CN109334292B - Water-based ink-jet transfer printing method for personalized printing of textiles - Google Patents
Water-based ink-jet transfer printing method for personalized printing of textiles Download PDFInfo
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- CN109334292B CN109334292B CN201811449559.7A CN201811449559A CN109334292B CN 109334292 B CN109334292 B CN 109334292B CN 201811449559 A CN201811449559 A CN 201811449559A CN 109334292 B CN109334292 B CN 109334292B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/03—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
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Abstract
The invention discloses a water-based ink-jet transfer printing method for personalized printing of textiles, wherein a water-based ink-jet transfer printing material sequentially comprises a substrate layer, a release layer and an ink-applying layer, wherein the release layer is a PP release layer, and the ink-applying layer is made of nano SiO with 50-85 parts of deionized water and 20-48% of solid content21-30 parts of emulsion, 0.1-10 parts of sodium alginate and 0.1-3 parts of alkynediol ethoxy compound and/or alkynediol, ink-jet printing is performed on one side of an inking layer to form a mirror image pattern, powder resin is uniformly spread on the mirror image surface, the surface of a non-pattern position is cleaned, the pattern side containing the powder resin is placed on the textile for 8-240 s of high-temperature and high-pressure pressing at 120-160 ℃, cooling is performed, a transfer material is torn off, color printing of the textile made of various materials can be achieved, the textile is soft in hand feeling, bright in color, strong in washing resistance and weather resistance, air permeability, good in color reduction ratio and higher in fastness than that of a direct injection textile, and the rejection rate is greatly reduced.
Description
Technical Field
The invention belongs to the technical field of aqueous ink-jet transfer printing, and particularly relates to an aqueous ink-jet transfer printing method for personalized printing of textiles.
Background
The printing and dyeing of the complex patterns on the textile mainly comprises the following modes: gravure printing, screen printing, thermal transfer printing, thermal sublimation printing (containing more than 60% of polyester fabrics) and direct injection printing, and the water transfer printing technology of the Changsheng company are the main technologies. Wherein, gravure printing is suitable for mass printing, screen printing, thermal transfer printing and water transfer printing are suitable for mass production, the printing cost of a single color pattern is extremely high, and no people can use the method as personalized printing in the industry at present; the thermal sublimation printing only uses cloth containing polyester material more than 60% because of using dispersed ink, and the sun-proof grade of the dispersed dye is lower.
Direct injection printing is the first choice of personalized printing in the industry at present, but the process is complex, the problems of poor dot and color reduction are easily caused due to poor surface flatness and inconsistent water absorption of textiles, the clothes need to be pretreated, and the final product has poor washing performance and color loss and cannot meet the requirements on color fastness due to the fact that the solvent of the water-based paint is water; internationally, such as coating ink produced by DuPont and other companies, can meet the requirements of part of customers in the aspects of color fastness and washing fastness, but the use cost is extremely high, the process is complex, and the whole piece of clothes is easily scrapped due to the blockage of an ink jet nozzle or ink flying of the nozzle in the production process.
Disclosure of Invention
In view of the above, the present invention aims to provide an aqueous inkjet transfer printing method for personalized printing of textiles, which solves personalized, variable pattern and high-quality garment printing, and has the advantages of environment-friendly and efficient whole transfer printing process, yield up to 100%, no waste of resources and no environmental pollution.
The technical scheme adopted by the invention for solving the technical problems is as follows:
in a first aspect, an aqueous jet transfer material comprises a substrate layer, a release layer and an ink layer in sequence,
the release layer is a PP release layer;
the ink-applying layer is formed by uniformly mixing the following raw materials in parts by mass, coating the mixture on the surface of the release layer, and drying the mixture at room temperature or drying the mixture at room temperature:
the nano SiO2The solid content of the emulsion is 20-48 percent;
the functional auxiliary agent is an acetylene glycol ethoxy compound and/or acetylene glycol.
Preferably, the aqueous jet transfer printing material sequentially comprises a substrate layer, a release layer and an ink applying layer, wherein,
the release layer is a PP release layer;
the ink-applying layer is formed by uniformly mixing the following raw materials in parts by mass, coating the mixture on the surface of the release layer, and drying the mixture at room temperature or drying the mixture at room temperature:
more preferably, the aqueous jet transfer material comprises a substrate layer, a release layer and an ink applying layer in sequence, wherein,
the release layer is a PP release layer;
the ink-applying layer is formed by uniformly mixing the following raw materials in parts by mass, coating the mixture on the surface of the release layer, and drying the mixture at room temperature or drying the mixture at room temperature:
more preferably, the aqueous jet transfer material comprises a substrate layer, a release layer and an ink applying layer in sequence, wherein,
the release layer is a PP release layer;
the ink-applying layer is formed by uniformly mixing the following raw materials in parts by mass, coating the mixture on the surface of the release layer, and drying the mixture at room temperature or drying the mixture at room temperature:
in a second aspect, an aqueous inkjet transfer method for personalized printing of textiles, comprising the steps of:
(1) adjusting the surface tension of pigment ink to match with the aqueous jet transfer printing material of any one of claims 1 to 4, carrying out ink-jet printing on the pigment ink on one side of an inking layer of the aqueous jet transfer printing material to form a mirror image pattern, adding a spot color channel through RIP (raster image processor) analysis, and carrying out jet printing on transparent or white ink to form a surface ink layer, completely covering a jet printing flower position and enabling the size of the jet printing flower position to be consistent with the pattern;
(2) after the ink jet is finished, uniformly scattering powder resin on the surface of the surface ink layer in the step (1), and cleaning the powder resin on the surface of the non-pattern position;
(3) placing one side of the pattern containing the powder resin of the water-based spray transfer printing material in the step (2) on a textile, and pressing under high temperature and high pressure, wherein the pressing temperature is 120-160 ℃, and the pressing time is 8-240 s;
(4) and (4) after the pressing in the step (3), naturally standing and cooling to room temperature, and tearing off the water-based spray transfer printing material to obtain the ink.
In a preferred embodiment, in the step (2), the powdered resin comprises one or a mixture of more than two of PES powder, TPU powder or PA powder, and the particle size of the powder comprises 1-80 microns and/or 80-160 microns.
In a preferred embodiment, in the step (3), pressing is sequentially carried out at 120 ℃ for 8s, 140 ℃ for 10s, 150 ℃ for 50s, 160 ℃ for 80s and 180 ℃ for 100 s.
According to the invention, the printing performance of the pigment ink can be ensured to be matched with that of the water-based spray transfer printing material by adding the functional auxiliary agent, so that the mirror image pattern achieves an ideal printing effect.
In a third aspect, the aqueous jet transfer printing material is used for personalized printing of textiles according to the aqueous ink jet transfer printing method.
Compared with the prior art, the invention has the beneficial effects that:
1. the water-based ink-jet transfer printing method can realize color printing on textiles made of various materials, and has the advantages of soft hand feeling, bright color, water resistance, strong weather resistance and air permeability.
2. The transfer printing contact of the invention is a release layer containing a coating, the surface tension is stable, the dot reduction is good, and the powder resin is used as an intermediate agent for printing and textiles, so that the printing surface of the textiles is smooth, the water resistance of pigment ink can be increased, the color reduction is better than that of direct injection, the fastness is far higher than that of the direct injection textiles, and the weather resistance is greatly improved.
3. Compared with other printing modes, the printing process of the invention has no harmful substance emission, and the finished product can be directly worn without retreatment.
4. The transfer printing method directly prints on the surface of the printing stock, so that the whole textile is not scrapped due to printing errors, and the rejection rate is greatly reduced.
Drawings
FIG. 1 is a schematic structural view of an aqueous jet transfer material.
Fig. 2 is a flow chart of an aqueous inkjet transfer process for textile personalization printing.
FIG. 3 is a diagram showing the effect of the prior art after the direct jet printing of the spun yarn is washed.
Fig. 4 is an effect diagram of the conventional thermal transfer.
FIG. 5 is a diagram showing the effect of aqueous inkjet transfer according to the present invention.
FIG. 6 is a contact angle test of pigmented inks adjusted to match the surface tension of the aqueous jet transfer material.
FIG. 7 is a graph of the effects of aqueous inkjet transfer printing and direct jet printing, respectively, for textile personalization printing; among these, the water-based ink jet transfer effect (left) and the direct jet printing effect (right).
FIG. 8 is a diagram of the effect of aqueous inkjet transfer printing and direct jet printing after washing 5 times for personalized textile printing; among these, the water-based ink jet transfer effect (left) and the direct jet printing effect (right).
Detailed Description
The invention is further illustrated with reference to the following figures and examples.
The starting materials in the following examples include: PP release layer, deionized water and nano SiO with solid content of 20-48 percent2Emulsion, sodium alginate, DYNOL 604607 and SURFYNOL 420440465.
Referring to fig. 1, the aqueous spray transfer material sequentially comprises a substrate layer, a release layer and an inking layer, wherein the release layer is a PP release layer, and the inking layer is prepared from deionized water and nano SiO with a solid content of 20% -48%2The emulsion, sodium alginate, DYNOL 604607 and/or SURFYNOL 420440465.
Referring to fig. 2, the aqueous inkjet transfer printing method for personalized printing of textiles specifically comprises:
(1) adjusting the surface tension of the pigment ink to match with the aqueous jet transfer printing material (as shown in fig. 6), carrying out ink-jet printing on the pigment ink on one side of an inking layer of the aqueous jet transfer printing material to form a mirror image pattern, carrying out RIP analysis to increase a spot color channel, and carrying out jet printing on transparent or white ink to form a surface ink layer, wherein the surface ink layer completely covers a jet printing flower position and has the same size as the pattern;
(2) after the ink jet is finished, uniformly scattering powder resin on the surface of the surface ink layer in the step (1), and cleaning the powder resin on the surface of the non-pattern position;
(3) placing one side of the pattern containing the powder resin of the water-based spray transfer printing material in the step (2) on a textile, and pressing under high temperature and high pressure, wherein the pressing temperature is 120-160 ℃, and the pressing time is 8-240 s;
(4) and (4) after pressing and ironing in the step (3), naturally standing and cooling to room temperature, and tearing off the water-based spray transfer printing material to obtain the water-based spray transfer printing ink.
Example 1
The water-based ink-jet transfer printing material adopted by the water-based ink-jet transfer printing method for individualized printing of textiles sequentially comprises a substrate layer, a release layer and an inking layer, wherein the release layer is a PP release layer, and the inking layer is prepared from nano SiO which comprises 50 parts of deionized water and has a solid content of 20-48%21 part of emulsion, 0.1 part of sodium alginate, DYNOL 604607 and SURFYNOL 4204404650.1.
Example 2
The water-based ink-jet transfer printing material adopted by the water-based ink-jet transfer printing method for individualized printing of textiles sequentially comprises a substrate layer, a release layer and an inking layer, wherein the release layer is a PP release layer, and the inking layer is prepared from 55 parts of deionized water and 20-48% of nano SiO with solid content25 parts of emulsion, 1 part of sodium alginate and 4204404650.5 parts of SURFYNOL.
Example 3
The water-based ink-jet transfer printing material adopted by the water-based ink-jet transfer printing method for individualized printing of textiles sequentially comprises a substrate layer, a release layer and an inking layer, wherein the release layer is a PP release layer, and the inking layer is prepared from 60 parts of deionized water and 20-48% of nano SiO with solid content210 parts of emulsion, 2 parts of sodium alginate, 2 parts of DYNOL 604607 and 4204404651 parts of SURFYNOL.
Example 4
The water-based ink-jet transfer printing material adopted by the water-based ink-jet transfer printing method for individualized printing of textiles sequentially comprises a substrate layer, a release layer and an inking layer, wherein the release layer is a PP release layer, and the inking layer is prepared from 68 parts of deionized water and 20-48% of nano SiO with solid content215 parts of emulsion, 5 parts of sodium alginate, DYNOL 604607 and SURFYAnd (4) NOL 4204404652 parts by weight.
Example 5
The water-based ink-jet transfer printing material adopted by the water-based ink-jet transfer printing method for individualized printing of textiles sequentially comprises a substrate layer, a release layer and an inking layer, wherein the release layer is a PP release layer, and the inking layer is prepared from 75 parts of deionized water and 20-48% of nano SiO with solid content220 parts of emulsion, 6 parts of sodium alginate, DYNOL 604607 and SURFYNOL 4204404652.
Example 6
The water-based ink-jet transfer printing material adopted by the water-based ink-jet transfer printing method for individualized printing of textiles sequentially comprises a substrate layer, a release layer and an inking layer, wherein the release layer is a PP release layer, and the inking layer is prepared from 80 parts of deionized water and 20-48% of nano SiO with solid content225 parts of emulsion, 8 parts of sodium alginate and 6046072.5 parts of DYNOL.
Example 7
The water-based ink-jet transfer printing material adopted by the water-based ink-jet transfer printing method for individualized printing of textiles sequentially comprises a substrate layer, a release layer and an inking layer, wherein the release layer is a PP release layer, and the inking layer is prepared from 85 parts of deionized water and 20-48% of nano SiO with solid content230 parts of emulsion, 10 parts of sodium alginate, DYNOL 604607 and SURFYNOL 4204404653.
Example 8
The aqueous ink-jet transfer printing method for the personalized printing of the textiles is different only in that the powder resin in the step (2) is PES powder mixed with particles of 1-80 micrometers and 80-160 micrometers.
Example 9
The aqueous ink-jet transfer printing method for the personalized printing of the textile is different only in that the powder resin in the step (2) is TPU powder with the particle size of 80-160 microns.
Example 10
The aqueous ink-jet transfer printing method for the personalized printing of the textiles is different only in that the powder resin in the step (2) is a mixture of PES powder, TPU powder and PA powder, and the particle size of the powder comprises 1-80 microns and 80-160 microns.
Example 11
The aqueous ink-jet transfer printing method for the personalized printing of the textile is different only in that in the step (3), the water-jet transfer printing method is respectively pressed and scalded at 120 ℃ for 8s, 140 ℃ for 10s, 150 ℃ for 50s, 160 ℃ for 80s and 180 ℃ for 100s in sequence.
Referring to fig. 3-5, fig. 3 is an effect diagram of a spun yarn directly-jet printed after washing in the prior art, and can be seen as a fuzzy pattern, poor washing resistance and poor color fastness, fig. 4 is an effect diagram of a traditional heat transfer printing, and the defects are that the printed layer is airtight and the surface printed layer is hard, and personalized printing cannot be realized, and fig. 5 is an effect diagram of the water-based ink-jet transfer printing of the invention, and the water-based ink-jet printing has soft hand feeling, air permeability, washing resistance, sun resistance and good weather resistance.
Referring to fig. 7 and 8, comparing the aqueous inkjet transfer printing of the present invention with the prior art in which direct jet printing is used for personalized printing of textiles, it can be seen that the color reduction effect of the aqueous inkjet transfer printing of the present invention is significantly better than that of the direct jet printing; washing the individually printed textiles obtained by the two printing methods at normal room temperature, airing or drying after 20 minutes each time, and washing for 5 times to see that the patterns of the directly-sprayed printed textiles are blurred and seriously faded, which indicates that the washing performance is poor and the color fastness cannot meet the requirements; the textile transferred by the water-based ink-jet printing method has clear patterns, bright colors and good color fastness after being washed for 5 times.
The same pigment ink is respectively subjected to direct spinning injection, dispersion sublimation and the aqueous ink-jet transfer printing method of the invention to perform personalized printing on the textile, and the sunlight fastness, the washing fastness, the processing complexity and the color reduction performance of the textile are shown in table 1.
TABLE 1
Claims (5)
1. An aqueous jet transfer material characterized in that,
comprises a substrate layer and a PP release layer in sequenceAnd the ink-applying layer consists of 50-85 parts of deionized water and 1-30 parts of nano SiO with the solid content of 20-48 percent2The emulsion, 0.1-10 parts of sodium alginate, 0.1-3 parts of alkynediol ethoxy compound and/or alkynediol are uniformly mixed and coated on the surface of the PP release layer to be dried or dried at room temperature to obtain the PP release layer;
the aqueous ink-jet transfer printing method for performing personalized printing on textiles by using the aqueous ink-jet transfer printing material comprises the following steps:
(1) taking pigment ink as inkjet ink, adjusting the surface tension of the pigment ink to be matched with the aqueous jet transfer printing material, and performing inkjet printing on one side of the ink-applying layer to form a personalized mirror image pattern;
(2) adding a spot color channel through RIP analysis, and spray-printing transparent or white ink to form a surface ink layer which completely covers the spray-printed flower positions and has the size consistent with the personalized mirror image pattern in the step (1);
(3) uniformly spreading powder resin on the surface of the surface ink layer in the step (2), cleaning redundant powder resin in a non-pattern area, placing one side of the pattern containing the powder resin of the water-based spray transfer printing material on a textile, pressing and ironing for 8s at 120 ℃, 10s at 140 ℃, 50s at 150 ℃, 80s at 160 ℃ and 100s at 180 ℃ in sequence, then naturally cooling to room temperature, tearing off the water-based spray transfer printing material, and finishing the personalized printing of the textile; wherein:
the powder resin is selected from one or more of PES, TPU or PA;
the particle size of the powdered resin is selected from 1-80 microns and/or 80-160 microns.
2. The aqueous jet transfer material according to claim 1,
the ink-applying layer is prepared from 55-80 parts of deionized water and 5-25 parts of nano SiO2And the emulsion, 1-8 parts of sodium alginate and 0.5-2.5 parts of acetylenic diol ethoxy compound are uniformly mixed and coated on the surface of the PP release layer to be dried or dried at room temperature to obtain the PP release layer.
3. The aqueous jet transfer material according to claim 1,
the ink-applying layer is prepared from 60-75 parts of deionized water and 10-20 parts of nano SiO2And uniformly mixing the emulsion, 2-6 parts of sodium alginate and 1-2 parts of acetylenic diol ethoxy compound, coating the mixture on the surface of the PP release layer, and drying or drying at room temperature to obtain the PP release layer.
4. The aqueous jet transfer material according to claim 1,
the ink-applying layer is prepared from 68 parts of deionized water and 15 parts of nano SiO2And the emulsion, 5 parts of sodium alginate, 2 parts of acetylene glycol ethoxy compound and a mixture of acetylene glycol are uniformly mixed and coated on the surface of the PP release layer to be dried or dried at room temperature to obtain the PP release layer.
5. Use of the aqueous jet transfer material according to any of claims 1 to 4 for personalized printing of textiles.
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| CN111497483B (en) * | 2020-05-06 | 2023-01-24 | 莆田市睿光信息技术有限公司 | Printing embroidery process |
| CN113022185B (en) * | 2021-01-29 | 2023-03-28 | 广东冠豪高新技术股份有限公司 | Production process of water-based digital ink-jet transfer printing intermediate medium |
| CN113059911A (en) * | 2021-03-19 | 2021-07-02 | 上海嵩阳印刷科技有限公司 | Nozzle arrangement combination structure and ink-jet printer comprising same |
| CN115464971B (en) * | 2022-09-19 | 2023-05-26 | 浙江中特机械科技股份有限公司 | Web full-rotary printing press |
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