CN102140276A - High temperature steaming resistant ink for ink jet recording - Google Patents
High temperature steaming resistant ink for ink jet recording Download PDFInfo
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- CN102140276A CN102140276A CN2011101032928A CN201110103292A CN102140276A CN 102140276 A CN102140276 A CN 102140276A CN 2011101032928 A CN2011101032928 A CN 2011101032928A CN 201110103292 A CN201110103292 A CN 201110103292A CN 102140276 A CN102140276 A CN 102140276A
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Abstract
The invention relates to high temperature steaming resistant ink for current ink jet recording and the ink can have good high temperature steaming resistance, scuff resistance and printing drying property. The ink is characterized in that the ink is an ink composite using polyurethane as main adhesive. The viscosity of the ink is 2-10CP/25 DEG C, the electrical conductivity is 500-2000mu S and the surface tension is 27-35Dyn/cm. The ink contains one or more of organic solvents, adhesives, colourants, additives and the like. As vinyl chloride/vinyl acetate copolymer or polyketide resin or cellulosic resin is added in the ink, the adhesion performance on base materials such as glass, metal, polypropylene or polyethylene can be increased and the steam resistance can be increased. After steamed at high temperature, the high temperature steaming resistant ink for current ink jet recording can not fade, fall off, seep or move.
Description
Technical field
The present invention relates to the printing ink paint field, be specifically related to a kind of ink-vapor recording high-temperature boiling resistant ink.
Background technology
Along with expanding economy, growth in the living standard, people more and more pay close attention to safety and sanitation, the trade mark of food and medicine makeup etc., and food sanitation, medical rules and trade mark act etc. have been formulated successively for protection human consumer's interests in countries in the world.Clearly stipulate in these rules must indicate date manufactured, lot number and quality guaranteed period etc. on the label of products such as medicine, makeup, food, beverage.Because code jetting device is a noncontact spray printing and applicable to the product of different shape, but spray printing date manufactured, lot number, quality guaranteed period, barcode and simple symbol, and speed is fast, cost is low, is used widely in countries in the world at present.
According to the spray printing ground of identification information and the difference of environment for use, employed ink also there is different requirements.In the food product pack goods, package encapsulation is well back according to national legislation spray printing identification information, then in 100 ℃ of boiling water or 120 ℃ of steam high-temperature sterilization sterilization boilings.In the high temperature steaming process, requiring can not have considerable change before and after the identification information boiling, and ink does not move in digestion process, nondiscoloration, requirement such as do not come off.
In the market the ink-vapor recording of Chu Shouing with the high-temperature boiling resistant ink have price height, quality instability, printing is unintelligible, boiling resistance can be not good, wear resisting property is bad, and is not good etc. to metal, glass, PP, PE sticking power.
Therefore, a kind of novel fire resistant boiling ink that adapts to the modernization requirement of exploitation is one of ink-jet technology field urgent problem.
Summary of the invention
For solve the deficiency of existing ink-vapor recording, develop with the high-temperature boiling resistant ink have boiling resistance can excellence, high performance-price ratio, steady quality, sticking power, crocking resistance, glossiness, resolving power, compatible all good high-performance ink-jet write down and use the high-temperature boiling resistant ink.Coding clear picture jail, rub resistance, base material especially metal, glass, polyethylene, polypropylene etc. are had good sticking power, can satisfy the requirement of high temperature steaming spray printing.
For satisfying above requirement, the present invention contains composition for ink such as one or more organic solvents, tamanori, tinting material, auxiliary agent, and this ink viscosity is 2-10CP/25 ℃, specific conductivity 500-2000 μ S, and surface tension is 27-35Dyn/cm.
The objective of the invention is to realize by following technique means: ink-vapor recording high-temperature boiling resistant ink is characterized in that by massfraction it being to be prepared from by following raw material and solvent:
Below just respectively ink-vapor recording each component with the high-temperature boiling resistant ink is elaborated:
Solvent that the present invention is used or solubility promoter are that acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK), pimelinketone, cyclopentanone, methyl acetate, ethyl acetate, butylacetate, isopropyl acetate, methyl lactate, ethyl lactate, n-Butyl lactate gylcol ether, propylene glycol ethers, carbonatoms are low-carbon (LC) alcohols, methylene dichloride, trichloromethane, tetracol phenixin, chlorobutane, tetrahydrofuran (THF), N-Methyl pyrrolidone, polyoxyethylene glycol, phthalic acid lipid of 1-9 etc. or its composition.The low carbon number alcohols can comprise methyl alcohol, ethanol, Virahol, propyl carbinol, primary isoamyl alcohol, propylene glycol, glycerol, the one two different glycol etc. that contract; Described gylcol ether can comprise ethylene glycol monomethyl ether, ethylene glycol ethyl ether, butyl glycol ether, diethylene glycol diethyl ether etc.; Described propylene glycol ethers comprises propylene glycol monomethyl ether, propylene-glycol ethyl ether etc., dipropylene glycol methyl ether; Phthalate is dioctyl phthalate (DOP), dibutyl phthalate etc.The solvent usage quantity accounts for the 20-80wt% of ink-vapor recording with high-temperature boiling resistant ink total mass, preferred mass percentage ratio 50-75wt%; The solubility promoter usage quantity accounts for the 1-45wt% of ink-vapor recording with high-temperature boiling resistant ink total mass, preferred mass percentage ratio 3-18wt%.Solvent and solubility promoter mainly work effects such as regulating viscosity, dissolving resin.
The used tackiness agent of the present invention is one or more the combination in urethane resin, vinyl chloride-vinyl acetate resin, polyketone resin, the celluosic resin.With the urethane resin is matrix resin, and its usage quantity accounts for the 2-20wt% of ink-vapor recording with high-temperature boiling resistant ink total mass, and preferred mass percentage ratio is 412%.According to one or more the composite uses in different grounds and environment for use and vinyl chloride-vinyl acetate resin, polyketone resin, the celluosic resin to improve its boiling resistance energy and to the sticking power of ground, the assisted resin usage quantity is 0.35% of a total mass, and preferential mass percent is 0.5-3%.Suitably select resin also can play the effect of regulating ink.
The used tinting material of the present invention is that metallized dye, oil-soluble colourant, fluorescence dye, carbon black, titanium dioxide and known other name are called " C.I. solvent dye " and " C.I. pigment ".Mainly comprise solvent black 27, solvent black 29, solvent black 34, solvent blue 70, solvent red 124, carbon black, titanium dioxide etc.Tinting material mainly plays colouring, selects different tinting materials according to different ground colors with client's needs.
The used adhesion promoter of the present invention is fluorine modified polyorganosiloxane, phthalate ester coupling agent, organosilane, chlorinatedpolyethylene etc.Its usage quantity accounts for the 0-5wt% of ink-vapor recording with high-temperature boiling resistant ink total mass, and preferred mass percentage ratio is 0.2-2wt%.Adhesion promoter can improve the ink-vapor recording sticking power of high-temperature boiling resistant ink to plastic bottom materials such as metal, glass, polyethylene, polypropylene.
Other auxiliary agent used in the present invention comprises electricity and leads additives such as conditioning agent, sanitas, PH conditioning agent, tensio-active agent, chemical stabilizer softening agent.Because ink-vapor recording will form the ink droplet of uniformity and spray printing on the little ground of surface tension with the high-temperature boiling resistant ink, must the adding certain amount of surfactant, control its surface tension in certain scope.
Compared with prior art the present invention has following tangible advantage:
1, this ink-vapor recording has anti-100 ℃ of boiling water or 120 ℃ of steam boiling high-temperature sterilization sterilizations with the high-temperature boiling resistant ink, colour-fast behind the high temperature steaming, do not come off, impermeable, do not move.
2, this ink-vapor recording is with containing adhesion promoter in the high-temperature boiling resistant ink set, and grounds such as metal, glass, polyethylene, polypropylene are had very strong sticking power, ink-vapor recording with the wear resistance of high-temperature boiling resistant ink, resistance to marring, polluting proofing property, smooth property etc.。
Embodiment
The present invention is described in further detail below in conjunction with embodiment, but the present invention is not limited to these examples.
Example 1
A kind of ink-vapor recording is made up of following component and quality percentage composition with the high-temperature boiling resistant ink:
Through Imaje 9020 ink jet unit spray printings on the OPP material, 120 ℃ of high-temperature vapour boilings 40 minutes, no considerable change before and after the boiling of spray printing identification information before and after the boiling, do not have behind the high temperature steaming fade, does not have come off, do not have infiltration, nothing is moved.
Example 2
A kind of ink-vapor recording is made up of following component and quality percentage composition with the high-temperature boiling resistant ink:
Viscosity is 5.2CP/25 ℃ after tested, surface tension 27.9Dyn/cm, electric conductivity 890 μ S.100 ℃ of high temperature steamings are 30 minutes on the PE packing film, no considerable change before and after the boiling of spray printing identification information before and after the boiling, do not have behind the high temperature steaming fade, does not have come off, do not have infiltration, nothing is moved.
Example 3
A kind of ink-vapor recording is made up of following component and quality percentage composition with the high-temperature boiling resistant ink:
This printing ink has environment-friendly type, do not contain benzene class, ketones solvent, after tested at metal material to 120 ℃ of high-temperature vapour boilings 40 minutes, no considerable change before and after the boiling of spray printing identification information before and after the boiling, do not have behind the high temperature steaming fade, does not have come off, do not have infiltration, nothing is moved.
The above is a specific examples of the present invention only, and is not intended to limit the scope of the invention, and is within the spirit and principles in the present invention all, the institute make any modification, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (9)
1. an ink-vapor recording is with the high-temperature boiling resistant ink, it is characterized in that contain composition for ink such as one or more organic solvents, tamanori, tinting material, auxiliary agent, this ink viscosity is 2-10CP/25 ℃, specific conductivity 500-2000 μ S, surface tension is 27-35Dyn/cm.
2. according to the described ink-vapor recording of claim 1 high-temperature boiling resistant ink, it is characterized in that, what below relate to percentage composition complete is the mass percent of total mass, ink is by the 20-80wt% solvent, 1-45wt% solubility promoter, 2-20wt% tackiness agent, the 0.5-20wt% tinting material, the 0-5wt% adhesion promoter, conductive auxiliary agent 0.01-5wt%, other auxiliary agent 0-5wt% forms.
3. according to claim 1 and the described ink-vapor recording of claim 2 high-temperature boiling resistant ink, it is characterized in that solvent or solubility promoter are by acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK), pimelinketone, cyclopentanone, methyl acetate, ethyl acetate, butylacetate, isopropyl acetate, methyl lactate, ethyl lactate, n-Butyl lactate, gylcol ether, the propylene glycol ethers, carbonatoms is the low-carbon (LC) alcohols of 1-9, methylene dichloride, trichloromethane, tetracol phenixin, chlorobutane, tetrahydrofuran (THF), N-Methyl pyrrolidone, polyoxyethylene glycol, phthalic acid lipid etc. or its composition.
4. according to claim 1 and the described ink-vapor recording of claim 2 high-temperature boiling resistant ink, described tackiness agent is: the combination of one or more in urethane resin, vinyl chloride-vinyl acetate resin, polyketone resin, the celluosic resin.
5. according to claim 1 and claim 2 and the described ink-vapor recording of claim 4 high-temperature boiling resistant ink, be matrix resin with the urethane resin.
6. according to claim 1 and the described ink-vapor recording of claim 2 high-temperature boiling resistant ink, described tinting material is that metallized dye, oil-soluble colourant, fluorescence dye, carbon black, titanium dioxide and known other name are called " C.I. solvent dye " and " C.I. pigment ".
7. according to claim 1 and the described ink-vapor recording of claim 2 high-temperature boiling resistant ink, described adhesion promoter comprises fluorine modified polyorganosiloxane, phthalate ester coupling agent, organosilane, chlorinatedpolyethylene etc.
8. according to claim 1 and the described ink-vapor recording of claim 2 high-temperature boiling resistant ink, described other auxiliary agent can comprise electricity and lead additives such as conditioning agent, sanitas, PH conditioning agent, tensio-active agent, chemical stabilizer, softening agent.
9. according to claim 1 and claim 2 and the described ink-vapor recording of claim 3 high-temperature boiling resistant ink, described low carbon number alcohols can comprise methyl alcohol, ethanol, Virahol, propyl carbinol, primary isoamyl alcohol, propylene glycol, glycerol, contract monobasic or di-alcoholss such as two different glycol; Described gylcol ether can comprise ethylene glycol monomethyl ether, ethylene glycol ethyl ether, butyl glycol ether, diethylene glycol diethyl ether etc.; Described propylene glycol ethers comprises propylene glycol monomethyl ether, propylene-glycol ethyl ether, dipropylene glycol methyl ether etc., and described phthalate is dioctyl phthalate (DOP), dibutyl phthalate etc.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2011101032928A CN102140276A (en) | 2011-04-25 | 2011-04-25 | High temperature steaming resistant ink for ink jet recording |
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| CN2011101032928A CN102140276A (en) | 2011-04-25 | 2011-04-25 | High temperature steaming resistant ink for ink jet recording |
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| CN102140276A true CN102140276A (en) | 2011-08-03 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102399472A (en) * | 2011-11-04 | 2012-04-04 | 江苏泰格油墨有限公司 | Printing ink substituting gold stamping anodized aluminium |
| CN102757695A (en) * | 2012-08-08 | 2012-10-31 | 王文滔 | Ethylene-vinyl acetate copolymer (EVA) printing ink |
| CN103980762A (en) * | 2014-05-23 | 2014-08-13 | 黄山新力油墨科技有限公司 | Steaming-resistant and boiling-resistant printing ink and preparation method thereof |
| CN104650648A (en) * | 2015-02-26 | 2015-05-27 | 韦棋 | Wear-resistant and high-temperature-resistant printing ink |
| CN104804551A (en) * | 2015-04-13 | 2015-07-29 | 陈良伢 | High-temperature-resistant ink containing modified resin |
| CN105440798A (en) * | 2015-12-08 | 2016-03-30 | 北海市天硌打印耗材有限公司 | Ink for ink-jet printer and preparing method thereof |
| CN108248191A (en) * | 2017-08-29 | 2018-07-06 | 滕州市耀海玻雕有限公司 | A kind of preparation method of antibacterial colorful glass |
| CN117887307A (en) * | 2024-01-17 | 2024-04-16 | 广州市科帕电子科技有限公司 | High ink jet print Wen Moshui |
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| CN101198664A (en) * | 2005-06-14 | 2008-06-11 | 东洋油墨制造株式会社 | Inkjet ink for polyvinyl chloride resin sheet |
| CN101508760A (en) * | 2009-01-22 | 2009-08-19 | 中国印钞造币总公司 | Oil modified phenolic resin connection material and preparation thereof |
| CN101831215A (en) * | 2010-04-28 | 2010-09-15 | 王学珍 | High-performance jet ink |
| CN101987932A (en) * | 2010-11-03 | 2011-03-23 | 北京赛腾工业标识系统有限公司 | High-temperature steam endurance ink for spraying code and printing |
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2011
- 2011-04-25 CN CN2011101032928A patent/CN102140276A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101198664A (en) * | 2005-06-14 | 2008-06-11 | 东洋油墨制造株式会社 | Inkjet ink for polyvinyl chloride resin sheet |
| CN101508760A (en) * | 2009-01-22 | 2009-08-19 | 中国印钞造币总公司 | Oil modified phenolic resin connection material and preparation thereof |
| CN101831215A (en) * | 2010-04-28 | 2010-09-15 | 王学珍 | High-performance jet ink |
| CN101987932A (en) * | 2010-11-03 | 2011-03-23 | 北京赛腾工业标识系统有限公司 | High-temperature steam endurance ink for spraying code and printing |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102399472A (en) * | 2011-11-04 | 2012-04-04 | 江苏泰格油墨有限公司 | Printing ink substituting gold stamping anodized aluminium |
| CN102757695A (en) * | 2012-08-08 | 2012-10-31 | 王文滔 | Ethylene-vinyl acetate copolymer (EVA) printing ink |
| CN103980762A (en) * | 2014-05-23 | 2014-08-13 | 黄山新力油墨科技有限公司 | Steaming-resistant and boiling-resistant printing ink and preparation method thereof |
| CN104650648A (en) * | 2015-02-26 | 2015-05-27 | 韦棋 | Wear-resistant and high-temperature-resistant printing ink |
| CN104804551A (en) * | 2015-04-13 | 2015-07-29 | 陈良伢 | High-temperature-resistant ink containing modified resin |
| CN105440798A (en) * | 2015-12-08 | 2016-03-30 | 北海市天硌打印耗材有限公司 | Ink for ink-jet printer and preparing method thereof |
| CN105440798B (en) * | 2015-12-08 | 2018-11-02 | 北海市天硌打印耗材有限公司 | A kind of ink-jet printer ink and preparation method thereof |
| CN108248191A (en) * | 2017-08-29 | 2018-07-06 | 滕州市耀海玻雕有限公司 | A kind of preparation method of antibacterial colorful glass |
| CN117887307A (en) * | 2024-01-17 | 2024-04-16 | 广州市科帕电子科技有限公司 | High ink jet print Wen Moshui |
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Application publication date: 20110803 |