CN104802541A - Heat transfer printing ink ribbon for metal material - Google Patents
Heat transfer printing ink ribbon for metal material Download PDFInfo
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- CN104802541A CN104802541A CN201510188643.8A CN201510188643A CN104802541A CN 104802541 A CN104802541 A CN 104802541A CN 201510188643 A CN201510188643 A CN 201510188643A CN 104802541 A CN104802541 A CN 104802541A
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- heat transfer
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- colour ribbon
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Abstract
The invention provides a heat transfer printing ink ribbon for a metal material. The heat transfer printing ink ribbon for the metal material comprises a base membrane layer, wherein a heat transfer printing ink layer is arranged on one side of the base membrane layer, and a back coating is arranged on the other side of the base membrane layer. The heat transfer printing ink layer comprises, by weight, 20-25% of thermoplastic acrylic resin, 10-20% of E-20 bisphenol A epoxy resin, 5-10% of E-12 bisphenol A epoxy resin, 3-6% of tetra hydro phthalic anhydride, 20-35% of compound wax, 0.5-1% of 2-hydroxy ethyl methacrylate phosphate, 8-15% of coloring agents and 10-20% of solvent. According to the heat transfer printing ink ribbon, application of the heat transfer printing ink ribbon to metal printing media is achieved, the adhesion to metal is good, and the purpose that heat transfer printing operation is directly conducted on the metal printing media is achieved; the scraping resistance is good, printed patterns are clear and complete, and the application range of the heat transfer printing ink ribbon is broadened.
Description
Technical field
The present invention relates to a kind of heat transfer colour ribbon, particularly a kind of heat transfer colour ribbon for metal material.
Background technology
Heat transfer colour ribbon is that hot transfer printing prints necessary consumable material, is also the core material determining thermal transfer imaging quality.Heat transfer colour ribbon be a kind of purposes widely, product that consumption is very huge.Along with the fast development of China's information technology and the continuous expansion of computer application field and deeply, the printing demand that people export high speed, high-quality is increasing, and printing type traditional on market is difficult to meet the omnibearing demand of user in price, print quality, print speed etc.Heat transfer printing carbon tape is owing to adopting the film of high strength slim and the ink of high concentration, and the mode adopting single to use, and thus quality of printed character is high, colour band long service life, and overcomes ink-jet and to spread and sink in paper, the defect such as soluble in water.
Along with the development of social demand and the renewal of technology, the print media of heat-transferring method is by single paper (common paper, recycled writing paper, synthetic paper, envelope, label paper) develop into plastics (PET, PVC, PP, PE etc.), fiber, composite, cloth, pottery, press polish material etc., but for metal material (as aluminium, magnadure, tinplate, stainless steel), the heat transfer colour ribbon be not also suitable at present, because its specific properties, when printing with heat transfer colour ribbon on the metal material, easily there is poor adhesive force, Scratch Resistance is poor, pattern and the unintelligible complete problem of word.
Summary of the invention
For the problem of above-mentioned prior art, the invention provides a kind of heat transfer colour ribbon for metal material, after printing, adhesive force is good, and Scratch Resistance is good, pattern and word complete display.
In order to achieve the above object, the present invention adopts following technical scheme: a kind of heat transfer colour ribbon for metal material, comprises base membrane layer, and described base membrane layer one side is provided with hot transferred ink layer, described base membrane layer another side is provided with back coating, and the weight fraction of each component of described hot transferred ink layer is:
Thermoplastic acrylic resin 20 ~ 25%
E-20 bisphenol A epoxide resin 10 ~ 20%
E-12 bisphenol A epoxide resin 5 ~ 10%
Tetrabydrophthalic anhydride 3 ~ 6%
Complex wax 20 ~ 35%
2-HEMA phosphoesterase 30 .5 ~ 1%
Colouring agent 8 ~ 15%
Solvent 10 ~ 20%.
As further preferably, also comprise auxiliary agent, the weight fraction 0 ~ 2% shared by it.
As further preferred, described thermoplastic acrylic resin vitrification point Tg is 95 ~ 105 DEG C.
As further preferred, described thermoplastic acrylic resin model is the acrylic resin of 7131-TK-50, and vitrification point Tg is 98 DEG C, and Eternal company produces.The acrylic resin of 7131-TK-50 is good to metal adhesion, print pattern complete display; Under normal temperature, hardness is high, is also conducive to the Scratch Resistance improving transferred ink layer.
As further preferred, described E-20 bisphenol A epoxide resin softening point is 64 ~ 76 DEG C, and the DER671 of preferred DOW company can improve hot transferred ink layer to the adhesive force of metal and Scratch Resistance.
As further preferred, described E-12 bisphenol A epoxide resin softening point is 85 ~ ~ 95 DEG C, and the R302 of preferred Mitsui can improve hot transferred ink layer to the adhesive force of metal and Scratch Resistance.
Described tetrabydrophthalic anhydride as the high-temperature curing agent of epoxy resin, can strengthen adhesive force and the Scratch Resistance of hot transferred ink layer and metal in above-mentioned formula.
As further preferred, described 2-HEMA phosphate can strengthen the adhesive force to metal, the PM-2 of preferred Sartomer.
As further preferred, the weight fraction of each component of described complex wax is:
Natural paraffin wax 30 ~ 36%
Synthetic wax 15 ~ 30%
Brazil wax 35 ~ 50%.
As further preferred, described colouring agent is carbon black.
As further preferably, described solvent be butanone, toluene, propylene glycol monomethyl ether one or more.
As further preferred, described base membrane layer is PET basement membrane.The good mechanical performance of PET film, its obdurability is best in all thermoplastics, tensile strength and impact strength more much higher than general film, and dimensionally stable, is suitable for printing.
The invention has the beneficial effects as follows: the invention provides a kind of heat transfer colour ribbon for metal, this heat transfer colour ribbon solves the application problem on metal species print media, good to metal adhesion, realizes directly on metallic print medium, carrying out hot transfer operation; And Scratch Resistance is good, print pattern complete display; Extend the range of application of heat transfer colour ribbon.
Accompanying drawing explanation
Fig. 1 is the structural representation of the embodiment of the present invention for the heat transfer colour ribbon of metal material.
In accompanying drawing, mark is described as follows: 1-PET plastic sheeting, 2-back coating, the hot transferred ink layer of 3-.
Detailed description of the invention
The realization of the object of the invention, functional characteristics and beneficial effect, be described further below in conjunction with specific embodiment and accompanying drawing.
Below in conjunction with the drawings and specific embodiments, technical scheme of the present invention is described in further detail, can better understand the present invention to make those skilled in the art and can be implemented, but illustrated embodiment is not as a limitation of the invention.
Embodiment 1
The present embodiment provides a kind of heat transfer colour ribbon for metal material, comprises PET basement membrane 1, back coating 2 and hot transferred ink layer 3, and the weight fraction of hot transferred ink layer 3 is:
7131-TK-50 25%
E-20 bisphenol A epoxide resin 18%
E-12 bisphenol A epoxide resin 8%
Tetrabydrophthalic anhydride 4%
Complex wax 23.5%
PM-2 0.5%
Carbon black 10%
Auxiliary agent 1%
Solvent 10%
The acrylic resin of described thermoplastic acrylic resin to be model be 7131-TK-50, Tg is 98 DEG C, and Eternal company produces.7131-TK-50 is good to metal adhesion, print pattern complete display; Under normal temperature, hardness is high, is also conducive to the Scratch Resistance improving transferred ink layer.
Described E-20 bisphenol A epoxide resin softening point is 64 ~ 76 DEG C, and the DER671 of preferred DOW company can improve hot transferred ink layer to the adhesive force of metal and Scratch Resistance.
Described E-12 bisphenol A epoxide resin softening point is 85 ~ ~ 95 DEG C, and the R302 of preferred Mitsui can improve hot transferred ink layer to the adhesive force of metal and Scratch Resistance.
Described tetrabydrophthalic anhydride as the high-temperature curing agent of epoxy resin, strengthens adhesive force and the Scratch Resistance of hot transferred ink layer and metal in above-mentioned formula.
The weight fraction of each component of described complex wax is:
Natural paraffin wax 35
Synthetic wax 28
Brazil wax 37
Embodiment 2
The present embodiment provides a kind of heat transfer colour ribbon for metal material, comprises PET basement membrane 1, back coating 2 and hot transferred ink layer 3, and the weight fraction of hot transferred ink layer 3 is:
7131-TK-50 20%
E-20 bisphenol A epoxide resin 20%
E-12 bisphenol A epoxide resin 6%
Tetrabydrophthalic anhydride 3%
Complex wax 21%
PM-2 1%
Carbon black 11%
Auxiliary agent 2%
Solvent 16%
The acrylic resin of described thermoplastic acrylic resin to be model be 7131-TK-50, Tg is 98 DEG C, and Eternal company produces.7131-TK-50 is good to metal adhesion, print pattern complete display; Under normal temperature, hardness is high, is also conducive to the Scratch Resistance improving transferred ink layer.
Described E-20 bisphenol A epoxide resin softening point is 64 ~ 76 DEG C, and the DER671 of preferred DOW company can improve hot transferred ink layer to the adhesive force of metal and Scratch Resistance.
Described E-12 bisphenol A epoxide resin softening point is 85 ~ ~ 95C, the R302 of preferred Mitsui, can improve hot transferred ink layer to the adhesive force of metal and Scratch Resistance.
Described tetrabydrophthalic anhydride as the high-temperature curing agent of epoxy resin, strengthens adhesive force and the Scratch Resistance of hot transferred ink layer and metal in above-mentioned formula.Upper sea cowry combination work Products.
The weight fraction of each component of described complex wax is:
Natural paraffin wax 30
Synthetic wax 29
Brazil wax 41
Embodiment 3
The present embodiment provides a kind of heat transfer colour ribbon for metal material, comprises PET basement membrane 1, back coating 2 and hot transferred ink layer 3, and the weight fraction of hot transferred ink layer 3 is:
7131-TK-50 22%
E-20 bisphenol A epoxide resin 15%
E-12 bisphenol A epoxide resin 10%
Tetrabydrophthalic anhydride 3%
Complex wax 23%
PM-2 1%
Carbon black 12%
Auxiliary agent 1%
Solvent 13%
The acrylic resin of described thermoplastic acrylic resin to be model be 7131-TK-50, Tg is 98 DEG C, and Eternal company produces.7131-TK-50 is good to metal adhesion, print pattern complete display; Under normal temperature, hardness is high, is also conducive to the Scratch Resistance improving transferred ink layer.
Described E-20 bisphenol A epoxide resin softening point is 64 ~ 76 DEG C, and the DER671 of preferred DOW company can improve hot transferred ink layer to the adhesive force of metal and Scratch Resistance.
Described E-12 bisphenol A epoxide resin softening point is 85 ~ ~ 95 DEG C, and the R302 of preferred Mitsui can improve hot transferred ink layer to the adhesive force of metal and Scratch Resistance.
Described tetrabydrophthalic anhydride as the high-temperature curing agent of epoxy resin, strengthens adhesive force and the Scratch Resistance of hot transferred ink layer and metal in above-mentioned formula.
The weight fraction of each component of described complex wax is:
Natural paraffin wax 32
Synthetic wax 28
Brazil wax 40
Test performance:
Claims (10)
1. for a heat transfer colour ribbon for metal material, comprise base membrane layer, described base membrane layer one side is provided with hot transferred ink layer, and described base membrane layer another side is provided with back coating, it is characterized in that: the weight fraction of each component of described hot transferred ink layer is:
Thermoplastic acrylic resin 20 ~ 25%
E-20 bisphenol A epoxide resin 10 ~ 20%
E-12 bisphenol A epoxide resin 5 ~ 10%
Tetrabydrophthalic anhydride 3 ~ 6%
Complex wax 20 ~ 35%
2-HEMA phosphoesterase 30 .5 ~ 1%
Colouring agent 8 ~ 15%
Solvent 10 ~ 20%.
2. the heat transfer colour ribbon for metal material according to claim 1, is characterized in that: also comprise auxiliary agent, the weight fraction 0 ~ 2% shared by it.
3. the heat transfer colour ribbon for metal material according to claim 1, is characterized in that: the vitrification point Tg of described thermoplastic acrylic resin is 95 ~ 105 DEG C.
4. the heat transfer colour ribbon for metal material according to claim 3, is characterized in that: the vitrification point Tg of described thermoplastic acrylic resin is 98 DEG C.
5. the heat transfer colour ribbon for metal material according to claim 1, is characterized in that: described E-20 bisphenol A epoxide resin softening point is 64 ~ 76 DEG C.
6. the heat transfer colour ribbon for metal material according to claim 1, is characterized in that: described E-12 bisphenol A epoxide resin softening point is 85 ~ ~ 95 DEG C.
7. the heat transfer colour ribbon for metal material according to claim 1, is characterized in that: the weight fraction of each component of described complex wax is:
Natural paraffin wax 30 ~ 36%
Synthetic wax 15 ~ 30%
Brazil wax 35 ~ 50%.
8. the heat transfer colour ribbon for metal material according to claim 1, is characterized in that: described colouring agent is carbon black.
9. the heat transfer colour ribbon for metal material according to claim 1, is characterized in that: described solvent be butanone, toluene, propylene glycol monomethyl ether one or more.
10. the heat transfer colour ribbon for metal material according to claim 1, is characterized in that: described base membrane layer is PET basement membrane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510188643.8A CN104802541B (en) | 2015-04-21 | 2015-04-21 | A kind of heat transfer colour ribbon for metal material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510188643.8A CN104802541B (en) | 2015-04-21 | 2015-04-21 | A kind of heat transfer colour ribbon for metal material |
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| CN104802541A true CN104802541A (en) | 2015-07-29 |
| CN104802541B CN104802541B (en) | 2017-12-22 |
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| CN201510188643.8A Expired - Fee Related CN104802541B (en) | 2015-04-21 | 2015-04-21 | A kind of heat transfer colour ribbon for metal material |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106183515A (en) * | 2016-07-11 | 2016-12-07 | 鹏码实业(上海)有限公司 | A kind of heat transfer colour ribbon for metal material and preparation method thereof |
| CN108047812A (en) * | 2018-01-24 | 2018-05-18 | 佛山市三水金恒金属制品有限公司 | One kind is used for metallic aluminium thermal transfer ink |
| CN108047814A (en) * | 2018-01-24 | 2018-05-18 | 佛山市三水金恒金属制品有限公司 | A kind of high flexible thermal transfer ink of aluminium alloy |
| CN108178946A (en) * | 2018-01-24 | 2018-06-19 | 佛山市三水金恒金属制品有限公司 | The preparation method of the high flexible thermal transfer ink of aluminium alloy |
| CN108276824A (en) * | 2018-01-24 | 2018-07-13 | 佛山市三水金恒金属制品有限公司 | A kind of preparation method for metallic aluminium thermal transfer ink |
| CN112759781A (en) * | 2020-12-31 | 2021-05-07 | 福建省腾盈印刷工贸有限公司 | PET printing film special for water-based ink and manufacturing method thereof |
| CN114507370A (en) * | 2020-12-30 | 2022-05-17 | 湖南鼎一致远科技发展有限公司 | Ribbon structure and preparation method thereof |
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| JPH0310879A (en) * | 1989-06-08 | 1991-01-18 | Matsushita Electric Ind Co Ltd | Thermal transfer ink ribbon |
| CN101642987A (en) * | 2008-08-05 | 2010-02-10 | 焦作市卓立烫印材料有限公司 | Bar code carbon ribbon for ceramics and preparation method thereof |
| CN102381063A (en) * | 2011-07-26 | 2012-03-21 | 河北工程大学 | Heat-transfer-printing color tape capable of being printed with high-temperature-resistant marks and manufacturing method thereof |
| CN102673210A (en) * | 2012-05-23 | 2012-09-19 | 南京科晖印刷科技有限公司 | Thermal transfer coating film for metal products, preparation method thereof and metal products |
| CN103042845A (en) * | 2013-01-15 | 2013-04-17 | 杭州兴甬复合材料有限公司 | Thermal transfer ribbon |
| CN203126159U (en) * | 2012-05-23 | 2013-08-14 | 南京科晖印刷科技有限公司 | Heat transfer printing coating film applied to metal products |
| CN103273747A (en) * | 2013-05-31 | 2013-09-04 | 杭州瑞玖数码科技有限公司 | Heat transfer printing inked ribbon manufacturing method for advertisement banner |
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2015
- 2015-04-21 CN CN201510188643.8A patent/CN104802541B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JPH0310879A (en) * | 1989-06-08 | 1991-01-18 | Matsushita Electric Ind Co Ltd | Thermal transfer ink ribbon |
| CN101642987A (en) * | 2008-08-05 | 2010-02-10 | 焦作市卓立烫印材料有限公司 | Bar code carbon ribbon for ceramics and preparation method thereof |
| CN102381063A (en) * | 2011-07-26 | 2012-03-21 | 河北工程大学 | Heat-transfer-printing color tape capable of being printed with high-temperature-resistant marks and manufacturing method thereof |
| CN102673210A (en) * | 2012-05-23 | 2012-09-19 | 南京科晖印刷科技有限公司 | Thermal transfer coating film for metal products, preparation method thereof and metal products |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106183515A (en) * | 2016-07-11 | 2016-12-07 | 鹏码实业(上海)有限公司 | A kind of heat transfer colour ribbon for metal material and preparation method thereof |
| CN108047812A (en) * | 2018-01-24 | 2018-05-18 | 佛山市三水金恒金属制品有限公司 | One kind is used for metallic aluminium thermal transfer ink |
| CN108047814A (en) * | 2018-01-24 | 2018-05-18 | 佛山市三水金恒金属制品有限公司 | A kind of high flexible thermal transfer ink of aluminium alloy |
| CN108178946A (en) * | 2018-01-24 | 2018-06-19 | 佛山市三水金恒金属制品有限公司 | The preparation method of the high flexible thermal transfer ink of aluminium alloy |
| CN108276824A (en) * | 2018-01-24 | 2018-07-13 | 佛山市三水金恒金属制品有限公司 | A kind of preparation method for metallic aluminium thermal transfer ink |
| CN114507370A (en) * | 2020-12-30 | 2022-05-17 | 湖南鼎一致远科技发展有限公司 | Ribbon structure and preparation method thereof |
| CN112759781A (en) * | 2020-12-31 | 2021-05-07 | 福建省腾盈印刷工贸有限公司 | PET printing film special for water-based ink and manufacturing method thereof |
| CN112759781B (en) * | 2020-12-31 | 2022-08-23 | 福建省腾盈印刷工贸有限公司 | PET printing film special for water-based ink and manufacturing method thereof |
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| CN104802541B (en) | 2017-12-22 |
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| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Xu Xiaoguang Inventor after: Mou Jingwen Inventor after: Lu Qin Inventor after: Lin Die Inventor after: Huang Ting Inventor after: Kou Qianqian Inventor before: Xu Xiaoguang Inventor before: Zheng Chengfu |
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Granted publication date: 20171222 Termination date: 20180421 |