CN106758326A - The application of RIPSTOP and its stamp production technology and the special thermal transfer ink of nylon - Google Patents
The application of RIPSTOP and its stamp production technology and the special thermal transfer ink of nylon Download PDFInfo
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- CN106758326A CN106758326A CN201611208296.1A CN201611208296A CN106758326A CN 106758326 A CN106758326 A CN 106758326A CN 201611208296 A CN201611208296 A CN 201611208296A CN 106758326 A CN106758326 A CN 106758326A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
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- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5228—Polyalkenyl alcohols, e.g. PVA
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5271—Polyesters; Polycarbonates; Alkyd resins
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
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- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
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- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
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Abstract
The present invention relates to printing technology technical field, and in particular to the application of RIPSTOP and its stamp production technology and the special thermal transfer ink of nylon, the RIPSTOP stamp production technology is comprised the following steps：By digit printing printer by thermal transfer ink printed to transfer paper, be transferred to print pattern on RIPSTOP by caloric transfer printing technology by gained transfer paper, nylon printing fabric is obtained；The special thermal transfer ink of the nylon is comprised the following raw materials by weight percent：Disperse dyes mill base 20 40%, color fixing agent 1 10%, NMF 10 30%, surface tension modifier 0.01 0.1%, defoamer 0.01 0.5%, preservative 0.01 0.5%, deionized water surplus.The present invention can realize the clean manufacturing of RIPSTOP fabric revenue stamp process, realize trade effluent zero-emission target, and printing effect is good, and finished product color fastness is high, and properties meet market use requirement.
Description
Technical field
The present invention relates to printing technology technical field, and in particular to RIPSTOP and its stamp production technology and nylon are special
The application of thermal transfer ink.
Background technology
Conventional nylon fabric printing and dyeing stamp generally uses acid dyes mill base or ink, and needs by starching
The pre-treatments such as Final finishing process, the starching work such as evaporating, rinse Deng pre-treatment and high temperature can avoid acid dyes mill base or ink
The flushing on fabric, high temperature such as evaporates at the Final finishing process can effectively improve the color fastness of printing and dyeing PRINTED FABRIC.However, before fabric
Treatment and postfinishing process need to use substantial amounts of water, just inevitable in conventional nylon fabric printing and dyeing stamp production process
Ground produces substantial amounts of trade effluent, and colour migration shifting easily occurs in gained finished product, influences the presentation quality of product, and conventional nylon fabric
Printing technology is complicated, and production cost is high.
The content of the invention
An object of the present invention is to provide a kind of RIPSTOP stamp production technology, makes RIPSTOP fabric stamp process
Hoop structure is realized, while Simplified flowsheet, reduces production cost.
The second object of the present invention is to provide a kind of nylon printing fabric, the nylon print as obtained in above-mentioned stamp production technology
Loom figured color fastness is high.
The third object of the present invention is to provide a kind of with the nylon merged suitable for the RIPSTOP stamp production technology
Special thermal transfer ink, can be applied to digit printing printer, meet the high-precision requirement of digit printing, ink good weatherability.
To achieve the above object, the technical solution adopted by the present invention is as follows.
A kind of RIPSTOP stamp production technology, comprises the following steps that：
Step（1）By digital-code printer by thermal transfer ink printed to transfer paper, print pattern is formed with transfer paper；Beat
Shape and color for being patterned etc. have been designed on digital-code printer and associate device in advance, and digital-code printer is existing skill
Art, its concrete application method will not be repeated here；
Step（2）Is transferred to print pattern on RIPSTOP by caloric transfer printing technology by gained transfer paper, nylon printing is obtained
Fabric；The special thermal transfer ink of nylon is comprised the following raw materials by weight percent：
Disperse dyes mill base：20-40%；
Color fixing agent：1-10%；
NMF：10-30%；
Surface tension modifier：0.01-0.1%；
Defoamer：0.01-0.5%；
Preservative：0.01-0.5%；
Deionized water：Surplus.
Specifically, step（1）Be using digit printing printer by thermal transfer ink printed to containing coating transfer paper on,
The grammes per square metre of transfer paper is 58-100g/m2, weight ratio about 5% shared by coating, thermal transfer ink by printing device be attached to containing apply
On the transfer paper of layer, then print pattern is transferred on RIPSTOP fabric by caloric transfer printing technology.Further, the transfer
Paper is common transfer paper or nylon dedicated transfer paper, and dedicated transfer paper is preferably South Korea's Han Song paper industry（Hansol Paper）Production
The special thermal dye sublimation transfer printing paper of nylon, in this way, gained nylon printing textile design color saturation is good, reduction degree is high, color fastness
High and good weatherability.The special thermal transfer ink of nylon of the invention is used cooperatively with transfer paper, good transferring effect, the blotting of paper
Amount is few, saving ink, can effectively reduce production cost.
It is highly preferred that the thermal transfer ink is comprised the following raw materials by weight percent：
Disperse dyes mill base：25-35%；
Color fixing agent：2-8%；
NMF：10-25%；
Surface tension modifier：0.01-0.1%；
Defoamer：0.01-0.5%；
Preservative：0.01-0.5%；
Deionized water：Surplus.
Wherein, the step（2）Middle caloric transfer printing technology temperature is 180-220 DEG C, and the operating time is 25-60s.More preferably
Ground, operation temperature and time are respectively 190-200 DEG C and 40-50s.Specifically, by step（1）The decal transfer paper of preparation and Buddhist nun
Imperial fabric is stacked together in the thermal transfer equipment for being introduced into and setting operating condition in advance, and applying pressure by the external world ensures that heat turns
Printing ink is effectively transferred on nylon facing material.
Preferably, the disperse dyes mill base is comprised the following raw materials by weight percent：
Disperse dyes：15-35%；
Dispersant：5-25%；
Dispersing aid：15-35%；
Deionized water：Surplus；
Wherein, the disperse dyes mill base is formed by disperse dyes, dispersant, dispersing aid and deionized water mixed grinding.
Further, the grinding particle diameter of the disperse dyes mill base is 60-200nm.
Preferably, the disperse dyes be Red-1 200 9, disperse red 53, disperse red 54, disperse red 60, disperse red 86, point
Dissipate red 118, Red-1 200 79, disperse yellow 54, dispersion yellow 64, disperse yellow 79, disperse yellow 104, disperse yellow 163, disperse yellow 232, point
Dissipate blue 7, disperse blue 14, disperse blue 26, disperse blue 72, Disperse Blue-79, disperse blue 124, disperse blue 359, disperse orange 11, disperse orange
13rd, in disperse orange 29, disperse orange 31, disperse orange 73, disperse orange 149, disperse violet 17, disperse violet 26, disperse violet 28, disperse violet 63
At least one.Preferably, the dispersant is sodium lignin sulfonate.
Preferably, the dispersing aid is polyesters dispersing aid, polyethers dispersing aid, methyl pyrrolidone, ethyl
Pyrrolidones, diethylene glycol monobutyl ether, dimethyl ether, gamma-butyrolacton, PEG200, PEG2000, alpha-pyrrolidone, in
At least one.
Polyesters dispersing aid refers to the aqueous solution of lipin polymer, can be specifically Dispersant 5040,
At least one in Dispersant 1027, Dispersant 1029.
Polyethers dispersing aid refers to the aqueous solution of ethers copolymer.Can be specifically Houtch D-127, Houtch D-
156th, at least one in Houtch D-160.
It is dispersant that sodium lignin sulfonate is used in disperse dyes mill base, and adds dispersing aid, can strengthen dispersion
The stability and tinting strength, tinting power of dyestuff.
Preferably, the color fixing agent is comprised the following raw materials by weight percent：
Resin：5-15%；
Deionized water：Surplus；
Wherein, the resin is at least one in polyvinyl acetate, polyurethane, polyvinyl alcohol, polyacrylic resin.
Preferably, the resin be polyvinyl acetate and polyurethane with mass ratio be 2.3：1.8 ratio is mixed.
It is highly preferred that the resin be polyurethane, polyvinyl alcohol and polyacrylic resin with mass ratio be 2.2：1：1.5
Ratio is mixed.
It is further preferred that the resin be polyvinyl acetate, polyurethane, polyvinyl alcohol and polyacrylic resin with matter
Amount is than being 2：1.2：0.5：1.6 ratio is mixed.
Preferably, the NMF is glycerine, butanediol, polyethylene glycol, propane diols, hexylene glycol, xylitol, poly- the third two
At least one in alcohol, D-sorbite.
It is highly preferred that the NMF be D-sorbite and butanediol with mass ratio be 2：1.3 ratio is mixed.
It is further preferred that the NMF be glycerine and butanediol with mass ratio be 1.6：1.1 ratio mixing and
Into.
It is further preferred that the NMF be polyethylene glycol, propane diols and xylitol with mass ratio be 2.3：1.3：1
Ratio mix.
It is highly preferred that the NMF be propane diols, hexylene glycol, xylitol and D-sorbite with mass ratio be 3：2：1.5：
1 ratio is mixed.
Preferably, the surface tension modifier is at least one in fluorine-containing nonionic class surface tension modifier.
Specifically, fluorine-containing nonionic class surface tension modifier is DAPRO®W-77, can be with aqueous and solvent-based system
The performance of excellent reduction surface tension is provided, is strengthened soaking with this, disperseed, levelling and other surfaces performance.DAPRO® W-77
Without any VOC（VOC）, without APEO（APES）, non-flammable product, can with it is any from
The surfactant of sub- property is compatible.Certainly, surface tension modifier of the invention can also be other commercially available fluorine-containing nonionics
Class surface tension modifier.
Preferably, the defoamer is at least one in organic silicon defoamer, non-organic silicon class defoamer；
Organic silicon defoamer can be specifically at least one in Defom W-052, Defom W-074, Defom W-082.
It is non-that to have silicon class defoamer can be specifically DAPRO® AP 7015、DAPRO®In DF 1760, Defom 2700
It is at least one.
Certainly, defoamer of the invention can also be commercially available textile printing and dyeing organic silicon defoamer or non-organic silicon class
Defoamer.
Preferably, the preservative be potassium sorbate, sorbic acid, ethyl-para-hydroxybenzoate, propylparaben,
At least one in butyl p-hydroxybenzoate；
It is highly preferred that the preservative is potassium sorbate.
It is further preferred that the preservative be sorbic acid, ethyl-para-hydroxybenzoate with mass ratio be 3：1 ratio is mixed
Conjunction is formed.
It is further preferred that the preservative be potassium sorbate, salicylic acid and ethyl-para-hydroxybenzoate with mass ratio
It is 2.5：1.5：1 ratio is mixed.
The preparation technology of the special thermal transfer ink of nylon, comprises the following steps：
Step（1）Prepare disperse dyes mill base：After disperse dyes, dispersant, dispersing aid and deionized water are mixed in proportion,
Grinding in milling apparatus is put into, particle diameter is ground to for 60-200nm；
Step（2）Prepare color fixing agent：After resin, deionized water are mixed in proportion, heating stirring to resin is completely dissolved；
Step（3）By color fixing agent, NMF, bactericide, surface tension modifier, defoamer, preservative, anti-coagulants and deionization
Water mixes in proportion, and the mixture of formation stirs under the mixing speed of 100-600r/min；
Step（4）To step（3）Step is added in obtained mixture（1）Obtained disperse dyes mill base, stirs at room temperature
2-6h stands 1-3h after being well mixed to each component, then with 0.2-0.4 μm of membrane filtration, that is, obtains described nylon special
Thermal transfer ink.
The beneficial effects of the present invention are：A kind of RIPSTOP stamp production technology that the present invention is provided, knits to nylon
Without pre-treatment and Final finishing process during object plane material stamp, the clean manufacturing of RIPSTOP fabric revenue stamp process can be realized, it is real
Existing trade effluent zero-emission target；And printing quality is excellent, finished product property indices reach the higher of coherent detection mechanism
Standard（SGS all standards reach 4 grades or 4-5 grades）, color fastness is high, and its color transport phenomena is effectively prevented.The technique stream
Journey is simple, small investment, it is adaptable to industrialization and large-scale production.
The special thermal transfer ink of nylon involved in the present invention can be applied to digit printing printer, meet high accuracy stamp
It is required that.
Existing nylon digit printing ink that industry is used or ink main component are with acid dyes or part pigment etc.
Main, disperse dyes are rarely employed because its degree of fixation is too low.And in the special thermal transfer ink of nylon of application involved in the present invention
By the cooperation of contained color fixing agent, dedicated transfer paper and corresponding caloric transfer printing technology, can be good at solving disperse dyes in Buddhist nun
The problems such as color depth, saturation degree, color fastness and colour migration on imperial fabric are moved.
The color fastness of nylon printing fabric as obtained by the present invention, including light fastness, dry and wet crock fastness, washing
Fastness, perspiration fastness, soaping fastness etc., reach 4 or 4-5 grades.
Specific embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying is referred to not limitation of the invention.
Embodiment 1
A kind of RIPSTOP stamp production technology, comprises the following steps that：
Step（1）By digit printing printer by thermal transfer ink printed to transfer paper；
Step（2）Is transferred to print pattern on RIPSTOP by caloric transfer printing technology by gained transfer paper, operation temperature and when
Between be respectively 180 DEG C and 60s, nylon printing fabric is obtained；
The thermal transfer ink is comprised the following raw materials by weight percent：The mill base of dispersion red 11 8：30%th, D-sorbite：10%、
Butanediol：10%th, color fixing agent：3%th, defoamer：0.02%th, surface tension modifier：0.03%th, deionized water：Surplus.
Wherein, the mill base of dispersion red 11 8 is comprised the following raw materials by weight percent：Disperse red 86：21%th, lignin sulfonic acid
Sodium：17%th, polyesters dispersing aid：15%th, gamma-butyrolacton：7%th, deionized water：Surplus, average grain diameter is 65nm.
Wherein, color fixing agent is comprised the following raw materials by weight percent：Polyacrylic resin：8%th, polyvinyl alcohol：4%th, go
Ionized water：Surplus.
The defoamer is Defom W-052, and the surface tension modifier is DAPRO®W-77.Polyesters dispersion is helped
Agent is Dispersant 5040.
The preparation process of the thermal transfer ink includes：Prepare disperse dyes mill base：By dispersion red 11 8, sodium lignin sulfonate,
After polyesters dispersing aid, gamma-butyrolacton and deionized water mix in proportion, grinding in milling apparatus is put into；Then by fixation
Agent, defoamer, surface tension modifier, deionized water in adding the dispersion for preparing after mixing and stirring in proportion under normal temperature
Red 118 mill base, and 6h is stirred at room temperature, then stand 2h and filtered with 0.4 μm of glass fiber filter, obtain final product described thermal transfer
Ink.The preparation technology flow is simple, small investment, it is adaptable to industrialization and large-scale production, can produce batch performance steady
The special thermal transfer ink of fixed nylon.
In the present embodiment, using the special thermal transfer ink of nylon, stamp, nothing are carried out by digital printing and Thermal-printing Technology
Pre-treatment and Final finishing process, hence without industrial wastewater discharge.
In the present embodiment, it is dispersant that sodium lignin sulfonate is used in disperse dyes mill base, and adds dispersing aid, energy
Enough strengthen the stability and tinting strength, tinting power of disperse dyes.
A kind of RIPSTOP stamp production technology that the present invention is provided, during without pre-treatment and Final finishing process, can be real
The clean manufacturing of existing RIPSTOP fabric revenue stamp process, realizes trade effluent zero-emission target, and printing quality of printing and dyeing is good,
Finished product items test index is high, and color transport phenomena is also effectively prevented.
Embodiment 2
A kind of RIPSTOP stamp production technology, comprises the following steps that：
Step（1）By digital-code printer by thermal transfer ink printed to transfer paper；
Step（2）Is transferred to print pattern on RIPSTOP by caloric transfer printing technology by gained transfer paper, operation temperature and when
Between be respectively 190 DEG C and 50s, nylon printing fabric is obtained；The thermal transfer ink by following percentage by weight raw material
Composition：The mill base of disperse yellow 104：32%th, D-sorbite：10%th, butanediol：10%th, color fixing agent：3%th, defoamer：0.02%th, surface
Power conditioning agent：0.3%th, deionized water：Surplus.
Wherein, the mill base of disperse yellow 104 is comprised the following raw materials by weight percent：Dispersion yellow 64：24%th, lignin sulfonic acid
Sodium：21%th, polyesters dispersing aid：18%th, deionized water：Surplus, average grain diameter is 100nm.
Wherein, color fixing agent is comprised the following raw materials by weight percent：Polyacrylic resin：8%th, polyvinyl alcohol：4%th, gather
Urethane：1%th, deionized water：Surplus.The defoamer is Defom W-074, and the surface tension modifier is commercially available fluorine-containing
Nonionic class surface tension modifier.Polyesters dispersing aid is Dispersant 1027.
Remaining content of the present embodiment is same as Example 1, repeats no more here.
Embodiment 3
A kind of RIPSTOP stamp production technology, comprises the following steps that：
Step（1）By digit printing printer by thermal transfer ink printed to transfer paper；
Step（2）Is transferred to print pattern on RIPSTOP by caloric transfer printing technology by gained transfer paper, operation temperature and when
Between be respectively 200 DEG C and 45s, nylon printing fabric is obtained；The thermal transfer ink by following percentage by weight raw material
Composition：Disperse Blue-79 mill base：35%th, D-sorbite：10%th, butanediol：10%th, color fixing agent：3.5%th, defoamer：0.02%th, surface
Power conditioning agent：0.2%th, deionized water：Surplus.
Wherein, Disperse Blue-79 mill base is comprised the following raw materials by weight percent：Disperse blue 124：23%th, lignin sulfonic acid
Sodium：21%th, polyethers dispersing aid：16%th, gamma-butyrolacton：7%th, deionized water：Surplus, average grain diameter is 130nm.
Wherein, color fixing agent is comprised the following raw materials by weight percent：Polyacrylic resin：7%th, polyvinyl alcohol：4%th, gather
Urethane：2%th, deionized water：Surplus.
The defoamer is Defom W-082, and the surface tension modifier is DAPRO W-77.Polyethers dispersion is helped
Agent is Houtch D-127.
Remaining content of the present embodiment is same as Example 1, repeats no more here.
Embodiment 4
A kind of RIPSTOP stamp production technology, comprises the following steps that：
Step（1）By digital-code printer by thermal transfer ink printed to transfer paper；
Step（2）Is transferred to print pattern on RIPSTOP by caloric transfer printing technology by gained transfer paper, operation temperature and when
Between be respectively 210 DEG C and 40s, nylon printing fabric is obtained；The thermal transfer ink by following percentage by weight raw material
Composition：The mill base of disperse orange 31：33.5%th, glycerine：10%th, butanediol：10%th, color fixing agent：3.5%th, defoamer：0.02%th, surface
Power conditioning agent：0.2%th, deionized water：Surplus.
Wherein, the mill base of disperse orange 3 is comprised the following raw materials by weight percent：Disperse black 9：24%th, sodium lignin sulfonate：
21%th, polyethers dispersing aid：15%th, gamma-butyrolacton：7%th, deionized water：Surplus, average grain diameter is 135nm.
Wherein, color fixing agent is comprised the following raw materials by weight percent：Polyacrylic resin：8%th, polyvinyl alcohol：4%th, go
Ionized water：Surplus.
The defoamer is DAPRO®AP 7015, the surface tension modifier is DAPRO W-77.Polyethers point
It is Houtch D-156 to dissipate auxiliary agent.
Remaining content of the present embodiment is same as Example 1, repeats no more here.
Embodiment 5
A kind of RIPSTOP stamp production technology, comprises the following steps that：
Step（1）By digit printing printer by thermal transfer ink printed to transfer paper；
Step（2）Is transferred to print pattern on RIPSTOP by caloric transfer printing technology by gained transfer paper, operation temperature and when
Between be respectively 210 DEG C and 30s, nylon printing fabric is obtained；The thermal transfer ink by following percentage by weight raw material
Composition：The mill base of disperse violet 63：25%th, polyethylene glycol：10%th, hexylene glycol：10%th, D-sorbite：5%th, color fixing agent：3.5%th, defoamer：
0.02%th, surface tension modifier：0.1%th, potassium sorbate：0.3%th, deionized water：Surplus.
Wherein, the mill base of disperse violet 63 is comprised the following raw materials by weight percent：Disperse red 60：20%th, lignin sulfonic acid
Sodium：25%th, polyethers dispersing aid：16%th, methyl pyrrolidone：7%th, deionized water：Surplus, average grain diameter is 150nm.
Wherein, color fixing agent is comprised the following raw materials by weight percent：Polyurethane：8%th, polyvinyl alcohol：4%th, deionized water：
Surplus.The defoamer is DAPRO®DF 1760, the surface tension modifier is DAPRO W-77.Polyethers dispersion is helped
Agent is Houtch D-160.
Remaining content of the present embodiment is same as Example 1, repeats no more here.
Embodiment 6
A kind of RIPSTOP stamp production technology, comprises the following steps that：
Step（1）By digital-code printer by thermal transfer ink printed to transfer paper；
Step（2）Is transferred to print pattern on RIPSTOP by caloric transfer printing technology by gained transfer paper, operation temperature and when
Between be respectively 220 DEG C and 25s, nylon printing fabric is obtained；The thermal transfer ink by following percentage by weight raw material
Composition：The mill base of Red-1 200 79：40%th, xylitol：10%th, butanediol：10%th, color fixing agent：3.5%th, defoamer：0.02%th, surface
Power conditioning agent：0.4%th, sorbic acid：0.1%th, to hydroxy carboxylic acid ethyl ester：0.2%th, deionized water：Surplus.
Wherein, the mill base of Red-1 200 79 is comprised the following raw materials by weight percent：Disperse yellow 163：20%th, lignin sulfonic acid
Sodium：15%th, polyesters dispersing aid：16%、PEG200：7%th, deionized water：Surplus, average grain diameter is 200nm.
Wherein, color fixing agent is comprised the following raw materials by weight percent：Polyacrylic resin：8%th, polyvinyl alcohol：4%th, go
Ionized water：Surplus.
The defoamer is Defom 2700, and the surface tension modifier is DAPRO W-77.Polyesters dispersion is helped
Agent is Dispersant 1029.
The physical property of nylon printing fabric test is as shown in table 1 obtained in 1-embodiment of the embodiment of the present invention 6,
Wherein test temperature is 20 DEG C.
Table 1
| Detection project | Surface tension（mN/m） | Electrical conductivity（mS/cm） | Viscosity（cP） |
| Embodiment 1 | 37 | 6.8 | 2.6 |
| Embodiment 2 | 39 | 7.4 | 2.3 |
| Embodiment 3 | 43 | 6.1 | 2.5 |
| Embodiment 4 | 40 | 5.8 | 2. 3 |
| Embodiment 5 | 44 | 6.3 | 2.4 |
| Embodiment 6 | 45 | 6.5 | 2.5 |
Using the special thermal transfer ink of nylon through a kind of RIPSTOP stamp production technology of the present invention, obtained nylon
PRINTED FABRIC fabric decalcomania high precision, color rendition degree is high, and finished product property indices meet the requirements, and its colour migration is moved
Phenomenon is effectively prevented.
Nylon printing fabric color fastness is high obtained in embodiments of the invention 1-6, its light fastness, dry and wet friction jail
Degree, washing fastness, perspiration fastness, soaping fastness etc., reach 4 or 4-5 grades.Finished product good weatherability, and colourless migration, overall matter
Amount is high.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can be realized with other manner,
Any obvious replacement is within protection scope of the present invention on the premise of not departing from present inventive concept.
Claims (10)
1. a kind of RIPSTOP stamp production technology, it is characterised in that：Comprise the following steps that：
Step（1）By digit printing printer by thermal transfer ink printed to transfer paper；
Step（2）Is transferred to print pattern on RIPSTOP by caloric transfer printing technology by gained transfer paper, nylon printing is obtained
Fabric；The thermal transfer ink is comprised the following raw materials by weight percent：
Disperse dyes mill base：20-40%
Color fixing agent：1-10%
NMF：10-30%
Surface tension modifier：0.01-0.1%
Defoamer：0.01-0.5%
Preservative：0.01-0.5%
Deionized water：Surplus.
2. a kind of RIPSTOP stamp production technology according to claim 1, it is characterised in that：The step（2）Middle heat
Transfer printing process temperature is 180-220 DEG C, and the operating time is 25-60s.
3. a kind of RIPSTOP stamp production technology according to claim 1, it is characterised in that：The disperse dyes mill base
Comprise the following raw materials by weight percent：
Disperse dyes：15-35%
Dispersant：5-25%
Dispersing aid：15-35%
Deionized water：Surplus
Wherein, the disperse dyes mill base is formed by disperse dyes, dispersant, dispersing aid and deionized water mixed grinding.
4. a kind of RIPSTOP stamp production technology according to claim 3, it is characterised in that：The dispersant is wooden
Plain sodium sulfonate；The dispersing aid is polyesters dispersing aid, polyethers dispersing aid, methyl pyrrolidone, ethyl pyrrolidine
In ketone, diethylene glycol monobutyl ether, dimethyl ether, gamma-butyrolacton, PEG200, PEG2000, alpha-pyrrolidone at least
It is a kind of.
5. a kind of RIPSTOP stamp production technology according to claim 1, it is characterised in that：The color fixing agent is by following
The raw material composition of percentage by weight：
Resin：5-15%
Deionized water：Surplus；
Wherein, the resin is at least one in polyvinyl acetate, polyurethane, polyvinyl alcohol, polyacrylic resin.
6. a kind of RIPSTOP stamp production technology according to claim 1, it is characterised in that：The NMF is the third three
At least one in alcohol, butanediol, polyethylene glycol, propane diols, hexylene glycol, xylitol, polypropylene glycol, D-sorbite.
7. a kind of RIPSTOP stamp production technology according to claim 1, it is characterised in that：The surface tension adjustment
Agent is at least one in fluorine-containing nonionic class surface tension modifier.
8. a kind of RIPSTOP stamp production technology according to claim 1, it is characterised in that：The defoamer is organic
At least one in silicon class defoamer, non-organic silicon class defoamer；
The preservative be potassium sorbate, sorbic acid, salicylic acid, ethyl-para-hydroxybenzoate, propylparaben, to hydroxyl
At least one in yl benzoic acid butyl ester.
9. a kind of a kind of RIPSTOP, the RIPSTOP stamp production technology as described in claim any one of 1-8 is obtained.
10. the special thermal transfer ink of nylon of a kind of RIPSTOP stamp production technology as described in claim any one of 1-8
Application, be applied to digit printing printer.
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