CN106965575A - A kind of heat transfer printing carbon tape for printing label surface water resistance and preparation method thereof - Google Patents
A kind of heat transfer printing carbon tape for printing label surface water resistance and preparation method thereof Download PDFInfo
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- CN106965575A CN106965575A CN201710306638.1A CN201710306638A CN106965575A CN 106965575 A CN106965575 A CN 106965575A CN 201710306638 A CN201710306638 A CN 201710306638A CN 106965575 A CN106965575 A CN 106965575A
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- layer
- resin
- tape base
- rotating speed
- release layer
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J31/00—Ink ribbons; Renovating or testing ink ribbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of heat transfer printing carbon tape for printing label surface water resistance, including tape base, it is coated in the refractory layer of tape base side, is coated in the release layer of tape base opposite side and the ink layer being coated on the outside of release layer, the refractory layer is made up of the raw material below according to mass fraction：Polyester resin 45 52%, acrylic acid modified polyurethane resin 12 15%, polyimide resin 16 24%；The release layer is made up of the raw material below according to mass fraction：Toluene 62 70%, acrylic resin 12 15%, emulsifiable polyethylene wax 3 6%, emulsification polypropylene wax 5 8%；The ink layer is made up of the raw material below according to mass fraction：Butanone 45 50%, cyclohexanone 8 12%, polyester resin 12 17%, note alkene phenol resin 5 8%, carbon black 6 8%, auxiliary agent 1 2%.
Description
Technical field
The present invention relates to heat transfer printing carbon tape technical field, more particularly to a kind of thermal transfer carbon for printing label surface water resistance
Band and preparation method thereof.
Background technology
Water resistance and alcohol resistance of the existing resin base carbon ribbon in the market after label surface is printed to be not it is very good,
It is mainly ink coating poor-performing, and its water resistance and alcohol resistance are poor, and influence ink coating printing is unintelligible and prints
The shortcomings of effect is poor, therefore, it is proposed that a kind of heat transfer printing carbon tape for printing label surface water resistance and preparation method thereof, comes
Improve heat transfer printing carbon tape water resistance and alcohol resistance using effect.
The content of the invention
To solve the defect of prior art, the invention discloses a kind of thermal transfer carbon for printing label surface water resistance
Band and preparation method thereof.
The heat transfer printing carbon tape of label surface water resistance is printed the invention discloses a kind of, including tape base, is coated in tape base one
The refractory layer of side, the release layer for being coated in tape base opposite side and the ink layer being coated on the outside of release layer, the refractory layer by
Constituted below according to the raw material of mass fraction：Polyester resin 45-52%, acrylic acid modified polyurethane resin 12-15%, polyimides
Resin 16-24%；The release layer is made up of the raw material below according to mass fraction：Toluene 62-70%, acrylic resin 12-
15%th, emulsifiable polyethylene wax 3-6%, emulsification polypropylene wax 5-8%；The ink layer is made up of the raw material below according to mass fraction：
Butanone 45-50%, cyclohexanone 8-12%, polyester resin 12-17%, note alkene phenol resin 5-8%, carbon black 6-8%, auxiliary agent 1-2%.
It is preferred that, the material of the tape base is polyester film, and the thickness of tape base is 6-8 μm.
A kind of preparation method for the heat transfer printing carbon tape for printing label surface water resistance, its preparation method is as follows：
（1）Weigh in emulsifiable polyethylene wax, emulsification polypropylene wax, input shearing equipment, shearing equipment is warming up to 68-75 DEG C,
Under 1500-2000 revs/min of rotating speed, stirring mixing decentralized processing 0.3-0.5h, then slow cooling is to 32-38 DEG C, obtains breast
Change liquid；
（2）Weigh in toluene solvant, acrylic resin soln, input emulsion, under 2500-3000 revs/min of rotating speed, point
Processing 1-1.5h is dissipated, release layer mixed solution is obtained, it is standby；
（3）Weigh in butanone, cyclohexanone, input dispersed with stirring device, under 1500-2000 revs/min of rotating speed, decentralized processing
0.5-1h, obtains configuration mixed solvent；
（4）Weigh polyester resin, note alkene phenol resin, add in mixed solvent, input shearing dispersing apparatus, turn in 2500-3000/
Under the rotating speed of minute, decentralized processing 2-3h obtains the main resin mixture liquor of ink layer；
（5）Carbon black is weighed, after crushing, 800-900 mesh sieves is crossed, obtains powdered carbon black；
（6）Powdered carbon black is put into the main resin mixture liquor of ink layer, dispersed with stirring, in 1000-1500 revs/min turn of rotating speed
Under speed, decentralized processing 1-1.5h, then weigh auxiliary agent, under the rotating speed of 1000-1500 revs/min of rotating speed, decentralized processing 0.5-1h,
Ink layer liquid is obtained, it is standby;
（7）Weigh in polyester resin, acrylic acid modified polyurethane resin, polyimide resin, input shearing equipment, decentralized processing
2-3h, obtains refractory layer coating liquid, standby；
（8）Refractory layer coating liquid is coated uniformly on by tape base front using coating machine, after drying, forms heat-resisting in tape base front
Layer；
（9）Release layer coating liquid is coated uniformly on by the tape base back side using coating machine, after drying, forms release at the tape base back side
Layer；
（10）In the uniform coating oil layer of ink coating liquid of release layer surface, after drying, in release layer surface formation ink layer.
Beneficial effect is：Prepared by the ink layer of the present invention is to use a kind of polyester resin, while adding to improve printing effect
Plus appropriate terpene phenol resin is configured to main resin system, blended solvent adds the warp such as auxiliary agent, carbon black fillers again after fully dissolving
It is ground to blowing after suitable fineness to use, so as to improve the performance of ink coating, improves its water resistance and alcohol resistance performance,
So that heat transfer printing carbon tape prints clear by ink layer, its printing effect is improved.
Embodiment
Embodiment 1
It is a kind of to print the heat transfer printing carbon tape of label surface water resistance, including tape base, be coated in the refractory layer of tape base side, be coated in
The release layer of tape base opposite side and the ink layer being coated on the outside of release layer, the refractory layer is by below according to mass fraction
Raw material is constituted：Polyester resin 45%, acrylic acid modified polyurethane resin 12%, polyimide resin 16%；The release layer is by following
Constituted according to the raw material of mass fraction：Toluene 62%, acrylic resin 12%, emulsifiable polyethylene wax 3%, emulsification polypropylene wax 5%；
The ink layer is made up of the raw material below according to mass fraction：Butanone 45%, cyclohexanone 8%, polyester resin 12%, note alkene phenol tree
Fat 5%, carbon black 6%, auxiliary agent 1%.
The material of the tape base is polyester film, and the thickness of tape base is 6 μm.
A kind of preparation method for the heat transfer printing carbon tape for printing label surface water resistance, its preparation method is as follows：
（1）Weigh in emulsifiable polyethylene wax, emulsification polypropylene wax, input shearing equipment, shearing equipment is warming up to 68 DEG C, 1500
Rev/min rotating speed under, stirring mixing decentralized processing 0.3h, then slow cooling is to 32 DEG C, obtains emulsion；
（2）Weigh in toluene solvant, acrylic resin soln, input emulsion, under 2500 revs/min of rotating speed, disperse place
1h is managed, release layer mixed solution is obtained, it is standby；
（3）Weigh in butanone, cyclohexanone, input dispersed with stirring device, under 1500 revs/min of rotating speed, decentralized processing 0.5h,
Obtain configuration mixed solvent；
（4）Polyester resin, note alkene phenol resin are weighed, is added in mixed solvent, input shearing dispersing apparatus, at 2500 revs/min
Rotating speed under, decentralized processing 2h, obtain the main resin mixture liquor of ink layer；
（5）Carbon black is weighed, after crushing, 800 mesh sieves is crossed, obtains powdered carbon black；
（6）Powdered carbon black is put into the main resin mixture liquor of ink layer, dispersed with stirring, under the rotating speed of 1000 revs/min of rotating speed,
Decentralized processing 1h, then weigh auxiliary agent, auxiliary agent is sodium alginate and polyether-modified silicon defoaming agent mixed aid, 1000 turns of rotating speed/
Under the rotating speed of minute, decentralized processing 0.5h obtains ink layer liquid, standby;
（7）Weigh in polyester resin, acrylic acid modified polyurethane resin, polyimide resin, input shearing equipment, decentralized processing
2h, obtains refractory layer coating liquid, standby；
（8）Refractory layer coating liquid is coated uniformly on by tape base front using coating machine, after drying, forms heat-resisting in tape base front
Layer；
（9）Release layer coating liquid is coated uniformly on by the tape base back side using coating machine, after drying, forms release at the tape base back side
Layer；
（10）In the uniform coating oil layer of ink coating liquid of release layer surface, after drying, in release layer surface formation ink layer.
Embodiment 2
It is a kind of to print the heat transfer printing carbon tape of label surface water resistance, including tape base, be coated in the refractory layer of tape base side, be coated in
The release layer of tape base opposite side and the ink layer being coated on the outside of release layer, the refractory layer is by below according to mass fraction
Raw material is constituted：Polyester resin 48%, acrylic acid modified polyurethane resin 13.5%, polyimide resin 20%；The release layer by with
Under according to mass fraction raw material constitute：Toluene 66%, acrylic resin 13.5%, emulsifiable polyethylene wax 4.5%, emulsification polypropylene
Wax 6.5%；The ink layer is made up of the raw material below according to mass fraction：Butanone 47.5%, cyclohexanone 10%, polyester resin
14.5%th, note alkene phenol resin 6.5%, carbon black 6.5%, auxiliary agent 1.5%.
The material of the tape base is polyester film, and the thickness of tape base is 7 μm.
A kind of preparation method for the heat transfer printing carbon tape for printing label surface water resistance, its preparation method is as follows：
（1）Weigh in emulsifiable polyethylene wax, emulsification polypropylene wax, input shearing equipment, shearing equipment is warming up to 71 DEG C, 1750
Rev/min rotating speed under, stirring mixing decentralized processing 0.4h, then slow cooling is to 35 DEG C, obtains emulsion；
（2）Weigh in toluene solvant, acrylic resin soln, input emulsion, under 2750 revs/min of rotating speed, disperse place
1.3h is managed, release layer mixed solution is obtained, it is standby；
（3）Weigh in butanone, cyclohexanone, input dispersed with stirring device, under 1750 revs/min of rotating speed, decentralized processing 0.7h,
Obtain configuration mixed solvent；
（4）Polyester resin, note alkene phenol resin are weighed, is added in mixed solvent, input shearing dispersing apparatus, at 2750 revs/min
Rotating speed under, decentralized processing 2.5h, obtain the main resin mixture liquor of ink layer；
（5）Carbon black is weighed, after crushing, 850 mesh sieves is crossed, obtains powdered carbon black；
（6）Powdered carbon black is put into the main resin mixture liquor of ink layer, dispersed with stirring, under the rotating speed of 1250 revs/min of rotating speed,
Decentralized processing 1.3h, then auxiliary agent is weighed, auxiliary agent is sodium alginate and polyether-modified silicon defoaming agent mixed aid, in rotating speed 1250
Rev/min rotating speed under, decentralized processing 0.8h, obtain ink layer liquid, it is standby;
（7）Weigh in polyester resin, acrylic acid modified polyurethane resin, polyimide resin, input shearing equipment, decentralized processing
2.5h, obtains refractory layer coating liquid, standby；
（8）Refractory layer coating liquid is coated uniformly on by tape base front using coating machine, after drying, forms heat-resisting in tape base front
Layer；
（9）Release layer coating liquid is coated uniformly on by the tape base back side using coating machine, after drying, forms release at the tape base back side
Layer；
（10）In the uniform coating oil layer of ink coating liquid of release layer surface, after drying, in release layer surface formation ink layer.
Embodiment 3
It is a kind of to print the heat transfer printing carbon tape of label surface water resistance, including tape base, be coated in the refractory layer of tape base side, be coated in
The release layer of tape base opposite side and the ink layer being coated on the outside of release layer, the refractory layer is by below according to mass fraction
Raw material is constituted：Polyester resin 52%, acrylic acid modified polyurethane resin 15%, polyimide resin 24%；The release layer is by following
Constituted according to the raw material of mass fraction：Toluene 70%, acrylic resin 15%, emulsifiable polyethylene wax 6%, emulsification polypropylene wax 8%；
The ink layer is made up of the raw material below according to mass fraction：Butanone 50%, cyclohexanone 12%, polyester resin 17%, note alkene phenol
Resin 8%, carbon black 8%, auxiliary agent 2%.
The material of the tape base is polyester film, and the thickness of tape base is 8 μm.
A kind of preparation method for the heat transfer printing carbon tape for printing label surface water resistance, its preparation method is as follows：
（1）Weigh in emulsifiable polyethylene wax, emulsification polypropylene wax, input shearing equipment, shearing equipment is warming up to 75 DEG C, 2000
Rev/min rotating speed under, stirring mixing decentralized processing 0.5h, then slow cooling is to 38 DEG C, obtains emulsion；
（2）Weigh in toluene solvant, acrylic resin soln, input emulsion, under 3000 revs/min of rotating speed, disperse place
1.5h is managed, release layer mixed solution is obtained, it is standby；
（3）Weigh in butanone, cyclohexanone, input dispersed with stirring device, under 2000 revs/min of rotating speed, decentralized processing 1h is obtained
Mixed solvent must be configured；
（4）Polyester resin, note alkene phenol resin are weighed, is added in mixed solvent, input shearing dispersing apparatus, at 3000 revs/min
Rotating speed under, decentralized processing 3h, obtain the main resin mixture liquor of ink layer；
（5）Carbon black is weighed, after crushing, 900 mesh sieves is crossed, obtains powdered carbon black；
（6）Powdered carbon black is put into the main resin mixture liquor of ink layer, dispersed with stirring, under the rotating speed of 1500 revs/min of rotating speed,
Decentralized processing 1.5h, then auxiliary agent is weighed, auxiliary agent is sodium alginate and polyether-modified silicon defoaming agent mixed aid, in rotating speed 1500
Rev/min rotating speed under, decentralized processing 1h, obtain ink layer liquid, it is standby;
（7）Weigh in polyester resin, acrylic acid modified polyurethane resin, polyimide resin, input shearing equipment, decentralized processing
3h, obtains refractory layer coating liquid, standby；
（8）Refractory layer coating liquid is coated uniformly on by tape base front using coating machine, after drying, forms heat-resisting in tape base front
Layer；
（9）Release layer coating liquid is coated uniformly on by the tape base back side using coating machine, after drying, forms release at the tape base back side
Layer；
（10）In the uniform coating oil layer of ink coating liquid of release layer surface, after drying, in release layer surface formation ink layer.
Finally it should be noted that：Above example only not limits technology described in the invention to illustrate the present invention
Scheme；Therefore, although this specification with reference to each above-mentioned embodiment to present invention has been detailed description, this
Field it is to be appreciated by one skilled in the art that still can be modified to the present invention or equivalent substitution；And all do not depart from this
The technical scheme of the spirit and scope of invention and its improvement, it all should cover in scope of the presently claimed invention.
Claims (3)
1. a kind of heat transfer printing carbon tape for printing label surface water resistance, it is characterised in that：Including tape base, it is coated in tape base side
Refractory layer, the release layer for being coated in tape base opposite side and the ink layer being coated on the outside of release layer, the refractory layer is by following
Constituted according to the raw material of mass fraction：Polyester resin 45-52%, acrylic acid modified polyurethane resin 12-15%, polyimide resin
16-24%；The release layer is made up of the raw material below according to mass fraction：Toluene 62-70%, acrylic resin 12-15%, breast
Change Tissuemat E 3-6%, emulsification polypropylene wax 5-8%；The ink layer is made up of the raw material below according to mass fraction：Butanone
45-50%, cyclohexanone 8-12%, polyester resin 12-17%, note alkene phenol resin 5-8%, carbon black 6-8%, auxiliary agent 1-2%.
2. a kind of printing label surface water resistance heat transfer printing carbon tape according to claim 1, it is characterised in that：The tape base
Material be polyester film, and tape base thickness be 6-8 μm.
3. a kind of preparation method for the heat transfer printing carbon tape for printing label surface water resistance, its preparation method is as follows：
（1）Weigh in emulsifiable polyethylene wax, emulsification polypropylene wax, input shearing equipment, shearing equipment is warming up to 68-75 DEG C,
Under 1500-2000 revs/min of rotating speed, stirring mixing decentralized processing 0.3-0.5h, then slow cooling is to 32-38 DEG C, obtains breast
Change liquid；
（2）Weigh in toluene solvant, acrylic resin soln, input emulsion, under 2500-3000 revs/min of rotating speed, point
Processing 1-1.5h is dissipated, release layer mixed solution is obtained, it is standby；
（3）Weigh in butanone, cyclohexanone, input dispersed with stirring device, under 1500-2000 revs/min of rotating speed, decentralized processing
0.5-1h, obtains configuration mixed solvent；
（4）Weigh polyester resin, note alkene phenol resin, add in mixed solvent, input shearing dispersing apparatus, turn in 2500-3000/
Under the rotating speed of minute, decentralized processing 2-3h obtains the main resin mixture liquor of ink layer；
（5）Carbon black is weighed, after crushing, 800-900 mesh sieves is crossed, obtains powdered carbon black；
（6）Powdered carbon black is put into the main resin mixture liquor of ink layer, dispersed with stirring, in 1000-1500 revs/min turn of rotating speed
Under speed, decentralized processing 1-1.5h, then weigh auxiliary agent, under the rotating speed of 1000-1500 revs/min of rotating speed, decentralized processing 0.5-1h,
Ink layer liquid is obtained, it is standby;
（7）Weigh in polyester resin, acrylic acid modified polyurethane resin, polyimide resin, input shearing equipment, decentralized processing
2-3h, obtains refractory layer coating liquid, standby；
（8）Refractory layer coating liquid is coated uniformly on by tape base front using coating machine, after drying, forms heat-resisting in tape base front
Layer；
（9）Release layer coating liquid is coated uniformly on by the tape base back side using coating machine, after drying, forms release at the tape base back side
Layer；
（10）In the uniform coating oil layer of ink coating liquid of release layer surface, after drying, in release layer surface formation ink layer.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710306638.1A CN106965575A (en) | 2017-05-04 | 2017-05-04 | A kind of heat transfer printing carbon tape for printing label surface water resistance and preparation method thereof |
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|---|---|---|---|
| CN201710306638.1A CN106965575A (en) | 2017-05-04 | 2017-05-04 | A kind of heat transfer printing carbon tape for printing label surface water resistance and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112552736A (en) * | 2020-11-27 | 2021-03-26 | 杭州天地数码科技股份有限公司 | Ink for washing label carbon ribbon, and preparation method and application thereof |
| CN115179674A (en) * | 2022-08-15 | 2022-10-14 | 福建鸣友新材料科技有限公司 | UV (ultraviolet) photocuring thermal transfer ribbon and preparation method thereof |
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| CN201998578U (en) * | 2011-04-02 | 2011-10-05 | 泉州市山水电脑耗材有限公司 | Multi-layer heat transfer printing carbon ribbon |
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| CN1688453A (en) * | 2002-10-04 | 2005-10-26 | 柯尼卡美能达影像株式会社 | Authentication/identification card and mfg.method thereof |
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Application publication date: 20170721 |
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