CN101671504A - Soybean oil type offset printing color ink - Google Patents
Soybean oil type offset printing color ink Download PDFInfo
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- CN101671504A CN101671504A CN200910075669A CN200910075669A CN101671504A CN 101671504 A CN101671504 A CN 101671504A CN 200910075669 A CN200910075669 A CN 200910075669A CN 200910075669 A CN200910075669 A CN 200910075669A CN 101671504 A CN101671504 A CN 101671504A
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- offset printing
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Abstract
The invention relates to a soybean oil type offset printing color ink which aims at realizing safety, environmental protection and good coloring property. The oil ink comprises the following components by weight percent: 10-25% of organic pigment, 5-10% of extender pigment, 20-30% of soybean oil, 5-15% of bleaching sesame oil, 10-20% of mineral oil, 25-35% of resin, 0.5-1% of antioxidant and 0.1-0.5% of gelatinizing agent; the sum of weights of all the components is 100%, wherein the mineral oil is any one of high-boiling point kerosene and solvent oil or the mixture of the two by any proportion; the resin is the mixture of rosin modified phenolic resin and petroleum resin, wherein the rosin modified phenolic resin accounts for 16-30% of the total weight percent of the oil ink, and the petroleum resin accounts for 5-15% of the total weight percent of the oil ink; the antioxidant is 2,6-di-tert-butyl-4-methylphenol; and the gelatinizing agent is liquid aluminum AO-3. The oil ink adoptsthe production technology of the ordinary offset printing oil ink for production.
Description
Technical field
The present invention relates to a kind of soybean oil type offset printing color ink that adopts the planography way printshop to use.
Background technology
Printing ink for present lithography industry use, mostly be to make with resin and oil series solvent to be connected material, mix with pigment dyestuff, pigment extender, auxiliary agent etc. again, and oil is to contain more multiring aromatic hydrocarbon substance in the mineral oil, wherein contains carcinogenic composition, as 3,4-benzo pyrrole, 3-nitro benzo ketone etc., residual quantity is big on printed matters such as books and periodicals, newspaper, picture album, and the survival time is long.To children still is that the grownup can work the mischief.Do not reach the requirement of human safety and feature of environmental protection aspect.Human safety has the implication of two aspects: the one, and to producing and use the health of operators and the safety control of printing ink.Be to the healthy and safe guarantee of use on the other hand with the people of the printed matter of this ink printing.The safety control of health that comprises the people of this content of use that printing ink on the printed matter causes the pollution of this printed matter content.The feature of environmental protection is meant and reduces volatile organic matter especially to the discharging of human body, atmosphere and the deleterious organic substance of animal and plant, do not influence the recovery with regeneration printing ground.Soybean oil printing ink mainly refers to the not abundant dry vegetable oil of soybean oil instead of part resource, and the oil that contains carcinogenic substance is the mineral wet goods, soybean oil is inhibited to the volatile organic matter that causes topsoil, can reduce the discharging of volatile organic matter (VOC), and compare with mineral oil, soybean oil is a renewable resources, but the oil fuel resource of saves valuable again contributes for energy-conservation.
Summary of the invention
Purpose of the present invention is intended to overcome the deficiency of above-mentioned prior art, and a kind of safety and environmental protection, soybean oil type offset printing color ink that tint permanence is good are provided.
Soybean oil type offset printing printing ink of the present invention comprises pigment dyestuff, pigment extender, vegetables oil, mineral oil, resin, auxiliary agent, gelatinizing agent.Contained component of printing ink of the present invention and weight percent thereof are: pigment dyestuff 10-25%, and pigment extender 5-10%, soybean oil 20-30% floats siritch 5-15%, mineral oil 10-20%, resin 25-35%, oxidation inhibitor 0.5-1%, gelatinizing agent 0.1-0.5%; Each composition weight sum is 100%.
Wherein, mineral oil be in high-boiling point kerosene and the solvent oil any one, or the mixture of both arbitrary proportions.Resin is the two a mixture of rosin modified phenolic resin and petroleum resin, and these two kinds of resins account for the total weight percent of printing ink of the present invention and are: rosin modified phenolic resin 16-30%, petroleum resin 5-15%.Oxidation inhibitor is 2,6 di tert butyl 4 methyl phenol.Gelatinizing agent is liquid aluminium AO-3.
Pigment dyestuff is a pigment of all kinds, is generally redness, yellow, blue look three-primary colours, as benzidine yellow G, lithol that fuchsin, the blue or green orchid of phthalein etc.; Pigment dyestuff is given printing ink bright colour, gloss, flowability, demulsification performance; Pigment extender comprises lime carbonate, organobentonite.Pigment extender strengthens the body bone of printing ink, influences the flowing property of printing ink.Vegetables oil comprises soybean oil, floats siritch; Soybean oil and float siritch play a part bridge in printing ink can better mix resin and solvent oil, goes back safety and environmental protection simultaneously.Mineral oil is high-boiling point kerosene, solvent oil; The viscosity size of adjustable fuel-economizing China ink, the viscosity of control printing ink.Resin comprises petroleum resin, rosin modified phenolic resin; Resin can strengthen the body bone of printing ink, improves the glossiness of printing ink, strengthens the demulsification performance of printing ink.Oxidation inhibitor can delay the skinning time.
Offset printing color ink of the present invention adopts the production technique of common flexographic ink to make.Earlier with resin, soybean oil, vegetables oil, mineral oil, gelatinizing agent, auxiliary agent, make gummy oil by technology and connect material, by certain proportioning pigment dyestuff, pigment extender, vegetables oil, mineral oil are connected material with gummy oil again and are mixed into Ji Mo, the utilization high speed dispersor carries out pre-dispersed, grind with three-roll grinder and sand mill again, after treating that fineness reaches standard, enter high-speed mixing equipment adjustment again, the qualified adding auxiliary agent of index can be packed.Major equipment is high speed dispersor, three-roll grinder, sand mill, high-speed mixing equipment etc.
The production technique that colloid connects material is: resin and vegetables oil are dropped in the reactor, be warming up to 220-230 ℃, be incubated and be cooled to 180 ℃ after 1 hour, add high-boiling point kerosene, continue to be cooled to 140 ℃, add gelatinizing agent, be warming up to 160-170 ℃, be incubated 0.5 hour, adjust with mineral oil, the qualified back of index adds oxidation inhibitor and gets final product.
The present invention has compared with prior art reduced volatile organic compound ingredients a large amount of in traditional printing ink, more adopts vegetables oil, and the feature of environmental protection is better, has the resource recyclability.Tint permanence is fabulous, and transfer performance is good, and printing effect is good, meets every standard-required of printing-ink.Rub resistance is good, and safety in utilization is good, deinking easily, and the damage of paper fiber is few, and the reclaiming paper product is good, and the useless soybean oil printing ink residue ratio after deinking is handled is easier to degraded, is convenient to recycle, good energy-conserving effect.
Embodiment
Embodiment 1: the present invention adopts following proportioning: benzidine yellow G 15%, and lime carbonate 9%, soybean oil 22% is floated siritch 8%, high-boiling point kerosene 11.3%, solvent oil 6%, rosin modified phenolic resin 19%, petroleum resin 9%, oxidation inhibitor 0.5%, liquid aluminium AO-3 0.2%.This prescription uses the lime carbonate can be with low cost, but requires the transparency of lime carbonate good.
Embodiment 2: the present invention adopts following proportioning: benzidine yellow G 15%, organobentonite 0.5%, lime carbonate 7%, soybean oil 22% is floated siritch 8%, high-boiling point kerosene 12.8%, solvent oil 6%, rosin modified phenolic resin 19%, petroleum resin 9%, oxidation inhibitor 0.5%, liquid aluminium AO-3 0.2%.Reduce lime carbonate in the prescription and increase organobentonite and can reduce solids content in the printing ink, make the levelling property of printing ink better, its is fit to high-speed printer printing.
Embodiment 3: the present invention adopts following proportioning: lithol that fuchsin 18%, and lime carbonate 7%, soybean oil 22% is floated siritch 8%, high-boiling point kerosene 11.3, solvent oil 5%, rosin modified phenolic resin 19%, petroleum resin 9%, oxidation inhibitor 0.5%, liquid aluminium AO-3 0.2%.Rosin modified phenolic resin content is low slightly in this prescription, can reduce cost, and is applicable to the less demanding printing of gloss.
Embodiment 4: the present invention adopts following proportioning: lithol that fuchsin 18, and lime carbonate 6, soybean oil 22 is floated siritch 9, high-boiling point kerosene 13.3, solvent oil 3, rosin modified phenolic resin 23, petroleum resin 5, oxidation inhibitor 0.5, liquid aluminium AO-30.2.Reduce petroleum resin in the prescription and increase the glossiness that rosin modified phenolic resin can improve printing ink.Improving solvent oil content in prescription can reduce cost.
Embodiment 5: the present invention adopts following proportioning: the blue or green orchid 15 of phthalein, and lime carbonate 10, organobentonite 0.5, soybean oil 22 is floated siritch 8, high-boiling point kerosene 10.8, solvent oil 5, rosin modified phenolic resin 19, petroleum resin 9, oxidation inhibitor 0.5, liquid aluminium AO-3 0.2.The blue or green blue pigment content of this prescription phthalein is low slightly, and calcium carbonate content is high slightly, can reduce cost, and is applicable to low and middle-grade printings.
Embodiment 6: the present invention adopts following proportioning: the blue or green orchid 16 of phthalein, and organobentonite 0.5, lime carbonate 9, soybean oil 22 is floated siritch 8, high-boiling point kerosene 10.8, solvent oil 5, rosin modified phenolic resin 19, petroleum resin 9, oxidation inhibitor 0.5, liquid aluminium AO-3 0.2.Pigment content height in the prescription can improve the tinting strength of printing ink.
Claims (2)
1, a kind of soybean oil type offset printing color ink, it is characterized in that contained component of this printing ink and weight percent thereof are: pigment dyestuff 10-25%, pigment extender 5-10%, soybean oil 20-30%, float siritch 5-15%, mineral oil 10-20%, resin 25-35%, oxidation inhibitor 0.5-1%, gelatinizing agent 0.1-0.5%; Each composition weight sum is 100%;
Wherein: mineral oil be in high-boiling point kerosene and the solvent oil any one, or the mixture of both arbitrary proportions;
Resin is the two a mixture of rosin modified phenolic resin and petroleum resin, and the per-cent that these two kinds of resins account for total weight is: rosin modified phenolic resin 16-30%, petroleum resin 5-15%;
Oxidation inhibitor is 2,6 di tert butyl 4 methyl phenol; Gelatinizing agent is liquid aluminium AO-3;
Pigment dyestuff is benzidine yellow G, lithol that fuchsin, the blue or green orchid of phthalein; Pigment extender is lime carbonate, organobentonite.
2, soybean oil type offset printing color ink as claimed in claim 1 is characterized in that adopting the production technique of common flexographic ink to make.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910075669A CN101671504A (en) | 2009-09-30 | 2009-09-30 | Soybean oil type offset printing color ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910075669A CN101671504A (en) | 2009-09-30 | 2009-09-30 | Soybean oil type offset printing color ink |
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| CN101671504A true CN101671504A (en) | 2010-03-17 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN200910075669A Pending CN101671504A (en) | 2009-09-30 | 2009-09-30 | Soybean oil type offset printing color ink |
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| CN (1) | CN101671504A (en) |
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914323A (en) * | 2010-08-19 | 2010-12-15 | 上海牡丹油墨有限公司 | Application of palm oil and palm oil derivative to ink vehicle |
| CN102108221A (en) * | 2011-01-14 | 2011-06-29 | 上海牡丹油墨有限公司 | Palm oil-base offset printing ink containing no mineral oil and preparation method thereof |
| CN103275546A (en) * | 2013-05-24 | 2013-09-04 | 苏州凹凸彩印厂 | Soybean oil type peacock blue offset ink and preparation method thereof |
| CN103275550A (en) * | 2013-05-31 | 2013-09-04 | 苏州凹凸彩印厂 | Soybean oil type offset printing ink |
| CN104877438A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Antioxidant soybean oil based offset printing ink and preparation method thereof |
| CN104877437A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Antimicrobial environment-friendly offset printing ink and preparation method thereof |
| CN104877451A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Soybean-oil-base offset printing ink and preparation method thereof |
| CN104877443A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Quick-drying soybean oil based offset printing ink and preparation method thereof |
| CN104877449A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Wear-resistant offset printing ink and preparation method thereof |
| CN104877439A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Flame-retardant soybean-oil-base offset printing ink and preparation method thereof |
| CN104877440A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Offset printing ink containing titanium dioxide nanofibers and preparation method thereof |
| CN104877450A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | High-abrasion-resistance offset printing ink and preparation method thereof |
| CN104877441A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Soybean oil based offset printing ink containing nano aluminium sesquioxide and preparation method of soybean oil based offset printing ink |
| CN105131702A (en) * | 2015-08-21 | 2015-12-09 | 深圳市颖博油墨实业有限公司 | Ink composition and preparation method thereof |
| CN105385222A (en) * | 2015-12-08 | 2016-03-09 | 上海杰易森股份有限公司 | Edible thermosetting printing ink and preparation method thereof |
| CN106118231A (en) * | 2016-08-09 | 2016-11-16 | 苏州市博来特油墨有限公司 | A kind of preparation method of high abrasion offset ink |
| CN106221360A (en) * | 2016-08-09 | 2016-12-14 | 苏州市博来特油墨有限公司 | High speed printing adaptive rub resistance environment-friendly ink |
| CN106433298A (en) * | 2016-06-30 | 2017-02-22 | 天津天女化工集团股份有限公司 | Binder and environment-friendly offset rotary ink containing same |
| CN106928767A (en) * | 2015-12-29 | 2017-07-07 | 天津天女化工集团股份有限公司 | A kind of offset printing environment protecting plant oil-based ink |
| CN107916028A (en) * | 2017-12-08 | 2018-04-17 | 马鞍山虹润彩印有限责任公司 | A kind of environment-friendlyink ink |
| CN108342124A (en) * | 2017-01-23 | 2018-07-31 | 上海杰易森股份有限公司 | A kind of environmental protection offset ink and preparation method thereof |
| CN113637353A (en) * | 2021-09-03 | 2021-11-12 | 杭华油墨股份有限公司 | Ink binder and preparation method and application thereof |
| CN113652116A (en) * | 2021-08-13 | 2021-11-16 | 广州市帝天印刷材料有限公司 | Composition for plastic absorbable metal ink, plastic absorbable metal ink and preparation method thereof |
| CN113861756A (en) * | 2021-11-11 | 2021-12-31 | 苏州市大象印刷包装有限公司 | Waterless offset printing ink and preparation method thereof |
| CN117004272A (en) * | 2023-08-18 | 2023-11-07 | 中山市富日印刷材料有限公司 | Rosin phenolic resin for printing ink with good flexibility and preparation method thereof |
-
2009
- 2009-09-30 CN CN200910075669A patent/CN101671504A/en active Pending
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914323A (en) * | 2010-08-19 | 2010-12-15 | 上海牡丹油墨有限公司 | Application of palm oil and palm oil derivative to ink vehicle |
| CN101914323B (en) * | 2010-08-19 | 2013-04-24 | 上海牡丹油墨有限公司 | Application of palm oil and palm oil derivative in ink binder |
| CN102108221A (en) * | 2011-01-14 | 2011-06-29 | 上海牡丹油墨有限公司 | Palm oil-base offset printing ink containing no mineral oil and preparation method thereof |
| CN102108221B (en) * | 2011-01-14 | 2013-08-21 | 上海牡丹油墨有限公司 | Palm oil-base offset printing ink containing no mineral oil and preparation method thereof |
| CN103275546A (en) * | 2013-05-24 | 2013-09-04 | 苏州凹凸彩印厂 | Soybean oil type peacock blue offset ink and preparation method thereof |
| CN103275550A (en) * | 2013-05-31 | 2013-09-04 | 苏州凹凸彩印厂 | Soybean oil type offset printing ink |
| CN104877441A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Soybean oil based offset printing ink containing nano aluminium sesquioxide and preparation method of soybean oil based offset printing ink |
| CN104877451A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Soybean-oil-base offset printing ink and preparation method thereof |
| CN104877443A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Quick-drying soybean oil based offset printing ink and preparation method thereof |
| CN104877449A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Wear-resistant offset printing ink and preparation method thereof |
| CN104877439A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Flame-retardant soybean-oil-base offset printing ink and preparation method thereof |
| CN104877440A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Offset printing ink containing titanium dioxide nanofibers and preparation method thereof |
| CN104877450A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | High-abrasion-resistance offset printing ink and preparation method thereof |
| CN104877438A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Antioxidant soybean oil based offset printing ink and preparation method thereof |
| CN104877437A (en) * | 2015-05-05 | 2015-09-02 | 安徽雅美油墨有限公司 | Antimicrobial environment-friendly offset printing ink and preparation method thereof |
| CN105131702A (en) * | 2015-08-21 | 2015-12-09 | 深圳市颖博油墨实业有限公司 | Ink composition and preparation method thereof |
| CN105385222A (en) * | 2015-12-08 | 2016-03-09 | 上海杰易森股份有限公司 | Edible thermosetting printing ink and preparation method thereof |
| CN106928767A (en) * | 2015-12-29 | 2017-07-07 | 天津天女化工集团股份有限公司 | A kind of offset printing environment protecting plant oil-based ink |
| CN106433298A (en) * | 2016-06-30 | 2017-02-22 | 天津天女化工集团股份有限公司 | Binder and environment-friendly offset rotary ink containing same |
| CN106118231A (en) * | 2016-08-09 | 2016-11-16 | 苏州市博来特油墨有限公司 | A kind of preparation method of high abrasion offset ink |
| CN106221360A (en) * | 2016-08-09 | 2016-12-14 | 苏州市博来特油墨有限公司 | High speed printing adaptive rub resistance environment-friendly ink |
| CN108342124A (en) * | 2017-01-23 | 2018-07-31 | 上海杰易森股份有限公司 | A kind of environmental protection offset ink and preparation method thereof |
| CN107916028A (en) * | 2017-12-08 | 2018-04-17 | 马鞍山虹润彩印有限责任公司 | A kind of environment-friendlyink ink |
| CN113652116A (en) * | 2021-08-13 | 2021-11-16 | 广州市帝天印刷材料有限公司 | Composition for plastic absorbable metal ink, plastic absorbable metal ink and preparation method thereof |
| CN113652116B (en) * | 2021-08-13 | 2023-10-31 | 广州市帝天印刷材料有限公司 | Composition for plastic-sucking metal ink, plastic-sucking metal ink and preparation method thereof |
| CN113637353A (en) * | 2021-09-03 | 2021-11-12 | 杭华油墨股份有限公司 | Ink binder and preparation method and application thereof |
| CN113637353B (en) * | 2021-09-03 | 2023-10-24 | 杭华油墨股份有限公司 | Printing ink binder and preparation method and application thereof |
| CN113861756A (en) * | 2021-11-11 | 2021-12-31 | 苏州市大象印刷包装有限公司 | Waterless offset printing ink and preparation method thereof |
| CN117004272A (en) * | 2023-08-18 | 2023-11-07 | 中山市富日印刷材料有限公司 | Rosin phenolic resin for printing ink with good flexibility and preparation method thereof |
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Application publication date: 20100317 |