CN105821680A - Reactive dye duplex printing method - Google Patents
Reactive dye duplex printing method Download PDFInfo
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- CN105821680A CN105821680A CN201610362497.0A CN201610362497A CN105821680A CN 105821680 A CN105821680 A CN 105821680A CN 201610362497 A CN201610362497 A CN 201610362497A CN 105821680 A CN105821680 A CN 105821680A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0004—General aspects of dyeing
- D06P1/002—Processing by repeated dyeing, e.g. in different baths
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5278—Polyamides; Polyimides; Polylactames; Polyalkyleneimines
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5285—Polyurethanes; Polyurea; Polyguanides
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5292—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
- D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6491—(Thio)urea or (cyclic) derivatives
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
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- D06P1/673—Inorganic compounds
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- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
Abstract
The invention discloses a reactive dye duplex printing method and belongs to the technical field of textile inkjet printing .The reactive dye duplex printing method comprises the steps that fabric is padded with a pretreatment working solution containing an opacifying agent and a penetrating preventing agent, the pretreatment working solution is uniformly applied to the front and back sides of the fabric, the fabric is dried, the front side of the fabric is subjected to inkjet printing with reactive dye ink and dried, then the back side of the fabric is subjected to inkjet printing with the reactive dye ink and dried, steaming is carried out for fixation, and washing, drying and tentering are carried out .The reactive dye duplex printing method is suitable for duplex printing of pure-spun or blended fabric made of cellulose fibers .The double-side floral designs of the fabric obtained after inkjet printing do not influence each other and are high in fineness, bright in color, high in expressive force and rich in layering sense .
Description
Technical field
A kind of method that the present invention relates to reactive dye duplex pringing, belongs to textile inkjet printing technical field.
Background technology
Tapissendis such as tablecloth, tippet, silk scarf, flag, handkerchief etc. can realize front-back two-sided diverse printing quality, have wide market prospect.
It is to utilize print paste to penetrate into envers that plain net or ROTARY SCREAM PRINTING produce tapissendis, makes the floral designs of fabric face, penetrates into the reverse side of fabric, then through evaporating operations such as washing or bake.But the permeance property of mill base and the fineness with floral designs are conflicts, if mill base penetrates into the back side of fabric, floral designs fineness will certainly be reduced, thus the two-sided homochromy same flower pattern PRINTED FABRIC that fineness is poor can only be obtained.Chinese patent CN201510136958.8 discloses a kind of perfecting dye transfer flower process, with dye paste fabric carries out one side is monochromatic or after many topping printings dries, and carries out with dye paste that reverse side is monochromatic or many topping printings post-drying；Then pad with the mangle containing color fixing agent, then vapour steaming colour fixing, i.e. obtain double-face dyeing PRINTED FABRIC finished product after washing sizing.But this process needs according to flower pattern color color separation, retouches original text, different colours half tone processed, the dye paste of preparation different colours, extremely complex time-consuming, production cycle is long, small lot, multi items, the supply of material demand of fast delivery cannot be met, and the floral designs of positive and negative easily interact, lose the effect of one side pattern, in addition pattern fineness it is difficult to ensure that.
Increase, environmental protection pressure along with labor cost, the market share shared by traditional PLATE SCREAM PRINTING and ROTARY SCREAM PRINTING is gradually lowered, and ink-jet printed adapt to small lot, personalization because of it, hand over phase, multi-pattern type, motility, the trend of fast fashion soon, and there is the significant advantage such as environment-protection low-consumption, precision height rich color, obtain very fast growth.Wu Yanwen et al. reports a kind of method (Wu Yanwen utilizing ink-jet printed technology to produce cashmere tippet tapissendis, Liu Fengli, Li Xiaofeng etc. the exploitation [C] of cashmere tippet two-sided digital Printing. functional textile and nanotechnology seminar .2008.), the method is only suitable for two-sided homochromy same flower pattern stamp, and for relatively thin fabric, can there is slur, the disadvantage that visual effect is more random.Tapissendis is produced currently with ink-jet printed technology, yet suffer from the interactional problem of positive and negative, two-sided homochromy same flower pattern stamp can only be realized, this greatly limits style and the product of tapissendis, serious restriction duplex pringing technology and the development of application.
Summary of the invention
A kind of method that it is an object of the invention to provide reactive dye duplex pringing, it is intended to overcome at present by the ink-jet printed technology problem that positive and negative interferes when spray printing tapissendis.
The present invention solves the technical scheme of the problems referred to above:
Fabric tow sides uniformly apply pretreatment fluid and dry, fabric face reactive dye ink carry out ink-jet printed and dry after, fabric backing reactive dye ink carry out ink-jet printed and dry after, evaporate, washing, dry, tentering.
Concretely comprise the following steps:
(1) the pretreatment work liquid being made up of opacifier 1% ~ 3%, impermeable dose 1.5% ~ 3%, thickening agent 3% ~ 10%, carbamide 8% ~ 20%, sodium bicarbonate 2% ~ 4%, soda 0.5% ~ 1%, Matrii Sulfas Exsiccatus 1% ~ 3%, reservehao S 0.5% ~ 1.5% and water is prepared；
(2) textile pad pretreatment work liquid, liquid carrying rate is 50% ~ 80%, 85 ~ 120 DEG C of drying；
(3) fabric face reactive dye ink carries out ink-jet printed, and after 85 ~ 120 DEG C dry, fabric backing reactive dye ink carries out ink-jet printed, 85 ~ 120 DEG C of drying；
(4) saturated vapor, under the conditions of 101～103 DEG C, evaporates 7～14min, washes, dry, tentering.
Described opacifier is diphenyl dimethicone, the poly-trimethicone of diphenyl silicon phenyl, phenyl trimethicone, titanium dioxide, the one of polyaminoamide or combination.Preferably opacifier can stop that light penetration arrives other one side, increases fabric face and the independence of reverse side floral designs.
Described impermeable dose is the combination of one or more of organic fluorine, fatty acid, fatty acid amide, aliphatic alcohol polyethenoxy, polysiloxanes.Impermeable dose, by reducing surface free energy and the spreading area of ink of fabric, preventing woven designs pattern in stamp from penetrating into the another side of fabric, affects fineness and the contour sharpness of fabric backing floral designs.Kind according to fabric and weave specification, regulate impermeable dose of consumption, and thick heavy weave is compared thin fabric and had preferable impermeable function, now only need to add a small amount of impermeable dose in pretreatment work liquid.
Described thickening agent is carboxymethyl cellulose, starch, modified starch, polyacrylic acid sodium ester, sodium polyacrylate, polyacrylamide, the one of polyurethane or combination.Thickening agent prevents dyestuff imbibition in spray printing post-drying and steaming procedure, and the anti-permeability of thickening agent is higher simultaneously, is more beneficial for keeping flower pattern and pattern contour definition.
Carbamide increases the dissolubility of fabric face dyestuff, needs pure to spin and the consumption of hygroscopicity regulation carbamide of blend fabric according to what cellulose fibre, regenerated celulose fibre and protein fibre formed.Sodium bicarbonate and soda provide reactive dye color fixing condition.Matrii Sulfas Exsiccatus promotes absorption and the fixation of reactive dye.Reservehao S prevents the destruction to reactive dye of the reducibility gas in steaming procedure.
Beneficial effects of the present invention
The present invention is applicable to cellulose fibre pure and spins and the same flower pattern of blend fabric and different flower pattern, homochromy and heterochromatic duplex pringing.Fabric two-face floral designs after spray printing of the present invention are independent of each other, fineness is high, bright in colour, representability is strong, be rich in stereovision, soft and there is good fastness.
Detailed description of the invention
For further appreciating that the present invention, below in conjunction with embodiment, embodiment of the present invention is described, but it is to be understood that these descriptions are intended merely to further illustrate the features and advantages of the present invention rather than limiting to the claimed invention.
The present invention provide a kind of reactive dye duplex pringing method particularly as follows:
First, the pretreatment work liquid being made up of opacifier 1% ~ 3%, impermeable dose 1.5% ~ 3%, thickening agent 3% ~ 10%, carbamide 8% ~ 20%, sodium bicarbonate 2% ~ 4%, soda 0.5% ~ 1%, Matrii Sulfas Exsiccatus 1% ~ 3%, reservehao S 0.5% ~ 1.5% and water is prepared.
Described opacifier is diphenyl dimethicone, the poly-trimethicone of diphenyl silicon phenyl, phenyl trimethicone, titanium dioxide, the one of polyaminoamide or combination.
Described impermeable dose is organic fluorine, fatty acid, fatty acid amide, aliphatic alcohol polyethenoxy, the one of polysiloxanes or combination.Described thickening agent is carboxymethyl cellulose, starch, modified starch, polyacrylic acid sodium ester, sodium polyacrylate, polyacrylamide, the one of polyurethane or combination.
Secondly, fabric through evenness calender, an immersing and rolling, pad pretreatment work liquid, applying pretreatment fluid uniform to tow sides, fabric liquid carrying rate is 50% ~ 80%, 85 ~ 120 DEG C of drying.
Then, fabric face reactive dye ink carries out ink-jet printed, and after 85 ~ 120 DEG C dry, fabric backing reactive dye ink carries out ink-jet printed, 85 ~ 120 DEG C of drying.
Finally, saturated vapor, under the conditions of 101～103 DEG C, evaporates 7～14min, washes, dry, tentering.
Embodiment 1
First, pretreatment work liquid is prepared according to following formula.
Secondly, pure cotton fabric, through evenness calender, pads pretreatment work liquid, and tow sides uniformly apply pretreatment fluid, and fabric liquid carrying rate is 70%, 105 DEG C of drying.
Then, pure cotton fabric front reactive dye ink carries out ink-jet printed, and after 105 DEG C dry, fabric backing reactive dye ink carries out ink-jet printed, 105 DEG C of drying.
Finally, saturated vapor, under the conditions of 102 DEG C, evaporate 7min, washing, dry, tentering.
Being analyzed pure cotton fabric duplex pringing cloth specimen, the obverse and reverse floral designs of fabric are independent of each other, have higher fineness, lovely luster, representability is strong, be rich in stereovision, soft and have good fastness.This absolutely proves that the present invention has good result to pure cotton fabric duplex pringing.
Embodiment 2
First, pretreatment work liquid is prepared according to following formula.
Secondly, Tencel fabric through evenness calender, an immersing and rolling, pad pretreatment work liquid, applying pretreatment fluid uniform to tow sides, fabric liquid carrying rate is 80%, 95 DEG C of drying.
Then, fabric face reactive dye ink carries out ink-jet printed, and after 90 DEG C dry, fabric backing reactive dye ink carries out ink-jet printed, 90 DEG C of drying.
Finally, saturated vapor, under the conditions of 102 DEG C, evaporate 14min, washing, dry, tentering.
Being analyzed Tencel fabric duplex pringing cloth specimen, there is core-skin layer in Tencel fabric, and this has larger difference with pure cotton fabric, needs to adjust the formula composition of pretreatment work liquid.The obverse and reverse floral designs of Tencel fabric are independent of each other, have higher fineness, lovely luster, representability is strong, be rich in stereovision, soft and there is good fastness.This absolutely proves that the present invention has good result to Tencel fabric duplex pringing.
Embodiment 3
First, pretreatment work liquid is prepared according to following formula.
Secondly, real silk fabric through evenness calender, an immersing and rolling, pad pretreatment work liquid, applying pretreatment fluid uniform to tow sides, fabric liquid carrying rate is 75%, 85 DEG C of drying.
Then, fabric face reactive dye ink carries out ink-jet printed, and after 85 DEG C dry, fabric backing reactive dye ink carries out ink-jet printed, 85 DEG C of drying.
Finally, saturated vapor, under the conditions of 102 DEG C, evaporate 7min, washing, dry, tentering.
Claims (4)
1. the method for a reactive dye duplex pringing, it is characterised in that comprise the steps:
(1) the pretreatment work liquid being made up of opacifier 1% ~ 3%, impermeable dose 1.5% ~ 3%, thickening agent 3% ~ 10%, carbamide 8% ~ 20%, sodium bicarbonate 2% ~ 4%, soda 0.5% ~ 1%, Matrii Sulfas Exsiccatus 1% ~ 3%, reservehao S 0.5% ~ 1.5% and water is prepared；
(2) textile pad pretreatment work liquid, liquid carrying rate is 50% ~ 80%, 85 ~ 120 DEG C of drying；
(3) fabric face reactive dye ink carries out ink-jet printed, and after 85 ~ 120 DEG C dry, fabric backing reactive dye ink carries out ink-jet printed, 85 ~ 120 DEG C of drying；
(4) saturated vapor, under the conditions of 101～103 DEG C, evaporates 7～14min, washes, dry, tentering.
The method of a kind of reactive dye duplex pringing the most according to claim 1, it is characterized in that, described opacifier is diphenyl dimethicone, the poly-trimethicone of diphenyl silicon phenyl, phenyl trimethicone, titanium dioxide, the one of polyaminoamide or combination.
The method of a kind of reactive dye duplex pringing the most according to claim 1, it is characterised in that described impermeable dose is organic fluorine, fatty acid ester, fatty acid amide, the one of aliphatic alcohol polyethenoxy or combination.
The method of a kind of reactive dye duplex pringing the most according to claim 1, it is characterised in that described thickening agent is carboxymethyl cellulose, starch, modified starch, polyacrylate, sodium polyacrylate, polyacrylamide, the one of polyurethane or combination.
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| CN106351036A (en) * | 2016-08-26 | 2017-01-25 | 深圳市墨库图文技术有限公司 | Environmental-friendly active dye digital printing pretreatment prime pulp and preparation method thereof |
| CN106521988A (en) * | 2016-10-31 | 2017-03-22 | 江西服装学院 | Printing method |
| CN106820360A (en) * | 2017-01-06 | 2017-06-13 | 德清县玉缘服饰有限公司 | A kind of erosion hair technique of tasselled silk scarf |
| CN107574697A (en) * | 2017-09-01 | 2018-01-12 | 深圳诚拓数码设备有限公司 | A kind of weaving face fabric Method of printing |
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| CN110029511B (en) * | 2019-04-19 | 2021-09-24 | 天津工业大学 | Ink-jet printing pretreating agent and surface pretreatment method of silk fabric |
| CN110747663A (en) * | 2019-10-28 | 2020-02-04 | 湖南特俪洁新材料科技有限公司 | Reactive dye printing paste and printing method thereof |
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| CN113417155A (en) * | 2021-06-23 | 2021-09-21 | 鲁丰织染有限公司 | Method for improving printing blocking of fluffy fabric rotary screen |
| CN113846497A (en) * | 2021-08-09 | 2021-12-28 | 浙江理工大学 | Preparation method of high-precision superfine silk front and back digital printing silk fabric |
| CN113846497B (en) * | 2021-08-09 | 2023-07-04 | 浙江理工大学 | Preparation method of high-precision superfine silk front and back digital printing silk fabric |
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