CN108583032A - A kind of side pressure printer carbon ribbon and preparation method thereof - Google Patents
A kind of side pressure printer carbon ribbon and preparation method thereof Download PDFInfo
- Publication number
- CN108583032A CN108583032A CN201810338348.XA CN201810338348A CN108583032A CN 108583032 A CN108583032 A CN 108583032A CN 201810338348 A CN201810338348 A CN 201810338348A CN 108583032 A CN108583032 A CN 108583032A
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- carbon ribbon
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J31/00—Ink ribbons; Renovating or testing ink ribbons
- B41J31/05—Ink ribbons having coatings other than impression-material coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J31/00—Ink ribbons; Renovating or testing ink ribbons
Abstract
A kind of side pressure printer carbon ribbon and preparation method thereof, which, which presses carbon ribbon, is made of basement membrane, release layer, thermal transfer ink layer, refractory layer.Thermal transfer ink is made of the solvent of the resin of 10 30% parts by weight, the auxiliary agent of 0.5 4% parts by weight, the pigment of 10 20% parts by weight and 50 70% parts by weight；Solvent heating is dissolved by heating into resin and is prepared into resin liquid, horizontal sand mill is reused by itself and pigment, auxiliary agent is sufficiently mixed grinding and ink is made, first release coating is coated on basement membrane, coating weight is 3.2 every square of 4.0g, then ink is coated on release layer surface, and coating weight is 1.8 every square of 2.5g, heat-resisting paint is coated on to other one layer of basement membrane again, coating weight is 0.1 every square of 1.0g.The image that carbon ribbon made of the present invention is printed by printer has a high resolution, rub resistance, it is ageing-resistant the advantages that.Print speed can meet ultrahigh speed printing demand up to 24inch/S.
Description
Technical field
The invention belongs to heat transfer printing carbon tape technical field, it is related to a kind of side pressure printer carbon ribbon and preparation method thereof.
Background technology
Carbon ribbon is a kind of current commonly used printing consumables.Finally from the English printer of earliest mechanical impact formula
Computer stylus printer, what is used is all carbon ribbon.The operation principle of carbon ribbon is exactly to utilize the dot matrix in stylus printer head
Alphabetical striker in striker or english typewriter goes to hit printing carbon ribbon, printing effect is generated on printing paper.
With the development of market economy, thermal transfer technology is more and more extensive, ripe in the application of every profession and trade, corresponding to fight each other
The effect requirements of print and the requirement of working efficiency are also increased therewith, and the demand of flying print is also more and more obvious, and present market
On in addition to side pressure printer can preferably meet high-speed label printing other than, flexible packaging industry thermal transfer equipment application also fast
Speed increases.
Overseas market is extremely wide using thermal transfer stamp, and especially in flexible package, and domestic market is from 2007 years
Just there are some enterprises to begin to take on identification information of the intelligent thermal transfer coder as product.Although both at home and abroad for side pressure and height
The preparation research of the heat transfer printing carbon tape of speed printing has some achievements, but is directed to the heat transfer printing carbon tape by side pressure and flying print
Visual performance usability after printing use is combined, to meet some to the label and Soft Roll that are imprinted with particular/special requirement
The exploitation and production of material flying print still belong to blank, because being the formulating by thermal transfer ink, coating arts techniques
Tackling key problem and the key technology difficulty of industries general character such as advanced mass production facilities technique and proceeding in quality control restriction.
Existing carbon ribbon film surface is relatively viscous, and film surface is easy to change under high temperature, carries on the back the high-temperature resistant result of the high-temperature resistant coating of painting and anti-sticking glutinous effect
Fruit is poor.
Therefore, how to solve the above problems, be the content that those skilled in the art of the present technique important research.
Invention content
To solve the above problems, a kind of side pressure printer carbon ribbon of present invention offer and preparation method thereof.
In order to achieve the above objects and other related objects, the present invention provides a kind of side pressure printer carbon ribbon, including successively
Basement membrane, release layer, thermal transfer ink layer and the refractory layer of setting；Wherein,
The basement membrane is the biaxial tension mylar without sided corona treatment that thickness is 3.5-4.5um；
The release layer by the brazil wax of 40-60% parts by weight, the synthetic wax of 40-60% parts by weight and 10-20% parts by weight second
Alkene-acetate ethylene copolymer composition；
The thermal transfer ink layer by the resin of 10-30% parts by weight, the auxiliary agent of 0.5-4% parts by weight, 10-20% parts by weight face
Material and the solvent of 50-70% parts by weight composition；
The refractory layer is by 20-30% weight of polyester resin, the MEK solvents of the TDI curing agent of 1-3% parts by weight and 70-80%
Composition.
In said program, related content is explained as follows：
1, in said program, the fusing point of the release layer is 70-90 DEG C.
2, one or more in the synthetic wax selection native paraffin, animal wax, artificial synthesized wax in said program, and
The fusing point of the synthetic wax is 70-90 DEG C.
3, in said program, the resin in the thermal transfer ink layer uses solid thermoplastics resin, fusing point to exist
Between 80-120 DEG C；It selects in ethylene-vinyl acetate copolymer, Petropols, acrylic resin, polyester resin or PU resins
One or more.
4, in said program, TDI curing agent, which is called, does toluene di-isocyanate(TDI)（C9H6N2O2）, it is water white transparency or yellowish
Color liquid is the organic compound with intense irritation gas.TDI is the important foundation chemical industry original for producing polyurethane material
Material, mainly for the manufacture of the curing agent of high concentrations of toluene diisocyanate and polyurethane coating, while being also used for production flexible polyurethane foams etc..
5, in said program, the MEK solvents are butanone, are derived from English,Methyl ethyl ketone, also known as first and second Ketone, methyl ethyl ketone。
A kind of production method of side pressure printer carbon ribbon, includes the following steps：
1., by the brazil wax of release layer material therefor 40-60% parts by weight, the synthetic wax of 40-60% parts by weight and 10-20% weight
After the ethylene-vinyl acetate copolymer heating hot melt for measuring part, it is coated on basement membrane, coating weight is every square of 3.2-4.0g, and is led to
Cross blowing spontaneous curing；
2., by after the heating heating of the solvents of 50-70% parts by weight, be prepared into resin liquid after dissolving the resin of 10-30% parts by weight, then
Itself and the pigment of 10-20% parts by weight and the auxiliary agent of 0.5-4% parts by weight are sufficiently mixed grinding and heat are made using horizontal sand mill
Transfer ink；Thermal transfer ink is coated on to the surface of release layer again, coating weight is every square of 1.8-2.5g, and is dried by drying tunnel
Solidization；
3., again by the MEK solvent systems of the polyester resin of 20-30% parts by weight and 1-3% parts by weight TDI curing agent and 70-80%
At heat-resisting paint, be coated on the other one side of basement membrane, form refractory layer, coating weight is every square of 0.1-1.0g, most afterwards through drying
It is wound after road drying.
Compared with prior art, the present invention having the advantages that：
The present invention has carried out targeted design optimization to each layer of carbon ribbon.Experiment detection shows：According to the method for the present invention and proportioning
Manufactured carbon ribbon has many advantages, such as high resolution, rub resistance, ageing-resistant by the image that printer prints.Print speed is reachable
24inch/S can meet ultrahigh speed printing demand.With preferable metastatic and color, while preferably avoiding coating and falling
Powder phenomenon occurs.The clear N/D of the transfer marking, scratch resistance is strong and glossiness is high；There is in print procedure low noise simultaneously
Property and the features such as coating picking function admirable, the marking printing that can be used for having particular/special requirement to marking color and luster has and preferably pushes away
Wide application value.
Description of the drawings
Fig. 1 is the structural schematic diagram of the carbon ribbon of the present invention.
Specific implementation mode
The present invention is further described below by way of specific implementation mode, but the present invention is not limited only to following embodiment.
Embodiment：
As shown in Figure 1, printer carbon ribbon is pressed on a kind of side, including basement membrane 1, release layer 2, the thermal transfer ink layer 3 set gradually
With refractory layer 4；Wherein,
The basement membrane 1 is the biaxial tension mylar without sided corona treatment that thickness is 3.5-4.5um；
The release layer 2 is by the brazil wax of 40-60% parts by weight, the synthetic wax of 40-60% parts by weight and 10-20% parts by weight
Ethylene-vinyl acetate copolymer forms；
The thermal transfer ink layer 3 by the resin of 10-30% parts by weight, the auxiliary agent of 0.5-4% parts by weight, 10-20% parts by weight face
Material and the solvent of 50-70% parts by weight composition；
The refractory layer 4 is molten by the MEK of 20-30% weight of polyester resin, the TDI curing agent of 1-3% parts by weight and 70-80%
Agent forms.
The fusing point of the release layer 2 is 70-90 DEG C.
It is one or more in the synthetic wax selection native paraffin, animal wax, artificial synthesized wax, and the synthetic wax is molten
Point is 70-90 DEG C.
The resin in the thermal transfer ink layer 3 uses solid thermoplastics resin, and fusing point is between 80-120 DEG C；
Select one or more in ethylene-vinyl acetate copolymer, Petropols, acrylic resin, polyester resin or PU resins.
Wherein, TDI curing agent, which is called, does toluene di-isocyanate(TDI)（C9H6N2O2）, be water white transparency or weak yellow liquid,
It is the organic compound with intense irritation gas.TDI is the important foundation industrial chemicals for producing polyurethane material, main to use
In the curing agent of manufacture high concentrations of toluene diisocyanate and polyurethane coating, while being also used for production flexible polyurethane foams etc..
The MEK solvents are butanone, are derived from English,Methyl ethyl ketone, also known as methyl ethyl ketone, methyl ethyl ketone。
A kind of production method of side pressure printer carbon ribbon, includes the following steps：
1., by the brazil wax of release layer material therefor 40-60% parts by weight, the synthetic wax of 40-60% parts by weight and 10-20% weight
After the ethylene-vinyl acetate copolymer heating hot melt for measuring part, it is coated on basement membrane, coating weight is every square of 3.2-4.0g, and is led to
Cross blowing spontaneous curing；
2., by after the heating heating of the solvents of 50-70% parts by weight, be prepared into resin liquid after dissolving the resin of 10-30% parts by weight, then
Itself and the pigment of 10-20% parts by weight and the auxiliary agent of 0.5-4% parts by weight are sufficiently mixed grinding and heat are made using horizontal sand mill
Transfer ink；Thermal transfer ink is coated on to the surface of release layer again, coating weight is every square of 1.8-2.5g, and is dried by drying tunnel
Solidization；
3., again by the MEK solvent systems of the polyester resin of 20-30% parts by weight and 1-3% parts by weight TDI curing agent and 70-80%
At heat-resisting paint, be coated on the other one side of basement membrane, form refractory layer, coating weight is every square of 0.1-1.0g, most afterwards through drying
It is wound after road drying.
The present invention has carried out targeted design optimization to each layer of carbon ribbon.Experiment detection shows：According to the method for the present invention and
Carbon ribbon made of proportioning has many advantages, such as high resolution, rub resistance, ageing-resistant by the image that printer prints.Print speed can
Up to 24inch/S, ultrahigh speed printing demand can be met.With preferable metastatic and color, while preferably avoiding coating
Lose powder phenomenon.The clear N/D of the transfer marking, scratch resistance is strong and glossiness is high；There is in print procedure noise simultaneously
The features such as low property and coating picking function admirable, the marking printing that can be used for having particular/special requirement to marking color and luster have preferable
Application value.
It is described herein and claimed invention is not limited to the ranges of particular aspects disclosed here, because of these sides
Face is intended as illustrations of several aspects of the invention.It is expected that any equivalent aspect is all in the scope of the present invention.In fact, removing
Except those of shown here and description, different modifications of the invention are for those of ordinary skills from foregoing description
It will be apparent.Such modification, which is also intended to, to be fallen within the scope of the appended claims.In case of conflict, to include fixed
Subject to the present disclosure of justice.
Claims (5)
1. printer carbon ribbon is pressed on a kind of side, it is characterised in that：Including the basement membrane, release layer, thermal transfer ink layer set gradually
And refractory layer；Wherein,
The basement membrane is the biaxial tension mylar without sided corona treatment that thickness is 3.5-4.5um；
The release layer by the brazil wax of 40-60% parts by weight, the synthetic wax of 40-60% parts by weight and 10-20% parts by weight second
Alkene-acetate ethylene copolymer composition；
The thermal transfer ink layer by the resin of 10-30% parts by weight, the auxiliary agent of 0.5-4% parts by weight, 10-20% parts by weight face
Material and the solvent of 50-70% parts by weight composition；
The refractory layer is by 20-30% weight of polyester resin, the MEK solvents of the TDI curing agent of 1-3% parts by weight and 70-80%
Composition.
2. printer carbon ribbon is pressed on side according to claim 1, it is characterised in that：The fusing point of the release layer is 70-90
℃。
3. printer carbon ribbon is pressed on side according to claim 1, it is characterised in that：The synthetic wax is selected native paraffin, is moved
It is one or more in object wax, artificial synthesized wax, and the fusing point of the synthetic wax is 70-90 DEG C.
4. printer carbon ribbon is pressed on side according to claim 1, it is characterised in that：It is described in the thermal transfer ink layer
Resin uses solid thermoplastics resin, and fusing point is between 80-120 DEG C；Select ethylene-vinyl acetate copolymer, Petropols,
One or more in acrylic resin, polyester resin or PU resins.
5. the production method that printer carbon ribbon is pressed on a kind of side as described in claim 1 to 5 is arbitrary, it is characterised in that：Including
Following steps：
1., by the brazil wax of release layer material therefor 40-60% parts by weight, the synthetic wax of 40-60% parts by weight and 10-20% weight
After the ethylene-vinyl acetate copolymer heating hot melt for measuring part, it is coated on basement membrane, coating weight is every square of 3.2-4.0g, and is led to
Cross blowing spontaneous curing；
2., by after the heating heating of the solvents of 50-70% parts by weight, be prepared into resin liquid after dissolving the resin of 10-30% parts by weight, then
Itself and the pigment of 10-20% parts by weight and the auxiliary agent of 0.5-4% parts by weight are sufficiently mixed grinding and heat are made using horizontal sand mill
Transfer ink；Thermal transfer ink is coated on to the surface of release layer again, coating weight is every square of 1.8-2.5g, and is dried by drying tunnel
Solidization；
3., again by the MEK solvent systems of the polyester resin of 20-30% parts by weight and 1-3% parts by weight TDI curing agent and 70-80%
At heat-resisting paint, be coated on the other one side of basement membrane, form refractory layer, coating weight is every square of 0.1-1.0g, most afterwards through drying
It is wound after road drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810338348.XA CN108583032B (en) | 2018-04-16 | 2018-04-16 | Carbon ribbon for edge-pressing printer and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810338348.XA CN108583032B (en) | 2018-04-16 | 2018-04-16 | Carbon ribbon for edge-pressing printer and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108583032A true CN108583032A (en) | 2018-09-28 |
| CN108583032B CN108583032B (en) | 2020-10-09 |
Family
ID=63622666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810338348.XA Active CN108583032B (en) | 2018-04-16 | 2018-04-16 | Carbon ribbon for edge-pressing printer and manufacturing method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111497474A (en) * | 2020-04-21 | 2020-08-07 | 福建鸣友新材料科技有限公司 | Special thermal transfer ribbon for portable printer and preparation method thereof |
| CN111848879A (en) * | 2020-08-14 | 2020-10-30 | 广州中码科技股份有限公司 | Bar code carbon tape edge pressure resin and preparation method thereof |
| CN112679774A (en) * | 2020-12-15 | 2021-04-20 | 福建鸣友新材料科技有限公司 | Rare earth luminescent carbon ribbon and preparation method thereof |
| CN114133788A (en) * | 2021-12-31 | 2022-03-04 | 福建鸣友新材料科技有限公司 | Ink and release layer solution for washable thermal transfer ribbon and preparation method thereof |
| CN114874477A (en) * | 2022-06-08 | 2022-08-09 | 南京爱宝文仪有限公司 | Water-based edge-pressing carbon ribbon and manufacturing method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111497474A (en) * | 2020-04-21 | 2020-08-07 | 福建鸣友新材料科技有限公司 | Special thermal transfer ribbon for portable printer and preparation method thereof |
| CN111848879A (en) * | 2020-08-14 | 2020-10-30 | 广州中码科技股份有限公司 | Bar code carbon tape edge pressure resin and preparation method thereof |
| CN112679774A (en) * | 2020-12-15 | 2021-04-20 | 福建鸣友新材料科技有限公司 | Rare earth luminescent carbon ribbon and preparation method thereof |
| CN114133788A (en) * | 2021-12-31 | 2022-03-04 | 福建鸣友新材料科技有限公司 | Ink and release layer solution for washable thermal transfer ribbon and preparation method thereof |
| CN114874477A (en) * | 2022-06-08 | 2022-08-09 | 南京爱宝文仪有限公司 | Water-based edge-pressing carbon ribbon and manufacturing method thereof |
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| Publication number | Publication date |
|---|---|
| CN108583032B (en) | 2020-10-09 |
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Address after: Room 432, Building 29, high tech Development Zone, Nanjing, Jiangsu Province, 210000 Patentee after: NANJING AIBO WENYI Co.,Ltd. Address before: 210000 11 Huang Road, Ma Qun Industrial Park, Qixia District, Nanjing, Jiangsu. Patentee before: NANJING AIBO WENYI Co.,Ltd. |