CN106928767A - A kind of offset printing environment protecting plant oil-based ink - Google Patents
A kind of offset printing environment protecting plant oil-based ink Download PDFInfo
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- CN106928767A CN106928767A CN201511030160.1A CN201511030160A CN106928767A CN 106928767 A CN106928767 A CN 106928767A CN 201511030160 A CN201511030160 A CN 201511030160A CN 106928767 A CN106928767 A CN 106928767A
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- oil
- auxiliary agent
- based ink
- soya
- offset printing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
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- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention belongs to ink-printing techniques field, more particularly to a kind of offset printing environment protecting plant oil-based ink, it is characterised in that:Each material composition and weight percentage are:Colloid oil 30-34, resinon 25-39, soya-bean oil solvent 13-16, color pigment 13-27, auxiliary agent 0.5-2, drier 0.8-2.5.The beneficial effects of the invention are as follows:With the outstanding feature of environmental protection, preferably rub resistance, good inking is non-toxic, is more prone to deinking, and number to be printed is more, and color is deep, abundant and beautiful, is widely portable to colored printing.
Description
Technical field
The invention belongs to ink-printing techniques field, more particularly to a kind of offset printing environment protecting plant oil-based ink.
Background technology
Ink is the main consumptive material of printing industry, according to ink component and content, stock purposes, print
Brush equipment, mode of printing and application method etc. can be divided into multiple species.In existing most ink mostly
The requirement of environment-friendly and green printing will not be met containing organic (or inorganic) solvent, pigment etc..Now such as
The present, with the raising of people's environmental consciousness and growing to even greater heights for environmental protection cry, ink is used as green
The chief component of printing, also increasingly strengthens its environmental requirement, is suitable to the printing-ink of environmental protection
Consumption increasing year by year, environmental protection has turned into the only way that following ink develops.
Environment-friendly ink is pure plant oil solventless ink, and it uses vegetable oil as binder, grinds at present
Mainly there are soybean oil, rapeseed oil and sunflower oil etc. in the connection section of hair and application.Its advantage is:Can
The burst size of VOC is reduced, plant ink all eliminates the hydro carbons in common ink
Resin, reduces arene content, to human body fanout free region.Plant ink is applied widely, applicable
In flexible package, box sack, toilet article packaging fast food lunch-box, the various trade marks of shopping bag dixie cup cigarette case,
The printing of papers and magazines adhesive label beverage, wine, medicine and various cosmetics, additionally, vegetable oil
Ink will not occur triboelectrification phenomenon, can also distribute natural flavor.Plant ink is upper in technology and application
Polynary feature, become application prospect environment-friendly ink widely.
In the prior art, environment-friendly ink can not fully meet society need, ink penetrating odor compared with
Greatly, there is still a need for entering one in terms of the basic printed datas such as ink, gloss, density, set speed
The expansion of step and perfect, more excellent to obtain more environmentally friendly, performance product.
The content of the invention
In order to overcome the above-mentioned deficiencies of the prior art, planted it is an object of the invention to provide a kind of offset printing environmental protection
Thing oil-based ink, with the outstanding feature of environmental protection, preferably rub resistance, good inking is nontoxic
Property, it is more prone to deinking, number to be printed is more, and color is deep, abundant and beautiful, can be extensive
Suitable for colored printing.
To achieve the above object, the technical solution adopted by the present invention is:
A kind of offset printing environment protecting plant oil-based ink, it is characterised in that:Each material composition and weight percent contain
Measure and be:Colloid oil 30-34, resinon 25-39, soya-bean oil solvent 13-16, color pigment 13-27, help
Agent 0.5-2, drier 0.8-2.5.
Preferably, the auxiliary agent includes lubricating auxiliary agent and water resistant auxiliary agent.
Preferably, the drier includes cobalt and manganese.
A kind of offset printing environment protecting plant oil-based ink, each material composition and weight percentage are:Colloid oil
30-34, resinon 25-39, soya-bean oil solvent 13-16, color pigment 13-27, lubricating auxiliary agent 0.4-1.4,
Water resistant auxiliary agent 0.1-0.6, cobalt 0.15-0.5, manganese 0.45-1.5.
Preferably, the color pigment is the one kind in four kinds of colors of yellow, red, blue, black, yellow choosing
Pigment is benzidine yellow, and the pigment that red is selected is fuchsin, and the pigment that blueness is selected is phthalocyanine blue,
The pigment that black is selected is carbon black, Hua Lan, penetrates the mixture of light indigo plant.
A kind of offset printing environment protecting plant oil-based ink, each material composition and weight percentage are:Colloid oil
30, resinon 39, soya-bean oil solvent 14.8, benzidine yellow 14, lubricating auxiliary agent 1, water resistant auxiliary agent 0.4,
Cobalt 0.2, manganese 0.6.
A kind of offset printing environment protecting plant oil-based ink, each material composition and weight percentage are:Colloid oil
32, resinon 33, soya-bean oil solvent 15.8, fuchsin 17, lubricating auxiliary agent 1, water resistant auxiliary agent 0.4, cobalt
0.2, manganese 0.6.
A kind of offset printing environment protecting plant oil-based ink, each material composition and weight percentage are:Colloid oil
34, resinon 31, soya-bean oil solvent 15.8, phthalocyanine blue 17, lubricating auxiliary agent 1, water resistant auxiliary agent 0.4,
Cobalt 0.2, manganese 0.6.
A kind of offset printing environment protecting plant oil-based ink, each material composition and weight percentage are:Colloid oil
30, light indigo plant 3 is penetrated by resinon 25, soya-bean oil solvent 14.1, carbon black 22, China blue 2, lubricating auxiliary agent 1,
Water resistant auxiliary agent 0.4, cobalt 0.9, manganese 1.6.
Preferably, each material composition of the colloid oil and weight percentage are:TN-21 resin 29-50,
Soya-bean oil 49-70, liquid aluminium 0.5-1.5;
Each material composition of resinon and weight percentage are:TN-20 resin 30-50, soya-bean oil
50-70。
The present invention has the advantages and positive effects that:
1. the outstanding feature of environmental protection:Polycyclic aromatic hydrocarbon compounds content is low in plant oil-based ink of the invention,
VOC is not discharged when using substantially, is not polluted the environment, be conducive to producing and protecting the health of user.
Additionally, plant oil-based ink of the invention such as soybean oil etc. is taken from naturally, can infinite regeneration, and can give birth to
Thing is degraded, therefore, no matter from the utilization of resources or in terms of environmental protection, plant oil base of the invention
Ink all has the incomparable advantage of common ink.
2. preferably rub resistance:The publicity that plant oil-based ink of the invention is printed using soya-bean ink
Product, because soya-bean ink just compares rub resistance, reader when reading not by perplexing that hand is stained with, while again
There is no pessimal stimulation peculiar smell, therefore suffer from the popular welcome of reader.In addition, the boiling point ratio of plant ink
Oil volatile ingredient is much higher, when heating printing (such as laser printing, duplicating) is needed, Bu Huiyin
It is bonded on paper for volatilization, this is also the spy that plant oil-based ink of the invention is significantly better than common ink
Point.
3. good inking:Plant oil-based ink metastatic of the invention is good, part inking on the spot
Good, bright part site is good colour.After common offset ink reaches paper, because solvent penetration is fast,
Near the part of paper, ink film has dialysis phenomenon, and plant oil-based ink of the invention is then because of infiltration
Slowly, the release surface of ink makes thicker ink film be transferred to paper in fact closer to blanket side,
Therefore printing ink transfer amount is improved.
4. non-toxic:Plant oil-based ink of the invention is due to without polycyclic hydrocarbon of aromatic series etc.
Volatile organic harmful components, are non-toxic ink, are conducive to environmental protection.
5. it is more prone to deinking:Plant oil-based ink of the invention is de- in paper reclaiming process
Ink is good, and recycled writing paper papery is good, and discarded object is few, and cost recovery is low.
6. number to be printed is more:Plant oil-based ink of the invention can represent more dense and beautiful face
Color effect, so that printer can use ink less, cost reduction and increases about 10%~15%
Unit number to be printed.
7. plant oil-based ink color of the invention is deep, abundant and beautiful, is widely portable to colour
Printing, obtains carrying greatly very much in terms of the basic printed datas such as ink, gloss, density, set speed
It is high.
Specific embodiment
Of the invention making is further explained with reference to specific embodiment.
The present invention provides a kind of offset printing environment protecting plant oil-based ink, it is characterised in that:Each material composition and
Weight percentage is:Colloid oil 30-34, resinon 25-39, soya-bean oil solvent 13-16, colored face
Material 13-27, auxiliary agent 0.5-2, drier 0.8-2.5.
Preferably, the auxiliary agent includes lubricating auxiliary agent and water resistant auxiliary agent.
Preferably, the drier includes cobalt and manganese.
A kind of offset printing environment protecting plant oil-based ink, each material composition and weight percentage are:Colloid oil
30-34, resinon 25-39, soya-bean oil solvent 13-16, color pigment 13-27, lubricating auxiliary agent 0.4-1.4,
Water resistant auxiliary agent 0.1-0.6, cobalt 0.15-0.5, manganese 0.45-1.5.
Preferably, the color pigment is the one kind in four kinds of colors of yellow, red, blue, black, yellow choosing
Pigment is benzidine yellow, and the pigment that red is selected is fuchsin, and the pigment that blueness is selected is phthalocyanine blue,
The pigment that black is selected is carbon black, Hua Lan, penetrates the mixture of light indigo plant.
A kind of offset printing environment protecting plant oil-based ink, each material composition and weight percentage are:Colloid oil
30, resinon 39, soya-bean oil solvent 14.8, benzidine yellow 14, lubricating auxiliary agent 1, water resistant auxiliary agent 0.4,
Cobalt 0.2, manganese 0.6.
A kind of offset printing environment protecting plant oil-based ink, each material composition and weight percentage are:Colloid oil
32, resinon 33, soya-bean oil solvent 15.8, fuchsin 17, lubricating auxiliary agent 1, water resistant auxiliary agent 0.4, cobalt
0.2, manganese 0.6.
A kind of offset printing environment protecting plant oil-based ink, each material composition and weight percentage are:Colloid oil
34, resinon 31, soya-bean oil solvent 15.8, phthalocyanine blue 17, lubricating auxiliary agent 1, water resistant auxiliary agent 0.4,
Cobalt 0.2, manganese 0.6.
A kind of offset printing environment protecting plant oil-based ink, each material composition and weight percentage are:Colloid oil
30, light indigo plant 3 is penetrated by resinon 25, soya-bean oil solvent 14.1, carbon black 22, China blue 2, lubricating auxiliary agent 1,
Water resistant auxiliary agent 0.4, cobalt 0.9, manganese 1.6.
Preferably, each material composition of the colloid oil and weight percentage are:TN-21 resin 29-50,
Soya-bean oil 49-70, liquid aluminium 0.5-1.5;
Each material composition of resinon and weight percentage are:TN-20 resin 30-50, soya-bean oil
50-70。
The present invention is illustrated through some selections that experiment is made below.
1. the determination of test course:
We successively devise several test courses altogether:Route one:With pure soya-bean oil carburetion, 161 replace ore deposit
Oil solvent;Route two:With pure soya-bean oil carburetion, Dormant oils solvent is replaced with outsourcing plant solvent;Route three:
With sunflower oil carburetion, and with it as solvent;Route four:It is solvent carburetion with soya-bean oil, soya-bean oil is additional
Solvent.
Result can be obtained from combination property analysis, and the gloss of route one can be with, but set is partially slow;The light of route two
Damp set is good, but relatively costly, for outsourcing solvent to form mass selling, can as with
Deposit research afterwards;The Semen Benincasae oil of route three it is relatively costly, slow drying speed, on paper have bleed-through existing
As;Route four can reach design requirement substantially, the experiment of system carried out, it is determined that with soya-bean oil as solvent
Carburetion, soya-bean oil is the route of plus solvent.
Expected technical indicator:
Mineral oil content≤1%;Nontoxic, low taste, it is adaptable to packages printing.
2. the determination of binder:
Colloid oil 599#, resinon 299# and environmentally friendly kerosene D110# in existing TSO Soybean Oil Inks
In all contain micro solvent, and pure plant oil also some gaps of the theory without arene environment-friendly, thus
The purpose for making every effort to reach complete environmental protection to the design of binder is paid special attention in current research and development, and has selected
Suitable carburetion temperature, the balance of gloss and set in ink formulations, finally determines new glue
Basic meet the requirement of environmental protection of the matter oil with resinon with soybean oil as carburetion.
(1) formula of binder:
Colloid oil formula
Material name | Specification | Percentage composition |
Resin | TN-21 | 40 |
Soya-bean oil | 59 | |
Liquid aluminium | 1 | |
It is total | 100 |
Carburetion temperature:220 degree
Resin oil formula
Carburetion temperature:240 degree
Material name | Specification | Percentage composition |
Soya-bean oil | 60 | |
Resin | TN-20 | 40 |
It is total | 100 |
(2) technical indicator of binder:
3. the selection of pigment
Either quality or level are all constantly being carried the pigment market of pigment aspect recent year
Height, by the substantial amounts of experiment of my seminar and screening, comprehensive cost performance and technological requirement, finally determines
Be benzidine yellow 12-6, fuchsin 247, Jiangsu phthalocyanine blue and carbon black P35.Specific data are as follows:
Fuchsin is contrasted:
Title | Fluidity | Viscosity | Color power | Gloss | Density |
247 | 36 | 9.6 | 100 | 82.5 | 2.40 |
6BD | 35 | 9.8 | 100 | 80.2 | 2.34 |
Phthalocyanine blue is contrasted:
Title | Fluidity | Viscosity | Color power | Gloss | Density |
Prompt rainbow phthalocyanine blue | 37 | 10 | 100 | 61.3 | 2.24 |
Capital contaminates | 37 | 9.8 | 100 | 61.2 | 2.23 |
Huanghua | 38 | 10 | 100 | 62.5 | 2.25 |
Jiangsu phthalocyanine blue | 38 | 10.2 | 100+ | 64 | 2.24 |
The contrast of carbon black:
Title | Fluidity | Viscosity | Color power | Gloss | Density |
P35 | 36.5 | 9 | 100 | 52.7 | 2.58 |
MA-7 | 33 | 9 | 100 | 44 | 2.58 |
N505 | 34 | 9 | 100 | 49.2 | 2.64 |
4. the selection of auxiliary agent, drier:
By the substantial amounts of experiment of my seminar and screening, comprehensive cost performance and technological requirement, finally determine
It is water resistant auxiliary agent with water resistant auxiliary agent 4# with wax powder as lubricating auxiliary agent, the mixture with 4% cobalt and 3% manganese is
Drier.
Embodiment 1:
Each material composition of colloid oil and weight percentage are in the present invention:TN-21 resins 40, soya-bean oil
59, liquid aluminium 1.
Embodiment 2:
Each material composition of resinon and weight percentage are in the present invention:TN-20 resins 40, soya-bean oil
60。
Embodiment 3:
Each material composition of the present invention and weight percentage are:Colloid oil 30, resinon 39, soya-bean oil is molten
Agent 14.8,12-6 benzidine yellows 14, wax powder Isosorbide-5-Nitrae # water resistants auxiliary agent 0.4,4% cobalt 0.2,3% manganese 0.6.
Embodiment 4:
Each material composition of the present invention and weight percentage are:Colloid oil 32, resinon 33, soya-bean oil is molten
The fuchsin 17 of agent 15.8,247, wax powder Isosorbide-5-Nitrae # water resistants auxiliary agent 0.4,4% cobalt 0.2,3% manganese 0.6.
Embodiment 5:
Each material composition of the present invention and weight percentage are:Colloid oil 34, resinon 31, soya-bean oil is molten
Agent 15.8, Jiangsu phthalocyanine blue 17, wax powder Isosorbide-5-Nitrae # water resistants auxiliary agent 0.4,4% cobalt 0.2,3% manganese 0.6.
Embodiment 6:
Each material composition of the present invention and weight percentage are:Colloid oil 30, resinon 25, soya-bean oil is molten
Light indigo plant 3, wax powder Isosorbide-5-Nitrae # water resistants auxiliary agent 0.4,4% cobalt are penetrated by agent 14.1, P35 carbon blacks 22, China blue 2
0.9,3% manganese 1.6.
Embodiment 7:
Each material composition of the present invention and weight percentage are:Colloid oil 30, resinon 25, soya-bean oil is molten
Light indigo plant 3 is penetrated by agent 14.1, P35 carbon blacks 20, alkyd resin 2, China blue 2, and wax powder Isosorbide-5-Nitrae # water resistants are helped
Agent 0.4,4% cobalt 0.9,3% manganese 1.6 adds alkyd resin to be used to increase wetability, glossiness.
Embodiment 8:
Each material composition of the present invention and weight percentage are:Colloid oil 30, resinon 25, soya-bean oil is molten
Light indigo plant 3, wax are penetrated by agent 14.1, P35 carbon blacks 2, huge port 6# carbon black 18, alkyd resin 2, China blue 2
Powder Isosorbide-5-Nitrae # water resistants auxiliary agent 0.4,4% cobalt 0.9,3% manganese 1.6 adds huge port 6# carbon blacks to be used to balance color
Phase.
Reference Product comparing result such as following table:
By Experimental comparison, offset printing environment protecting plant oil-based ink of the present invention is than original TSO soybean oils oil
Ink is greatly improved, either the basic printing such as ink or gloss, density, set speed
Data have and are obviously improved, more it is emphasised that the aspect of the feature of environmental protection, has reached world-class ring
Guarantor's index, (the original pungent taste of ink has just been greatly reduced from taste), generally
Reach the purpose being pre-designed.
Example of the invention has been described in detail above, but the content is only of the invention preferable
Embodiment, it is impossible to be considered as limiting practical range of the invention.It is all according to the present patent application scope institute
The impartial change of work and improvement etc., all should still belong within patent covering scope of the invention.
Claims (10)
1. a kind of offset printing environment protecting plant oil-based ink, it is characterised in that:Each material composition and weight percent contain
Measure and be:Colloid oil 30-34, resinon 25-39, soya-bean oil solvent 13-16, color pigment 13-27, help
Agent 0.5-2, drier 0.8-2.5.
2. offset printing environment protecting plant oil-based ink according to claim 1, it is characterised in that:It is described to help
Agent includes lubricating auxiliary agent and water resistant auxiliary agent.
3. offset printing environment protecting plant oil-based ink according to claim 2, it is characterised in that:It is described dry
Drying prescription includes cobalt and manganese.
4. offset printing environment protecting plant oil-based ink according to claim 3, it is characterised in that:Each material
Component and weight percentage are:Colloid oil 30-34, resinon 25-39, soya-bean oil solvent 13-16,
Color pigment 13-27, lubricating auxiliary agent 0.4-1.4, water resistant auxiliary agent 0.1-0.6, cobalt 0.15-0.5, manganese
0.45-1.5。
5. offset printing environment protecting plant oil-based ink according to claim 4, it is characterised in that:The coloured silk
Color pigment is the one kind in four kinds of colors of yellow, red, blue, black, and the pigment that yellow is selected is benzidine yellow,
The pigment that red is selected is fuchsin, and the pigment that blueness is selected is phthalocyanine blue, and the pigment that black is selected is charcoal
Black, Hua Lan, the mixture for penetrating light indigo plant.
6. offset printing environment protecting plant oil-based ink according to claim 5, it is characterised in that:Each material
Component and weight percentage are:Colloid oil 30, resinon 39, soya-bean oil solvent 14.8, benzidine yellow
14, lubricating auxiliary agent 1, water resistant auxiliary agent 0.4, cobalt 0.2, manganese 0.6.
7. offset printing environment protecting plant oil-based ink according to claim 5, it is characterised in that:Each material
Component and weight percentage are:Colloid oil 32, resinon 33, soya-bean oil solvent 15.8, fuchsin 17,
Lubricating auxiliary agent 1, water resistant auxiliary agent 0.4, cobalt 0.2, manganese 0.6.
8. offset printing environment protecting plant oil-based ink according to claim 5, it is characterised in that:Each material
Component and weight percentage are:Colloid oil 34, resinon 31, soya-bean oil solvent 15.8, phthalocyanine blue 17,
Lubricating auxiliary agent 1, water resistant auxiliary agent 0.4, cobalt 0.2, manganese 0.6.
9. offset printing environment protecting plant oil-based ink according to claim 5, it is characterised in that:Each material
Component and weight percentage are:Colloid oil 30, resinon 25, soya-bean oil solvent 14.1, carbon black 22,
Magnificent blue 2, penetrate light indigo plant 3, lubricating auxiliary agent 1, water resistant auxiliary agent 0.4, cobalt 0.9, manganese 1.6.
10. the offset printing environment protecting plant oil-based ink according to claim 1-9 any one, its feature
It is:Each material composition of the colloid oil and weight percentage are:TN-21 resin 29-50, soya-bean oil
49-70, liquid aluminium 0.5-1.5;
Each material composition of resinon and weight percentage are:TN-20 resin 30-50, soya-bean oil
50-70。
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CN201511030160.1A CN106928767A (en) | 2015-12-29 | 2015-12-29 | A kind of offset printing environment protecting plant oil-based ink |
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CN201511030160.1A CN106928767A (en) | 2015-12-29 | 2015-12-29 | A kind of offset printing environment protecting plant oil-based ink |
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ID=59444369
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN115725203A (en) * | 2021-08-31 | 2023-03-03 | 敬业(东莞)印刷包装厂有限公司 | Orange printing ink and preparation method thereof |
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CN101671504A (en) * | 2009-09-30 | 2010-03-17 | 太原印科油墨有限公司 | Soybean oil type offset printing color ink |
JP4552430B2 (en) * | 2003-12-05 | 2010-09-29 | 凸版印刷株式会社 | Ink for waterless web offset press |
CN102585595A (en) * | 2011-12-23 | 2012-07-18 | 安徽雅美油墨有限公司 | Environmentally-friendly pure soybean four-color ink |
CN104031469A (en) * | 2014-06-29 | 2014-09-10 | 繁昌县朱氏印务有限责任公司 | Formula of lithographic offset printing ink |
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2015
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Publication number | Priority date | Publication date | Assignee | Title |
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CN1375528A (en) * | 2001-03-19 | 2002-10-23 | 樊官保 | Photochromic ink compound and its application |
JP4552430B2 (en) * | 2003-12-05 | 2010-09-29 | 凸版印刷株式会社 | Ink for waterless web offset press |
CN101671504A (en) * | 2009-09-30 | 2010-03-17 | 太原印科油墨有限公司 | Soybean oil type offset printing color ink |
CN102585595A (en) * | 2011-12-23 | 2012-07-18 | 安徽雅美油墨有限公司 | Environmentally-friendly pure soybean four-color ink |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN115725203A (en) * | 2021-08-31 | 2023-03-03 | 敬业(东莞)印刷包装厂有限公司 | Orange printing ink and preparation method thereof |
CN115725203B (en) * | 2021-08-31 | 2024-04-12 | 当纳利(广东)印务有限公司 | Orange ink and preparation method thereof |
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Application publication date: 20170707 |