liquid for being adjusted to 30~800mPas as viscosity, can obtain being adapted to intaglio printing to use
Or the aqueous ink of flexographic printing.When viscosity (25 DEG C) is less than 30mPas, printing image easily produces the uneven (Japanese of flowing：
Flow れ system ラ).On the other hand, if more than 800mPas, print and the uneven (Japanese of the style of calligraphy characterized by hollow strokes is easily produced in image：Power ス レ system
ラ)。
(6) water soluble dyestuffs system prints the making of black liquid
The water soluble dyestuffs system of the present invention, which prints black liquid, to be mixed above-mentioned neccessary composition etc. and dissolve and black liquid
Afterwards, it is filtered to remove foreign matter and obtains.The filter progress is simultaneously not present：Carried out as inkjet, ink liquid in clogging countermeasure
Below the μ of use 1 film filter carry out secondary filter needs, with paper filter or silk screen filter.Therefore, operate
Extremely simple productivity ratio is high.
(7) printing of black liquid is printed based on water soluble dyestuffs system
Black liquid is printed by using the water soluble dyestuffs system of the present invention, to printing and dyeing with paper or printing and dyeing with film carry out intaglio printing or
Flexographic printing, excellent printed article (printing and dyeing paper or printing and dyeing film through printing) can be obtained.
2. the method for printing and dyeing
The present invention the method for printing and dyeing be characterised by, including：
Above-mentioned water soluble dyestuffs system of the invention is printed into black liquid intaglio printing or flexographic printing in printing and dyeing paper or printing and dyeing
With film, printing and dyeing paper or print and dye film production process；With
The printing and dyeing paper obtained in above-mentioned production process or printing and dyeing film are sealed at paper or fibrous material, by printed ink
The transfer colour developing process of liquid transfer.
And by the method for printing and dyeing, can gallantly it be printed and dyed with high production rate.
(1) production process of printing and dyeing paper or film of printing and dyeing
The printing and dyeing paper or printing and dyeing film used in making as printing and dyeing paper or film of printing and dyeing, for example, can enumerate：It is Japanese special
The dry transfer printing and dyeing paper of the paper printing and dyeing of the records such as profit the 4778124th records such as paper, Japanese Patent No. 5054673,
Known wet type transfer printing and dyeing paper, sublimation transfer paper, the ready-made paper with black liquid receiving layer form black liquid receiving
The film of layer.Printing and dyeing paper, printing and dyeing film can be by using following methods in painting application body paper as shown below (also comprising film)
It is upper to form black liquid receiving layer and obtain.
(2) apply application body paper (also comprising film)
For printing and dyeing for the painting application body paper used in the making of paper, printing and dyeing with film, as long as forming ink
In the working procedure of coating of liquid receiving layer, do not rupture or wrinkle under the moisture state assigned by paste liquid, i.e., being assigned in paste liquid turns into original
Paper with intensity etc., then can use, be not particularly limited under the moisture state of cause.For example, as application body paper is applied, can arrange
Lift the processing such as cheap pulp based paper, premium-quality paper, mean quality paper, brown paper, recycled writing paper or coating paper typically used
Paper.The absorption of water of paper (can be tested suddenly：Cobb test) it is preferably less high.Sometimes processing release paper can also be used.In addition, it can also arrange
Lift the films such as polyester film, polypropylene screen, polyethylene film, polylactic acid membrane or PA membrane.
It is preferred that use Substance 10g~150g/m2, more preferably 30~120g/m2, with kraft pulp or pouncing paper
The paper pulp such as slurry or recyclable papers are that raw material has carried out the pulp based paper of copy paper, premium-quality paper, recycled writing paper, coating paper etc..From operation
Property is set out 0.01~0.5mm of preferred thickness or so paper.If enumerating concrete example, the advanced matter of Nippon Paper company system can be enumerated
Measure paper, pure white, bleaching or non-BK bleached kraft, silver-colored bamboo, Yin Ling, silver, one-side finish (Japanese：Pian Yan) brown paper, glassine paper,
The various coating papers of three Dao Zhi paper companies, the premium-quality paper of paper company of Mitsubishi, pearl coating paper, wave matt paper
(Japanese：スイングマツト), the various coating papers such as PVC ス タ グ ロ ス paper, but these only one.
(3) black liquid receiving layer
On application body paper is applied the black liquid receiving layer that is coated be coordinated water-soluble synthesis be resin, it is natural be paste and each
The layer (multicomponent system paste layer) of the mixing paste of kind auxiliary agent.For black liquid receiving layer, it is expected with the intermiscibility of dyestuff black liquid it is good,
Black liquid absorbability is good, equably absorbs the dyeing (Japanese for keeping dyestuff black liquid, not hindering dyestuff：Stained with) and promotion is dyed, is outer
Black liquid drying property in sight is good, the tractability (not infiltrating) of color pattern is also excellent etc..In addition, also it is desirable to by pressurization and
Become with the temporary joint power of fabric in washing strong, after fixing of dye processing and easily come off.As long as it is with water solubility synthesis
Resin or/and it is natural be paste for principal component and the mixing paste for the black liquid receiving layer for meeting above-mentioned condition can be formed, then
The purpose of the present invention can be reached, it is thus possible to use.
In order to improve various physical property or dyeing promoter as dyestuff in mixing paste, various auxiliary agents can be added.Make
For the auxiliary agent, can enumerate：Anion system or nonionic surfactants, such as Olfine systems, with above-mentioned black liquid auxiliary agent one
Identical surface tension modifier, penetrant (0.1~5%) described in, in order to improve paste of the black liquid receiving layer to fabric
The moistening NMF of viscous force and dyeing capacity, the polyalcohols such as polyethylene glycol, glycerine, thiodiglycol, diethylene glycol, urine
Element, thiocarbamide, dicyandiamide etc. (1~15%), in order to increase coating when reaction control acrylic acid series synthesis paste (0~3%), anti-
Soda ash, sodium acid carbonate, silicon in the case of rotten agent, mould inhibitor, defoamer, degasser, reduction preventing agent, reactive dye black liquid use
The alkaline agents such as sour sodium, sodium acetate (1~15%), disperse dyes use or acid dyes black liquid use in the case of ammonium sulfate, tartaric acid,
PH adjusting agent (0.1~3%) of sodium dihydrogen phosphate etc etc., can obtain preferable result if these are coordinated.Need to illustrate
, in () in the illustration, the scope of the preferred use level in liquid is pasted in the mixing for representing each auxiliary agent with quality %.
By the table that above-mentioned mixing paste is imparted to above-mentioned painting application body paper (or applying application film) with applying device
Face, and drying is allowed to, so as to form black liquid receiving layer.As the applying device of mixing paste liquid, comma coater, intaglio plate can be enumerated
Coating machine, reverse coating machine, Kohler coater, flush coater, kiss painting machine, set gravure, electric arc intaglio plate, dipping device etc..It is expected
Coating amount it is different according to purpose, but generally 1~60g/m2.It should be noted that in the case of sublimation transfer paper also
Common commercially available paper can directly be used.
The coated surfaces of the paper or film that form black liquid receiving layer are preferably smoothed.
Smoothing processing be in order to carry out the printing of no spot and it is preferred that.Smoothing processing can make by using 2 roller strong pressurizings
The concavo-convex smooth method on surface is carried out.
(4) making of printing and dyeing paper or film of printing and dyeing
To applying application body paper or applying the printing and dyeing paper or printing and dyeing film that form black liquid receiving layer on application film and make, or
To the commercially available ready-made paper with black liquid receiving layer, with intaglio press or flexible printing machine intaglio printing or flexographic printing this hair
Bright water soluble dyestuffs system prints black liquid, is dried, and can make printing and dyeing paper or printing and dyeing film.
(5) print and dye
After making printing and dyeing paper or printing and dyeing film, make printing and dyeing paper or film of printing and dyeing, the fibrous material, such as with the object as printing and dyeing
Fabric, knitting overlap, and are crimped (pressurization and/or heating).In the case of the paper method of printing and dyeing, it be able to will be printed and dyed by crimping
Paper or printing and dyeing film, which attach, to be implemented decatize etc. in the state of fabric and thus carries out fixing of dye processing, makes dyeing in knitting
Thing.In the case of dry transfer method or wet type transfer printing, after can crimping and black liquid receiving layer entirely being transferred into fabric, it will print
Fixing of dye processing is carried out after contaminating paper or printing and dyeing film stripping, makes dyeing in fabric.In the case of sublimation transfer method, only need
Heated 30 seconds~10 minutes with 160~220 DEG C.
For fixing process, the rigid condition used in common direct printing method can be used directly.For example,
In 1 phase steam fixation of reactive dye, 100~105 DEG C, the individual composition of 5~20 minutes can be applied, in alkali free black liquid
In the case of receiving layer, 2 phase methods (such as freezing off color method) can be applied.For acid dyes, carry out 100~105 DEG C, 10~
The individual composition of 30 minutes.In the case of disperse dyes, 160~220 DEG C of progress, the HT decatizes of 1~20 minute or xeothermic place
Reason.After the decatize in the case that paper is printed and dyed, from the fabric (Japanese of fabric：The dried rhizome of rehmannia) peeling paper when, due to be to confer to moisture,
The state of moisture thus be easily peeled off paper.
After fixing of dye processing, (wash, soap, wash in the cleaning condition of conventional method.In the case of disperse dyes
Washing, reduction cleaning, washing) under handle and complete, be thus attached to the water-soluble resin of fabric on a small quantity, paste is washed with water removing,
Good and fine, the dense dyeing material (fabric or print product) of the texture of fiber can be obtained.Disperse dyes (S or SE types
Non- subliming type disperse dyes and E types subliming type disperse dyes) in the case of (in the case of polyester etc.) even if omitting clear
The dyeing material that texture is good and fine, dense can also be obtained by washing process.
In the case of the present invention, paste, the usage amount of black liquid are few, and are handled by the fixing of dye after fabric, quilt
Peel off and adhere to the major part of a small amount of unlocked dyestuff and paste on the paper removed, on fabric it is basic without attachment excess dye,
Paste, thus drainage load during fabric cleaning significantly reduces compared with known method.Printed using the dry transfer of processing release paper
In the case of dye, wet type transfer printing and dyeing and direct method, black liquid receiving layer (paste and black liquid) is all shifted or is endowed to fabric,
Therefore drainage load caused by loose excess dye and paste is big.
As the fabric (fibrous material) used in the present invention, for example, can enumerate：Cotton, fiber crops, Lyocell, artificial silk, second
The protein series fiber such as the cellulose fibre such as acid esters material, thin,tough silk, wool material, nylon, vinylon, polyester, polyacrylic
The independent of yarn fabric, braid, non-woven fabrics Deng composite fibre materials etc., blending, mixed fine or blending product.It can also be compound system
Fiber.
As needed, fabric can promote effective medicament etc. with the colored zone to dyestuff come the medicament that influences or to dyeing
Pre-treatment is carried out, or is used with the water containing penetrant, wetting agent etc. or after only being humidified with water.The feelings of the paper method of printing and dyeing
Under condition, in crimping process, if being humidified in the way of more than the official regain of fiber (cotton is about 8%), (additional moisture is 5
~20%) then colour rendering further improves.But the reason for more than 30% superfluous humidification turns into infiltration sometimes, and can not
Carry out the printing and dyeing of beautiful decorative pattern apperance.
Embodiment
Hereinafter, the present invention is further described by embodiment, but the scope of the present invention is not limited by these embodiments.
It should be noted that in embodiment, " part " refers to mass parts, and " % " refers to quality %.
Embodiment 1
1. water soluble dyestuffs system prints the manufacture of black liquid (intaglio printing black liquid)
As viscosity modifier, carboxymethyl cellulose (Daicel company systems are used：Production code member 1150) and polyvinyl alcohol
(synthesis chemical company of Japan system：GOHSENOL GL-05),
As auxiliary agent, degasser (HOKKO CHEMICALS Co., Ltd company systems are used：MAC-100S) and repel (day
Text：は じ I) preventing agent (helps wild company system：1004),
As water Combination organic solvent, using isopropanol (hereinafter referred to as " IPA "),
As dyestuff, the 226 former powder of C.I.Reactive Red of reactive dye is used.
By 75 parts of 225 parts of carboxymethyl cellulose, 225 parts of polyvinyl alcohol, 75 parts of degasser, repulsion preventing agent addition purified waters
Mixed in 11500 parts and 5000 parts of IPA, obtain the transparent paste of uniform colorless.To total 17100 parts above-mentioned paste
In, add 226 former 1300 parts of powder of C.I.Reactive Red and be stirred mixing, dissolve.After dissolving, carried out by 150 mesh yarns
Filtering, plastic tank is contained in by filtrate.Into total 18400 parts of the filtrate so obtained, add 30%IPA water and by viscosity
210mPas is adjusted to, water soluble dyestuffs system is obtained and prints black liquid (intaglio printing black liquid).
2. the making of printing and dyeing paper
By the 20% water-soluble polyvinyl alcohol resin aqueous solution (Japan Vam＆Povel Co., Ltd systems：POVAL AP-
17) 20 parts, 60% water-soluble propenoic-acids resin (DIC company systems：VONCOAT S-5) 10 parts, 25% water-soluble polyester system tree
Fat (mutual induction chemical company system：PLUS COAT Z-730) 80 parts, 20%PIOSTARCH LT (Dian chemical companies systems：Etherificate is formed sediment
Powder) 50 parts, ENBATEX (Japaneses：エ Application バ テ Star Network ス) D-23 (alumina silicate derivatives：Common prosperity chemical company system) 5 parts,
SORBITOZE C-5 (producing starch：AVEBE company systems) 5 parts, 10 parts of urea, 5 parts of dicyandiamide, NS acid sodium (reduction preventing agent：
It is bright into chemical company's system) 5 parts, 5 parts of thiocarbamide, 3 parts of degasser, 20 parts of soda ash, the mixture for repelling 50 parts of 3 parts of preventing agent and water
It is sufficiently stirred with high speed decentralized mixer (about 5000r.p.m.), makes highly viscous paste (mixing paste liquid).The mixing is pasted
Being coated on paper, (Nippon Paper company system, BK bleached kraft, paper are fixed using coating machine (Hengshan Mountain makes made comma coater) for liquid
Measure 75g/m2, thickness 0.15mm) after, be dried, form black liquid receiving layer and bonding layer on the surface of paper and obtain coating paper.
The coating amount (dry weight) of mixing paste liquid is 20g/m2.The coating paper is applied with 2 rollers of metal system and vulcanie
30kg/em2Pressure be smoothed and obtain the printing and dyeing paper of reactive dye.
3. the making (printing process) for paper of printing and dyeing
The printing and dyeing that printed to by above-mentioned water soluble dyestuffs system black liquid and above-mentioned reactive dye are arranged at intaglio printing with paper
Testing machine (sell by Kurabo Techno System companies：GP-10) print and dry with the speed of 15m/ minutes, printed and dyed
Paper.
4. dyeing process
Using the press-connection machine being made up of heating metallic roll and vulcanie roller, make resulting printing and dyeing paper and cotton broadcloth by
It is closely sealed according to the mode of cotton contacting metal roller side, paper contact rubber rollers side, heating, pressurization (200 DEG C, 35kg/em2, 8m/ point
Clock), printing and dyeing paper is attached at cotton broadcloth.Then, to attached printing and dyeing paper in the state of cotton broadcloth carry out 100 DEG C, 10
Minute, HT steam treatments.Thereafter, after paper is peeled off, washed, soaped by conventional method, being washed, being dried.So obtain
Product (dyeing cloth) be that fine and smooth design is fine, firmly, densely dye, show the dyeing cloth of the texture of softness.
Embodiment 2
Instead of the carboxymethyl cellulose in embodiment 1 and GOHSENOL GL-05, METOLOSE 65SH400 are used
(100 parts, the water-soluble methyl cellulose of chemical company of SHIN-ETSU HANTOTAI) and METOLOSE 65SH4000 (50 parts, SHIN-ETSU HANTOTAI's chemistry public affairs
Take charge of the water-soluble methyl cellulose of system) and POVAL AP-17 (250 parts, Japan Vam＆Povel Co., Ltd company systems
Carboxy-modified polyvinyl alcohol), the viscosity that printed to by water soluble dyestuffs system black liquid is adjusted to 190mPas, same with embodiment 1 in addition
Handle, result is to obtain the dyeing cloth of the soft texture of designing for exquisiteness display that is fine, firm, densely dyeing sample.
Embodiment 3
1. water soluble dyestuffs system prints the manufacture of black liquid
As dyestuff, instead of 226 former powder of C.I.Reactive Red, the C.I.Acid Red 257 of acid dyes are used
Former 1300 parts of powder, in addition, water soluble dyestuffs system is made similarly to Example 1 and prints black liquid (acid black liquid).
2. the making of printing and dyeing paper
By water-soluble polyvinyl alcohol resin (Japan Vam＆Povel Co., Ltd company systems：POVAL AP-17)20
Part, 25% water-soluble polyester system resin (mutual induction chemical company system：PLUSCOAT Z-730) 75 parts, PENNON JE66 (day shallow lakeizations
Learn company system：Etherification starch) 35 parts, 10 parts of urea, 3 parts of dicyandiamide, 20 parts of thiocarbamide, 5 parts of degasser, repel 5 parts of preventing agent, sulphur
The mixture of 120 parts of 10 parts of sour ammonium and water is sufficiently stirred with high speed decentralized mixer, makes highly viscous paste (mixing paste liquid).
Mixing paste liquid is coated on paper (Nippon Paper company system, advanced matter using coating machine (Hengshan Mountain makes made comma coater)
Measure paper, Substance 80g/m2) after, it is dried, forms black liquid receiving layer and bonding layer on the surface of paper and obtain coating paper.
The coating amount (dry weight) of mixing paste liquid is 22g/m2.Further it is smoothed to obtain acidity similarly to Example 1
The printing and dyeing paper of dyestuff.
3. the making (printing process) for paper of printing and dyeing
Above-mentioned water soluble dyestuffs system is printed into black liquid (acid black liquid) and the printing and dyeing of above-mentioned acid dyes are set with paper
Print and dry with the speed of 20m/ minutes in intaglio printing testing machine (GP-10), obtain paper of printing and dyeing.
4. dyeing process
Make resulting printing and dyeing paper closely sealed using press-connection machine by maneuver similarly to Example 1 with Nylon Taffeta, carry out
Heating, pressurization (170 DEG C, 35kg/cm2, 5m/ minutes), will printing and dyeing paper be attached at nylon fabric.Then the shape of printing and dyeing paper is being attached
Under state to nylon fabric carry out 100 DEG C 30 minutes, HT steam treatments.Thereafter, after paper is peeled off, water-filling is entered by conventional method
Wash, soap, washing, drying.The dyeing cloth of the nylon so obtained is fine, firmly, densely dye for fine and smooth design, and aobvious
Show the dyeing cloth of the texture of softness.
Embodiment 4
1. water soluble dyestuffs system prints the manufacture of black liquid (disperse dyes black liquid)
As dyestuff, use：By using a diameter of 0.3mm zirconium pearl in the way of average grain diameter turns into 0.5 μm
Ball mill micronized obtained by non-subliming type disperse dyes C.I.Disperse Blue60.With the disperse dyes 5%, second two
Alcohol 5%, nonionic system dispersant 5%, anion system dispersant 5% and the regulation of the identical viscosity with being used in embodiment 2
Agent 2.4% and the composition of ion exchange water containing IPA 77.6%, in the way of viscosity turns into 250mPas, adjust water soluble dyestuffs system
Print black liquid (disperse dyes black liquid).
2. the making for paper of printing and dyeing
, will be above-mentioned obtained from saving PLUSCOAT Z-730 from embodiment 3, similarly operating afterwards on printing and dyeing paper
Water soluble dyestuffs system print after black liquid (disperse dyes black liquid) is printed by flexible printing machine dry, obtain print and dye paper.
3. dyeing process
By resulting printing and dyeing paper and polyester satin (Japanese：Port リ エ ス テ Le サ テ Application) fabric entered using roll shape press-connection machine
Row heating, pressurization (180 DEG C, 32kg/em2, 5m/ minutes), will printing and dyeing paper be attached at polyester fabric.Then printing and dyeing paper is being attached
In the state of to polyester fabric carry out 180 DEG C 8 minutes, HT steam treatments.Thereafter, after paper is peeled off, entered by conventional method
Water-filling is washed, reduction cleaning, washing, drying.The polyester dyeing cloth so obtained has fine and smooth design, and the texture of fiber is soft,
Various fastnesses are also more than 4 grades.The reduction cleaning liquid of the fabric is water white transparency, and the texture caused by cleaning whether there is also does not become
Change, it was demonstrated that reduction cleaning can be omitted.
Usability in industry
The present invention the method for printing and dyeing be,
For mixing paste liquid (black liquid receiving layer) can be assigned simultaneously by the coating machine paper commercially available to cheap in general or film
The printing and dyeing paper or printing and dyeing film for drying it and obtaining, print black liquid using the water soluble dyestuffs system of the invention developed alone,
Carry out intaglio printing or flexographic printing and make printing and dyeing paper or printing and dyeing film,
The printing and dyeing paper or printing and dyeing film are sealed at the fibrous material of fabric etc., the method for carrying out transferring colour developing,
It was found that with it, the multiple fibers such as cellulose fibre, protein series fiber or synthetic fibers can be carried out
Equalization, tractability and colour rendering be good and economy (particularly high production rate) and ecological excellent printing and dyeing, and then obtains
Practical target and complete to invent.
By the method for printing and dyeing of the present invention, the remarkable dyeing and printing products such as texture, exquisiteness, fastness, colour rendering can be obtained,
Bring reduction, stable supplying, the repeatability raising of processing, the reduction of drainage load, the raising of production efficiency of cost.In this way,
Pass through the present invention, there is provided the ecological and economic method of printing and dyeing.
Claims (11)
1. a kind of water soluble dyestuffs system prints black liquid, it is characterised in that
Containing dyestuff, viscosity modifier, auxiliary agent, water Combination organic solvent and water, viscosity at its 25 DEG C is more than 30mPas
And below 800mPas.
2. water soluble dyestuffs system according to claim 1 prints black liquid, it is characterised in that
The water miscible dyestuff is selected from reactive dye, acid dyes, metallic complex salt type dye, direct dyes, cation dye
One kind or two or more dyestuff in the aqueous dispersions of material and disperse dyes.
3. the water soluble dyestuffs system according to claim 1 or claim 2 prints black liquid, it is characterised in that
The viscosity modifier coordinates selected from water-soluble poval and its derivative, water-soluble polyacrylate and its derivative
Thing, soluble polyurethane and its derivative, water-soluble polyethylene oxide and its derivative, water soluble polyamide and its derivative,
The water miscible copolymer and its derivative of styrene and acrylic acid, water-soluble polyester and its derivative, polyethylene glycol, glycerine,
1 kind or 2 kinds in polyvinylpyrrolidone, natural adhesive paste, cellulose derivative, polysaccharide, seaweeds and animality thickener with
On.
4. the water soluble dyestuffs system according to any one of claim 1 to claim 3 prints black liquid, it is characterised in that
The auxiliary agent is included selected from dyestuff lytic agent, dispersant, surfactant, NMF, pH adjusting agent, dense stain, anti-corrosion
It is one kind or two or more in agent, mould inhibitor, degasser, defoamer, redox preventing agent and metal ion end-capping reagent.
5. the water soluble dyestuffs system according to any one of claim 1 to claim 4 prints black liquid, it is characterised in that
The water Combination organic solvent include selected from the single methanol class of carbon number 1~5, the aklylene glycol of carbon number 2~5, carbon number 2~
The ether of 5 aklylene glycol, the ester of the aklylene glycol of carbon number 2~5, single oxyalkylene glycol, the carbon number 5~10 of carbon number 2~5
Polyether polyols, glycerine, thiodiglycol, monoalkanolamine, one kind or two or more in dialkanol amine and three alkanolamines.
6. the water soluble dyestuffs system according to any one of claim 1 to claim 5 prints black liquid, it is characterised in that
The content of the water Combination organic solvent is the 10 of the water Combination organic solvent and total content of the water
More than quality % and below 60 mass %.
A kind of 7. manufacture method of print and dye paper or film of printing and dyeing, it is characterised in that
With printed by the water soluble dyestuffs system any one of claim 1 to claim 6 into black liquid intaglio printing or soft version
The process for being printed in printing and dyeing paper or printing and dyeing film.
8. a kind of printing and dyeing paper or printing and dyeing film through printing, it is characterised in that
Manufactured by the manufacture method of the printing and dyeing paper described in claim 7 or film of printing and dyeing.
A kind of 9. method of printing and dyeing, it is characterised in that including；
Water soluble dyestuffs system any one of claim 1 to claim 6 is printed into black liquid intaglio printing or flexographic printing
In the process that printing and dyeing paper or printing and dyeing film make printing and dyeing paper or film of printing and dyeing；With
The printing and dyeing paper or printing and dyeing film are sealed at fibrous material, carry out the process for transferring colour developing.
10. the method for printing and dyeing according to claim 9, it is characterised in that
The printing and dyeing are in premium-quality paper, mean quality paper, recycled writing paper, brown paper, glassine paper, coating with paper or printing and dyeing with film
The printing and dyeing of black liquid receiving layer are formd on paper, polyester film, polypropylene screen, polyethylene film or PA membrane with paper or printing and dyeing film.
A kind of 11. fibrous material through printing and dyeing, it is characterised in that
Made by the method for printing and dyeing described in claim 9 or claim 10.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015133092A JP5970588B1 (en) | 2015-06-15 | 2015-06-15 | Aqueous dye-based printing ink, and printing method and printing method using this aqueous dye-based printing ink |
| JP2015-133092 | 2015-06-15 | ||
| PCT/JP2016/067746 WO2016204167A1 (en) | 2015-06-15 | 2016-06-15 | Aqueous dye-based printing ink, and printing method and textile-printing method each using said aqueous dye-based printing ink |
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|---|---|
| CN107709479A true CN107709479A (en) | 2018-02-16 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680034031.6A Pending CN107709479A (en) | 2015-06-15 | 2016-06-15 | Water soluble dyestuffs system is printed black liquid and printing process and the method for printing and dyeing of black liquid is printed using the water soluble dyestuffs system |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5970588B1 (en) |
| KR (1) | KR101764656B1 (en) |
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| WO (1) | WO2016204167A1 (en) |
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- 2016-06-15 KR KR1020167033930A patent/KR101764656B1/en not_active Application Discontinuation
- 2016-06-15 CN CN201680034031.6A patent/CN107709479A/en active Pending
- 2016-06-15 WO PCT/JP2016/067746 patent/WO2016204167A1/en active Application Filing
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI698565B (en) * | 2018-09-10 | 2020-07-11 | 日商三菱製紙股份有限公司 | Transfer paper |
| CN110501499A (en) * | 2019-08-07 | 2019-11-26 | 上海艾瑞德生物科技有限公司 | Effluent reagent strip with indicating area and preparation method thereof |
| CN111607286A (en) * | 2020-05-28 | 2020-09-01 | 珠海天威新材料股份有限公司 | Environment-friendly pyrograph ink, PET film heat transfer printing method and application thereof |
| CN115093776A (en) * | 2022-07-08 | 2022-09-23 | 广东睿智环保科技有限责任公司 | Antibacterial powder coating for MDF heat transfer printing and application method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2016204167A1 (en) | 2016-12-22 |
| KR101764656B1 (en) | 2017-08-04 |
| KR20170002549A (en) | 2017-01-06 |
| JP2017002266A (en) | 2017-01-05 |
| JP5970588B1 (en) | 2016-08-17 |
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