CN103587259A - Thermal transfer ribbon for printing edge crushing resin base bar code and preparing method thereof - Google Patents
Thermal transfer ribbon for printing edge crushing resin base bar code and preparing method thereof Download PDFInfo
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- CN103587259A CN103587259A CN201310561930.XA CN201310561930A CN103587259A CN 103587259 A CN103587259 A CN 103587259A CN 201310561930 A CN201310561930 A CN 201310561930A CN 103587259 A CN103587259 A CN 103587259A
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Abstract
The invention provides a thermal transfer ribbon for printing an edge crushing resin base bar code. The thermal transfer ribbon for printing the edge crushing resin base bar code is composed of a ribbon base, a back coating and a thermal transfer printing layer, wherein the two sides of the ribbon base are coated with the back coating and the thermal transfer printing layer respectively. The thermal transfer printing layer is composed of a release layer and a color layer and the surface of one side of the ribbon base is provided with the release layer and the color layer in sequence from the inner portion to the outer portion. The release layer is composed of wax and a binder, wherein the release layer comprises, by weight, 5%-15% of the binder, and the color layer is composed of the binder, the wax, dye and an additive. The thermal transfer ribbon for printing the edge crushing resin base bar code has the advantages of being reasonable in design, simple in preparing method, convenient to prepare, easy to popularize and apply, capable of enabling the release layer and the color layer to be printed on a flexible package material through an edge crushing type bar code printer, high in printing speed, good in adhesive force and good in application prospect.
Description
Technical field
The invention belongs to technical field of hot stamping materials, be specifically related to a kind of limit pressurizing resin base bar code printing ribbon and preparation method thereof.
Background technology
In recent years, development along with hot transfer technique, enterprise is for enhancing productivity, and the floated printer of high speed occurs day by day, and it has obvious advantage, print speed is high, the printer life-span is long, thereby it is popular gradually to be more and more subject to being widely used ， developed country, floated printing carbon ribbon expands and has developed hot transfer printing field, and limit pressure type carbon ribbon is also simultaneously along with the direction that develops into barcode ribbon and carry out research and development of products.
Summary of the invention
The object of the present invention is to provide the limit pressurizing resin base bar code printing ribbon that a kind of preparation method is easy, be easy to apply.
For achieving the above object, the technical solution used in the present invention is, a kind of limit pressurizing resin base bar code printing ribbon, by tape base and back coating and the thermal transfer ink layer of coating respectively tape base both sides form, it is characterized in that, thermal transfer ink layer is comprised of abscission layer and chromatograph, by tape base one side surface, is followed successively by from inside to outside abscission layer and chromatograph; Described abscission layer is comprised of wax and link stuff, and wherein the weight content of link stuff is 5%-15%; Described chromatograph is comprised of link stuff, wax, pigment and auxiliary agent.
Described link stuff can be one or both in EVA resin or styrene acrylic resin.
The VA(vinyl acetate of described EVA resin) mass content is 19-33%, MI(melt index (MI)) below 150.
Described wax can be one or more in OPE, paraffin, rice bran wax, candelila wax, microwax, Tissuemat E, palm wax, insect wax, montan wax, cerosin or beeswax.
In described chromatograph, the percentage by weight of each raw material is: link stuff 50 ~ 85%, wax 0 ~ 20%, pigment 10 ~ 30%, auxiliary agent 0 ~ 5%.
Described tape base can be polyester film, preferred high strength polyester film.
Above-mentioned base thick is 4.5 μ m, and back coating thickness is 0.1 ~ 0.2 μ m, abscission layer thickness 0.5 ~ 1.5 μ m, and chromatograph thickness is 1-2 μ m, limit pressurizing resin base bar code printing ribbon gross thickness is 6.1 ~ 8.2 μ m.
Described styrene acrylic resin is the resin that styrene and acrylic monomers copolymerization make, and wherein styrene monomer content is 35-45%(mass fraction).
Described acrylic monomers can be one or more in methacrylic acid, butyl methacrylate, butyl acrylate.
The preparation method of described limit pressurizing resin base bar code printing ribbon is to comprise the following steps: a, with solvent, the dilution of the link stuff of back coating and auxiliary agent is mixed after, be coated on tape base one side surface, dry; B, by the wax of abscission layer and link stuff with dissolution with solvents evenly after, be coated on the other side surface of tape base, dry; C, with solvent, link stuff, wax, pigment and auxiliary agent dilution are mixed, are ground after, coat abscission layer outside, dry and form chromatograph.
In above-mentioned steps a, solvent used can be gasoline, and bake out temperature is 70 ℃-80 ℃.
In above-mentioned steps b, solvent used can be toluene or dimethylbenzene, and bake out temperature is 70 ℃-80 ℃.
In above-mentioned steps c, solvent used is the mixed solvent of toluene and butanone, and wherein the weight ratio of toluene and butanone is 5: 2, and bake out temperature is 70 ℃-100 ℃.
In the present invention, in back coating, the composition of link stuff and auxiliary agent can be selected by the prior art in hot transfer printing bar code field.
Limit of the present invention pressurizing resin base bar code printing ribbon is reasonable in design, preparation method is easy, be easy to apply, and through limit pressure type bar code printer, abscission layer and chromatograph can be transferred in flexible package material, has print speed high, the good feature of adhesive force, thereby have a good application prospect.
The specific embodiment
Below in conjunction with specific embodiment, further illustrate technical scheme of the present invention, but protection scope of the present invention is not limited to this.Link stuff in following examples is one or both of EVA resin, styrene acrylic resin, and tape base is biaxial tension PET film; In abscission layer, resin is that softening point is the EVA resin of 80-100 ℃; In chromatograph, the EVA resin VA content of selecting is 19-33%(mass content), MI index is below 150; Styrene acrylic resin is that styrene-content is at 35-45%(mass fraction) between with the resin of acrylic acid copolymer.
Embodiment 1
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.1 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 0.5 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 80 ℃, dry the chromatograph that forms thickness 1.5 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 6.6 μ m of the present invention.
Embodiment 2
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.2 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 1.0 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 80 ℃, dry the chromatograph that forms thickness 2 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 7.7 μ m of the present invention.
Embodiment 3
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.2 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 1.0 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 80 ℃, dry the chromatograph that forms thickness 1.5 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 7.2 μ m of the present invention.
Embodiment 4
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.2 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 1.5 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 80 ℃, dry the chromatograph that forms thickness 2 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 8.2 μ m of the present invention.
Embodiment 5
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.1 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 0.5 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 80 ℃, dry the chromatograph that forms thickness 1 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 6.1 μ m of the present invention.
Embodiment 6
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.2 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 1 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 80 ℃, dry the chromatograph that forms thickness 1.5 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 7.2 μ m of the present invention.
Embodiment 7
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.2 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 1.5 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 80 ℃, dry the chromatograph that forms thickness 1 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 7.2 μ m of the present invention.
Embodiment 8
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.1 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 1.5 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 80 ℃, dry the chromatograph that forms thickness 1 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 7.1 μ m of the present invention.
Embodiment 9
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.2 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 1 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 100 ℃, dry the chromatograph that forms thickness 2 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 7.7 μ m of the present invention.
Embodiment 10
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.2 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 0.5 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 80 ℃, dry the chromatograph that forms thickness 1.5 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 6.7 μ m of the present invention.
Embodiment 11
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.1 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 1 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 82 ℃, dry the chromatograph that forms thickness 1 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 6.6 μ m of the present invention.
Embodiment 12
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.1 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 1.5 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 85 ℃, dry the chromatograph that forms thickness 1.5 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 7.6 μ m of the present invention.
Embodiment 13
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.2 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 0.5 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 80 ℃, dry the chromatograph that forms thickness 2 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 7.2 μ m of the present invention.
Embodiment 14
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.2 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 1.5 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 80 ℃, dry the chromatograph that forms thickness 1.5 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 7.7 μ m of the present invention.
Embodiment 15
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.1 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 1 μ m at 70 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 100 ℃, dry the chromatograph that forms thickness 2 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 7.6 μ m of the present invention.
Embodiment 16
After the link stuff dilution of back coating being mixed with gasoline, then add before use auxiliary agent, being coated on thickness is tape base one side surface of 4.5 μ m, dries the back coating that forms thickness 0.2 μ m at 80 ℃; The kind that abscission layer and chromatograph are raw materials used and quality proportioning are as following table:
The preparation method of abscission layer is, with toluene solvant, the resin of abscission layer and wax dissolved, and mixes, and is coated on the other side surface of tape base, dries the abscission layer that forms thickness 0.5 μ m at 80 ℃; The preparation method of chromatograph is, with toluene and butanone, link stuff, wax are dissolved, add in proportion again pigment and auxiliary agent, be ground to pigment fineness and be less than 2.5 μ m, after grinding, coat abscission layer outside, at 80 ℃, dry the chromatograph that forms thickness 1 μ m, obtain the limit pressurizing resin base bar code printing ribbon of gross thickness 6.2 μ m of the present invention.
Claims (10)
1. a limit pressurizing resin base bar code printing ribbon, by tape base and back coating and the thermal transfer ink layer of coating respectively tape base both sides form, it is characterized in that, thermal transfer ink layer is comprised of abscission layer and chromatograph, by tape base one side surface, is followed successively by from inside to outside abscission layer and chromatograph; Described abscission layer is comprised of wax and link stuff, and wherein the weight content of link stuff is 5%-15%; Described chromatograph is comprised of link stuff, wax, pigment and auxiliary agent.
2. a kind of limit as claimed in claim 1 pressurizing resin base bar code printing ribbon, is characterized in that, described link stuff is one or both of EVA resin or styrene acrylic resin, and the VA content of EVA resin is that 19-33%, MI index are below 150.
3. a kind of limit as claimed in claim 1 pressurizing resin base bar code printing ribbon, in described chromatograph, the percentage by weight of each raw material is: link stuff 50 ~ 85%, wax 0 ~ 20%, pigment 10 ~ 30%, auxiliary agent 0 ~ 5%.
4. a kind of limit as claimed in claim 1 pressurizing resin base bar code printing ribbon, it is characterized in that, described wax is one or more in OPE, paraffin, rice bran wax, candelila wax, microwax, Tissuemat E, palm wax, insect wax, montan wax, cerosin or beeswax.
5. a kind of limit as claimed in claim 1 pressurizing resin base bar code printing ribbon, is characterized in that, described tape base is polyester film.
6. a kind of limit as claimed in claim 1 pressurizing resin base bar code printing ribbon, it is characterized in that, described base thick is 4.5 μ m, back coating thickness is 0.1 ~ 0.2 μ m, abscission layer thickness 0.5 ~ 1.5 μ m, chromatograph thickness is 1-2 μ m, and limit pressurizing resin base bar code printing ribbon gross thickness is 6.1 ~ 8.2 μ m.
7. a kind of limit as claimed in claim 2 pressurizing resin base bar code printing ribbon, is characterized in that, styrene acrylic resin is the resin that styrene and acrylic monomers copolymerization make, and wherein styrene monomer content is 35-45%.
8. a kind of limit as claimed in claim 7 pressurizing resin base bar code printing ribbon, is characterized in that, described acrylic monomers is one or more in methacrylic acid, butyl methacrylate, butyl acrylate.
9. a preparation method for limit pressurizing resin base bar code printing ribbon as described in claim 1-8, is characterized in that, comprises the following steps: a, with solvent, the dilution of the link stuff of back coating and auxiliary agent is mixed after, be coated on tape base one side surface, dry; B, by the wax of abscission layer and link stuff with dissolution with solvents evenly after, be coated on the other side surface of tape base, dry; C, with solvent, link stuff, wax, pigment and auxiliary agent dilution are mixed, are ground after, coat abscission layer outside, dry and form chromatograph.
10. the preparation method of limit as claimed in claim 9 pressurizing resin base bar code printing ribbon, is characterized in that, in described step a, solvent used is gasoline, and bake out temperature is 70 ℃-80 ℃; In described step b, solvent used is toluene or dimethylbenzene, and bake out temperature is 70 ℃-80 ℃; In described step c, solvent used is the mixed solvent of toluene and butanone, and wherein the weight ratio of toluene and butanone is 5: 2, and bake out temperature is 70 ℃-100 ℃.
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| CN106274090A (en) * | 2016-08-10 | 2017-01-04 | 河南卓立膜材料股份有限公司 | A kind of aqueous environment protection concora crush resin base carbon ribbon and preparation method thereof |
| CN111690162A (en) * | 2020-07-22 | 2020-09-22 | 曲阜市玉樵夫科技有限公司 | Scroll ribbon |
| CN111848879A (en) * | 2020-08-14 | 2020-10-30 | 广州中码科技股份有限公司 | Bar code carbon tape edge pressure resin and preparation method thereof |
| CN116729012A (en) * | 2023-06-12 | 2023-09-12 | 河南东方印新材料科技有限公司 | Machine tattooing transfer film and production process and use method thereof |
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