CN108178946A - The preparation method of the high flexible thermal transfer ink of aluminium alloy - Google Patents
The preparation method of the high flexible thermal transfer ink of aluminium alloy Download PDFInfo
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- CN108178946A CN108178946A CN201810069458.0A CN201810069458A CN108178946A CN 108178946 A CN108178946 A CN 108178946A CN 201810069458 A CN201810069458 A CN 201810069458A CN 108178946 A CN108178946 A CN 108178946A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses the preparation method of the high flexible thermal transfer ink of aluminium alloy, method includes：Polyester resin, epoxy resin and acrylic resin are added in into organic solvent, are warming up to 50-70 DEG C, turn on agitator, mixing speed 40-80r/min stirs 15-25min, until resin is completely dissolved；It adds a pigment in above-mentioned solution, opens ultrasonic vibrator, work 5-9min, until pigment is completely dispersed；Dispersant, antistatic agent, levelling agent and brightener are added in into the solution with pigment, mixing speed is adjusted to 200-300r/min, stirs 30-40min, obtains crude oil ink；Crude oil ink by 150-200 mesh is sieved, obtains ink.Ink fineness prepared by this preparation method is small, when being transferred on aluminium alloy, strong adhesive force, and, oil lamella flexibility is strong, and after transfer, aluminium alloy transport and carrying all will not be there is a situation where cracking, excellent combination property, and preparation method is simple, materials are cheap, of low cost.
Description
Technical field
The present invention relates to technical field of ink more particularly to the preparation methods of the high flexible thermal transfer ink of aluminium alloy.
Background technology
Thermal transfer technology refers to ink is first made transfer film on specific ground by press printing, then will be printed on
The transfer film of pattern transfers pattern to target ground (such as photo frame, furniture facade, macromolecule by certain temperature and pressure
Plank, stationery plastic cement, aluminium alloy etc.) on a kind of technology.
But the ink for preparing of existing preparation method by thermal transfer by printing ink transfer to aluminium alloy when, due to aluminium
Product material is firmly crisp, and the oil lamella to be formed is caused to be very easy to crack, particularly in the case where there is external force stress, such as：Fortune
Defeated, carrying causes very big loss, and preparation section is complicated in this way, and materials are expensive, of high cost.
Invention content
In view of this, the present invention provides the preparation methods of the high flexible thermal transfer ink of aluminium alloy.
The preparation method of the high flexible thermal transfer ink of aluminium alloy, method include：
Polyester resin, epoxy resin and acrylic resin are added in into organic solvent, are warming up to 50-70 DEG C, is opened
Blender, mixing speed 40-80r/min stir 15-25min, until resin is completely dissolved；
It adds a pigment in above-mentioned solution, opens ultrasonic vibrator, work 5-9min, until pigment is completely dispersed；
Dispersant, antistatic agent, levelling agent and brightener are added in into the solution with pigment, by mixing speed tune
To 200-300r/min, 30-40min is stirred, obtains crude oil ink；
Crude oil ink by 150-200 mesh is sieved, obtains ink.
Preferably, method includes：
Polyester resin, epoxy resin and acrylic resin are added in into organic solvent, are warming up to 55-64 DEG C, is opened
Blender, mixing speed 48-72r/min stir 18-22min, until resin is completely dissolved；
It adds a pigment in above-mentioned solution, opens ultrasonic vibrator, work 6-8min, until pigment is completely dispersed；
Dispersant, antistatic agent, levelling agent and brightener are added in into the solution with pigment, by mixing speed tune
To 220-270r/min, 33-38min is stirred, obtains crude oil ink；
Crude oil ink by 160-180 mesh is sieved, obtains ink.
Preferably, method includes：
Polyester resin, epoxy resin and acrylic resin are added in into organic solvent, are warming up to 58 DEG C, opens stirring
Device, mixing speed 62r/min stir 22min, until resin is completely dissolved；
It adds a pigment in above-mentioned solution, opens ultrasonic vibrator, work 7min, until pigment is completely dispersed；
Dispersant, antistatic agent, levelling agent and brightener are added in into the solution with pigment, by mixing speed tune
To 250r/min, 36min is stirred, obtains crude oil ink；
Crude oil ink by 170 mesh is sieved, obtains ink.
Preferably, method, which is further included, weighs polyester resin by component amount, epoxy resin, acrylic resin, organic solvent, divides
Powder, antistatic agent, levelling agent, brightener, pigment.
Preferably, method, which further includes, weighs to ink, packing.
Preferably, the organic solvent is that toluene, isopropanol, propylene glycol monomethyl ether, butyl acetate and methyl are different
At least one of butanone.
Preferably, the dispersant is triethyl group hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, cellulose derive
One kind in object and polyacrylamide.
Preferably, the antistatic agent is sodium alkyl sulfonate or nabam.
Preferably, the levelling agent is dimethyl silicone polymer, polymethylphenylsiloxane and Organo-modified poly- silicon
One or both of oxygen alkane.
Preferably, the brightener is acid zinc plating brightener.
The present invention provides the preparation method of the high flexible thermal transfer ink of aluminium alloy, ink prepared by this preparation method is thin
Spend small, when being transferred on aluminium alloy, strong adhesive force, moreover, oil lamella flexibility is strong, after transfer, aluminium alloy is transported and removed
Fortune all will not be there is a situation where cracking, excellent combination property, and preparation method is simple, and materials are cheap, of low cost.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical solution in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is part of the embodiment of the present invention, instead of all the embodiments.Based on the implementation in the present invention
Example, those of ordinary skill in the art's all other embodiments obtained without making creative work, belongs to
The scope of protection of the invention.
It should be appreciated that ought use in this specification and in the appended claims, term " comprising " and "comprising" instruction
Described feature, entirety, step, operation, the presence of element and/or component, but one or more of the other feature, whole is not precluded
Body, step, operation, element, component and/or its presence or addition gathered.
It will be further appreciated that the term "and/or" used in description of the invention and the appended claims is
Refer to any combinations and all possible combinations of one or more of the associated item listed, and including these combinations.
Embodiment 1
The high flexible thermal transfer ink of aluminium alloy, by mass fraction, its material component includes：
Preparation method is：
Polyester resin, epoxy resin, acrylic resin, toluene, triethyl group hexyl phosphoric acid, two thio ammonia are weighed by component amount
Base sodium formate, dimethyl silicone polymer, acid zinc plating brightener, pigment；
Polyester resin, epoxy resin and acrylic resin are added in into toluene, are warming up to 70 DEG C, turn on agitator,
Mixing speed is 40r/min, stirs 25min, until resin is completely dissolved；
It adds a pigment in above-mentioned solution, opens ultrasonic vibrator, work 9min, until pigment is completely dispersed；
Triethyl group hexyl phosphoric acid, nabam, dimethyl silicone polymer and acid zinc plating brightener are added
Enter into the solution with pigment, mixing speed is adjusted to 200r/min, stirs 40min, obtain crude oil ink；
Crude oil ink by 150 mesh is sieved, obtains ink；
It weighs, dispenses to ink.
Embodiment 2
The high flexible thermal transfer ink of aluminium alloy, by mass fraction, its material component includes：
Preparation method is：
Polyester resin, epoxy resin, acrylic resin, isopropanol and propylene glycol monomethyl ether, 12 are weighed by component amount
Sodium alkyl sulfate, nabam, Organo-modified polysiloxanes, acid zinc plating brightener, pigment；
Polyester resin, epoxy resin and acrylic resin are added in into isopropanol and propylene glycol monomethyl ether, heated up
To 55 DEG C, turn on agitator, mixing speed 72r/min stirs 18min, until resin is completely dissolved；
It adds a pigment in above-mentioned solution, opens ultrasonic vibrator, work 8min, until pigment is completely dispersed；
Lauryl sodium sulfate, nabam, Organo-modified polysiloxanes and acid zinc plating is bright
Agent is added in into the solution with pigment, and mixing speed is adjusted to 270r/min, stirs 33min, obtains crude oil ink；
Crude oil ink by 180 mesh is sieved, obtains ink；
It weighs, dispenses to ink.
Embodiment 3
The high flexible thermal transfer ink of aluminium alloy, by mass fraction, its material component includes：
Preparation method is：
By component amount weigh polyester resin, epoxy resin, acrylic resin, isopropanol, methyl anyl alcohol, sodium alkyl sulfonate,
Organo-modified polysiloxanes, acid zinc plating brightener, pigment；
Polyester resin, epoxy resin and acrylic resin are added in into isopropanol, are warming up to 50 DEG C, opens stirring
Device, mixing speed 80r/min stir 15min, until resin is completely dissolved；
It adds a pigment in above-mentioned solution, opens ultrasonic vibrator, work 9min, until pigment is completely dispersed；
Methyl anyl alcohol, sodium alkyl sulfonate, Organo-modified polysiloxanes and acid zinc plating brightener are added in carrying
In the solution of pigment, mixing speed is adjusted to 300r/min, stirs 30min, obtain crude oil ink；
Crude oil ink by 200 mesh is sieved, obtains ink；
It weighs, dispenses to ink.
Embodiment 4
The high flexible thermal transfer ink of aluminium alloy, by mass fraction, its material component includes：
Preparation method is：
Polyester resin, epoxy resin, acrylic resin, methylisobutylketone, polyacrylamide, alkyl sulphur are weighed by component amount
Sour sodium, Organo-modified polysiloxanes, acid zinc plating brightener, pigment；
Polyester resin, epoxy resin and acrylic resin are added in into methylisobutylketone, are warming up to 64 DEG C, unlatching is stirred
Device is mixed, mixing speed 48r/min stirs 22min, until resin is completely dissolved；
It adds a pigment in above-mentioned solution, opens ultrasonic vibrator, work 6min, until pigment is completely dispersed；
Polyacrylamide, sodium alkyl sulfonate, Organo-modified polysiloxanes and acid zinc plating brightener are added in band
Have in the solution of pigment, mixing speed is adjusted to 220r/min, stirs 38min, obtain crude oil ink；
Crude oil ink by 160 mesh is sieved, obtains ink；
It weighs, dispenses to ink.
Embodiment 5
The high flexible thermal transfer ink of aluminium alloy, by mass fraction, its material component includes：
Preparation method is：
Polyester resin, epoxy resin, acrylic resin, butyl acetate, cellulose derivative, two thio is weighed by component amount
Carbamic acid sodium, polymethylphenylsiloxane, acid zinc plating brightener, pigment；
Polyester resin, epoxy resin and acrylic resin are added in into butyl acetate, are warming up to 58 DEG C, opens stirring
Device, mixing speed 62r/min stir 22min, until resin is completely dissolved；
It adds a pigment in above-mentioned solution, opens ultrasonic vibrator, work 7min, until pigment is completely dispersed；
Cellulose derivative, nabam, polymethylphenylsiloxane and acid zinc plating brightener are added
Enter into the solution with pigment, mixing speed is adjusted to 250r/min, stirs 36min, obtain crude oil ink；
Crude oil ink by 170 mesh is sieved, obtains ink；
It weighs, dispenses to ink.
Ink prepared by 1 to 5 preparation method of embodiment, is affixed on aluminum alloy surface by thermal transfer, tests its performance：
Particle diameter is performed according to GB/T13217.3；
Fastness is transferred according to GB/T13217.7, evaluation result is not fall the effect of ink the lattice number of layer except in 100.
Flexibility evaluation result is 1-5 points, and 5 points do not rupture completely for layer of ink, and 1 point is completely severed and comes off for layer of ink.
| Particle diameter (μm) | Transfer fastness (%) | Flexibility | |
| Embodiment 1 | ＜ 13 | 97 | 5 |
| Embodiment 2 | ＜ 12 | 99 | 5 |
| Embodiment 3 | ＜ 15 | 98 | 5 |
| Embodiment 4 | ＜ 10 | 98 | 5 |
| Embodiment 5 | ＜ 13 | 99 | 5 |
As can be seen that this ink fineness is small, averagely less than 15um, when being transferred on aluminium alloy, strong adhesive force transfers fastness
Reach more than 97%, moreover, oil lamella flexibility is strong, after transfer, aluminium alloy transports and carry what will not all be cracked
Situation, excellent combination property.
The steps in the embodiment of the present invention can be sequentially adjusted, merged and deleted according to actual needs.
It is described in detail herein, applies specific case and the principle of the present invention and embodiment are explained
It states, above example is merely used to help understand the method and its core concept of the present invention；Meanwhile for the general skill of this field
Art personnel, thought according to the present invention, there will be changes in specific embodiments and applications, in conclusion this
Description should not be construed as limiting the invention.
Claims (10)
1. the preparation method of the high flexible thermal transfer ink of aluminium alloy, which is characterized in that method includes：
Polyester resin, epoxy resin and acrylic resin are added in into organic solvent, are warming up to 50-70 DEG C, opens stirring
Device, mixing speed 40-80r/min stir 15-25min, until resin is completely dissolved；
It adds a pigment in above-mentioned solution, opens ultrasonic vibrator, work 5-9min, until pigment is completely dispersed；
Dispersant, antistatic agent, levelling agent and brightener are added in into the solution with pigment, mixing speed is adjusted to
200-300r/min stirs 30-40min, obtains crude oil ink；
Crude oil ink by 150-200 mesh is sieved, obtains ink.
2. preparation method according to claim 1, which is characterized in that method includes：
Polyester resin, epoxy resin and acrylic resin are added in into organic solvent, are warming up to 55-64 DEG C, opens stirring
Device, mixing speed 48-72r/min stir 18-22min, until resin is completely dissolved；
It adds a pigment in above-mentioned solution, opens ultrasonic vibrator, work 6-8min, until pigment is completely dispersed；
Dispersant, antistatic agent, levelling agent and brightener are added in into the solution with pigment, mixing speed is adjusted to
220-270r/min stirs 33-38min, obtains crude oil ink；
Crude oil ink by 160-180 mesh is sieved, obtains ink.
3. preparation method according to claim 2, which is characterized in that method includes：
Polyester resin, epoxy resin and acrylic resin are added in into organic solvent, are warming up to 58 DEG C, turn on agitator,
Mixing speed is 62r/min, stirs 22min, until resin is completely dissolved；
It adds a pigment in above-mentioned solution, opens ultrasonic vibrator, work 7min, until pigment is completely dispersed；
Dispersant, antistatic agent, levelling agent and brightener are added in into the solution with pigment, mixing speed is adjusted to
250r/min stirs 36min, obtains crude oil ink；
Crude oil ink by 170 mesh is sieved, obtains ink.
4. according to any preparation methods of claim 1-3, it is characterised in that：Method is further included weighs polyester by component amount
Resin, epoxy resin, acrylic resin, organic solvent, dispersant, antistatic agent, levelling agent, brightener, pigment.
5. according to any preparation methods of claim 1-3, it is characterised in that：Method, which further includes, weighs to ink,
Packing.
6. according to any preparation methods of claim 1-3, it is characterised in that：The organic solvent is toluene, different
At least one of propyl alcohol, propylene glycol monomethyl ether, butyl acetate and methylisobutylketone.
7. according to any preparation methods of claim 1-3, it is characterised in that：The dispersant is triethyl group hexyl phosphorus
One kind in acid, lauryl sodium sulfate, methyl anyl alcohol, cellulose derivative and polyacrylamide.
8. according to any preparation methods of claim 1-3, it is characterised in that：The antistatic agent for sodium alkyl sulfonate or
Person's nabam.
9. according to any preparation methods of claim 1-3, it is characterised in that：The levelling agent is polydimethylsiloxanes
One or both of alkane, polymethylphenylsiloxane and Organo-modified polysiloxanes.
10. according to any preparation methods of claim 1-3, it is characterised in that：The brightener is bright for acid zinc plating
Agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810069458.0A CN108178946A (en) | 2018-01-24 | 2018-01-24 | The preparation method of the high flexible thermal transfer ink of aluminium alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810069458.0A CN108178946A (en) | 2018-01-24 | 2018-01-24 | The preparation method of the high flexible thermal transfer ink of aluminium alloy |
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| CN108178946A true CN108178946A (en) | 2018-06-19 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002274064A (en) * | 2001-01-15 | 2002-09-25 | Dainippon Printing Co Ltd | Heat-transfer sheet and image printed article |
| CN102173234A (en) * | 2011-03-14 | 2011-09-07 | 杭州天地数码科技有限公司 | Water-based resin thermal transfer printing ribbon and preparation method thereof |
| CN104312282A (en) * | 2014-09-23 | 2015-01-28 | 广州大学 | Plastic product mold internal decorative thermal transfer printing ink and preparation method thereof |
| CN104476937A (en) * | 2014-12-29 | 2015-04-01 | 东莞市卓艺印刷制品有限公司 | Baking printing ink transfer film and preparation method thereof |
| CN104802541A (en) * | 2015-04-21 | 2015-07-29 | 武汉华工图像技术开发有限公司 | Heat transfer printing ink ribbon for metal material |
| CN105419475A (en) * | 2014-09-11 | 2016-03-23 | 洋紫荆油墨（浙江）有限公司 | Gluing-free thermal transfer printing ink having release function |
-
2018
- 2018-01-24 CN CN201810069458.0A patent/CN108178946A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002274064A (en) * | 2001-01-15 | 2002-09-25 | Dainippon Printing Co Ltd | Heat-transfer sheet and image printed article |
| CN102173234A (en) * | 2011-03-14 | 2011-09-07 | 杭州天地数码科技有限公司 | Water-based resin thermal transfer printing ribbon and preparation method thereof |
| CN105419475A (en) * | 2014-09-11 | 2016-03-23 | 洋紫荆油墨（浙江）有限公司 | Gluing-free thermal transfer printing ink having release function |
| CN104312282A (en) * | 2014-09-23 | 2015-01-28 | 广州大学 | Plastic product mold internal decorative thermal transfer printing ink and preparation method thereof |
| CN104476937A (en) * | 2014-12-29 | 2015-04-01 | 东莞市卓艺印刷制品有限公司 | Baking printing ink transfer film and preparation method thereof |
| CN104802541A (en) * | 2015-04-21 | 2015-07-29 | 武汉华工图像技术开发有限公司 | Heat transfer printing ink ribbon for metal material |
Non-Patent Citations (1)
| Title |
|---|
| 凌云星等: "《油墨技术手册（中）》", 31 May 2009, 印刷工业出版社 * |
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