CN106758422A - The application of stamp RIPSTOP and its production technology and thermal transfer ink - Google Patents
The application of stamp RIPSTOP and its production technology and thermal transfer ink Download PDFInfo
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- CN106758422A CN106758422A CN201611209315.2A CN201611209315A CN106758422A CN 106758422 A CN106758422 A CN 106758422A CN 201611209315 A CN201611209315 A CN 201611209315A CN 106758422 A CN106758422 A CN 106758422A
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- ripstop
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5285—Polyurethanes; Polyurea; Polyguanides
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
- D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
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- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
- D06P3/26—Polyamides; Polyurethanes using dispersed dyestuffs
Abstract
The present invention relates to nylon printing technology field, and in particular to the application of stamp RIPSTOP and its production technology and thermal transfer ink, the stamp RIPSTOP production technology is comprised the following steps that：By intaglio printing printing machine by thermal transfer ink to transfer paper；Is transferred to printed patterns on RIPSTOP by caloric transfer printing technology by gained transfer paper, stamp RIPSTOP fabric is obtained.Thermal transfer ink is comprised the following raw materials by weight percent：Disperse dyes mill base 15 35%, thickener 15 35%, NMF 0 25%, surface tension modifier：0.1 1%, defoamer 0.01 0.5%, preservative 0.01 0.5%, anti-coagulants 0.01 1%, deionized water：Surplus.The present invention can realize the clean manufacturing of RIPSTOP fabric revenue stamp process, realize trade effluent zero-emission target, can effectively prevent disperse dyes from being moved in the colour migration of RIPSTOP fabric.
Description
Technical field
The present invention relates to nylon printing technology field, and in particular to a kind of stamp RIPSTOP and its production technology and
The application of thermal transfer ink.
Background technology
Conventional nylon fabric printing and dyeing stamp generally uses acid dyes mill base or ink, and needs by starching
The pre-treatments such as Final finishing process, the starching work such as evaporating, rinse Deng pre-treatment and high temperature can avoid acid dyes mill base or ink
The flushing on fabric, high temperature such as evaporates at the Final finishing process can effectively improve the color fastness of printing and dyeing PRINTED FABRIC.However, pre-treatment and
Aftertreatment technology needs to use substantial amounts of water, so, with regard to inevitable real estate in conventional nylon fabric stamp production process
Give birth to substantial amounts of trade effluent and colour migration shifting easily occurs in gained finished product, influence the presentation quality of product, and conventional nylon fabric intaglio plate
Printing technology is complicated, and production cost is high.
The content of the invention
An object of the present invention is to provide a kind of production technology of stamp RIPSTOP, the printing and dyeing print of RIPSTOP fabric
Hoop structure is realized during flower, can effectively be improved printing and dyeing color fastness of the disperse dyes on RIPSTOP fabric and be prevented
Disperse dyes are moved in the colour migration of RIPSTOP fabric, process is simple, low production cost.
The second object of the present invention is to provide a kind of stamp RIPSTOP, and stamp nylon is knitted as obtained in above-mentioned production technology
Object plane material color fastness is high, and colour migration shifting, fabric color fastness occur on RIPSTOP fabric in disperse dyes after can avoiding printing and dyeing stamp
It is high.
The third object of the present invention is to provide a kind of thermal transfer ink of stamp RIPSTOP production technology, can be applied to recessed
Version printing printing machine, meets the requirement of gravure printing, high in machining efficiency, thermal transfer ink good weatherability.
To achieve the above object, the technical solution adopted by the present invention is as follows.
A kind of stamp RIPSTOP production technology, comprises the following steps that：
Step（1）Printing figure will be formed with by intaglio printing printing machine on thermal transfer ink to transfer paper, on transfer paper
Case；Shape and color of printed patterns etc. have been designed on intaglio printing printing machine and associate device in advance, intaglio printing
Printing machine is prior art, and its concrete application method will not be repeated here；
Step（2）Is transferred to printed patterns on RIPSTOP by caloric transfer printing technology by gained transfer paper, stamp nylon is obtained
Fabric；
The thermal transfer ink is comprised the following raw materials by weight percent：
Disperse dyes mill base：15-35%；
Thickener：15-35%；
NMF：0-25%
Surface tension modifier：0.1-1%；
Defoamer：0.01-0.5%；
Preservative：0.01-0.5%；
Anti-coagulants：0.01-1%
Deionized water：Surplus.
Specifically, step（1）Be using intaglio printing printing machine by thermal transfer ink gravure to transfer paper, transfer paper
Solid content is about 5%, and the grammes per square metre of transfer paper is 58-100g/m2.Further, the transfer paper is that common transfer paper or nylon are special
With transfer paper, nylon dedicated transfer paper is preferably South Korea's Han Song paper industry（Hansol Paper）The special heat sublimation of nylon of production turns
Printing paper, in this way, gained stamp RIPSTOP pattern color saturation degree is good, pattern color reduction degree is high, and picture is true to nature, and brightness is high,
Color fastness is high and good weatherability, and the special thermal transfer ink of nylon of the invention is used cooperatively with transfer paper, good transferring effect, and paper
The blotting amount opened is few, saves about with ink, can effectively reduce production cost, and the fabric texture after transfer is excellent.
Preferably, the thermal transfer ink, comprises the following raw materials by weight percent：
Disperse dyes mill base：15-35%；
Thickener：15-35%；
NMF：0.1-25%；
Surface tension modifier：0.1-1%；
Defoamer：0.01-0.5%；
Preservative：0.01-0.5%；
Deionized water：Surplus.
Wherein, the step（2）Middle caloric transfer printing technology temperature is 180-220 DEG C, and the thermal transfer time is 25-60s.Thermal transfer
Technological temperature is preferably 190-200 DEG C, and the thermal transfer time is preferably 40-50s.Specifically, by step（1）The decal transfer of preparation
Paper and nylon facing material are stacked together in the thermal transfer equipment for being introduced into and setting operating condition in advance, and it is true to apply pressure by the external world
Thermal protection transfer ink is effectively transferred on nylon facing material.
The disperse dyes mill base is formed by disperse dyes, dispersant, dispersing aid and deionized water mixed grinding.
Further, the grinding particle diameter of the disperse dyes mill base is 100-800nm.
Preferably, the disperse dyes be Red-1 200 9, disperse red 53, disperse red 54, disperse red 60, disperse red 86, point
Dissipate red 118, Red-1 200 79, disperse yellow 54, dispersion yellow 64, disperse yellow 79, disperse yellow 104, disperse yellow 163, disperse yellow 232, point
Dissipate blue 7, disperse blue 14, disperse blue 26, disperse blue 72, Disperse Blue-79, disperse blue 124, disperse blue 359, disperse orange 11, disperse orange
13rd, in disperse orange 29, disperse orange 31, disperse orange 73, disperse orange 149, disperse violet 17, disperse violet 26, disperse violet 28, disperse violet 63
One kind.Preferably, the dispersant is sodium lignin sulfonate.
Preferably, the dispersing aid is polyesters dispersing aid, polyethers dispersing aid, methyl pyrrolidone, ethyl
In pyrrolidones, diethylene glycol monobutyl ether, dimethyl ether, gamma-butyrolacton, PEG200, PEG2000, alpha-pyrrolidone
At least one.
Polyesters dispersing aid can be specifically Dispersant 5040, Dispersant 1027, Dispersant
At least one in 1029.
Polyethers dispersing aid can be specifically in Houtch D-127, Houtch D-156, Houtch D-160 extremely
Few one kind.
The NMF is diethylene glycol (DEG), glycerine, butanediol, polyethylene glycol, propane diols, hexylene glycol, xylitol, poly- the third two
One or more mixture in alcohol, D-sorbite.
It is dispersion that sodium lignin sulfonate is used in disperse dyes mill base, and adds dispersing aid, can strengthen dispersion dye
The stability and tinting strength, tinting power of material.
Preferably, the thickener is comprised the following raw materials by weight percent：
Thickener：5-15%；
Deionized water：Surplus；
Wherein, the thickener is sodium alginate, carboxymethylcellulose calcium, starch, Chinese honey locust glue, polyvinyl acetate, polyurethane, poly- second
At least one in enol, polyacrylic resin.
Preferably, the surface tension modifier is at least one in fluorine-containing nonionic class surface tension modifier.
Specifically, fluorine-containing nonionic class surface tension modifier is DAPRO®W-77, can be with aqueous and solvent-based system
The performance of excellent reduction surface tension is provided, is strengthened soaking with this, disperseed, levelling and other surfaces performance.DAPRO® W-77
Without any VOC（VOC）, without APEO（APES）, non-flammable product, can with it is any from
The surfactant of sub- property is compatible.Certainly, surface tension modifier of the invention can also be other commercially available fluorine-containing nonionics
Class surface tension modifier.
Preferably, the defoamer is at least one in organic silicon defoamer, non-organic silicon class defoamer.
Organic silicon defoamer can be specifically at least in Defom W-052, Defom W-074, Defom W-082
Kind.
Non-organic silicon class defoamer can be specifically DAPRO® AP 7015、DAPRO®In DF 1760, Defom 2700
At least one.
Certainly, defoamer of the invention can also be that commercially available water process organic silicon defoamer or non-organic silicon class disappear
Infusion.
Preferably, the preservative be potassium sorbate, sorbic acid, ethyl-para-hydroxybenzoate, propylparaben,
At least one in butyl p-hydroxybenzoate.
It is highly preferred that the preservative is potassium sorbate.
It is further preferred that the preservative be sorbic acid and ethyl-para-hydroxybenzoate with mass ratio be 3：1 ratio
Mix.
It is further preferred that the preservative be potassium sorbate, salicylic acid and ethyl-para-hydroxybenzoate with mass ratio
It is 2.5：1.5：1 ratio is mixed.
A kind of preparation technology of RIPSTOP thermal transfer ink, comprises the following steps：
Step（1）Prepare disperse dyes mill base：By disperse dyes, dispersant, dispersing aid, NMF and deionized water in proportion
After mixing, grinding in milling apparatus is put into, is ground to particle diameter for 100-800nm；
Step（2) thickener, surface tension modifier, defoamer, preservative, anti-coagulants and deionized water are mixed in proportion,
The mixture of formation stirs under the mixing speed of 100-600r/min；
Step（3) to step（2）Step is added in obtained mixture（1）Obtained disperse dyes mill base, stirs at room temperature
2-6h stands 1-3h again after being well mixed to each component, that is, obtain described intaglio printing printing machine aqueous RIPSTOP heat and turn
Printing ink.
The beneficial effects of the present invention are：Stamp RIPSTOP production technology of the invention, prints to RIPSTOP fabric
Without pre-treatment and Final finishing process during flower, the clean manufacturing of RIPSTOP fabric revenue stamp process can be realized, realize that industry is dirty
Water zero discharge target, and printing quality is excellent, finished product property indices reach the higher standard of coherent detection mechanism（SGS
All standard reaches 4 grades or 4-5 grades）, finished product color fastness is high, and its color transport phenomena is effectively prevented, and properties are accorded with
Close market use requirement；The technological process is simple, small investment, it is adaptable to industrialization and large-scale production.
The thermal transfer ink of the stamp RIPSTOP production technology that the present invention is provided can be applied to intaglio printing printing machine, full
The requirement of the high efficiency of sufficient gravure printing, gravure printing average efficiency can reach 4000-6000 meters/h.
Existing nylon digit printing ink that industry is used or ink main component are with acid dyes or part pigment etc.
Main, disperse dyes are rarely employed because its degree of fixation is too low.And in the special thermal transfer ink of nylon of application involved in the present invention
By the cooperation of contained color fixing agent, dedicated transfer paper and corresponding caloric transfer printing technology, can be good at solving disperse dyes in Buddhist nun
The problems such as color depth, saturation degree, color fastness and colour migration on imperial fabric are moved.
By the color fastness of stamp RIPSTOP fabric obtained in production technology of the invention, including light fastness, dry and wet
Crock fastness, washing fastness, perspiration fastness, soaping fastness etc., reach 4 or 4-5 grades, and color fastness is high, are conducive to extending fabric
Weatherability, colour vividness is good.
Specific embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying is referred to not limitation of the invention.
Embodiment 1
A kind of stamp RIPSTOP production technology, comprises the following steps that：
Step（1）By intaglio printing printing machine by thermal transfer ink to transfer paper；
Step（2）Is transferred to printed patterns on RIPSTOP by caloric transfer printing technology by gained transfer paper, caloric transfer printing technology temperature
It is 180 DEG C to spend, and the thermal transfer time is 60s, and stamp RIPSTOP fabric is obtained；
The thermal transfer ink is comprised the following raw materials by weight percent：Disperse red 86 mill base：30%th, thickener：32%th, moisturizing
Agent glycerine：8%th, defoamer：0.2%th, surface tension modifier：0.3%th, propylparaben：0.02%th, deionized water：
Surplus.
Wherein, disperse red 86 mill base is comprised the following raw materials by weight percent：Disperse red 86：27%th, lignin sulfonic acid
Sodium：18%th, polyesters dispersing aid：1%th, gamma-butyrolacton：1%th, deionized water：Surplus, average grain diameter is 200nm.
Wherein, thickener is comprised the following raw materials by weight percent：Sodium alginate：15%th, polyacrylic resin：9%th, gather
Vinyl alcohol：2%th, deionized water：Surplus.
The defoamer is Defom W-052, and the surface tension modifier is DAPRO®W-77.Polyesters dispersion is helped
Agent is Dispersant 1029.
The intaglio printing printing machine is included with the preparation process of aqueous RIPSTOP thermal transfer ink：Prepare disperse dyes color
Slurry：After disperse red 86, sodium lignin sulfonate, polyesters dispersing aid, gamma-butyrolacton and deionized water are mixed in proportion, put
Enter grinding in milling apparatus；Then by thickener, defoamer, surface tension modifier, deionized water in being mixed in proportion under normal temperature
Conjunction is stirring evenly and then adding into the disperse red 86 mill base for preparing, and 6h is stirred at room temperature, and then stands 2h, obtains final product described heat
Transfer ink.The preparation technology flow is simple, small investment, it is adaptable to industrialization and large-scale production, can produce batch
Can stabilization intaglio printing printing machine with aqueous RIPSTOP thermal transfer ink.
In the present embodiment, intaglio printing printing machine is made with aqueous RIPSTOP thermal transfer ink of disperse dyes, is led to
Gravure printing is crossed and when Thermal-printing Technology carries out printing and dyeing stamp, without pre-treatment and Final finishing process, hence without trade effluent row
Put.
In the present embodiment, it is dispersant that sodium lignin sulfonate is used in disperse dyes mill base, and adds dispersing aid, energy
Enough strengthen the stability and tinting strength, tinting power of disperse dyes, while reducing the damage to printing equipment.
The present invention provide a kind of stamp RIPSTOP production technology, by intaglio printing printing machine to RIPSTOP
Without pre-treatment and finishing process during fabric stamp, the clean manufacturing of RIPSTOP fabric revenue stamp process and anhydrous can be realized
Production, makes its industrial wastewater discharge convergence zero, and printing quality is excellent, and properties meet the requirements, and can effectively improve
Printing and dyeing color fastness of the disperse dyes on RIPSTOP fabric and disperse dyes can be effectively prevented in the color of RIPSTOP fabric
Migration.
The stamp RIPSTOP of the present embodiment is obtained by the stamp RIPSTOP production technology of the present embodiment；Stamp nylon is knitted
The thermal transfer ink that thing production technology is used is applied to intaglio printing printing machine.
Embodiment 2
A kind of stamp RIPSTOP production technology, comprises the following steps that：
Step（1）By intaglio printing printing machine by thermal transfer ink to transfer paper；
Step（2）Is transferred to printed patterns on RIPSTOP by caloric transfer printing technology by gained transfer paper, caloric transfer printing technology temperature
It is 190 DEG C to spend, and the thermal transfer time is 50s, and stamp RIPSTOP fabric is obtained；
The thermal transfer ink is comprised the following raw materials by weight percent：Dispersion yellow 64 mill base：33%th, thickener：35%th, moisturizing
Agent D-sorbite：7%th, defoamer：0.2%th, surface tension modifier：0.3%th, propylparaben：0.02%th, deionization
Water：Surplus.
Wherein, dispersion yellow 64 mill base is comprised the following raw materials by weight percent：Dispersion yellow 64：28%th, lignin sulfonic acid
Sodium：17%th, polyesters dispersing aid：1%th, ethyl pyrrolidone：1.5%th, deionized water：Surplus, average grain diameter is 200nm.
Wherein, thickener is comprised the following raw materials by weight percent：Sodium alginate：15%th, polyacrylic resin：7%th, gather
Vinyl alcohol：4%th, polyurethane：2%th, deionized water：Surplus.
The defoamer is Defom W-074, and the surface tension modifier is DAPRO®W-77.Polyesters dispersion is helped
Agent is Dispersant 5040.
Remaining content of the present embodiment is same as Example 1, repeats no more here.
Embodiment 3
A kind of stamp RIPSTOP production technology, comprises the following steps that：
Step（1）By intaglio printing printing machine by thermal transfer ink to transfer paper；
Step（2）Is transferred to printed patterns on RIPSTOP by caloric transfer printing technology by gained transfer paper, caloric transfer printing technology temperature
It is 200 DEG C to spend, and the thermal transfer time is 45s, and stamp RIPSTOP fabric is obtained；
The thermal transfer ink is comprised the following raw materials by weight percent：The mill base of disperse blue 124：30%th, thickener：30%th, protect
Humectant diethylene glycol (DEG) 10%, defoamer：0.2%th, surface tension modifier：0.3%th, propylparaben：0.02%th, deionization
Water：Surplus.
Wherein, the mill base of disperse blue 124 is comprised the following raw materials by weight percent：Disperse blue 124：27%th, lignin sulfonic acid
Sodium：18%th, polyesters dispersing aid Dispersant 1027：1%th, polysorbas20：0.5%th, deionized water：Surplus, average grain diameter is
230nm。
Wherein, thickener is comprised the following raw materials by weight percent：Carboxymethylcellulose calcium：15%th, polyacrylic resin：
7%th, polyvinyl alcohol：5%th, deionized water：Surplus.
The defoamer is Defom W-082, and the surface tension modifier is commercially available fluorine-containing nonionic class surface
Power conditioning agent.
Remaining content of the present embodiment is same as Example 1, repeats no more here.
Embodiment 4
A kind of stamp RIPSTOP production technology, comprises the following steps that：
Step（1）By intaglio printing printing machine by thermal transfer ink to transfer paper；
Step（2）Is transferred to printed patterns on RIPSTOP by caloric transfer printing technology by gained transfer paper, caloric transfer printing technology temperature
It is 210 DEG C to spend, and the thermal transfer time is 40s, and stamp RIPSTOP fabric is obtained；
The thermal transfer ink is comprised the following raw materials by weight percent：The mill base of disperse orange 149：33%th, thickener：30%th, protect
Humectant propane diols：11%th, defoamer：0.2%th, surface tension modifier：0.3%th, polyethers dispersing aid Houtch D-127：
0.3%th, propylparaben：0.02%th, deionized water：Surplus.
Wherein, black 9 mill base is disperseed to comprise the following raw materials by weight percent：Disperse orange 149：28%th, lignin sulfonic acid
Sodium：17%th, polyesters dispersing aid：1.5%th, gamma-butyrolacton：0.5%th, deionized water：Surplus, average grain diameter is 230nm.
Wherein, thickener is comprised the following raw materials by weight percent：Starch：13%th, polyacrylic resin：8%th, polyethylene
Alcohol：4%th, deionized water：Surplus.
The defoamer is DAPRO®AP 7015, the surface tension modifier is DAPRO® W-77。
Remaining content of the present embodiment is same as Example 1, repeats no more here.
Embodiment 5
A kind of stamp RIPSTOP production technology, comprises the following steps that：
Step（1）By intaglio printing printing machine by thermal transfer ink to transfer paper；
Step（2）Is transferred to printed patterns on RIPSTOP by caloric transfer printing technology by gained transfer paper, caloric transfer printing technology temperature
It is 210 DEG C to spend, and the thermal transfer time is 30s, and stamp RIPSTOP fabric is obtained；
The mill base of disperse violet 26：25%th, thickener：35%th, NMF polyethylene glycol：15%th, defoamer：0.3%th, surface tension adjustment
Agent：0.5%th, potassium sorbate：0.2%th, deionized water：Surplus.
Wherein, disperse red 60 mill base is comprised the following raw materials by weight percent：Disperse violet 26：20%th, lignin sulfonic acid
Sodium：25%th, polyethers dispersing aid：2%th, methyl pyrrolidone：1%th, deionized water：Surplus, average grain diameter is 250nm.
Wherein, thickener is comprised the following raw materials by weight percent：Sodium alginate：15%th, polyurethane：8%th, polyethylene
Alcohol：4%th, deionized water：Surplus.
The defoamer is DAPRO®DF 1760, the surface tension modifier is DAPRO®W-77.Polyethers are disperseed
Auxiliary agent is Houtch D-156.
Remaining content of the present embodiment is same as Example 1, repeats no more here.
Embodiment 6
A kind of stamp RIPSTOP production technology, comprises the following steps that：
Step（1）By intaglio printing printing machine by thermal transfer ink to transfer paper；
Step（2）Is transferred to printed patterns on RIPSTOP by caloric transfer printing technology by gained transfer paper, caloric transfer printing technology temperature
It is 220 DEG C to spend, and the thermal transfer time is 25s, and stamp RIPSTOP fabric is obtained；
The thermal transfer ink is comprised the following raw materials by weight percent：The mill base of disperse yellow 163：40%th, thickener：25%th, protect
Humectant polypropylene glycol：12%th, defoamer：0. 3%, surface tension modifier：0.2%th, sorbic acid：0.1%th, to hydroxy carboxylic acid ethyl ester：
0.2%th, deionized water：Surplus.
Wherein, the mill base of disperse yellow 163 is comprised the following raw materials by weight percent：Disperse yellow 163：20%th, lignin sulfonic acid
Sodium：15%th, polyesters dispersing aid：2%、PEG 200：1%th, deionized water：Surplus, average grain diameter is 320nm.
Wherein, thickener is comprised the following raw materials by weight percent：Carboxymethylcellulose calcium：15%th, polyurethane：8%th, poly- second
Enol：4%th, deionized water：Surplus.
The defoamer is Defom 2700, and the surface tension modifier is DAPRO®W-77.Polyethers dispersing aid
It is Houtch D-160.
The physical property of stamp RIPSTOP test is as shown in table 1 obtained in 1-embodiment of the embodiment of the present invention 6, wherein
Test temperature is 20 DEG C.
Table 1
In fabric stamp of the use intaglio printing printing machine to RIPSTOP, the properties of decalcomania and ink meet
It is required that, can effectively improve printing and dyeing color fastness of the disperse dyes on RIPSTOP fabric and prevent disperse dyes in RIPSTOP
The colour migration of fabric is moved.
The light fastness of stamp RIPSTOP fabric, dry fastness, wet friction jail obtained in embodiments of the invention 1-6
Degree, washing fastness, perspiration fastness, soaping fastness reach 4-5 grades, and light fastness is 4 grades, and color fastness is high, is conducive to elongated surfaces
The weatherability of material, it is to avoid colour migration is moved, colour vividness is good.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can be realized with other manner,
Any obvious replacement is within protection scope of the present invention on the premise of not departing from present inventive concept.
Claims (10)
1. a kind of stamp RIPSTOP production technology, it is characterised in that：Comprise the following steps that：
Step（1）By intaglio printing printing machine by thermal transfer ink to transfer paper；
Step（2）Is transferred to printed patterns on RIPSTOP by caloric transfer printing technology by gained transfer paper, stamp nylon is obtained
Fabric；
The thermal transfer ink is comprised the following raw materials by weight percent：
Disperse dyes mill base：15-35%
Thickener：15-35%
NMF：0-25%
Surface tension modifier：0.1-1%
Defoamer：0.01-0.5%
Preservative：0.01-0.5%
Anti-coagulants：0.01-1%
Deionized water：Surplus.
2. a kind of stamp RIPSTOP production technology according to claim 1, it is characterised in that：The step（2）Middle heat
Transfer printing process temperature is 180-220 DEG C, and the operating time is 25-60s.
3. a kind of stamp RIPSTOP production technology according to claim 1, it is characterised in that：The disperse dyes mill base
Comprise the following raw materials by weight percent：
Disperse dyes：15-35%
Dispersant：5-25%
Dispersing aid：0.5-5%
Deionized water：Surplus；
Wherein, the disperse dyes mill base is formed by disperse dyes, dispersant, dispersing aid and deionized water mixed grinding.
4. a kind of stamp RIPSTOP production technology according to claim 3, it is characterised in that：The dispersant is wooden
Plain sodium sulfonate；The dispersing aid is polyester polymer, polyether-based polymers, methyl pyrrolidone, ethyl pyrrolidone, two
One or more in ethylene glycol monobutyl ether, dimethyl ether, gamma-butyrolacton, alpha-pyrrolidone.
5. a kind of stamp RIPSTOP production technology according to claim 1, it is characterised in that：The thickener is by following
The raw material composition of percentage by weight：
Thickener：10-30%；
Deionized water：Surplus；
Wherein, the thickener is sodium alginate, carboxymethylcellulose calcium, starch, Chinese honey locust glue, polyvinyl acetate, polyurethane, poly- second
At least one in enol, polyacrylic resin.
6. a kind of stamp RIPSTOP production technology according to claim 1, it is characterised in that：The NMF is two sweet
One kind in alcohol, glycerine, butanediol, polyethylene glycol, propane diols, hexylene glycol, xylitol, polypropylene glycol, D-sorbite or two
Plant the mixture of the above.
7. a kind of stamp RIPSTOP production technology according to claim 1, it is characterised in that：The surface tension adjustment
Agent is at least one in fluorine-containing nonionic class surface tension modifier.
8. a kind of stamp RIPSTOP production technology according to claim 1, it is characterised in that：The defoamer is organic
At least one in silicon class defoamer, non-organic silicon class defoamer；
The preservative be potassium sorbate, sorbic acid, salicylic acid, ethyl-para-hydroxybenzoate, propylparaben, to hydroxyl
At least one in yl benzoic acid butyl ester.
9. a kind of a kind of stamp RIPSTOP, the stamp RIPSTOP production technology as described in claim any one of 1-8 is obtained.
10. the application of the thermal transfer ink of a kind of stamp RIPSTOP production technology as described in claim any one of 1-8, should
For intaglio printing printing machine.
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| CN201611209315.2A CN106758422A (en) | 2016-12-23 | 2016-12-23 | The application of stamp RIPSTOP and its production technology and thermal transfer ink |
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| CN201611209315.2A CN106758422A (en) | 2016-12-23 | 2016-12-23 | The application of stamp RIPSTOP and its production technology and thermal transfer ink |
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